SAFETY DATA SHEET ARKEMA . 7 PEBAX® MH 1657 [4 PRODUCT AND COMPANY IDENTIFICATION Company Arkema Ine, 900 First Avenue King of Prussia, Pennsylvania 19408 Customer Service Telephone Number: (800) 932-0420 (Monday through Friday, 8:00 AM to 5:00 PM EST) Emergency Information ‘Transportation: CHEMTREC: (800) 424-9300 (24 hrs, 7 days a week) Medical Rocky Mountain Poison Center: (66) 767-5089 (24 hrs, 7 days.a week) Product information Product name: PEBAX® MH 1657 ‘Synonyms: Not available Molecular formut: Not applicable ‘Chemical tami Polyether block amides Product use: Mouldings and Extrusion 72, HAZARDS IDENTIFICATION Emergeney Over Color: colourtess to sightly yellow Physical state: sol Form: pellets Oder: one “Classification of the substance of mixtu ‘Not a hazardous substance or mixture GHS-Labelling Processing may release vapors andlor funes which cause eye, skin and respiratory wact ration. ‘Supplemental information: Potential Health Effects: Contains high molecular weight polymer(s). Effects due to processing releases or residual monomer: Initating to eyes, respiratory system and skin Prolonged or repeated exposure may cause: headache, drowsiness, nausea, weakness, (severity of effects depends on extent of exposure) Product code: AO7381 Version 3.0 Issued on: 04/11/2015 Page: 1/9 cue F0s (17269-16607-11051-011579)-2018.04-12 04:96:47SAFETY DATA SHEET PEBAX® MH 1657 othe: Handle in accordance with good industral hygiene and safety practice. (pelete/granuies) This material may Contain residual caprolactam monomer. This product may release fume andlor vapor of variable composition depending on processing tie and temperature (3. COMPOSITIONINFORMATION ON INGREDIENTS Chemical Name CAS-No. wewe GHS Classifieation** Proprietary polymer Proprietary* [> 99% Not classified “The specific chemical identity is withheld because itis trade secret information of Arkeme Inc. “For the full text of the H-Statements mentioned inthis Section, see Section 16. 4. FIRST AID MEASURES Inhalation: Ifinhaled, remove viet to fresh ar. skin: In case of contact, immediately lush skin with plenty of water. If molten polymer gets on the skin, cool reply with cold water. Do not peel solidified product off the skin. Obtain medical treatment for thermal burns. Remove material from clothing, Wash citing before reuse, Thoroughly clean shoes before reuse, Eyes: Immediately lush eye(s) with plenty of water. Obtain medical treatment for thermal burns. Ingestion: if swallowed, DO NOT induce vomiting. Get medical attention. Never give anything by mouth to an unconscious person 5. FIREFIGHTING MEASURES Extinguishing media (suitable): Water spray, Carbon dioxide (C2), Foam Protective equipment: Fire fighters and others who may be exposed to products of combustion should wear fll fre fighting turn out gear (full Bunker Gear) anc eol-contained breathing apparatus (pressure demand / NIOSH approved or equivalent). Further firefighting advice: Product code: AO7381 Version 3.0 Issued on: 04/11/2015 Page: 2/9 cue F0s (17269-16607-11051-011579)-2018.04-12 04:96:47SAFETY DATA SHEET ARKEMA . 7 PEBAX® MH 1657 Fire fighting equipment should be thoroughly decontaminated after use Fire and explosion hazards: \When burned, the folowing hazardous products of combustion can occur: Carbon oxides lazardous organic compounds Hydrogen cyanide (hydrocyanic acid) (aces) 6, ACCIDENTAL RELEASE MEASURES: In ease of spill or leak: Prevent further leakage or spillage ifyou can do so without risk. Ventlate the area. Sweep up and shovel into suitable propery labeled containers for prompt disposal. Possible fall hazard —fioor may become slippery from leakage/spilage of product. Avoid dispersal of spilled material and runoff and contact with sol, waterways, drains and sewers. Consulta regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization andlor hazardous waste disposal and other requirements listed in pertinent environmental permits, 7. HANDLING AND STORAGE Handling General information on handling: Avoid breathing dust Avoid breathing processing fumes or vapors. Handle in accordance with good industrial hygiene and safety practices. Thee practices include avoiding Unnecessary exposure and removal of materia from eyes, skin, and clothing Storage General information on storage conditions: Keep in a dry, c00l place. Store in closed containers, in a secure area to prevent container damage and subsequent spilage. Store away from moisture and heat to maintain the technical propertes of the product, Storage stability ~ Remarks: ‘Stable under recommended storage conditions. Storage incompatibility ~ General: None known ‘Temperature tolerance - Do not store above: 140 °F (60 °C) ‘8. EXPOSURE CONTROLS/PERSONAL PROTECTION Airborne Exposure Guidelines: Partloles Not Otherwise Specified / Nulsanoe Dust (Proprietary) US. ACGIH Threshold Limit Values. Product code: AO7381 Version 3.0 Issued on: 04/11/2015 Page: 3/9 cue F0s (17269-16607-11051-011579)-2018.04-12 04:96:47SAFETY DATA SHEET ARKEMA . 