T-144457

Ai²TS-1(XII)
APT – 2

SECTION-I : PHYSICS
PART-A (One or More Correct Type)
This section contains 06 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONE or MORE is correct.

. An object may have

(A) varying speed without having varying velocity
(B) varying velocity without having varying speed
(C) nonzero acceleration without having varying velocity
(D) nonzero acceleration without having varying speed.

Ans: BD

Sol:
Velocity measurement will be measure of speed and direction. So, velocity can change due to
change in direction as well.

2. The accelerations of a particle as seen from two frames S1 and S2 have equal magnitude
4 m/s2.
(A) The frames must be at rest with respect to each other.
(B) The frames may be moving with respect to each other but neither should be accelerated
with respect to the other.
(C) The acceleration of S2 with respect to S1 may either be zero or 8 m/s2.
(D) The acceleration of S2 with respect to S1 may be anything between zero and 8 m/s2.

Ans: D

Sol:
  
as2 ,s1  as2,P  aP,s1

as ,s  42  42  2  4  4 cos 
2 1
Since cos  will be from -1 to +1
0 as ,s  8
2 1

3. An electric dipole is placed in an electric field generated by a point charge.

(A) The net electric force on the dipole must be zero
(B) The net electric force on the dipole may be zero.
(C) The torque on the dipole due to the field must be zero
(D) The torque on the dipole due to the fiddle may be zero

Ans: D

Sol:   
Since torque on dipole is      ,
If dipole and electric field are parallel to each other then torque will be zero

4. A capacitor of capacitance 500 F is connected to a battery through a 10 k resistor. The

charge stored on the capacitor in the first 5 s is larger than the charge stored in the next.
(A) 5 S (B) 50 S (C) 500 S (D) 5000 S

Ans: ABCD
 Sol:
Charge on capacitor at any instant is q  CV 1  e 
 t /Rc

here Rc  10  103  500  106  5 Second

 
So, charge on first 5 second will be CV 1  eS/5  0.632 CV
So, this is more than half of total charge.

5. Two blocks of masses m1 and m2 connected by a spring of spring constant k are kept on a
plank which in turn is kept over a frictionless horizontal surface as shown. Coefficients of
friction between masses m1 and m2 and plank are 1 and 2 . Plank is given a horizontal
acceleration of magnitude a. Then

(A) Elongation may take place in spring if 2  1

(B) Compression may take place in spring 1  2
(C) Elongation may take place in spring 2  1
(D) There will be no elongation or compression in the spring if 1  2

Ans: AD

Sol:
Write f & d of blocks with respect to Plank.
ma m1 m2a m2
f1 f2

6. Two nonconducting spheres of radii R1 and R 2 and carrying uniform volume charge densities
 and   , respectively, are placed such that they partially overlap, as shown in the figure.
At all points in the overlapping region,

 

(A) the electrostatic field is zero

(B) the electrostatic potential is constant
(C) the electrostatic field is constant in magnitude
(D) the electrostatic field has same direction

Ans: CD

Sol:   
In triangle PC1C2 , r2  d  r1
The electrostatic field at point P is
 4 3    4 3  
 K   R
 3 1 2 r K   R 2   r1 
E     3 
3 3
R1 R2
 
  
4

 K   r2  r1 
3
 3 0
d
 PART – C : Numerical Answer Type
This section contains 06 questions. The answer to each question is a NUMERICAL VALUE. The
answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9.

1. Figure shows a small block of mass = 1 kg kept at the left end of a larger block of mass M = 3
kg and length l = 12 m. The system can slide on a horizontal road. The system is started
towards right with an initial velocity V. The friction coefficient between the road and the bigger
block is   0.4 and that between the blocks is  / 2 . Find the time elapsed before the smaller
block separates from the bigger block.

Ans: 3

Sol:
Let acceleration of m is a1 and acceleration of M is a2 .
So, a1 should be greater than a2 .
Let both will get separated after t second.
a t2 a t2
So, vt  1  vt  2  
2 2

2. Two identical capacitors each of capacitor 6 F are connected with 5 volt battery in
arrangement given below with switch in closed position. If switch will be opened then find heat
generated.

6 F 6 F

5V

Ans: 0

Sol:
Charge will not flow in circuit even after opening the switch hence no heat will be generated.

