Wa0004.

DPP NO.
(JEE MAIN+ADVANCED)
Max Marks: Max Time:
]
1. Identify the group which exert -I, -M & +M effect
TB
(a) -NO2 (c) -SO2H
(b) -NO (d) -C≡N
2. Identify the group which exert -I, -M & +M effect

(a) -C=CH2
(b) -C≡CH [II
(c) -Ph
(d) All of these
NA
3. Which of the following is a strong withdrawing group?
(a) -F (c) -N+H3
(b) -O+H2 (d) -NH-COCH3
RA
4. Group showing the strongest +M effect:

(a) -NH2 (c) -NH-CH3
(b) -N(CH3)2 (d) -O-
IN
5. Which of the following is correct order of +M effect?

(a) NH2 > -OH (c) -O-COCH3 > -OH
(b) -OH > -O -
(d) -NH-COCH3 > -NH2
CH
6. Which of the following show both +M and -M effect?

(a) -Cl (c) -F
SA
(b) -CH=CH2 (d) -Ph
Page No. 1
7. Which of the following is showing greater +M effect?
(a) F (c) Br
(b) Cl (d) I
8. Which of the following group when attached to benzene ring

show withdrawing effect?
(a) -N+R3 (c) -C2H5
(b) -P+R3 (d) -OCH3
9. What is the correct order of +R effect?
]
(A) -O- (C) -NH2
TB
(B) -COOR (D) -OH
(a) A>D>C>B (c) A>C>D>B
(b) A>B>C>D (d) A>D>B>C
(b) -N R3
+
[II
10. Which of the following is releasing group when in resonance?
(a) -N+H3 (c) -NH-COCH3
(d) -F
NA
RA
IN
CH
SA
Page No. 2
ANSWERS
1. bc
2. d
3. bc
4. d
5. a
6. abd
7. a
8. ab
9. c
]
10. c
TB
[II
NA
RA
IN
CH
SA
Page No. 3
DPP NO. (JEE MAIN+ADVANCED)
Q. Find the no. of α-Hydrogens in the following compounds:
]
TB
CH3
1.
[II
NA
5.
CH3
RA
2. CH3
6.
IN
CH3
7. CH3
CH
3.
SA
4.
Page No. 1
CH3 CH2
13. CH3
CH3
14. H2C
8. CH3
CH3
15. H3C CH3
CH3
16. H3C
]
TB
CH2
9. CH3
17. H3C
CH3
CH3
10. CH3 [II

H3C
CH3
NA
CH3 18. CH3
CH2
RA
CH3
H3C
19. CH3
IN
CH3
11. CH3
H3C
CH
20. H3C
SA
12.
Page No. 2
ANSWERS
1. 4
2. 5
3. 6
4. 8
5. 2
6. 8
7. 6
8. 6
9. 6
]
10. 10
TB
11. 5
12. 3
13. 3
[II
14. 2
15. 5
16. 5
17. 2
NA
18. 12
19. 4
20. 4
RA
IN
CH
SA
Page No. 3
]
TB
CH2 CH3
1. H3C CH3
[II
NA
5.
2. H3C CH3
RA
3.
6.
IN
CH3
CH3
CH
H3C CH3
4.
SA
7.
Page No. 1
CH3
8.
CH3 13.
14.
9. CH3
]
CH2
TB
H3C
10.
[II
15.
CH3
NA
H2C
16.
RA
CH3
11.
IN
H3C 17. CH3

