∆ U =Q+W ∆ H =Q+We=Hf −Hi

Analisando o reservatório frio

We=0
TF=0 °C e TQ=200° C Q=Q ' +Qσ
'
Hf −Hi=Q +Qσ +We
0−2676=−2000+Qσ+ 0 →Q=−676 kJ
t −Q 2000 kJ
∆ S Q= = =4 , 23
T 473 ,15 K
t −Q 676 kJ
∆ S F= = =2 , 47
T 273 ,15 K
kJ
Sf −Si=0−7,3554=−7,3554
K
kJ
∆ S total=−0,6554
K
dH=dU+PdV+VdP