CCR i ct ® Transition Element : According to IUPAC, transition metals are defined as metals which have incomplete d subshel] either i in neutral atom or in their ions. 2m, cag Mg aarts “S) Pahl Fille A wn Ee 4 (ee) ok | ®t cai ps Ms wp ss is Frew Clemd be co? si wily d in ih a General Electronic configuration @ \-lo nel fo Fo ra in Pa (ccephana sh excepianel Ws + Novawd Gakgshos (n-lndCompl /| Tu eee ee eee eeu ae / (ene (axdintn ) @ Atomic size 4 * Complex formation p1 . wf ee * Ionization Enthalpy' * (Colour of aqueous ion * Spin only magnetic moment) Jina Unpained & Vina point Somat Alloy formation % Catalytic power: D ‘Interstitial compound formation of a dl! ** Variable oxidation state we: unless & Melting point will he da X Standard reduction potential ’ Atomic size Already discussed ult eee = 2 a eae a ny in ~~ La Hf Ta W Re Os Ir Pt Au Hg V ud yi lee wu 5 of duh LClonization Enthalpy Min pax @ @® ase O.... . _.& M bd seouer ® oe . @ Sd Sedier 6 -s = “Se iy wwe pa Kyuuste Final ody vie ete Scere Ti Mind Wi Cus Cot Fe Zn Gn Kind MN Kn Hua Gi My a Be aay OO] Lr be) qys! nde ol file a Conia aret f %Spin only magnetic moment @ = fn(n+2) (ypall he Nes © oe Qey bed qi Py y23 Ue oie e Alloy formation @ Alloys are formed by atoms with metallic radii that are within about 15 percent of each other. es Ex.:>! Brass (Cu(60%) + Zn(40%) © German silver(Cu(1) + Zn(1) + Ni(2)) 25 Bronze (Cu + Sn) 660perro Sh 25 : i Trsor , 4, +50, @ Catalytic Properties e - 3 & a Reasons > oe eral state Spa TA ttfet (i) Complex formation property Pe Lt e 0, feorids. / 9 & sey) Sy tfe N, +3H,—> 2NH, Ziegler Nata TiCl, + (GH), (use in polymerization) 50, +1225 so, Wilkinson catalyst (PPh); RhCl i) Na Veg. Oil > Veg. ghee (Hydrogenation of alkene) csc 2 cx,cuo| aco P04) & Interstitial compound formation @ * These can be prepared by trapping of small sized non-metal like 30) CG Nin interstitial space of crystal lattice of metals. * Non-stoichiometric compound-> Mong r fos", Vis e * Neither ionic nor covalent «Afardnesst(NiB — hardness similar to diamond) *, due +p Be in Pang efeclency » Mp ty v Conductance remain same . Chemically inert &Variable oxidation state Hie ® Due to low energy gap between ns & (n- 1)d. (ns) (n-1)d sc-942 Cro4+1 e° ofns=Y) unpaired e° Fe,Co>+5 Cu++2 (n-1) 45x) % OS. range = ¥ to (X + Y) , \ k Gis steble to Wy) & In Aq. Medium +! d Cut + Cut —> Cu + Cu Stability > Cut< Cu Hydration’ Release energy t Stability T ches Highea. chudge. Te Te = PblaX Pb‘. . Ph’? Cull x Bis Bis Cul ¥ Fes Fe’ Cuak v Cur. Cutt & Fary= to (5%2) = gto} Ma WEY aot te Hh eS 2+ Vea + My +tyMelting point (rey NCERT) @ M.P. depends on (i) unpaired e9 in (n- 1) d subshell (ii) atomic mass 7 7 (iii) packing efficiency in solid 4 * Maximum M.P. in d block W) + MP = J2n>Cd>Hg & Sc>y > 1a Cu>Au>Ag 3 A | Vv A vi Tae ud ud hy 2 Vv A ‘ sa] || 5a A 3 ° sya )le ~ve Standard reduction potential 5 oe AG +ve [Bem = efor al 3d-series except|E” ..., = We goa on: sport or (due to greater IP,) c = 4ve ey ia ow +ve a =e (2-1 46 ) Won spt shy Cu Cnn ta Ny go Fr, A as }eT] cout (onto) @ ee ete Bagge = NE 0.79 ea» ret ( edoivg cya) 0 a Eco =tve 19 E 0 S at pe = *¥E Eee Identify 0.A. and R.A. 5 @ ac- 9 Stabe cre (RA) Mn** (0-A) Qwik &LACE ELC / @ ph) @ 2- a % Chyomralg (vir) xe dichroreds jan \0n rte In adidic stable diva ‘yn Bau “ Modiuey * Ovonye pir CxO chromehson jun dP bul 7 Aw fC 4K av. Adkotod ed P y 070 be Gey dechpamade (ow A, bonds (um 4% yi "© wht 0 4 at Cr-0 Bond lengths his Smale re) ete fd a vm f Srl Cr es 4TP We i cr) Nog03 > lacing (™ HE] SIL) @ Nay, KG}, Syvbyoki «|e thy eo Pun Snel” (eu + chots a et Sn Need Mesum & ty tie | a Pram Chatite ore ( Fecg%) Bandit % x6 NgoC0. at, + C10, Py NajGOu sd Goan Bowe — Acidic yt yllna ve Sdidion cae RSI We t (tgs “bn ta Lan Seley & rire (Air) 0. Fe odin=x @ as . Toy 7 i hoy ate Mi Masgande. on Permongnul: a in Bane, jon y ne Vict 9 PORE oe. g 9 = on Gr 46, hands Avy: FC on's’ ) Pode fr bios _ ~ Aer hed. 3 Gebahuitel fy My -) Boe I te ete i . water (#U) Avy My-0 Bo why ei Sat" fi oe bays 6 4 ys ut Gd) yeo 1 ei hamagnahic fara a Gud enpahin dcgeodint vu Ei gon cor) | Pave; M Doing , . 8 tay + May +4 ee ch / ni lug Kr [Pa ne” 6 i ee () 3 Kino { Pow oA / Important properties of K,Cr,0, & KMnO, / @ + Oxidizing power —> re Strong ofidising Reubn + Beth Ma i atianreoh ie order ¢ ORs POE? oy > ONOidising Rewctons a Tor in neutral i AR lane . iy oe Od Pudgle ret ie amid elt Ney es Ba sm sd" sit si" ie ys Gay Cop ad 7Q Ws —-S ob TN, Sy Sa sage ot (ug) ciferft— aa 4 if ma FT| 4s Th & Ni on h Cay0g” (avenge) at pei vedi 8 eva fee gytt -Esi(t T 1, Hys SRS ee cpLe ‘ +h 2 80. a ee Cx,03 (RA) th G | otonge Cy (54), Kon ct & ip hos 4” Gombe Shige in Pesencedy Wig EN @ Clrwts like F &0 7 Hos My is wore stable ath 0 ap compu dn 4o tru ple bad Faxon Capa 0 2 aay My Oy / MF, Hh Mnf, tik He + dyn En Hd Ug duns stent Wo, & ify CoonStability 1-0-5 in d-blod< Tse dowdy te. “ : Inverse imertpars effect ey 8 (brblack ) ids) +6 Coos nm eC . Stable Gt, > Mal,” wo, | fs More Stobke te nf sh in t6 § Vo one | Gon nt 02 wig | oriaisng ff a~ General Electronic configuration Ve * Ionization Enthalpy S * Atomic size & lonic oye Ale discusse] le falls.Lontruneids Acknwds @ O & filkdin vf € filedin Sf © poor r4 uf (ore poor o4 5fe- @ zt P Conteaction zal ‘he ae ® Gmmm os +3 Ate 0s shedy by qh, Vani os MayioyunO'S “HE shawh by Np & fu Achnwids > Losthenside (sw @ Achnaids bie) Sing Ise Eat 5 move Bayic OF Han, Lohans ds Bae charasta 4 uke Hore Renchne tuun, Leaunet Lolo, - oo fee _Lu(O™), SH ENT Acidic? ganic)que Alot all tunvaonds (M (wt) ny \ Lanter Q) ase Count eet git Lu” ae, , Chole la a” Get er ie" yo duoaayn @ =m LnCls a HCI jf. ae OX Xe alt) “On as ; & 2e uptown wo An ui ® LnN ae = uf IS) iy ie eagent Ce* Can be used as analytical reagent in aqueous medium. Renastn — Readion blu) CeMH & Hy? IS i at Vi Slow cot col at és "I +4 2+ \Tb 5 yo yet oA | © * Nd Max. paramagnetic * Sm Steel like, * Pm — Radio active * Misch metal (metal alloy) + (Ln=95%, Fe=5%, C,5, Ca, Al) * Ruby (Red) — Cr** In Al,O; * Emerald (green) -> Cr?*in Beryl * ‘UK copper’ — copper coated steel + ‘Silver UK’ — Cu/Ni alloy