3. In the figure shown, find the ratio of the linear charge densities 1 (on semi-infinite straight wire)
and  2 (on semi-circular part) that is 1 /  2 so that the field at O is along y direction.

Ans: 2

Sol:
2 1

20R 40R
4. Consider small ball of mass m thrown horizontally from top of tower with kinetic energy E. It
remain in air for time t before hitting ground. If force of air resistance is directly proportional to

speed and proportion constant is k then horizontal range is

k

mEx

1  ekt /m then find x.

Ans: 2

Sol:
kv cos  k
 ax   vx
m m

5. A charge of 20  C is placed on the positive plate of an isolated parallel plate capacitor of

capacitance 10  F . Calculate the potential difference (in V) developed between the plates.

Ans: 1

Sol:
Given that capacitance C  10  F and charge  20  C . But the is effective charge q  10  C .

Potential difference is q/C = 1 V.

6. A point charge Q is located on the axis of disc of radius R at a distance b from the plane of the
disk. If one fourth of the electric flux from the charge passes through the disk, then R  x b (as
shown in figure). Find x.

Ans: 3

Sol:
 b 
Solid angle subtended by disc at Q= 2 1  cos    2 1  
 b  R2
2 

PART – C : Numerical Answer Type

This section contains 06 questions. The answer to each question is a NUMERICAL VALUE. The
answer of which maybe POSITIVE or NEGATIVE numbers or DECIMALS (e.g. 6.25, 7.00, -0.33, -.30,
30.27, -127.30).

7. A battery of emf 0  12 V is connected across a 4 m long uniform wire having resistance

4  m1 . The cells of small emf 1  2 V and 2  4 V having internal resistances
r1  2  and r2  6  , respectively, are connected as shown in the figure. If galvanometer
shows no deflection at point N, the distance of point N from point A is equal to (in cm)
 Ans: 25

Sol:
  42
I 2 1   3
4
A
r1  r2 26
3 AN
2 2  8
4 4

8. The direction    of E at point P due to uniform charged finite rod will be (from x axis in degree)

Ans: 30

Sol:
Using symmetry property.

9. Consider small block of mass m lying at rest at point P of wedge having smooth semi circular
track of radius r is given below. Find minimum horizontal acceleration of wedge, that block can
just reach at point Q. (Take g = 10 m/s2)

Ans: 10

Sol:
We will calculate it with respect to wedge
So, gravity  psedo  change in kinetic energy
mgr  mar  0
 a  g  10m / s2

10. A ball is thrown horizontally from cliff such that it strikes ground after 5 second. Line of sight
from point of projection to point of hitting makes angle 37 with horizontal. What is initial speed
of projection (m/s).

Ans: 33.3

Sol:
 2u sin 
Time of flight = ,   37 &   37
g cos 

11. A chain of mass m  2 kg forming a circle of radius R = 2m is slipped on a smooth round cone
with half angle   45 . Find the tension of chain if it rotates with constant angular velocity

   rad/s about a vertical axis coinciding with symmetry axis of the cone. 2  10 
Ans: 30

Sol:
Required Centripetal force will be given by Tension developed in chain.

12. Three identical capacitors C1, C2 and C3 have a capacitance of 1.0  F each and they are
uncharged initially. They are connected in a circuit as shown in the figure and C1 is then filled
completely with a dielectric material of relative permittivity r . The cell electromotive force (emf)
V0  8 V . First the switch S1 is closed while the switch S2 is kept open. When the capacitor
C3 is fully charged, S1 is opened and S2 is closed simultaneously. When all the capacitors
reach equilibrium, the charge on C3 is found to be 5  C . The value of r .

Ans: 1.50

Sol:
When S1 is closed and S2 is open charge in capacitor C3 q3  C3 V0  1 8  8C
Now S1 is opened and S2 is closed. Final charge in C3 is 5  C , hence the charge in
capacitors C1 and C2 should be 3C .
 SECTION-II : CHEMISTRY
PART-A (One or More Correct Type)
This section contains 06 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONE or MORE is correct.