CH
CH3
18. CH3
SA
12.
Page No. 2
CH3 CH3 CH3 CH3
CH3
CH3
H3C
H3C CH3
19. CH3 CH3
21. CH3
H3C
]
TB
20.
[II
NA
RA
IN
CH
SA
Page No. 3
ANSWERS
1. 5
2. 8
3. 5
4. 3
5. 2
6. 1
7. 0
8. 4
9. 2
]
10. 7
TB
11. 1
12. 6
13. 3
[II
14. 3
15. 4
16. 7
17. 6
NA
18. 4
19. 6
20. 0
21. 6
RA
IN
CH
SA
Page No. 4
]
TB
+
CH +
H3C C CH3
1. H3C CH3
2. H3C
CH
+
CH3
[II 6. CH3
NA
CH3
+
C
+ 7. H3C CH3
H3C C CH3
RA
CH3
3. CH3
+
8. H3C CH2
IN
+
H3C C CH3
CH
4. CH3
9.
+
CH
CH3
+
SA
H3C C
+
CH
5. CH3
10.
Page No. 1
CH3 H3C CH3
+
C
+
C
11.
17.
CH3
+
HC
+
CH
CH3
]
12.
TB
18.
CH3
[II
CH3
+
HC
13.
+
NA
CH
19.
+
C
RA
H3C CH3
14. C
+
+
CH
IN
20.
15.
CH
+
CH
+ CH3
CH
SA
16.
21.
Page No. 2
+
CH
22.
+
C
+
CH
24.
23.
CH3
]
CH3
25.
+
TB
CH
[II
NA
RA
IN
CH
SA
Page No. 3
ANSWERS
1. 6
2. 5
3. 6
4. 6
5. 6
6. 7
7. 9
]
8. 1
TB
9. 4
10. 4
11. 7
12. 3
13.
14.
15.
4
5
3 [II
NA
16. 4
17. 6
18. 2
19. 3
20. 6
RA
21. 5
22. 2
23. 4
24. 4
IN
25. 3
CH
SA
Page No. 4
Q. Give the relative stability of the following compounds:
]
TB
1. I. II.
[II III.
NA
H
RA
IV. V.
Me Me Me
IN
Ph CH2 CH CH C Me Me C CH CH C Me
CH
2. I. Me II. Me Me
Me Me Me
SA
Ph CH CH C Me Me C CH CH C Me
III. Me IV. Me Me
Page No. 1
Me
+ +
H3C CH CH CH3 Me CH2
+ +
3. I. Me II. Me CH2 III. CH3 IV. Me
+ + + +
C CH C C
4. I. II. III. IV.
]
TB
+
C
[II
+
C + +
CH C
5. I. II. III. IV.
NA
6. I. II. III. IV.

RA
7. I. Me II. III.
IN
CH CH2
CH
SA
Page No. 2
ANSWERS
1. I>II>III>IV>V
2. III>I>II>IV
3. I>II>IV>III
4. I>III>IV>II
5. I>IV>II>III
]
TB
6. I>III>II>IV
7. III>I>II
[II
NA
RA
IN
CH
SA
Page No. 3
]
TB
1. I. II.
[II
NA
2. I. II. III.
RA
3. I. II.
IN
CH
III.
SA
4. I. II. III.
Page No. 1
.
. .
5. I. II. III.
6. I. II.
]
TB
CH CH CH CH
7. I. II.
[II III. CH CH
IV. H3C C C CH3

NA
RA
8. I. II.
IN
CH
SA
Page No. 2
ANSWERS
1. I>II
2. I>II>III
3. II>I>III
4. I>II>III
5. II>I>III
6. I>II
7. IV>III>II>I
]
TB
8. II>I
[II
NA
RA
IN
CH
SA
Page No. 3
]
TB
1. a. b.
[II
NA
2. a. b.
RA
3. a. b.
IN
CH
SA
4. a. b. c.
Page No. 1
5. a. b.
6. a. b.
]
TB
7. a. b. [II
NA
RA
8. a. b.
O O
IN
CH
9. a. b.
SA
10. a. b.
Page No. 2
ANSWERS
1. b>a
2. a>b
3. a>b
4. c>a>b
5. a>b
6. b>a
7. a>b
]
TB
8. a>b
9. a>b
10. a>b
[II
NA
RA
IN
CH
SA
Page No. 3
]
TB
1. a. b.
[II c.
NA
2. a. b. c.
RA
IN
CH
3. a. b. c.
SA
Page No. 1
4. a. b. c.
]
5. a. b. c.
TB
+ +
CH C
[II
+
CH
6. a. b. c.
NA
RA
7. a. b. c.
IN
CH
8. a. b.
SA
9. a. b.
Page No. 2
ANSWERS
1. b>a>c
2. a>b>c
3. b>c>a
]
TB
4. c>a>b
5. a>b>c
6. c>a>b
7. a>b>c
8. a=b [II
NA
9. a>b
RA
IN
CH
SA
Page No. 3
Sl. Compound Huckel’s All carbon of Cyclic Complete Nature
]
No. Rule the ring is Delocalisation
TB
(4n + 2)π e-
sp or sp
2
1.
2. [II
NA
N OH
3.
RA
4.
IN
CH
5.
SA
Page No. 1
Sl. Compound Huckel’s All carbon of Cyclic Complete Nature
No. Rule the ring is Delocalisation
(4n + 2)π e-
sp or sp
2
6.
NH
7. NH
]
8.
TB
NH O
9.
[II
N
NA
N
10. BH
RA
IN
CH
SA
Page No. 2
ANSWERS
1. ✕, ✕, ✓, ✕, Non-Aromatic
2. 6π, ✓, ✓, ✓, Aromatic
4. 6π, ✓, ✓, ✓, Aromatic
5. ✕, ✓, ✓, ✓, Anti-Aromatic
]
TB
7. 6π, ✓, ✓, ✓, Aromatic
8. 6π, ✓, ✓, ✓, Aromatic
9. 6π, ✓, ✓, ✓, Aromatic
10. ✕, ✓, ✓, ✕, Anti-Aromatic [II

