@ JE-8043 B. E. II (Sem. II) (Chemical) Examination May / June - 2013 Process Calculations (New Course) Time : 3 Hours] [Total Marks : 100 Instructions : Ti cata g Rardaedl fan Saeed we ware wed Seat No. Filup strety the detals of @~ signs on your answer book Name ofthe Examination B.E. 2 (SEM. 3) (CHEMICAL) Name ofthe Subject PROCESS CALCULATIONS (NEW) SubjectCodeNo.| 8 |] 0 |] 4 |] 3 |e SectonNo. (1,2...) 182 Swen Senate 2) @) @ Figures to the right indicate full marks. ‘Assume suitable data if necessary Use of scientific calculator casio Fx 82, 83 or Fx 100 or equivalent of other companies are allowed. SECTION - 1 (a) Answer the following 5 @) Define : Pressure Gi) 1latm=____ KPa (ii) Molarity (iv) How many kilograms of ethane are there in 210 k mol ? () Find molecular weight of (@) H,S0, () Na,COg () 20 g of caustic soda are dissolved in water to prepare 4 500 ml of solution. Find the normality and molarity of solution (© The conductance of a fluid flow system is defined 7 as the volumetric flow rate, referred to a pressure of one torr (133.322 P,). For an orifice, the conductance C can be computed from C=89. 2A fe/s JE-8043] 1 [Contd...where A = Area of opening, ft? T = Temperature, °R M = Molar Mass Convert the empirical equation into SI units. 2 Answer the following : 16 fa) (b) © © Explain the Block Diagram with material balance of — 4 following operations : (Absorption Gi) Distillation. Assuming air to contain 79% Ny and 21% O, by 4 volume. Calculate the density of air at NTP. The waste acid from a nitrating process containing 20% HNO,, 55% H,SO, and 25% H,O by weight is to be concentrated by addition of concentrated sulphuric acid containing 95% H SO, and conentrated nitric acid containing 90% HNO; to get desired mixed acid containing 26% HNO; and 60% H,SO,. Calculate the quantities of waste and concentrated acids required for 1000 kg of desired mixed acid. OR Explain outline procedure for Material Balance without chemical reaction, 3 Answer the following : 18 fa) f) JE-8043] Ethylene oxide is produced by oxidation of ethylene 100 kmol of ethylene are fed to the reactor and the product is found to contain 80 kmol ethylene oxide and 10 kmol Cp. Calculate : (i) the % conversion of ethylene and (ii) the % yield of ethylene oxide. OR A combustion chamber is fed with butane and exces: combustion of butane is complete. The composition of combustion gases on volume basis is given below : CO, 9.39%, HO = 11.73%, Oy 70% and Ny 4.18% Find % excess air used and mole. ratio of air to butane used. Chlorobenzene is nitrated using a mixture of nitric acid and sulphuric acid. During the pilot plant studies a charge consisted of 100 kg of chlorobenzene, 106.5 kg of 65.5% (by mass) nitric acid and 108.0 kg of 93.6% (by mass) sulphuric acid. After two hours of operation, the final mixture was analyzed. air 2 [Contd...(b) 4 @) (b) 5 fa) () JE-8043] It was found that the final product contained 2% unreacted chlorobenzene. Also, the product distribution was found to be 66% p-nitrochlorobenzene (P-NoB) and 34% o-nitrochlorobenzene (o-NoB). Calculate : @ the analysis of charge Gi) the % conversion of chlorobenzene and (ii) the composition of the product mixture. OR The feed containing 60 mole %, A, 30 mole % B and 10 mole % Inerts enters a reactor. The product stream leaving the reactor is found to contain 2 mole % A reaction taking place. 2A+B > C Find the % of original A getting converted to C, SECTION - IT Define the following : (any eight) 8 (@ Potential Energy (i) First law of Thermodynamics Gii) Specific heat of substance (iv) Heat of combustion ) GCV = NCV + (vi) Thermal efficiency of boiler (vii) Calorific values of fuels (viii) Excess air leat capacity with unit and explain relationship 8 between C, and C, for ideal gas. A natural gas has the following composition on mole 9 basis : CH, = 84%, C)Hg = 13% and Ny = 3% Calculate the heat to be added to heat 10 kmol of natural gas from 298 K to 523 K using heat capacity data given below: Ci, = a+bT+cT? + aT, kd/kmol K. Gas_|a xi _|exio® | dx10? CH, [19.2494 | 52.1135 [11.973 [113173 CyHg | 54129 | 178.0872 | -67.3749 | 8.7147 Ny [29.5909] -S.141 | 13.1829 | -4.968 Crude oil is analysed to contain 87% Carbon, 12.5% 5 Hydrogen and 0.5% Sulphur (by wt.). Calculate the net calorific value of crude oil at 298 K. Data : Gross calorific value of crude oil at 298 K is 45071 kd/kg Oil Latent heat of water vapour at 298 K = 2442.5 kJ/kg. 3 [Contd...© Calculate heat of reaction at 298.15 K of following 4 reaction : CoH > CoH + Haw Data : Component | AH?, kJ/mol CHeg) —1560.69 CH yg) 14112 Ebr 285.83 6 Attempt any two 8x2=16 (a) Obtain an empirical equation for calculating the heat of reaction at any temperature 'T (in K) for the reaction CO) + 2Hy@) > CHjOH Data : AH, = 90.41 kJ/mol Cf =a + bT + ef? + aT®, (ksikmol-K) or (Simol- K) Component | a bx10>_[exi0®_|dx10? CO) 29.0277 | -2.8165 | 11.6437 | -4.7063 Ay 28.6105 | 1.0194 | -0.1476 | 0.769 (g) CH,OH,g, [21.137 | 70.843 [25.86 |-28.497 () The orsat analysis of the flue gases from a boiler house chimney gives CO, = 11.4%, Oy = 4.2% and Hy = 84.4% (mole %). Assuming that complete combustion has taken place (a) calculate the % excess air and (b) find the C : H ratio in the fuel. (© The analysis of a refinery gas by volume is : Hy = 74%, CH, = 13.5%, CyHg = 7.4%, Cgly = 3.6%, n-CyHyp = 1.2% and nC;Hyy = 0. Data : Component | -AH¢, (Gross), kl mol | ~SH;.(net), kil /mol CH, 390.65 802.62 CH, 1560.69 1428.64 CH, 219.17 2043.11 n-CiHy 2877.40 2657.32 n=CHyy 3535.77 3271.67 AH? of H,O(g) = -241.82 kd/mol at 298 K AH? of H,0() = -285.83 kd/mol at 298 K Specific volume at 298 K and 101.3 KPa = 24.465 m“/k mol Caleulate GCV and NCV of the refinery gas in kJ/mol, kd/ kg and kJ/m®, JE-8043] 4 {100}