12" Chemistry mat) 2 Bille, cartsiant Me-Piet OSyqute sesia) 1.5 Rae stand 948 ai ulate eam aia adel n 0.322 dia, al stacrl sill2l vii, Re a wizw iad aren 474 at qaemt 8. Xytidin aude = 0.068 viata rial sialaal (F) | : | Awdamo- i - 4 _ ~ 0.082 _ 1000 > siete 24 (214i WO” DEN 0.8224 444 er pONeRpE YARN x tae $8 (AAD xyyo TAMA ALE LAE pe ape UE SL 5 _ 1000 x 948 4 Mio = 1 ~ Xetee suuia = 1 - 0.088 474 x 5000 | - xno = 0.992 =04F 4,20 % HO -n vela atari well daria eel, (EAMCET 1993) 24 100 ar stage 20 3% H,0, wall 6a = 80 m4 wlata ean aad all 0.4 F ad | 2.2 Faze sanvnl 4.78 wlan aie stay ave db 20 % H,0, atau sina aail, daw Bian Meas qaem 474 ane QE anita i ra de = 8 «- 2 Vata Rare aR OF) ase OS "ig aA OS = 1000 « aed end) We ri0 cue at ade si = HOLM crated wus ye x aiaeid se (PA) mine _ 1000 « 4.78 iz 474 x 2000 - wen - 2 = 0.0050 F 18 Wlzta aiamet staal sial2l 0.0050 F a2. 3. lle samasie (CoHg02) Hata staoini emell PA ce « 20% sill cauusia ola, al au Hla-sien eile. rawact sl, oar + 0.017 wild siat ail, 20 aH slldla casi ee. | 1000 im sas (wy ALS Ale ste . 80 WH HO e2. i - wellat ata = 1000 ill sander ala (ny = St easiad on ; Ad ouedla 2 aiatt ae via = E> 20 a4 — 62 BIH) mia 0.822 56 = 605s = 0.0825 = 0.082 ‘ wollen 8.2 Mize siamai 5 va aim MA 45 ala sas adel swell via (N) = 5 3 7 A aed sated en a, dl citi alea-via Bear aa 7 (Guj. Board July 2008) 0 a4 : =ieanna 7 444 Ha zotiet 21 wa : 0.1 ut” & 13° Chemistry by Nirmal9.4 WH NaOH A 90 we wellHi alowerdi ota ataeiti NaOH oi Hle-2iet owe, Ea 4 12" Chemistry aa va = a, welt ala = > NaOH tt ale = 3-01 augda ea 40 ie 4a wld 0.5 + 0.5 + 9.0 = 10.0 wolhu aa - —"_ _ © _5 OB "suede en 18 2 oslo alleoia = [> = 0.05 ee 13,180, 11 ataniai wot wa-oia 0.86 la dl aa ale staal wlaldl = = ou o1 (Haryana CEET 1994) oa 51 > 51 | - . welt *e-24a [xy,0) = 0.85 = 7 10. 225 un wellai 18 3% 24511 (CgH120¢) = * a+ 8, 342, aarti (Cy2H22011) aieundi eta, tatttL H,804"tt 28-34 by go) = 0.15 = —2 ga Mavi BA eds zs we-via Bean al ? 490) ben 5 1B asian Wd = 335 = 0-1 5 tl Mla (N) = “CEP = 55.55 aH. afin wa = 282 J on i? ke OAS XN _ 0.15% 55.55 _ 9 a5 wettu ala = 72 = 12.5 08s 085 alla 12.5 + 0.1 + 0.1 = 12.7 steal ya Masia = 1 on saginn siasin — OE = 0.00787 = 0.008 " a7 agiott Wezia = = = 0,008 12. welt aiasia = 125 — 0.984 ~ 0.98 12.7 11,45 sland ze A Bat la 2: Bt MUELAl eu di 2s Bott didi wel # a2e At We 2x a Bet ala Bx @. Beat we