1. What is/are the final products in the following sequence of reactions:

Anhy.
Cl AlCl3 O 2 , 130o c H+
O + Catalyst

(A) Cumene (B) Phenol (C) Benzoid acid (D) Acetone

Ans: BD

Sol:

2. In the reaction:
OH

aq. NaOH
Br 2

The intermediate(s) is/are:

- -
O O O
-
Br O

(A) Br (B) Br Br (C) Br (D) Br

Ans: ABC

Sol:

3.
O
(i) CH3MgBr
Product
(ii) H+/H2O

Correct statements(s) about product is/are:

(A) it shows optical isomerism
(B) it shows geometrical isomerism
(C) it gives blue colour in Victor-Meyer test
(D) it does not give turbidity with Luca’s reagent

Ans: BC

Sol:
4. Which of the following reaction(s) proceed via carbanion intermediate?
O

OH- OH-
CHO
(A) (B)
CHO
O
O AcONa
O C C O
OH
-
O
AcOH
(C) (D)

Ans: BD

Sol:
(B) E1cb mechanism (Aldol)
(D) Perkin

5. Which of the following is/are correct ?

(A) Rate of diffusion of a gas through a pinhole is directly proportional to the temperature of the
gas.
(B) Rate of diffusion of a gas through a pinhole is directly proportional to its partial pressure.
(C) Rate of diffusion of a gas through a pinhole is directly proportional to its mole fraction, inside
the container.
(D) Rate of diffusion of a gas through a pin hole is directly proportional to the cross section area
of the pinhole.

Ans: BCD

Sol:
Factual

6. Alkyl iodide can be prepared by

CCl4 acetone
(A) R – CH2COOAg + I2  (B) R – CH2 – Cl + NaI  

(C) R – OH + HI  (D) None of these

Ans: ABC

Sol:
(A) Borodin Hunsdiecker reaction
(B) Finkelstein reaction
(C) SN1 or SN2

PART – C : Numerical Answer Type

This section contains 06 questions. The answer to each question is a NUMERICAL VALUE. The
answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9.

1. 9 gm of CH4 is burnt with 40 gm of oxygen, under the requisite conditions. If the yield of the
process is 50%, then find the amount of water produced (in gm).

Ans: 9

Sol:
  CH4  2O2 
 CO 2  2H2O
16 g 36 g

8g 18 g 
9 g

2.

Aq. AgNO3
Products + AgBr

Br
Total number of all possible products including stereoisomers----------

Ans: 3

Sol:

3.
O O
aq. NaOH
H3C C CH3 + H3C CH 2 C CH3
Total number of all aldol condensation products-------------

Ans: 9

Sol:
Aldol Reaction

OCH 3

4. When 1 mole OH CH2 CH CH2 OH is reacted by excess HIO , x mole HIO

4 4 is
consumed, y mole HCOOH and Z mole HCHO are formed. (x+y+z) is --------

Ans: 0

Sol:
No reaction

5. How many moles of CO2 will released when following compound treated with heat.

Ans: 4

Sol:
 - keto acid loses all CO2

6. Find out number of substrates those cannot undergo Cannizzaro’s reaction.

 Ans: 4

Sol:
Factual

PART – C : Numerical Answer Type

This section contains 06 questions. The answer to each question is a NUMERICAL VALUE. The
answer of which maybe POSITIVE or NEGATIVE numbers or DECIMALS (e.g. 6.25, 7.00, -0.33, -.30,
30.27, -127.30).

N
7. 0.4 g mixture of NaOH, Na2CO3 and some inert impurities was first titrated with HCl using
10
phenolphthalein as an indicator, 17.5 mL of HCl was required at the end point. After this methyl
orange was added and titrated. 1.5 mL of same HCl was required for the next end end point.
The weight percentage of Na2CO3 in the mixture is ___________. (Rounded-off to the nearest
integer)

Ans: 5.30

Sol:
Let m. moles of NaOH = x,
m. moles of Na2CO3 = y
when used HPh : m. moles of NaOH + m. moles of Na2CO3 = m. moles of HCl
1
x  y  17.5 
10
x  y  1.75
After end point when MeOH is added : NaHCO3 converted into H2CO3
1
 y  2.0 
10
y  0.2
wt. of Na2CO3 = 0.2  106  103 = 0.0212 g
0.0212
wt.% of Na2CO3 in sample   100  5.30%
0.4

