CO’ HOC LUOQNG TU - 1 cau 1. 1. Mot laze c6 nding long 0,4) durge tgo ra tir cc xung bic xa trong 3,0 ns (nano giy). Tinh cng sudt do 1 xung ciia laze dé tao ra. 2. Bitc xa vi séng cb buéc séng 1,0 cm. Tinh tin s6 va ning ling cia mét photon cia bite xa va cla mot Avogadro photon (goi la 1 einstien)? 3. Bite xa trong ving tir ngoai ciia phd dién tir thwéng dug mé ta theo bwéc séng theo don vi nanomet (10°m). Tinh tin s6, s6 s6ng va nang lugng ca bite xa din tir 6 burée séng 200 nm. Bai 2. 1. Tinh burée sng de Broglie trong mdi trudng hop sau: a) M@t electron di chuyén vai tc dé bing 10% tc d9 anh sang. b) Mét qua béng tenis (55 gam) di chuyén véi t6c 46 35 m.s*. 2. Nhiéu xa neutron dugc ding dé xdc dinh cau tric cla cdc phan tir. Khéi lugng cla neutron la 1,675.10?” kg. ‘a) Tinh bwée song de Broglie cia mét neutron di chuyén voi tdc dé bang 1,00% tc 46 Anh sang. b) Tinh tc dé cita neutron véi buéc séng 75 pm. 3. MOt nguyén tir cia nguyén té X chuyén déng voi téc dé bang 1% téc dé anh sang. Buéc song de Broglie do duc la 3,31.10-3 pm. Xac dinh nguyén t6 X, Bai 3. 1. Tinh tn s6 va buéc s6ng de Broglie trong méi treéng hop sau: a) Neutron c6 dng nang 0,1 eV. ) Electron tur do véi dng nang 300 eV. 2. Tinh buéc séng va déng ning cia mét electron trong chim electron duoc gia tc boi hiéu dién thé 100V. 3. Anh nhiéu xa cia mt hgp chat durgc chyp bang kinh hién vi dién tir truyén qua véi dién ap gia toc 14.200 KV. Tinh bude s6ng ctia chim dign tr gia toc. 4. Déng electron chuyén doi qua hiéu dién thé U cé dé dai séng la 6,1 pm. Tinh U. 5. M@t trong nhimng ki thudt hién dai higu qua nhat dé nghién ciru cu tric 18 nhiéu xa neutron. KT thuat nay lign quan dén sur tgo thinh chim neutron & nhiét d6 xc dinh tir ngudn neutron nang long cao trong may gia tc. Néu t6c dé cia neutron duoc xac dinh bdi cng thitc ve = (3ksT/m)}/%; trong dé: m 1,675.10? kg - kh6i luong ciia neutron, ke = R/Na= 1,382.10 J.K"" Ia hing s6 Bontzmann, Tinh nhiét 46 T can dé cdc neutron c6 buéc séng de Broglie bang 50 pm. Bai 4. Dong nang cita phan tt phy thudc vao nhiét 4 theo hé thirc: Ea = 1,5ksT. Trong d6 ke = 1,387.10: 23)K-1 1a hang s6 Boltzmann, T 1a nhiét d6 tuyét déi. 1. Tinh d6ng nang, van tc va d6ng lwong cia nguyén tir calcium thoat ra khdi 1d & nhiét dé 600°C. Cho me, = 39,96u, 2. Céc nguyén tt calcium bj cuén vao mot cdi bay, & 46 ching bi quang héa do bi ban pha boi tia laze c6 buéc séng A = 396,96 nm. Hay tinh tan s6, nang lwong, déng lugng ciia mot photon co bude song trén, 3. Tinh momen d6ng long obital (M = Ayi(/ +1) , | 4 s6 long tir phy) va momen dong lung spin (Ms = nJs{s +1), 11a s6 lwong ti spin) cia electron trong ion Ca* 6 trang thdi co ban. Cho biét n= la hing Qn ‘s6 Plank rit gon, 4. Khi hap thy bite xa v6i buée s6ng 396,96 nm thi nguyén tir Calcium chuyén lén trang thai kich thich eng voi mic ning luong thir nhdt, con hap thu bite xa cé buréc séng 393,48 nm thi chuyén lén mirc nang Gy. Le Think CHL ; 1 — Scanned with CamScannerluong thir hai, Hay tinh bu6c séng ctia photon phat ra khi nguyén tir calcium chuyén tir mirc nang lrong. thie hai vé mic nang luong thér nhat. Bais. 1. Cong thoat ciia khdi b® mat lt 2. Can 2084 kj dé tich 1 mol electron khdi cdc nguyén tir trén bé mat kim loai Rb. Chiéu chiim sng cé buc séng 254 nm vao kim loai Rb. Tinh dng nang cuc dai cia quang electron. 