CONFIDENTIAL *SULITS) RIKSAANMALAYSIA, Mayes UU DERIRSAAN MALAY STAMATEISPEPERIRN ERAT STAMA RIKSAANMALAYSI TR ANALALA SARL UL oe ot RUN MATANSIANLAULES “an als AYSIAN ry BRAN YMAMAJLIS. \ AYSIA ii y RIKSAANMA, wales AYSIAMAILIS, RIRY iS a AYSIA oe AAR AREDERTRSAANMATA Oe) VSIA MAL pe PERIKSAANMALAYSIAMATLISPEPERI Re ee RIRSUANTIALAYSIA see nERIRSAANMALAYS, RUSUNAALANVANA SPEPERIRSAANMALAYSIA Meds RIKRSAAN MALAY S SPEPERIKSAANMALAYSIA Le RIRSAANA 1 CHEMISTRY (KINA) | SPEFTRIRANAIALASIA MAyLIST! RIRAANMALAYSIANA RIRRYAAAUALARSIAMLAILS LIAN MALAYSIA SPEPERIKSA. MALAYS \ s AJLIS. RIKSA, 4ALAYS wus ©0000.) PAPER 2 (KERTAS 2) AMAJLISPEPERIKSAANMALAYSIA NAILISPEDERIKSAAN MALAY STAMAYLISPEPERI COUNTY are NALA SPEPERIKSAANA SIAM: SPEPERIKS. MALAYSL. VURAL One and a half hours (Satu jam setengah) |). 1900914 SPEPERIKSAANMALAYSIAA RIRIAAINEALAL SLAY Y Niall \ RIKSAANMALAYSIA PERIASAANMALAYSTAMAJL RIKSAANMALAYSIA MAJLIS PEPERIKSAAN MALAYSIA (MALAYSIAN EXAMINATIONS COUNCIL) SWIL TINGGI PERSEKOLAHAN MALAYSIA (MALAYSIA HIGHER SCHOOL CERTIFICATE) Instructions to candidates: DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO. Answer all questions in Section A. Indicate the correct answer on the Multiple-choice Answer Sheet provided. Answer all questions in Section B. Write the answers in the spaces provided. Answer two questions only in Section C. You may answer all the questions but, only the first two answers will be marked. Write the answers in the answer sheets provided. All ig should be shown. For numerical answers, units should on a new page of answer sheet. : Answers may be written either Arahan kepada calon: JANGAN BUKA KERTAS BERBUAT i Aneke Jawab semua soalan dalam apan Aneka Pilihan yang dibekalkan. Jawab semua soalan dalam B Jawab dua soalan sahaja da akan dip Scanned with CamScannerCONFIDENTIAL® 5 Section A (15 marks all questions Answ 10 g water, the temperature of the solution decrease in 100 g water, the ¢ f solution of NH4Cl? 1 When 7.91 g NH,CI is dissolved ty of the solution is 4.2 J £ by 5.2 °C, What is the enthalpy o1 [Assuming that the specific heat capaci NH,C1 is 53.5 g mol '] 25 mer? A 40.173 KJ mol! BB. +117 kJ mol! Cy ts ' eC !; molar mass of D +14.8k3 mort 1-' and the standard enthalpies of 1-1, respectively. What is the a f kJ mol 2 The standard enthalpy of formation of CH, is ~75 atomisation of C and CH, are +715 kJ mol | and +1664 kJ mol bond energy of H,? A +219 kJ mol! B +437 kJ mol! © +512 kJ mol! D +874 kJ mot! 3 The selected enthalpy changes of certain thermochemical equations are shown below, Thermochemical equations AMP /kI mol! Scanned with CamScannerCONFIDENTIAL 4 be arpeinlut “up of an electrochemical cell consisting of copper electrodes, P and Qs is wnt below P. 1.0 mol dm* 0.01 mol dm? queou coppert tl) — aqueous copper(I) sulphate. sulphate ‘The reduction potentials of copper clectrodes at 298 K are shown below Half-cell reaction EN Cu(1.0 mol dm\aq) + 2° = Cus) 40.34 Cu(0.01 mot dm\(aq) + 2e —= Culs) +0.28 ‘Which statement is true about the electrochemical cell above? A. Q acts as a cathode. B The em of the cell is +0.06 V. © The electrons flow from P to Q. D_ The concentration of Cu?* ions in Cu?*(0.01 mol dm*YCu(s) half-cell decreases. 