Bat dasa = SO wl 12.90 24 24 41% (CoH 20.) *A BO 9H Yard (NH,CONH,) 162 wa welai aleunai orar aiaal aslo ale: 24a Ke 500 wr alaaMi 3241 9M NaOH 2Aleunai 5 % wiw ize aaiad ata wil ? arte] er UMA x 100 % wiw = ciated 2 (ai) x x 100 .6=75 500 x 5 5 x Too 7 25 att 15, 10 % w/w aizdl uaiaj NaOH | 500 sm ata ntaat 2241 ath NaOH al ¥32 ub ? (GUICET 2007) Ramuel sel. aver 2 50 16. 10% w/w aise Hetadt BOO aH 2gsi%4 ctaOL eantaan H2 Bear ae aqslordl ¥3e WA? sn = WW x statis saa, ey = BNE casei 10x 300 _ , = Tp = 30 a 17. 200 at aiauini 32a ath NaOH aiieundi 4.5% wiw aigat Balad sia Nd 7 cist et 100 ee % ww = ut” & 13° Chemistry by Nirmal9% wiw x siae en 2 ald 8 = 18. 5.85 wa Nacla 72 wi welsti vileunani 2a @. NaCl wle-2ia ale. NaCl (2104) ott Hl = aes well (asa de = 2 = 4 garda ators 41 . Nacht se NaClat ala-sig = SCS ra on = 3y = 0.024 19.2 Ree sddan velu aaeri 200 AR vida way well dla al dal % V/V Wil. 2 Rzzr Sadia sia a2d 2000 AM aiast,| ald se = . 100 A sale ¥32 43. 22.5 % W/V wis| 2 zz wdla stam Husa d2aL sun wise 432 Usd 7 2 zr aia = 2000 AR stat 100 > wise eer uenn) aiaee| se (RSI) 8d, % WV = = 100 9 2.5 % Walaa Haig 2 ee stam seUaA 100 su wise ge Wael 23,5 (azz aiaeri 200 si yar air adel sha, di en % WIV wil. 5 Maze stat = 5000 MR stazt save XQ ct ‘i 100 x yf em RAK’) 100 x sai se Nee ca, wy = OR aa, % vw = ONSEN aa se (BRM) aad t 100 x 200 = 100% 200 _ = 1020 = 10% sao + Salat wala sianrdl disdl 10% V/V 4a. 20.15 % V/V Saldlay Ualawi 5 [ze stam Huaat wd Sea MR Ballad wge Ww? 5 zz aia = 5000 a sive 100 x lalla se (AC oe saad ot (PAR) 100 x dalled 56 15 = 5000 Raley se = 158000 _ 759 ARR 100 215 % VV 5 [zz slam aaa 2 750 RR Babel #32 wsdl. *21.5 % V/V aisat a2ad Gddla] 2 Ree wdla aia oruaa 32a AR weal xge Ww? 100 x siaie $61 saat $6 (BMI) = 100 > ate se (fe) % VIN = ~ ~~~ 2000) o 4Rartt sive isc 4 % W/V aa. "24, 0.2 M NaOH -t valu start on-set 2stardl eile, 0.2 M NaOH 4 %dl4 siae 22d 100 mi siasd 0.2 ola NaOH waa 8. ea miele #4, NaOH ala = eee 20.2 = 2 NaOH (414) 4 #4 = 0.2 x 40 = 8 UH 200 x suse cen Gat 4 oy Sea 1 WN = ad se (RO) _ 1008 1000 = 0.8 % 925, 2 Raza aiaetnl 2 x 10-7 Relay HRN suastelz aie adel ola, ad ctastu ppm al. aided se = 2 Ree = 2x 109 AR ut” & 13° Chemistry by Nirmal26. 2 Rize aianini 2 x 10-6 Balan acer aaa adel 27. 