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D and F Block
D and F Block
Chapter
The dand -Block
Elements
Topic-1: Position in the Periodic Table, Electronic Configurations of the d-Block
Elements, General Properties of the Transition Elements (d-Block)
5. Which of the following ions has the clectronie
Multiple Choice Questions
configuration 3dº? (Atomic nunmber: Mn =25, Co =27.
Ni= 28) |Delhi 2023, Set-l, (K]
1. The trend of which property is represented by the
(a) N (b) Co+
following graph? |CBSE Sample 2023-24, U||
19
(c) Mn2+ (d) Mn3+
18
6.
Radius/nm
Which property of transition metals enables them to
behave as catalysts? |Delhi 2023, Set-1. R]
17
(a) High melting point
16
(b) High ionisation enthalpy
15 (c) Alloy formation
14 (d) Variable oxidation states
13 7. Which of the following is the reason for Zine not
12 exhibiting variable oxidation state
Sc Ti Vr Mn Fe Co Ni Cu Zn |CBSE Sample 2020-21. U|
(a) ionization enthalpy (a) inert pair eftect
(b) atomic radii (b) completely filled 3d subshell
(c) enthalpy of atomization (c) completely filled 4s subshell
(d) melting point (d) conmmon ion effect
2 Which of the following is not considered a transition 8. Which of the following is a diamagnetie ion: (Atoic
clement? |CBSE Sample 2023-24, IK| numbers of Sc, V, Mn and Cu are 21, 23, 25 and 29
(a) Scandium respectively) |CBSE Sample 2020-21. U
(b) Silver (a) y2+ (6) Spt
(c) Vanadium (c) Cu2+ (d) Mnt
(d) Zinc 9. Which set of ions exhibit specifie colours? (Atomic
3 Which of the following transition metals shows 4.1 and number of Sc = 21, Ti = 22, V=23, Mn = 25, Fe=26.
4.2 oxidation states? |All India 2023, Set-1, N) Ni=28 Cu=29 and Zu =30)
(a) Mn (b) Zn |CBSE Sample 2020-21, |
(c) Sc (d) Cu (a) Sct, T ,Mnt
4. Which onc among the following metals of 3d series has (b) Set, Zu, Ni
the lowest melting point? JAl lndia 2023 Set-11, K]
(b) Mn
(c) vt, y2, Fe+
(a) Fe
(c) Zn (d) Cu (d) T,T,Ni
15.
IAIIIndia 2022, Term-II|
2 Assertion Reason/Tvo Statement Type Questions Cr MI Fe Co Ni Cu Zn
E -1.18 -0.44 -0.28 -0.25 +0.34 -0.76
Given below are two statements labelled as Assertion (A) 'M/M -0.91
2 Assertion Reason/Tvo Statement Type Questions (ii) Transition metals form coloured compounds.
|Delhi 2015, K|
Given below are two statements labelled as Assertion (A) (b) Complete the following equation :
and Reason (R). Select the most appropriate answer from (Delhi 2015, K]
the 2MnO, + 6H + 5NO,
options given below: How would you account for the following ?
6.
(a) Both (A) and (R) are true and (R) is the correct (Delhi 2013, K]
explanation of (A). (i) Transition metals exhibit variable oxidation states.
(b) Both (A) and (R) are true, but (R) is not the correct [Delhi 2013, K]
explanation of (A). (ii) Zr(Z=40) and Hf(Z=72) have almost identical radii.
(c) (A) is true, but (R) is false. [Delhi 2013, K]
(d) (A) is false, but (R) is true. (iii) Transition metals and their compounds act as catalyst.