5 The Nernst equation is written as E=E- The standard emf. of a cell is +1.1 5.00 mol dm’ and the concentratios | value of the e.m.f. of the cell? A +104 B +107V 6 The electrolysis of brine using a dis about the cell? A. The electrodes are graphite. B Hy is produced at the cathode, C The diaphragm is permeable D_ The diaphragm separates the 7 Which element has the lowest A’ Aluminium B PhCONFIDENTIAL® * 8 The properties of thre oxides, x Y and Zin Period 3 ane Periodic Table are shown beloy, jes of three oxides, X. , ses a solution which has pH 3. : yeous solution of sodium hydroxide. lium hydroxide ang +X dissolves in water and prods us solution of § + Y-does not dissolve in water but dissolves in an 04 ves in an quent + Zdoes not dissolve in water but dissolv hydrochloric acid. What are represented by X, ¥ and Z? x y Zz POs SiO; A SO; B P.O; SiO, ALO; MgO ALO; PO; SiO, 9 Which property accounts for the trend in the reactivity of Group 2 elements down the group? A Metallic character B__ lonisation energy Thermal conductivity D Melting point 10 The elements of Group 14 react with eblorine to form tetrachlorides, MCl,, Which statement is true about the tetrachlorides down the Group 14? A. The volatility decreases. B c D scanned with CamScannerCONFIDENTIAL 12 The repewting unit of poly(dimethylsiloxane) is shown below, ny O— $i Hy Which is not true about the property of poly(dimethylsiloxane) and its explanation’? A A fluid due to the strong intermolecular forces B An insulator due to the lack of mobile ions and mobile electrons C Repels water due to the presence of hydrophobic group D_ Chemically stable due to the Presence of strong Si-O, Si-C and C-H bonds 13 The reaction scheme of an aqueous solution of MX and an aqueous solution of AgNO, followed by NH, is shown below, sandhill iaaiainaae AgNO. 7 fee MX(aq) |ABNOs@4) | Coloured cow Nites) | insoluble precipitate What is the colour of fumes formed when a concentrated H)SO, is added to MX? A Pale yellow B_ Greenish yellow C Red-brown D Purple 14 Why Cl, gas is used in water treatment A It is soluble in water. B Itis a strong oxidising agent. C It reacts with water to form Hi D_ It forms a bleaching agent. 15 A catalyst is used in the hydrogenati about the hydrogenation? A. The catalysis is homogenous. B The catalyst has various oxi C Adsorption of the hydrocarbon D The hydrocarbons form covalCONFIDENTIAL* Section B [15 marks] Answers all questions Write the answers in the spaces provided. obtained by electro 16 Aluminium is the most widely used metal after iron, Aluminium 1s Y slectrolysis of aluminium oxde in molten cryolite carbon electrode Carbon | Aluminium oxide ‘arbon lininy . in molten eryolite a= Molten aluminium (a) Label the anode and cathode on the diagram above. ta (6) Write the half-cquations e and cathode. 2] Anode: Cathode: (c) State a reason i} (d) Write theCONFIDENTIAL* 17 The bond energy of hydrogen halides is shown in the table below. Bond HF H-Cl H-Br HA Bond energy/k} mot +562 +430 4370 +300 (a) What is meant by bond energy? 2 (6) Based on the data given, explain the variation of thermal stability of the hydrogen halides. BI () Arrange the hydrogen halides in as (d) State the intermolecular forces pre Scanned with CamScannerCONFIDENTIAI Section € [30 marks} Answers two questions only: jeriodic Table are shown in the table 18 (a) The selected data for elements of Group 2 in the Pe below ea wtion enthalpy) Solubility/ ‘Sulphate | Tonic radius/ | Hydration enthalpy/ 0, val | am ki mol! —_|_100 mol g Mgso, | 0.064 1891 CaSOq 0.094 SrSO, 0.110 a 1 —— BaSO, 0.134 0.009 x 10 Explain the differences in the reactivities of the elements of Group 2 with water and the solubilities of their sulphates. Ho} (b) Magnesium react with nitrogen at a very high temperature to produce yellow solid which consists of 72% magnesium by mass. (i) Why a very high temperature is needed to produce the yellow solid? Give a reason to your answer. 2] (ii) Determine the empirical formula of the compound. B) 19 (a) State two factors [2] (6) The enthalpies of (i) Predict the standard of NaCl 1] egies of iol! and