MATERIAL SAFETY DATA SHEET

Section 1 – CHEMICAL PRODUCT& SUPPLIER IDENTIFICATION

MSDS Name: Triethylene glycol 99%
Synonym: Trigen; Triglycol; TEG; 2,2'-ethylenediqxybis(ethanol); 1,2-Bis(2-hydroxy)ethane; Ethylene glycal-
bis-(2-hydroxyethyl ether)

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS# Chemical Name content EINECS#
112-27-6 Triethylene glycol 100 203-953-2
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Exposure may cause irritation characterized by redness, dryness, and inflammation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Possible aspiration hazard.
Inhalation:
Inhalation of a mist of this material may cause respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get
medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or
equivalent), and full protective gear. Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up
spills immediately, observing precautions in the Protective Equipment section.

Section 7 - HANDLING and STORAGE

Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate
ventilation.
Storage:
Store in a cool, dry place. Keep containers tightly closed.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 112-27-6: Personal Protective Equipment Eyes: Wear appropriate protective
eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29
CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or
European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: clear to light yellow
Odor: mild odor
pH: Not available.
Vapor Pressure: < .001 mm Hg @2
Viscosity: 48 mPa s@20 C
Boiling Point: 285 deg C
Freezing/Melting Point: -7 deg C
Autoignition Temperature: 699.8 deg F ( 371.00 deg C)
Flash Point: 329 deg F ( 165.00 deg C)
Explosion Limits, lower: 0.9
Explosion Limits, upper: 9.2
Decomposition Temperature: Not available.
Solubility in water: Soluble in water
Specific Gravity/Density: 1.125
Molecular Formula: C6H14O4
Molecular Weight: 150.0956

Section 10 - STABILITY AND REACTIVITY

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Sulfuric acid, isocyanates, perchloric acid, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION

RTECS#:
CAS# 112-27-6: YE4550000 LD50/LC50:
CAS# 112-27-6: Draize test, rabbit, eye: 500 mg Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Oral,
mouse: LD50 = 20000 mg/kg; Oral, rabbit: LD50 = 8400 mg/kg; Oral, rabbit: LD50 = 8400 mg/kg; Oral, rat:
LD50 = 17 gm/kg; Oral, rat: LD50 = 15000 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
Carcinogenicity:
Triethylene glycol - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION

Ecotoxicity:
Fish: Fathead Minnow: LC50 = 70,200 mg/L; 96 Hr.; Flow-throughFish: Bluegill/Sunfish: LC50 = 10,000 mg/L;
96 Hr.; Static ConditionsBacteria: Phytobacterium phosphoreum: EC50 = 850 mg/L; 5 miuntes; Microtox test

Section 13 - DISPOSAL CONSIDERATIONS

Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 112-27-6: 1
Canada
CAS# 112-27-6 is listed on Canada's DSL List.
CAS# 112-27-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 112-27-6 is listed on the TSCA inventory.