1. Assertion (A) : Magnetic moment values of actinides (Delhi 2013, K]
are lesser than the theoretically predicted values. 7. Complete the following chemical equations:
Reason R) : Actinide elements are strongly () Cy0 +6Fe?* +14H+
paramagnetic. [CBSE Sample 2022-23, U|
(ii) 2Cr0 +2H+
in Short Answer Questions (2 or 3 Marks) 2MnO +5C,0 +16H
(iii) [Delhi 2013,K]
2. Account for the following: Al India 2022, Term-II]
Long Answer Questions
() Transition metals and their compounds show
catalytic activities. 8. Attempt any five of the following:
(ii) Zn, Cd and Hg are non-transition elements. [CBSE Sample 2023-24, U]
(ii)Zr and Hf are of almost identical atomic radii. (a) Which of the following ions will have a magnetic
3. Give reasons for the following: Delhi 2019, U] moment value of 1.73 BM.
(i) Transition elements and their compounds act as Set, Tt, Ti*, Cuzt, Zn2+
catalysts. [Delhi 2019, K| [CBSE Sample 2023-24, U|
(i) E° value for (Mn Mn) is negative whereas for (b) In order to protect iron from corrosion, which one
(Cu2t |Cu) is positive. [Delhi 2019, U] will you prefer as a sacrificial electrode, Ni or
(iii) Actinoids show iregularities in their electronic Zn? Why? (Given standard electrode potentials of
Ni, Fe and Zn are -0.25 V, -0.44 Vand-0.76 V
configuration. [Delhi2019, K|
4. Give reasons : [Delhi 2016, K| respectively.) [CBSE Sample 2023-24, U|
(c) The second ionization enthalpies of chromium and
(1) Mn shows the highest oxidation state of +7 with
oxygen but with fluorine it shows the highest
manganese are 1592 and 1s09 kJ/mol respectively,
(Delhi 2016, K| Explain the lower value of Mn.
oxidation state of +4.
(ii) Transition metals show variable oxidation states.
[CBSE Sample 2023-24, U]
(d) Give two similarities in the
[Delhi2016, K] properties of Sc and Zn.
[CBSE Sample 2023-24, K]
(ii) Actinoids show irregularities in their electronic (e) What is actinoidcontraction? What causes actinoid
|Delhi 2016, K|
configurations. contraction?
[CBSE
() What is the oxidation state of Sample 2023-24, K]|
5. (a) How would you account for the following chromium in chromate
[Delhi 2015, K] ion and dichromate ion?
(i) Actinoid contraction is greater than lanthanoid [CBSE Sample
contraction. [Delhi 2015, K| (g) Write the ionic equation for reaction 2023-24, K|
of KI with
acidified KMnO4: [CBSE Sample 2023-24, K]
9. (I) Account for the following: |AIl India 2023, U| 12. (a) Account for the following: JAIIIndia 2020, UI
(i) Transition metals form alloys. (i) Copper () compounds are white whereas
[AllIndia 2023, K| copper (I)compounds are coloured.
(ii) Cett is a strong oxidising agent. JAIl India 2020, UI
[AIl India 2023, U) (ii) Chromates change their colour when kept in an
(I) Write one similarity and one difference between acidic solution. [AIIndia 2020, U|
chemistry of Lanthanoids and Actinoids. (ii) Zn, Cd, Hg are considered as d-block elements
but not as transition elemnents.