7 PEBAX® MH 1657 Form: Inhalable particles. Time weighted average 40 mgim3 Form: Rospirable particles. Time weighted average 3 mgims US, OSHA Table 2-1 Limits for Air Contaminants (29 CFR 19101000) Form Respirable fraction. PEL 5 mgim3 Form: Total dust PEL 15 mgim3 US. OSHA Table 2-3 (29 CFR 1910.1000) Form Respirabe traction ‘Time weighted average 1 Smilions of particles per cubiefoct of air Form: Total dust Time weighted average Omilions of particles per cubic foot of air Form: Respirabe fraction ‘Time weighted average 5 mgim3 Form: Total dust Time weighted average 18 mgim3 (Only those components with exposure limits ate printed in this ection, Limits with ekn contact designation above have skin contact fect Airsampiing slone is insufficient to accurately quantate exposure, Measures to preven signfeant cutaneous absorption ‘may be required Lnsta wth senetizer designation above mean that exposure te thls materal may cause alergic reactions, Engineering control Investigate engineering techniques to reduce exposures below airborne exposure limits or to otherwise reduce ‘exposures, Provide ventilation if necessary to minimize exposures or to contrl exposure levels to below airbome exposure limits (applicable see above) If practcal, use local mechanical exhaust ventlation at ‘Sources of air contamination such as open process equipment, Respiratory protection: Avoid breathing dust. Avoid breathing processing fumes or vapors. Where airborne exposure is likely or aitbome exposure limits are exceeded [i applicable, see above), use NIOSH approved respiratory protection equipment appropriate to the material andior its components and substances released during processing Product code: AO7381 Version 3.0 Issued on: 04/11/2015 Page: 4/9 cue F0s (17269-16607-11051-011579)-2018.04-12 04:96:47SAFETY DATA SHEET ARKEMA . 7 PEBAX® MH 1657 Consult respirator manufacturer to determine appropriate type equipment fora given application. Observe respirator se imitations specified by NIOSH or the manufacturer, For emergency and other conditions where there may be a potental for significant exposure or vinere exposure limit may be significantly exceeded, use an ‘approved ful face positive. pressure, eel-contained breathing apparatus or positve-pressure aitine with ‘uxllary self-contained air supply. Respiratory protection programe must comply with 29 CFR § 1910-134 ‘Skin protection: Processing ofthis product releases vapors or fumes which may cause skin iritation. Minimize skin contamination by following good industrial hygiene practice. Wearing protective gloves is recommended. Wash hands and contaminated skin thoroughly after contact with processing fumes or vapors. Wash thoroughly after handing Eye protection: Use good industrial practice to avoid eye contact. Processing ofthis product releases vapors or furnes which may cause eye irtation. Where eye contact may be likely, wear chemical goggles and have eye fushing equipment available ‘9, PHYSICAL AND CHEMICAL PROPERTIES. Color: colourtess to slightly yellow Physieal state: solid Form: plots Oder: one Odor threshold: No data available Flash point No data available ‘Autorgnition 734.788 °F (380 - 420°C) temperatur Lower flammable limit Not applicable (ry: Upper flammable limit Not applicable (Uru pH: No data available Density: No data available Bulk density: 550 - 650 kg/m Vapor pressure: No data available Vapor density: No data available Bolling polntiboling No data avaiable range: Product code: AO7S81 Version 30 Issued on: 04/11/2015, Page: 5/9 cue F0s (17269-16607-11051-011579)-2018.04-12 04:96:47SAFETY DATA SHEET ARKEMA . 7 PEBAX® MH 1657 Melting pointirange: 383 - 401 *F (195 - 205 °C) Evaporation rate: No data available ‘Solubility in water: 68°F (20°C) insoluble Solubility in other Soluble in solvents: [qualitative and quantative] Phenols Formic acid (concentrate), Sulphuric acid (concentrate) Benzyl alcohol Metacresol lliwater partition No data available coefficient: Thermal decomposition 572 °F (300°C) Flammat ty: ‘See GHS Classification in Section 2 10, STABILITY AND REACTIVITY Stability: ‘The product is stable under normal handling and storage conditions Hazardous reaction: Hazardous polymerization does not occur. Materials to avoid: None known Conditions / hazards to avold: [Avoid storing in moist and warm conditions, (to maintain the technical properties of the product) See Hazardous Decomposition Products below. Hazardous decomposition