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TOPICS: Engineering Graphene Materials Science MIT Nanoscience > Subscribe Free to Email Digest
Nanotechnology Photonics

開く
施工及び販売

By JENNIFER CHU, MASSACHUSETTS INSTITUTE OF TECHNOLOGY APRIL 4, 2017

39,600円

MIT engineers have developed a new technique to produce graphene with fewer wrinkles, using 39,600円 17,600円 50,600円
wafer-scale “single-domain” graphene. The method can also iron out any wrinkles that do
appear.

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By using an adhesive-like layer of nickel to peel graphene from silicon carbide, POPULAR ARTICLES
engineers at MIT have developed a technique to produce highly conductive wrinkle-
free graphene wafers.

開く to silicon and for years


Graphene has been touted as a promising successor x
researchers around the globe have observed that electrons can blitz through
最高水準の室内環境
graphene at velocities approaching the speed of light. This is far faster than
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they can travel through silicon and other semiconducting materials and one of
the reasons why scientists believe graphene has the potential to enable faster,
more efficient electronic and photonic devices.

The holdup comes with the manufacturing process. It is extremely difficult to


manufacture a single, perfectly flat, ultrathin sheet of carbon atoms, precisely
AUGUST 18, 2023
aligned and linked together like chicken wire. Conventional fabrication
processes often produce wrinkles, which can significantly limit graphene’s
high-speed electrical performance.
Animal vs. Plant
Now a team of engineers from MIT think they might have solved this “wrinkle” Protein: New
problem. Using a technique that successfully produces wafer-scale, “single-
domain” graphene (single layers of graphene that are uniform in both atomic
Research Suggests
arrangement and electronic performance), they have developed a new way to
make graphene with fewer wrinkles and a way to iron out the wrinkles that do
That These Protein
appear.
Sources Are Not
The researchers tested the electrical conductivity after fabricating and then
flattening out the graphene, revealing that each wafer exhibited uniform Nutritionally
performance; meaning that electrons flowed freely across each wafer, at
similar speeds, even across previously wrinkled regions. Equivalent
Consuming equal ounce-equivalent
portions of animal-based and plant-
based protein foods, as per the Dietary
Guidelines for Americans, leads to
varying levels of essential amino acid…

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AUGUST 18, 2023

A New Way To Control


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The new research is published today in the Proceedings of the National Novel Nanoscale Material
Academy of Sciences.

“For graphene to play as a main semiconductor material for industry, it has to AUGUST 18, 2023
be single-domain, so that if you make millions of devices on it, the “Dirty” Surprise: Webb
performance of the devices is the same in any location,” says Jeehwan Kim, the Space Telescope Locates
Class of 1947 Career Development Assistant Professor in the departments of Dust Reservoirs in Two
Mechanical Engineering and Materials Science and Engineering at MIT. “Now Supernovae
we can really produce single-domain graphene at wafer scale.”
AUGUST 18, 2023
Kim’s co-authors include Sanghoon Bae, Samuel Cruz, and Yunjo Kim from
MIT, along with researchers from IBM, the University of California at Los UCLA Scientists Uncover
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A patchwork of wrinkles
The most common way to make graphene involves chemical vapor deposition,
or CVD, a process in which carbon atoms are deposited onto a crystalline
substrate such as copper foil. Once the copper foil is evenly coated with a
single layer of carbon atoms, scientists submerge the entire thing in acid to
etch away the copper. What remains is a single sheet of graphene, which
researchers then pull out from the acid.

The CVD process can produce relatively large, macroscropic wrinkles in


graphene, due to the roughness of the underlying copper itself and the process
of pulling the graphene out from the acid. The alignment of carbon atoms is
not uniform across the graphene, creating a “polycrystalline” state in which
graphene resembles an uneven, patchwork terrain, preventing electrons from
flowing at uniform rates.
x
In 2013, while working at IBM, Kim and his colleagues developed a method to
fabricate wafers of single-crystalline graphene, in which the orientation of
carbon atoms is exactly the same throughout a wafer.
Rather than using CVD, his team produced single-crystalline graphene from a
silicon carbide wafer with an atomically smooth surface, albeit with tiny, step-
like wrinkles on the order of several nanometers. They then used a thin sheet
of nickel to peel off the topmost graphene from the silicon carbide wafer, in a
process called layer-resolved graphene transfer.

Ironing charges
TAGS
In the newly published study, Kim and his colleagues discovered that the layer-
resolved graphene transfer irons out the steps and tiny wrinkles in silicon
carbide-fabricated graphene. Before transferring the layer of graphene onto a Artificial Intelligence Astronaut

silicon wafer, the team oxidized the silicon, creating a layer of silicon dioxide
that naturally exhibits electrostatic charges. When the researchers then Astronomy Astrophysics
deposited the graphene, the silicon dioxide effectively pulled graphene’s Behavioral Science Biochemistry Biotechnology Black
carbon atoms down onto the wafer, flattening out its steps and wrinkles. Hole Brain Cancer Cell Biology Climate

Change Cosmology COVID-19 Disease


Kim says this ironing method would not work on CVD-fabricated graphene, as
DOE Ecology Energy European Space Agency
the wrinkles generated through CVD are much larger, on the order of several
microns. Evolution Exoplanet Genetics Harvard-
Smithsonian Center for Astrophysics Hubble Space
“The CVD process creates wrinkles that are too high to be ironed out,” Kim Telescope Infectious Diseases International
notes. “For silicon carbide graphene, the wrinkles are just a few nanometers Space Station JPL Mars Materials Science Max
high, short enough to be flattened out.”
Planck Institute MIT Nanotechnology
The researchers fabricated tiny transistors on multiple sites on each wafer, NASA NASA Goddard Space Flight Center
including across previously wrinkled regions, to test whether the flattened,
Neuroscience Nutrition Paleontology Particle
single-crystalline graphene wafers were single-domain.
Physics Planetary Science Planets

Popular Public Health Quantum

Physics Virology Yale University

“We measured electron mobility throughout the wafers, and their performance
was comparable,” Kim says. “What’s more, this mobility in ironed graphene is
two times faster. So now we really have single-domain graphene, and its
electrical quality is much higher [than graphene-attached silicon carbide].”

Kim says that while there are still challenges to adapting graphene for use in
electronics, the group’s results give researchers a blueprint for how to reliably
manufacture pristine, single-domain, wrinkle-free graphene at wafer scale.
x
“If you want to make any electronic device using graphene, you need to work
with single-domain graphene,” Kim says. “There’s still a long way to go to
make an operational transistor out of graphene. But we can now show the
community guidelines for how you can make single-crystalline, single-domain
graphene.”

Reference: “Unveiling the carrier transport mechanism in epitaxial graphene


for forming wafer‐scale, single‐domain graphene” by Sang-Hoon Bae, Xiaodong
Zhou, Seyoung Kim, Yun Seog Lee, Samuel S. Cruz, Yunjo Kim, James B.
Hannon, Yang Yang, Devendra K. Sadana, Frances M. Ross, Hongsik Park and
Jeehwan Kim, 3 April 2017, PNAS.
DOI: 10.1073/pnas.1620176114

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