[AII India 2023, K|
(III) Complete the following ionic equation: [All India 2020, K|
Cr,0% +20H (b) Calculate the spin-only moment of Co (2=27) by
JAIlIndia 2023, K] writing the electronic configuration of Co and Co2t
10. (a) Why is chemistry of actinoids complicated as [AI India 2020, U|
compared tolanthanoids? |Delhi 2023 Set-I, K] 13. (a) Give three points of difference between lanthanoids
(b) Complete the following reaction and justify that it is and actinoids. [AIl India 2020, K]
a disproportionation reaction:Delhi 2023 Set-I, K|
(b) Give reason and select one atom/ion which will
3 MnO,?- 4H’ +2 H,0. exhibit asked property:
(c) The given graph shows the trends in melting points (i) Sc3+ or Cr (Exhibit diamagnetic behaviour)
of transition metals: [Delhi 2023 Set-I, U]
[AIl India 2020, U|
(ii) Cr or Cu (High melting and boiling point)
W
[AIIndia 2020, U
14. (a) Give reasons:
[Delhi 2020, U|
M.P/10'K MO (i) Transition metals and their compounds show
catalytic activities. |Delhi 2020, K)
(1) Separation of a mixture of lanthanoid elements
is difficult. (Delhi 2020, U|
Mn (ii) Zn, Cd and Hg are soft and have low melting
point. (Delhi2020, U)
Atomic number (b) Write the preparation of the following:
Explain the reason why Cr has highest melting point () Na,Cr,0, from Na,CrO4 [Delhi 2020, K)
manganese (Mn) a lower melting point. (i) KMnO, from MnO,
11. (a) A
transition element X has electronic configuration 15. (a) Account for the following: [Delhi 2020, U]
[Ar]4s2 3d³. [Delhi 2023, Set-I, U) () T* is coloured, whereas Sc3+ is colourless in
Predict its likely oxidation states. aqueous solution. [Delhi 2020, U]
(b) Complete the reaction mentioning all the products (ii) Cr* is a strong
reducing agent.
formed: (Delhi 2023, Set-1, K| [Delhi 2020, U]
(b) Write two similarities between
2KMnO4 chemistry ol
lanthanoids and actinoids. |Delhi 2020, K]
(c) Account for the following: (c) Complete the
(i) In the 3d transition series, zinc has the lowest following ionic equation:
enthalpy of atomisation. [Delhi 2023, Set-I, K|
3MnO +4H+ |Delhi 2020, K]
(ii) Cu ion is unstable in aqueous solution. 16. (a) Account for the following: [All India 2017, K]
|Delhi2023, Set-1, K| (1) Transition metals show variable
states.
oxidation
(iii) Actinoids show more number of oxidation [AIl India 2017, K]
states than lanthanoids. [Delhi 2023, Set-I, K) (ii) Zn, Cdand Hg are soft
metals.
[AIl India 2017, K)
(iii) E° value for the MnMn couple is
highly (ii) Transition metals show variable oxidation
positive (+1.57 V) as compared to Crt/Cr2+ states. [AllIndia 2015, KJ
|AlIndia 2017, K] (iii) Cut ion is unstable in aqueous solution.
(b) Write one similarity and one difference between the [AIl India 2015, K]
chemistry of lanthanoid and actinoid elements.
(b) Complete the following equations.
[AIlIndia 2017, K] (i) 2 MnO, + 4 KOH + O, ’
17, (a) Following are the transition metal ions of 3d series: JAII India 2015, K]
(ii) 2 Na,CrO, +2H’
T4+, V2, Mnt, C3+ [AIl India 2017, K]
C1 Mn Fe Co Ni Cu
(Atomic numbers: Ti=22, V=23, Mn = 25, Cr= 24) 21. (a) E°
M*/MLo91-L81-0.44|-0.28|-0.25|+0.34
Answer the following:
(i) Which ion is most stable in an From the given data of E° values, answer the
aqueous [AIl India 2015, U]
solutions and why? [AIlIndia 2017, K] following questions.
(ii) Which ion is a strong oxidising agent and why? (i) Why is Ecu2* ICu) value exception-ally
[All India 2017, K]
positive? [AII India 2015, U|
(iii) Which ion is colourless and why? (ii) Why is (Mn2+t /Mn) value highly negative as
JAII India 2017, K] compared to other elements?
(b) Complete the following equations: [AlIndia 2015, UI
(i) 2MnO,+ 16 H+ 5s (ii) Which is a stronger reducing agent Cr or
(ii) KMnO heat Fe2t? Give reason. [AIl India 2015, U]
[Áll India 2017, K]
(b) Why do actinoids show a wide range of oxidation
18. (a) Account for the following : Delhi 2017, K]
states? Write on similarity between the chemistry of
(i) Transition metals. form large number of lanthanoids and actinoids. [All India 2015, K]
complex compounds. [Delhi 2017, K
22. (a) Complete the following equations :
(ii) The lowest oxide of transition metal is basic
(i) Cr,0,+ 20H JAl India 2014, K]
whereas the highest oxide is amphoteric or
(i) Mn0,+ 4H + 3e
acidic. Delhi 2017, U]
(ii) E° value for the Mn/Mn2+ couple is highly (b) Account for the following:
(i) Zn is not considered as a transition element.
positive (+1.57 V) as compare to Crst/Cr2+.