products: ‘Thermal decomposition giving toxic, fammable, and / or corrosive products: Carbon oxides Ammonia ‘Amino derivatives Hydrogen cyanide (hydrocyanic acid) (traces) Hazardous organic compounds Product code: AO7381 Version 3.0 Issued on: 04/11/2015 Page: 6/9 cue F0s (17269-16607-11051-011579)-2018.04-12 04:96:47ARKEMA SAFETY DATA SHEET PEBAX® MH 1657 11, TOXICOLOGICAL INFORMATION No data are available, (42. ECOLOGICAL INFORMATION Chemical Fate and Pathway No data are avaliable Ecotoxicology No data are avaliable. (3. DISPOSAL CONSIDERATIONS Waste disposal: Where possible recycling is preferred to disposal or incineration. If recycling isnot an option, incinerate or dispose of in accordance with federal, state, and local regulations. Pigmented, filed andlor solvent laden product may require special disposal practioas in accordance with federal, stato and local regulations, Consulta regulatory specialist to determine appropriate state of local reporting requirements, for assistance in waste characterization andlor hazardous waste disposal and other cequirements listed in pertinent environmental permits. Note: Chemical ‘dditions to, processing of, or otherwise altering this material may make this waste menegement information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste cisposal requirements may bbe more restrictive or otherwise aifferent from federal laws and regulations, [44 TRANSPORT INFORMATION Us Department of Transportation (DOT): not regulated Intemational Maritime Dangerous Goods Code (IMDG): not regulated (45. REGULATORY INFORMATION (Chemical Inventory Status EU. EINECS. EINECS US. Toxie Substances Control Act TSCA Canadian Domestic Substances List (DSL) pst. China. inventory of Existing Chemical Substances in IECSC (CN) hina (IECSC) Conforms to ‘The components of this product are all on the TSCA Inventory, {All components of this product are on the Canadian OSL. Conforms to Product code: AO7381 Version 3.0 cue F0s (17269-16607-11051-011579)-2018.04-12 04:96:47 Issued on: 04/11/2015 Page: 7/9SAFETY DATA SHEET ARKEMA . 7 PEBAX® MH 1657 Japan. ENCS - Existing and New Chemical ENCS (JP) Does not conform Substances Inventory Japan. ISHL - Inventory of Chemical Substances ——_ISHL (JP) Does not conform Korea, Korean Existing Chemicals Inventory (KEC!) KECI(KR) Conforms to Philippines Inventory of Chemicals and Chemical PICS (PH) __The mixture contains a polymer. The Substances (PICCS) ‘monomers for this polymer have been. notified, Conforms to ‘Australia Inventory of Chemical Substances (AICS) AICS Conforms to United States ~ Federal Regulations ‘SARA Title Il - Section 302 Extremely Hazardous Chemicals: ‘The components in this product are elther not SARA Section 302 regulated or regulated but present in negligible concentrations, SARA Title Il - Section 311/312 Hazard Categories: No SARA Hazards SARA Title Il - Section 319 Toxle Chemicals: ‘This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Tite Il, Section 313. Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable ‘Quantity (Ra): The components in this product are either not CERCLA regulated, regulated but present in negligible concentrations, or regulated with no assigned reportable quantity United States ~ State Regulations New Jersey Right to Know No components are subject to the New Jersey Right to Know Act, Pennsylvania Right to Know ‘Chemical Name CAS-No, Proprietary polymer Proprietary California Prop. 66 This product does not contain any chemicals known to the State of Califomia to cause cancer, birt defects, or any other reproductive defects 16, OTHER INFORMATION Product code: AO7381 Version 3.0 Issued on: 04/11/2015 Page: 8/9 cue F0s (17269-16607-11051-011579)-2018.04-12 04:96:47SAFETY DATA SHEET ARKEMA . 7 PEBAX® MH 1657 Latest Revision(s) Reference number: ‘0000008536: Date of Revision, 04/11/2015 Date Printed 04711/2015 PEBAXG® is a registered trademark of Arkema Ine. Ackema Ine. believes thatthe information and recommendations contained herein (including data and Statements) are accurate as of the dato hereof, NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR. IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN, The information provided herein reiates only to the specific product designated and may not be valid where such product is used in combination with any other materials orn any process. Further, since the conditens and methods of use fare beyond the control of Arkema inc., Arkema Ino. expressly disclaims any and all iablity 2s to any results ‘obtained or arising from any use of the product or reliance on such information Product code: AO7381 Version 3.0 Issued on: 04/11/2015 Page: 9/9 cue F0s (17269-16607-11051-011579)-2018.04-12 04:96:47