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= Bionolecules lion 2 — TeV yn ae —thak has an oldetyde. ox a Ketone fae ee hemjacetal a P sail ave — alle §— Canbohy eluate: Monbohydvake ane substances haviog fervel Fewmala Lx Chao) y « sLlassftaln of _Covbohydules 4+ Meno sa cchanidles ?— * A pabohydvate “that —tannot be hyctecp sel fo Simple yom pourds Is galled =~ monosaccaside » 1 © Monosocchawde cahich hove ix foubon ane citer aildohexoses om Keto hexoses 4 Glucose “Bucfose 5 Guolactase the + | =O 0 Sacchowides -— * foubo that yield 2-40 10 monosacchanide units» On is 5 axe ee Olvy> acc hasidles - mt © They are "Raden velasified! 95 clisnechanides » .sacchewicks teluasocchasicls eke okpendig upon the no: of monecsacc hasidles » they ovide on — bude Pee a ee seeks units oblained by fyi of a disacchawich be asome ax — cliffewent - f QSucwse + Matias Jaclas ce: oe acces om A \toxbohyduate that can be elyzsd to may monocsacchasid € pees is talked 4 pol cchtsicks by AStouch> Cellulase che - Aldeses Monosacchauides ° veon'aini alclehycle up exe called — aldose. _Kelases ¢ Monasacchanides vonteining Kelonic gap ore Called Ketexs : ee g Non- eres cg © Both — monosacchauioks YB oe ane crystalline asolidls » ASoluble fn coakex asweet tn —foste hese, =e Voollect vely Known as es axe amouphous » Spevsingly ee Fae ‘Knewon as. -_ Non Btpane: ae Qseluble in water f auch Yo Non Reducing up ans $— a Asbechadcles “Tare Sotto chligy's pepe Blien's segents ae falted ag caeaery Digans “AN Mmonosochwddes uShethey aleose om Ketose, cue Lnueing Brpans by t= Glucose » Paulos mannase 5 galactose « d g UF ts ack as a sechieiny agent Conecluces ote Pligg’ solution asilvew pieorel Asoluhon): Gromoni ca! “pa pupexties ?— © Gucose 18 Guret in taste 8 cla opHeally %Htve Cexto sohbey) mutanotalion v * Gilucse — Ashows cent) o Expimens 2— ave pats oF diasteuio- mes that diffex only tn -the Con ipuxalion ahout A Glngle Lauber) Ahem + q fF Gatscose B Mannose cae Co chimes cHo Heo te OH Ho—t_,, H—_ on f—on CH OH D- Glucose. ChrOHCcHoH)y CHao) SH bi tol » f CHOW CCHon)y COOH + Cu,O4 Guconic aero Ceo), Povmahon) @ = NN H@te * tho che Structure of Gilucose -— «Vie open chain Swcture OP alucase ed by ayes iment post ota ves: Bub ip Tins el Pe ptishars: f ao” D Gilucase clees not ee cKhIPP's fast ~B cloes not each woth Noksos & ae ty ma pensul phite addi Hon pwodkict inspite of Doesence of - HO foe 2) entacctate “oP “placase cles not dtenct with NHa OH group fndicaHing absence of -CHo ger tation of Plucase y— © Tis Spontaneous 7” thon in cspecifre Hotalyons of an opticly achve sfompound ts vole! mutasiofalion » © These blac afan ‘be explained by tyclic Shuuckwe OF plucase: Glucose a Stable vuclic , hemiactal: Initially Rive membered ting stauc hore of qrlucase 8 psopased Bit Known as Nase * Aromas axe diastereomens that clifPer in the don Pipunalion at se acetal on hemiocetol’ C atom oP a span in its Cycle) Four @H Anomens ave epimens —ewhase. ton Potrmations cli PRese Obout Cue Tolsg abc) g p- bw glucase ate cnomens « O-SO©) f B-bO) Bauctase ~ one cnomess » A © Tn Alucose C2 Cayton ts anomeiic ‘\Caybon Bin fuefase C2 Veasiben fs Onenmesic —Casbon + (2) Fawetose © TF ts also Krown as @-Laevulose re nakwa! Occettung kembound — #5 faevastotal : y Fenny ne i Ghos mutauotalion lrke (lecase ° in 7 © TF is edu Orepans ° OSkruse bese 3 CH2-OH OCH, H H 4, -OH anO se i HO H | Ho-c—r h—bon peel # —C-on Bord nofoon Be lee . C—O) OY ~b~ Ruructofwanase BA Bt Preto Pusdnasc er en Shane tee cSpeciPire Rotation Secihie Rotation cSpeciPre Pie C52") Eaot (-433") Diasteweomens with — mane pe one Stexeocentue that li Pre In the wonrvpunation — abou moe ne AFFeweoCenbye ae galled epimenes: G)_ Be Giycen arden OS an edimen)* r 4 (i) D- Eiythwase 2 Letheose ane oy Gi) D-plucese g - galac ase ane ey cpimens fiycoroldehyde Chis pai IS an emnttomen as coelf (Sucrose 3 (Su Cio Hor Oy) : < : Aqueous asolubion OP Su 1S extoowvotaray its speciPie stotabion ip + 665°. na Wis tape pets acids csucwase yields an equimolax eae ba- bOI ~ Rructase Lr ie 0 n+ Hoos + G tin O * Since d¢-)zRuctase has Gecifie swtalion thon b Cr plucase sthe _Jtesul He mixtuxe 3 = ea © Sucwase is nor a wreclucing “aye: © It ches not Fawm an Orie asazone > ches not Soe mutase tedion + 20H Mal: malt Cet <— * When it is h bolysed — Uoit cliluke acids O% Mm by the en ye moltase, maltese yields +t00 y olecules of! bew- glucase - © Maltese ts a weducing csugay , ft ‘Foums an Oxime Qn Saz0nes Undespoes muto— Hoch re Z ‘o 1noH H c 1 H220y on Cete eae cd * by dituke acids om Qsructase —the Cr2yme lactose» +0 On eguimolay mixtue oF DH —glumse B BCH ~ galaclase : © [actese I a pL ing Gauge: CH20H at sk Ga (Bab 4- plucaisi tines) \ Plucacehandes ?— 4) VStouch (Ce Hie Os)n nee Armplose C20]:) Croakey osetulsle) Sais Ue Amylepectin (807) Cantey tnsoluble) « * Both 7 go tp fin ane veembased oP B- glucose Units © The tose "molec & mode up of beautease unit (c bin betrocen orl “oF one plucose fee i ries me unit: The no Ol Dap cer units in ores - 800° eine CH2OH HPO I ° ai if ecto fas a baanched ~chain Hise betwen -L to one i unit GB -4 of the next glileose unit: “Thase hains In Fawn Comected fo cach othex by L56> linkages: aay HOH ou x(imy Caipessiclic Gin H 4—YUr-6) o O busanch pein Ht mt o Hi CoH CH 4 ° (, _ Compopectin) ites G& ok tae 100 - sHedticing = Le face i Gs: ih Valid p Be py casile ey TWlien's » é Bene Reagents wae which a tests with these Uteagenks ane Ke as a, oy -the sAovbahy dba which vlontain Gg hemiace! posittve fess » C) bp [Csr] “aes ou Ph j—> a 4 + Onietion are rR chee Genedltc #! oridlise an allclase om Ketase A give Le rr a ee ee Glucose 4 Luuctose Aldase am Kehase Ford Behowen ‘hoo camo dcid molecules ts Pxphtte frend! 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