3. Tan s6 nguéng cia kim loai K la 5,464.101* s+, Néu sir dung kim loai nay lam cathode quang dién thi khi chigu anh séng tir ngogi c6 buéc séng 300 nm vao pin quang dién thi tc d6 cuc dai cia quang electron 1a bao nhigu? 4. Cong thodt cita Cr 4,40 eV, Tinh dong nang cia electron thost ra tir be mat Cr khi dwroc chi6u bite xa tir ngoai cé buéc séng 200 nm. 5. Khi chiéu xa_vao bé mat kim loai bac boi anh sing c6 bu6c séng 230 nm, dng ning ctia electron birt ra la 0,805 eV. Tinh cong thoat va tan sé ngwong cia bac. Bal 6, Khi chiéu photon anh sang 6 bur6c s6ng A (nm) vao bé mat kim loai sodium thi déng nang cue dai cia quang electron (Es) duge xc dinh qua thc nghigm nhu sau: 2 (nm) yoo [| 200 | 300 | 400 | 500 ieee SORE. (ev) tor | 394 | 188 | 0842 | 0,222 Sur phu thude dng nding cia electron (Ea) vao tin s6 cia photon 18 tuyén tinh. Xac dinh hang s6 Planck (h), tn sO nguong va cong thost cia kim loai sodium bing phwong phap d® thi tuyén tinh, Bai7. 1. Khi chiéu photon anh sang c6 bude séng A (nm) vao bé mat kim loai sodium thi déng nang cue dai iia quang electron (Es) doc xicdinh qua thue nghigm nhursau (amy 3125 | 365.0 | 4047 | 5461 | E410" (J) 341 2.56 295i SO ZS i "Sw phu thude déng nang cla electron (Ea) vao tin s6 cia photon Ia tuyén tinh. Xéc dinh hang s Planck (tn s6 ngudng va nang rong fon hoa (0) cia kim lai sodium bing phrong php th uy jium 1a 279,7 kJ/mol. Tinh bu6e séng cuc dai cia anh séng cé thé loai 1 electron 12 9 10 498 623 41 945 121 112 112 110 iu dé oan thank bang tren. vi hattrén cé hai vi hat c6 46 dai lign két nhur khac biét om Scanned with CamScannerCO’ HOC LUONG TU - 2 Bail. 1. Su pha v6 cdc lién két CI-Cl trong phan tt chlorine du6i téc dung photon cé buéc song ds 495nm. ‘Tinh nang lwong phan li lién két CI-Cl ciia phan tir Cle (theo don vi kj.mol) ? 2. Dé pha va lign két II trong mot mol Iz ddi hoi phai cung cp mot ming lung la 150,48 kj dui dang nh sng kich thich. Hay tinh bute song ting véi anh séng trén theo nm? 3. Anh séng nhin thay c6 phan hity duoc Bray thanh céc nguyén tir khéng, Biét rang nang long pha vo lién két gitta hai nguyén tir1a 190k).mol*. Tai sao hoi Bro c6 mau? Bai 2. Ozon hap thy tia tir ngoai va bj phan li nhur sau: 03 + hy -+ Op + 0. M6t mau khdng khf c6 thé tich 1,0 lit & 22°C va 748 mmHg chita 0,25 ppm Os (ppm: parts per million - mét phan trigu). Gia st rang méi photon hap thu am cho m6t phan tir ozon phan li va bu6c séng cita bie xa chiéu vao 1a 254 nm. 1. Khi to’n b6 long ozon trong mau khong khé trén phan li hét thi nang lwong da hap thu 1a bao “nhi@u (theo don vi)? ae p higu teng nhiét AH cia phan tng trén (nding lwong can thiét dé phan li hoan toan 1 mol 03). : 10®m.s3; h = 6,625.10" 3.022.102 mol, R = 0,082 atm.L.mol.K. phan tirc6 thé bi phan li thanh hai nguyén tik bing cach hp thu mot photon c6 nang luong di Jon. Nang lwgng néu du s@ chuyén thinh déng nang cia cdc nguyén tir khi chiing tach khdi nhau. Néu ‘mot phan tir chlorine & trang thai dirng (khéng chuyén dong) hap thu mt photon cé béc s6ng 300nm thi t6c dé cila hai nguyén tir khi téch ra khoi nhau la bao nhiéu? Gia sir nang long dw due chia déu cho hai nguyén tik 5,45; Na = 6,022.1023 mol pha vo’ cdc lign két Cl-Cl trong m@t mol chlorine doi hoi mot nang long bang 243 thé str dung doi dang quang nang). Hay tinh bu6c sng cia photon can sir dung phan tt 1H95Cl va HBr ngudi ta thay rang chiing hap thu photon c6 s6 song 2650 cm" khi chuyén tir v = 0lén v= 1. cctia HCI va HBr. Scanned with CamScanner