8. The radius of an orbit of H-atom is 0.2116 nm. Kinetic energy (in eV) of electron present in this
orbit is

Ans: 3.4

Sol:
n2
rn  0.529   2.116
z
 n2
13.6z 2 13.6  12
En      3.4 eV
n2 22
KE  En  3.4 eV
9. 0.32 gm of CH4(g) is diffused through a pin hole of rigid vessel in 20 sec, If all the SO2(g) at
same pressure and temperature that will be diffused through same pin hole in 40 sec in
separate experiment is collected in a closed vessel of volume 2.463 L over liquid water at 27 oC,
then calculate total pressure in container (in torr).
(Given: Vapour pressure of water at 27oC is 28 mm of Hg. Consider SO2(g) is water insoluble
and volume of water is negligible w.r.t. volume of vessel)

Ans: 180

Sol:
n1 40 64 0.02  2
  ;  2; n2  0.02 mole
20 n2 16 n2
nRT 0.02  24.63
PSO2    0.2 atm
V 2.463
 0.2  760  152mm of Hg
PT  152  28  180 torr

10. For real gas we can write the virial equation as

 B C 
PVm  RT 1   2  ...
 Vm Vm 
where B and C are virial coefficients. At 300 K for 1 mole real gas value of B = 0.004 L mol -1
and C = 0.0036 L2 mol-2. Calculate the temperature (in K) of real gas above which it is not
1
liquefied on applying pressure. (Given: R  L atm mol1 K 1 )
12

Ans: 82.96

Sol:
a
Second virial coefficients, B  b   0.004
RT
Third virial coefficients, C
= b2 = 0.0036  b = 0.06
a  12
at T = 300 K, 0.06   0.004  a  1.4
300
8 a 8 1.4  12
TC      82.96K
27 Rb 27 0.06

11. If heat of solution for AB(s) is 0.95  10x kcal/mol and lattice energy for AB(s) is 700 kcal/mol
and hydration energy for A+ (g) is 1000 kcal/mol and B (g) is 650 kcal/mol then calculate
value of x.

Ans: 3

Sol:
0.95  10x = 700 – 1000 – 650
0.95  10x = 950
x=3

12. 0.8 g of a metal oxide MO were dissolved in excess dilute sulphuric acid and Ba(MnO 4)2 of
strength 0.2 M are reacted. Volume of Ba(MnO4)2 required to reach the equivalence point is 8
mL and given that M2+ oxidizes into M4+ then atomic weight of metal M would be

Ans: 84

Sol:
 2
MO  Ba MnO 4 2 

H
 Mn2   M4 

0.8 0.2  8
2  10;
m  16 1000
where m is atomic mass of metal
m + 16 = 100
m = 84
 SECTION-III : MATHEMATICS
PART-A (One or More Correct Type)
This section contains 06 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONE or MORE is correct.

1. a  3x  4y  6   b  x  y  2   0 is a family of lines. The line of the family situated at the

greatest distance from the point P(2, 3) has equation
(A) 4x + 3y + 8 = 0 (B) 5x + 3y + 10 = 0
(C) 15x + 8y + 30 = 0 (D) x + y + 1 = 0

Ans: A

Sol:
Point of concurrence of the family is (-2, 0) required line will be one passing through
(-2, 0) and perpendicular to the line joining (-2, 0) and (2, 3)

2. Minimum radius of the circle which is orthogonal to both the circles x 2  y 2  12x  35  0 and
x2  y 2  4x  3  0 is
(A) 4 (B) 3 (C) 15 (D) 1

Ans: C

Sol:
Radical axis is x = 2
It intersects the line joining the centres at (2, 0)
 R  4  24  35
 15

3. From the point (15, 12) three normal are drawn to the parabola y 2  4x . Then centroid of the
triangle formed by three co-normal points is__________
 16   26 
(A)  ,0  (B) (4, 0) (C)  ,0  (D) (6, 0)
 3   3 

Ans: C

Sol:
y  tx  2t  t 3 is normal. It passes through (15, 12)
t = -1, -3, 4
     
 P at12 ,2at1 ,Q at 22 ,2at 2 ,R at 32 ,2at 3

4. f(x) is a decreasing function, then the set of values of k for which the major axis of the ellipse
x2 y2
  1 is the x-axis is______

f k 2  2k  5  f  k  11
(A) (-2, 3) (B) (-3, 2) (C) (-∞,-3)∪(2, ∞) (D) (-∞,-2)∪(3, ∞)

