Gralbeen PROCES SAND ESIC ‘American Galvanizers Association + 720.854,090 izing Note 0 + Fax: 720.884.0909 + technical@galvanizeit.org ACID RE ‘CYCLING BY KURT ETTER AND THOMAS LANGILL, PH.D ACID IN THE GALVANIZING PROCESS One of the most important operations in hot-NOx for treatment aT |—morganics for re-use organic wastes, BMWA) removed Keclaiyl by steam water condensed for re-use ee Figure 11: Stripping Process for Sulfuric Acid Recycling compressed air S02 +Hj0 +2% 02 J generation pro- regeneration of high concentration furnace pressure steam 1000 - 1200 °C cooling with heat exchanger feed sulphuric acid manufacture Figure 12: SATCO Process for Sulfurie Acid Recycling Protecting Steel for Generationsz APPENDIX 2: PROPERTY TABLES ‘Table 1: Chemical Properties of Hydrochloric Acid General General Systematic name Hydrochloric acid Systematic name Table 2: Chemical Properties of Sulfuric Acid Sulfuric Acid Other names Muriatic acid Other names Oil of Vitriol Molecular formula | HCI in water (HO) ‘Molecular formula HSO, Molar mass 36.46 g/mol (HCI) Molar mass 98.08 g/mol Appearance Clear liquid, colorless Appencance Clear, colorless, in pure form odorless oil CAS number [7647-01-0] (HCI) CAS number Properties Properties Density, phase 1,18 g/cm’, and phase 1.84 g/cm’, liquid in water fully miscible in water fully miscible Melting point -26°C (247 K) Melting point 10°C (283 K) Boiling point 48°C (321 K) Boiling point 337°C (610 K) Viscosity Viscosity 26.7 P at 20°C Hazards MSDS External MSDS MSDS External MSDS NEPA 704 & NFPA 704 > 6 MY R-phrases R34, R37 Rephrases R35 S-phrases $26, $36, S45 S-phrases $1/2, $26, $30, $45 RTECS number RTECS number WS5600000 10 Protecting Steel for Generations2/7/2006 APPENDIX 3: REFERENCES American Galvanizers Association, (Accessed 11.17.2005). ASTEC Engineering (Accessed 11.15.2005). Beta Control Systems, Ine., 4n Ecologically Sound Alternative to Dumping Waste Pickling Acid, November 2005, USA. Beta Control Systems, Ine. (Accessed 11.18.2005). Depend EQ (Accessed 11.14.2005). Greener Industry (Accessed 11.16.2005) New Zealand Steel (Accessed 11.21.2005). Phoenix Systems, Inc. (Accessed 11.16.2005). Wikipedia (Accessed 11.22.2005). Photos and flow diagrams courtesy of: © ASTEC Engineering © Beta Control Systems, Inc. © Corradina Enterprises, LLC © DependEQ © Greener Industry © New Zealand Steel © Phoenix Systems, Inc. ll Protecting Steel for Generations