28. (ous) Bam onasieilled en = 2x 107 Gala 2x 10-4 a0 + ersel wide we RRA = seen Gwe) © peated $6 (READ 108 2x104 2x10" x 108 = 0.1 ug/ml da, dl staern en-sedl wider ue Ra vil. alae 62 = 2 Mee = 2x 10° A (ay) meee] eM = 2 x 10 Balare = 2x 109 9H swig wR Pat ea-setll PARI Pet eal, Rat 1 ase are 450 mi saci 5 WH NaOH ste via dat iad lel ails. gj cece I a NaOH Alt = Gy Samia = 0.125 we 1000 x sist Mist watRA = aa set) _ 1000 x 0.125 = 450 = 0.278 m 0.278 wle/fze 0.278 wla/sallery> 75 ws Amal 2.5 wr whids as GAR de ei ten sae aeuladl all. 2.5 oy iss su le = OO = 0.0417 Wea 1000 taut Hie 1000 x 0.417 ales 2m fA) 75 wad = m = 0,556 4a/Galur WN 12" Chemistry 29,22 wy APard 122 sun sla 2grseilerwssni pitunami aud, di i we endl asia eile. saad em slong UA + alate, BM 22 + 122 = 144 WH 100 x ates en ag et 2% whe (ARB) 100 x 22 144 15.28 % 100 x arse ot 1. % whw (stele 2gisaleisss) = ee 100 x 122 144 84.72 % 30, sil 221 salewssui Utd 33 % (w/w) stam ona, a a AR asin 30 % w/w airt Azad 5 100 we stagiai 30 2 Na 8. 2 70 WH sas (CCL) a Ate Arte Mt) = Fe vece m celia _ 70 cei at ae tn) = = @ -oas4arta Aqauedy ea 154 2 AP tet esa (Sogn) = Ay si 85 ~ 0.385 +0.454 = 0.459 BL. DA eds sar we eR ele {a)4.3 Rize stati 30 3% CO(NO5); -6H,0 (b) 30 ml 0.5 M HyS0, 2 500 ml yl He 524. CO(NO), -6H,O 4 sued em = 201 w/a 30 am (a) COINOs),-6HL0 + d= 55S ta = 0.103 la maaett Wit 0.103 adaiRa = SANA _ O18 goa aaa ey 43 ut” & 13° Chemistry by Nirmal(b) atl M; = 0.5 M, V = 30 ml. V2 = 500 ml 2 My 2 MiV, = MaVa eM, = MM = 05x90 _ 2 My = AER = Oy 7 0.08 M 32.2.5 kg 0.25 waa yu (NH,CONH,) 4 xdlu samt ual M2 wg yRur} cm ait. i __ ‘laifal (m) = aa oundla x lade OA ke) aon 0.25 = os 2 wand GL = 0.25 x 60 x 2.5 = 37.5 wr 33.20 % (w/w) KI wala cial ada 1.202 ws FAR sla, a AL (a) weld (bo) we wr (co) wla-2ie ala, (a) aaa ; 20 % wav KI =z 100 24H siaeri 20 Ber KT «44g, 100 = 20 = 80 x well “Shs ao om ~ Gard aueda cm x aiaad en Oke) ar ~~ 166 x 0.08 sm = 1,506 (b) aA mae EN staal wi, = SSS poeercs aac et 2 weet ae = SR S atastell Yetett _ 100 ~ 1.202 = 83.19 ml = 0,083 [azz ste eh MURA = Fd see) 2s ~ 166 x 0.083 aes (o) esia + = — Se san RES Kijeedae ~ 166 ~ poe 12" Chemistry HO den HOE = Fo foul 444 i8 Ku we Kissa + well ala oe KE Aeaian = «ee ~ 0124444 Kieu ala-eia, = 0.0263 34, wibiewuni 68% cml vas «uss ARsd xd wae aani 20a B.A vu aad ata 1.504 wa/WR Ree sa, di ea sacl aaa abel. 68 % cml HNOs 2a, 100 art siaveti 68 aM HINO, 2NaCl + HyO + CO, 0 U1 ia) (2 ie) = ay = 0.01 if * Na,COs quz4 eu 2 Wid HC] we & 1 = is