Ans: B

Sol:
 
f k 2  2k  5  f  k  11  k 2  2k  5  k  11

 sin  x  3 
5. Lt   is equal to
  x  3 
x 0

(A) 0 (B) 1 (C) does not exist (D) sin 1

 Ans: C

Sol:
LHL = - 1 , RHL = 0 Limit does not exist

 d2 x   d2 x 
6. y  e2x then  2   2  is equal to_____
 dx   dy 
(A) 1 (B) e 2x (C) 2e2x (D) 2e 2x

Ans: D

Sol:
dy d2 y 2x dx 1 d2 x 1
 2e x , 2
 4e ,  2
 2
dx dx dy 2y dy 2y

PART – C : Numerical Answer Type

This section contains 06 questions. The answer to each question is a NUMERICAL VALUE. The
answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9.

1. For the hyperbola 9x 2  16y 2  18x  32y  151  0 , L is the latus rectum then the value of 2L is

Ans: 9

Sol:
 x  1  y  1
2 2
2b2
  1 Latus rectum  9/2
16 9 a

x2 y2
2. If PQ is focal chord of ellipse   1 which passes through S(3, 0) and PS = 2 then the
25 16
length of the chord PQ is L. The value of L/5 is

Ans: 2

Sol:
SP = 2, SR = 2

∴ P and R same
Length of focal chord = 10

1
3. f x 
tan x
 
, Lt  f  x    x 2 f  x   e  then the value of  is________ where [ ] and { } denotes
x x 0 
greatest integer and fractional part

Ans: 3

Sol:
  tan x  tan x
Lt    1 as is always great than one
x 0
 x  x
x
∴ Limit  Lt 1  x 2
x 0
  tan x  x

LT  x  2
 ex 0   x
 tan x  x 
 
 e3 u sin g L  Hospital

ee/ x  e e/ x
4. f x  , x0
e1/ x  e 1/ x
=k ,x=0
The number of values of k for which this function is continuous at x = 0 is________

Ans: 0

Sol:
RHL = ∞, LHL = - ∞
Limit does not exist

 2x  dy 1
5. If y  tan1  2x 1 
then at x = 0 is  n    the value of  is equal to_____
 1 2  dx 10

Ans: 2

Sol:
 2x 1  2x 
y  tan1  x 1 
 1 2  2 
x

 tan1  2 x 1   tan1 2x

6. a +b = 8, a > 0, b > 0 then the minimum value of a3  b3 is a three digit no. The number the
ten’s place is_____

Ans: 2

Sol:
ds
S  a3   8  a  ,  3a2  3  8  a 
3 2

da
ds
 0  a  4 so b  4 minimum  128
da

PART – C : Numerical Answer Type

This section contains 06 questions. The answer to each question is a NUMERICAL VALUE. The
answer of which maybe POSITIVE or NEGATIVE NUMBERS or DECIMALS (e.g. 6.25, 7.00, -0.33, -
.30, 30.27, -127.30).

7. The chord of the parabola y 2  4ax whose equation is y  x 2  4a 2  0 is a normal to the

curve and its length is  3 a then the value of  is

Ans: 6
 Sol:
y  mx  2am  am3 is normal to y 2  4ax
m  2
4
length of chord =
m2
1  m   a  mc 
2

8.  
If the possible values of ‘a’ such that the inequality 3  x 2  x  a has at least one negative
 13 
solution is   ,   then the value of  is
 4 

Ans: 2

Sol:
For maximum ‘a’ left arm of the modulus curve will pass through the vertex of the parabola

x
amin O amax

9. The minimum value of y in 4x 2  12xy  10y 2  4y  3  0 is________

Ans: 1

Sol:
 2x  3y    y  2  1, 0   y  2  1 so
2 2 2

1≤y≤3

d4 y
10. y  e  x cos x,  ky  0 then k is equal to
dx 4

Ans: 4

Sol:
y 4  4y  0

11. f  x   x  2, x  0
  x 2  2,0  x  1
x ,x  1
Then the number of points of discontinuity of f  x  is_______

Ans: 1

Sol:
At x = 1, LHL ≠ RHL so discontinuous

x esin x  e x sin1  sin x 

12. Lt is equal to
x 0 sin2 x  x sin x

Ans: 1
Sol:
 nex   esin x  x  1 
Lt  x  1
x 0 sin x
   sin x  x 