[AIl India 2014, K)
[Delhi 2017, U] (ii)
Transition metals form a large number of
(b) Write one similarity and one difference between the complexes. JAII India 2014, K]
chemistry of lanthanoid and actinoid elements.
(ii) The E° value for the Mn/Mn2+ couple is
[Delhi 2017, K] much more positive than that for Crt/C2+
19. (a) () How is the variability in oxidation states of couple. JAlIndia 2014, K]
transition metals different from that of the 23. (i) With reference to structural variability and chemical
p-block elements ? [Delhi 2017, K| reactivity, write the differences between lanthanoids
(ii)) Out of Cu and Cuz, which ion is unstable in and actinoids. |All India 2014, RI
aqueous solution and why? |Delhi 2017, K] (ii) Name a menmber of the lanthanoid series which is
(ii) Orange colour of Cr,0, ion changes to well known to exhibit +4 oxidation state.
yellow when treated with an alkali. Why ?
|AIl India 2014, K]
[Delhi 2017, K| (i) Complete the following equation :
(6) Chemistry of actinoids is complicated as compared MnO,+ 8H + 5e [AIl lndia 2014, K)
to lanthanoids, Give two reasons.. [Delhi 2017, K] (iv) Out of Mn and Cr*, which is more
20. (a) Account for the following. |AllIndia 2015, K| paramagnetic
and why? |AlIl India 2014, U)
() Zrand Hf have almost similar atomic radii. (Atomic nos. :Mn = 25, Cr= 24)
[AII India 2015, K|
24. (a) How do you 26. (a) Give reasons for the following : (AIl India 2013, U|
prepare : |Delhi 2014, K|
()K,Mno, from MnO, ? (i) Mn3+ is a good oxidising agent.
(ii)
Na,Cr,0, from Na,CrO,? [AIl India 2013, U|
(b) Account for the following:
(i) Mn* is more stable than Fezt towards (ii) E,2+ /M Values are not regular for frst .
transition metals (3d series).
oxidation to +3 state. |Delhi 2014, U|
(ii) The enthalpy of atomization is lowest for Zn in [AIl India 2013, U|
3d series of the transition (ii) Although 'F' is more electronegative than »0
elements. the highest Mn fluoride is MnF, whereas the
|Delhi 2014, U| highest oxide is Mn,O,. JAII India 2013, U|
(ii) Actinoid elements show wide range of
(b) Complete the following equations :
oxidation states. [Delhi 2014, K]
25. (i) Name the element of 3d transition series which (i) 2Cr0 +2H+ JAIl India 2013, K|
shows maximum number of oxidation states. Why
heat
does it show so ?
[Delhi2014, K] (i) KMnO,
(ii) Which transition metal of 3d series has positive E° 27. (a).Why do transition elements show variable oxidation
(M*M) value and why ? [Delhi 2014, K] states? JAII India 2013, K)
(iii) Out of Crt and Mn, which is a stronger (i) Name the element showing maximum number
oxidizing
agent and why ? [Delhi2014, K] of oxidation states among the first series of
(iv) Name a member of the lanthanoid series which is transition metals from Sc(Z=21) to Zn (Z=30).
well known to exhibit +2 oxidation state.
[AIl India 2013, K]
[Delhi 2014, K] (ii) Name the element which shows only +3
(v) Complete the following equation : Oxidation state. [AIl India 2013, K]
MnO +8H ++5e (b) What is lanthanoid contraction ? Name
an important
[Delhi2014, K| alloy which contains some of.the lanthanoid metals.
[All India 2013, K|