Spa i sree eis C8 = 0.01 chemictes* pgp Ma NagCOs aver cud (2) 1-001 = 0.99 bee —— oo = 190 We HCI awe silat. (M) = saaae meds om x ae NaHCO, + HCl > NaCl + H,0 + CO, (Mia) 1 ey =— 10 = 066M 180 * 0.088 1 la NaHCO, awe eat 1 vile HICL aut via = 0.66 M 1 sf 01 2 | aia uct 4 Jaq Mi NaHCO, WRI cUR Fo5 Hid HCL aR. iystuat wu sa w2 O.1 M HCl 4 bed se ¥3dl dl ? [Na,CO, #4 NaHCO, +1 Rani a iu a aot a] NagCOs 41 NaHCO3 «tt Raed ea = 1 ar ¢ 2 ade oi aoe ala auaila 4 HCL = 755 + G99 = ieo 0.1 M HCI aia ~ O.1 44 HCI+4{ 42 1000 ml 8. ul 3 NajCOs4 et = x att Ohd Geel <2 3 » NaHCOg4 wt = 1 = x a ae » ta Held =? 190 NajCO4en x Nagcoy via = Nis = . * cos = 341000 _ 157.8 mi 150% 01 eq — NavCO, din NaHCOg ct 48 = Sede 4 37. 300 wm 25 % start x at 400 wr 40 % sian , y Bex 58 ag atact dasa and, a nel saat Na,CO, 1 NaHCO, att Hla wad ‘a2 eel esd ae. cet (Pat) | 44 A = 300 + 400 = 700 34 300 wt 25 % alae x B2d, ut” & 13° Chemistry by Nirmal100 3 svaAi 25 wr sim % 800 IM s1AerL 75 APL at 400 wrt 40% a14R y 8 100 um ataerAl 40 wr aie 2a, £400 wrt ataBrri 160 30K ata . Reel Rae saved cdl estat | saw =< 100 wen Lott aieotai emell esradl 5 Fer 1g * 100 = 32% aia 2 a aicofai eaull extatdl = 100-82 = 68 % 88. 222.6 wH sildl+ saU4sla (CyHgOs) i 200 sua wellaidd 2iFeKo sam dae sean ag 8. i ciated vieul@Al aia. A stave ada 1.072 | PAR ela, di card sieulRA sila, be A ste welldla savestay auedla en = 62 aria’ 200 a4 waldlt suasiad on = 222.6 ar vuelta 1000 x sill sacs Bae esa ea waf2l (m) 1000 « 2: 62 = 200 = = 17.95 1000 ais 2s (7) = 15 « 10% oust +1000 ai welt Heal 15x 10% 4 sacl 2. 4U2b (1000 = 15 < 10%) = 999.985 Hr as alas (ately) ea 1000 aicae ame msl ort x aise et GOO wat@dl (m) = 1000 « 0.015 119.5 x 999.985 1.25 x 104 s Maal = 1.25 x 10% m 39.4 Rize 0.02 M Nacht valu ciaoid 1 Ree well RA we sean aud, al uReunll ataaedl | seal eel ws ? | M, = 0.02 M | 12" Chemistry 40. olsen teu 1 Ree S Hera wala atacr’ sauna uReul «tact 46 250 mi aw d. su eeu 8.65 WH HCI G2 aa B. aa URGual staged alga sided. silaffad) — 1000 % weed en (an) AeA SKE Gia aed #E (ml) 1 _ 1000 x N 5 ~ 365x100 ed x= 7.3 WH aad S5CMlA eet 56 250 ml sai ail 3.65 sue HCI 52 ave 5. oudl 28a HCI = 7.3 - 3.65 3.65 31m 1000 x gicarj een (404) stil = ae aa Gee x ata 9 (nl) 1000 « 365 aN 36.5 x 250 4 .N 5 41.8 we NaOH? well sieuld 250 mi aiaet omni J. 20 saad 500 ml uaa well Saat ed d, dl au ie stag NAOH - Hl 24 slau ail. agate