NA
RA
IN
CH
SA
Page No. 3
Q. Classify the following compounds as Aromatic (Aro), Anti-

Aromatic (AA) or Non-Aromatic (NA):
]
TB
1.
8.
–
HC
[II
–
CH
2.
HC
+ 9.
NA
3. +
CH
+
CH
RA
10.
4.
+
CH
BH
–
CH
IN
– 11.
5. CH
+
CH
CH
O
6. O
12.
SA
BH
7. O O
O
13.
Page No. 1
ANSWERS
1. NA
2. AA
3. Aro
4. Aro
5. Aro
]
6. NA
TB
7. NA
8. NA
9. Aro
10. AA
11. AA
[II
NA
12. Aro
13. Aro
RA
IN
CH
SA
Page No. 2

]
TB
1.
7. O
[II
O
2. 8.
NA
+
CH
S
3.
9.
RA
NH
4.
IN
10.
5. O
CH
+
CH
11. O O
SA
6. O
Page No. 1
ANSWERS
1. AA
2. Aro
3. Aro
4. Aro
5. NA
6. Aro
]
7. NA
TB
8. NA
9. Aro
10. NA
11. Aro [II
NA
RA
IN
CH
SA
Page No. 2

]
O N
TB
N
5.
1. O
[II
NA
6. NH
2. NH O
RA
7.
+
NH
N
IN
NH
3. NH
8.
N
CH
+
HN
NH
9.
4. N
SA
Page No. 1
ANSWERS
1. Aro
2. Aro
3. Aro
4. Aro
5. Aro
6. NA
]
7. Aro
TB
8. Aro
9. Aro
[II
NA
RA
IN
CH
SA
Page No. 2

]
TB
– –
CH N
1.
O
[II
5.
NA
6. NH
2.
RA
S
N
7.
IN
3. O
CH
8.
H3C
B N
SA
N N
9. HN N
4.
Page No. 1
ANSWERS
1. Aro
2. AA
3. Aro
4. Aro
5. Aro
6. NA
]
7. Aro
TB
8. Aro
9. Aro
[II
NA
RA
IN
CH
SA
Page No. 2

]
TB
[II
4. CH
–
NA
1.
5.
RA
+
CH2
6.
IN
–
CH2
2.
CH
7.
3.
SA
8. N
O
9.
Page No. 1
ANSWERS
1. Aro
2. Aro
3. Aro
4. Aro
5. Aro
6. Aro
]
7. Aro
TB
8. AA
9. Aro
[II
NA
RA
IN
CH
SA
Page No. 2

]
TB
O NH
[II
4.
NA
1.
CH2
RA
5.
2.
IN
O –
CH
CH
6.
3.
SA
7.
Page No. 1
9.
8.
SA
Page No. 2
CH
IN
RA
NA
[II
TB
]
ANSWERS
1. Aro
2. NA
3. Aro
4. Aro
5. Aro
6. AA
7. AA
]
8. Aro
TB
9. Aro
[II
NA
RA
IN
CH
SA
Page No. 3

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DPP NO.

2. Identify the group which exert -I, -M & +M effect

4. Group showing the strongest +M effect:

5. Which of the following is correct order of +M effect?

6. Which of the following show both +M and -M effect?

(b) -CH=CH2 (d) -Ph

8. Which of the following group when attached to benzene ring

9. What is the correct order of +R effect?

Q. Find the no. of α-Hydrogens in the following compounds:

10. CH3 [II

Q. Find the no. of α-Hydrogens in the following compounds:

H3C 17. CH3

Q. Find the no. of α-Hydrogens in the following compounds:

Q. Give the relative stability of the following compounds:

4. I. II. III. IV.

6. I. II. III. IV.

Q. Give the relative stability of the following compounds:

IV. H3C C C CH3

Q. Give the relative stability of the following compounds:

Q. Give the relative stability of the following compounds:

Sl. Compound Huckel’s All carbon of Cyclic Complete Nature

10. ✕, ✓, ✓, ✕, Anti-Aromatic [II

Q. Classify the following compounds as Aromatic (Aro), Anti-

Q. Classify the following compounds as Aromatic (Aro), Anti-

Q. Classify the following compounds as Aromatic (Aro), Anti-

Q. Classify the following compounds as Aromatic (Aro), Anti-

Q. Classify the following compounds as Aromatic (Aro), Anti-

Q. Classify the following compounds as Aromatic (Aro), Anti-

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