NAOH at stavedl HlaiRAl 1000 x 142 ey ed x aa 1000 x 8 u 40 x 250 Oe MV = MiN'p Mv, _ 08% 250 _ Mo = Wy 500 =04M 2 4e stant ail = 0.4 M me x 26. He sive NaOH at ia = “SO ut” & 13° Chemistry by Nirmal42. clad well selaleita ste ea aaull sifidle a2 ad D. greet aca mel 15 ppm 9 (4) AA aml estardlai celal (ai) well -tyumi selaleiell lewd cael, greed Heat eal 15 ppm & - wae, ptt 10 Att Ae 15 oat saat 2 Mellel seyret 102 eeE Ae 2) 10? «15 wa = 15 x 10% ow sai 0 15 x 10% oust wiei2l sulle eoyrttee 107 eu ale 15 Le salle 8 0.4 * 500 roo = 43.480 ml 1.2 M disat uztadt aiaetd 500 ml 1.2 M isa Hetant aaa al Ra sai Anat ware wiul2 ailai, (AIEEE 2005) MV, + MV2 = MV +. 1.5(480) + 1.2(500) = M x (480 + 720 + 600 = M x 980 1320 30 7 134 44,20 ml 0.1 M H,PO, “0 ays azadlse wi? 0.1 M KOH tt saad 324 42 wR OT IM\V, = IM3V> (HgPO3) (KOH) 2x 0.1.x 20=1x01xVe 2x 0.1% 20 Vy = AS Va = 40 ml 45.1 m Naci-t vale cial adel 1.21 syle B, ad ataorh wWeaaRA sila, m=1 d= 121 stated em = 1000 34H aiaety @A = 1058.5 4M Ma Xd x ae ot ara en 1x 1.21 «1000 10585 12" Chemistry 2M = 1.143 46. 2.05 M CH,COOH +t valu stand ata 1.02 wR dB, di sraerl wie aiid. | | | | | | alae wtal = tsa en . 102 = Se alae] eA = 1.02 x 1000 = 1020 6 sad on + stad on = sae on 123 aK + alae eA = 1020 wo ~ alas EX = 1020 ~ 123 = 897 UK M > ataeud em = Onna 2.05 x 1020 1.02 x 897 = 2.28 WP: S725 % wiw KOH ela aiaet ale aa lariat ait, 25 % wiw KOH 22: ud 100 wr 2136 25 3H KOH sea, el = 25 HO diated 2 = 100 - 20 = 75 aH 1000 x ateien Gere ni A x ae EA (AE) 1000 x 25 anal = = 5 wteudl = Fea 95 slated ale aa ae = 2B = 416 — ~ 18 2 ya da = 4.61 “KOH at viesin = 24 — 0.097 48.1 vlad wla staceti aeatt ala-viar ail, 1m valu sitar 2 1000 aur alas (Utell) Lala sea wd 8. ala ale nalts ila = ut” & 13° Chemistry by Nirmalarin iawial = “ated aa-2i = 0.0177 56.55 49.293 K are well ausalyt ay wane seat 50. aud, 1 Gee welll Bead -wsgeer ay avi wusdiet ay 2 ails cout 0.987 4 Bw 293 K auard wsglyd ay we oA ranis 76.48 (aeiue 3. Aafia Fear el, Xy, PK, * + Px Ky Xx, 0.987 4 76.480 4 2 Nyt asia = 1.29 x 105 1 faze welt aia 5.55 at Ny wale Xx) = = Nya wa > wl ail No ctl Mla << well Hit dlaell weil Me, aeAvHELAL Nant He sAaDLeL Na cuit walla sat 5 Neti 1.29 x 10) ee Nort Ala = 1.29 x 10 x 55.55 Nostt ole = 7.16 x 10-4 ale 1 Mig = 109 A via 7.16 x 104 Wa = ? = 7.16 x 10+ x 10° = 7.16 x 107 = 0.716 RR aia atai Se 2A art wuad 34 avy reas yasseur we aural aia J. A STP AHS ay wel Aa 0.195 m, al BAL sramisll aiadl s2l. (HS ayd ails cour = 0.987 4Uz). 0.195 m gael AZA_1000 wr ats (ULel 0.195 Hid HyS ay wt7e 51 i. sae oe (8) = 228° 2 55.55 “HS 4 tn) = 0.198 2 HyS it We 31 (4,5) Gdlan FHL 38 pigs = Kix xis » a ay oe? Ky 0.0035 ~ 282 UR CO, tt well etdaL ataeL WE BAL seamed yea 298 K auatd 1.67 x 108 wesa J, al dw AMAA 2.5 Ue StU GOO ml dist well CO, dL weil b2el ad A madd sai. Ky = 1.67 « 108 was 1.67 « 10% 101895 x Loe Ky - 1.648 x 109 oe dalle FA 4%, Poo, = Kit * Xo, . Ro, 2.5 4 MeO ee 1.688 « 108 1 Xeo, = 1.52 x 10-8 = 0 27-78 via co, Bo, = Bo go, >> Myo) 11.52 x 10% = OO 27.78 1.52 x 103 x 27.78 0.042 ala Copal ria = —"_ suede ea CO 4 eH = CO, -t Hl x CO, | aula « COn4 0.0042 x 44 » CO24 1 = 1.857 a0 ut” & 13° Chemistry by Nirmal12" Chemistry 3.322 x 10° x 50 1.681 x 103 Hla 1.661 x 10% x 10°3 BAR 1.661 Roa 52.298 K aun CO, aad ails cous 2 x 10% an mae dla, al AL ella aieatt Hawiawi wil, CO. avy W2 Ky4 yet 6.02 x 104 4 3. delat Peat op P = Ky-X 2 900 FHM wel! 1.661 FP wie CO, ay Poo, = KnXeo, ata al Pro, *55. 300 K aria Clp ayy willis coum 2.5 x 10% Rae aa su, a AL wel cise sotto el ay a2 ay10 MR - Ky d yet 7.1 x 10-4 oe B. = Goa tot a ~ 3922 x 10° Sal Gar yet, 2 CO, a4rll welli std 3.322 x 10% P= Ky X siecian wal Poy = Ku Xa 83,273 K atin He aya agit steel dou avin 2.4 x 10-9 al, al sited We He ay PAiBLs eeU5L “Kay = acl. dl aemtisd yeu 6.71 x 10-6 2d. dala Beat yee, Pre = Ky -X = 0.3521 x 104 = 3.521 x 105 Ch, avpl well staat 3.521 x 10% slaatantl ath + Piie = Ku Xie = 671 x 106 x 2.4 x 104 = 161 x 108 He *56.300 K aunt HAS ay 1 22 welldil uur sedi Beat Raia aia ad ? ‘ 7 7 Kyi Ye 5.6 x 10-4 oe BP AA aad ails 54,298 K wit CO, ay woldidl wae sei 900 saniaie dead FAR wellai zen GAR via CO, ary aid ati? Ky 4 Yet 6.02 < 10-4 m2 AA CO, ayy ails eee 2x 10-8 we BD 2 HAL UR He a4] sii cue 1.61 x 10% ate ea. Bala Ree yr, P= Kyx P. Pins = Ku Xiys co, aunt awoia = 7 Ku HLS ctl Wait [Xjy,5) 2x10 oe = 602x107 a = 3.322 x 10% 24, welll atar 1 aot Rt dlawll 900 FAR lly EM ws ae) a a well 60 900 Aw ase sa 1 G22 welt a= we oaedla 2 HgO al Hla = M 18 50 Hit _ 1000 wal 2 aa ma a 16 ach 2 aby Wain dy ag nae = (n + 50) = 50 a5 ate . nee ie (MeN ata 1 dlavll 1 Rize = 1000 RR = CO; At itewig = CO2K AE 1000 34) Pert : ial, HSU Ae nal, al ge ae SG OEs BA = (n + 55,55) = 55.55 4 as ut” & 13° Chemistry by Nirmal