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1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use : Sealant/adhesive
Precautionary statements :
Prevention:
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3.2 Mixtures
Components
Chemical name CAS-No. Classification Concentration
EC-No. (% w/w)
Registration number
Urea,N,N''-(methylenedi-4,1- 77703-56-1 Aquatic Chronic 4; >= 2,5 - < 5
phenylene)bis[N'-butyl- 416-600-4 H413
01-0000016345-72-
XXXX
xylene 1330-20-7 Flam. Liq. 3; H226 >= 1 - < 2,5
Contains: 215-535-7 Acute Tox. 4; H332
ethylbenzene <= 25 % 01-2119488216-32- Acute Tox. 4; H312
XXXX Skin Irrit. 2; H315
Eye Irrit. 2; H319
STOT SE 3; H335
STOT RE 2; H373
Asp. Tox. 1; H304
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Hydrocarbons, C9-C12, n- Not Assigned Flam. Liq. 3; H226 >= 1 - < 2,5
alkanes, isoalkanes, cyclics, aro- 919-446-0 STOT SE 3; H336
matics (2-25%) 01-2119458049-33- STOT RE 1; H372
XXXX [corresponding Asp. Tox. 1; H304
group CAS 64742-82- Aquatic Chronic 2;
1] H411
4,4'-methylenediphenyl diisocya- 101-68-8 Acute Tox. 4; H332 >= 0,1 - < 1
nate 202-966-0 Eye Irrit. 2; H319
01-2119457014-47- STOT SE 3; H335
XXXX Skin Irrit. 2; H315
Resp. Sens. 1; H334
Skin Sens. 1; H317
Carc. 2; H351
STOT RE 2; H373
m-tolylidene diisocyanate 26471-62-5 Carc. 2; H351 >= 0,0025 - <
247-722-4 Acute Tox. 1; H330 0,025
01-2119454791-34- Eye Irrit. 2; H319
XXXX STOT SE 3; H335
Skin Irrit. 2; H315
Resp. Sens. 1; H334
Skin Sens. 1; H317
Aquatic Chronic 3;
H412
In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Asthmatic appearance
Allergic reactions
See Section 11 for more detailed information on health effects
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and symptoms.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
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Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. When using do not eat or drink. When using do not
smoke. Wash hands before breaks and at the end of workday.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage : Keep container tightly closed in a dry and well-ventilated
areas and containers place. Store in accordance with local regulations.
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SAFETY DATA SHEET
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Skin and body protection : Protective clothing (e.g. Safety shoes acc. to EN ISO 20345,
long-sleeved working clothing, long trousers). Rubber aprons
and protective boots are additionaly recommended for mixing
and stirring work.
Respiratory protection : In case of inadequate ventilation wear respiratory protection.
Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe work-
ing limits of the selected respirator.
Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk as-
sessment indicates this is necessary.
organic vapor filter (Type A)
A1: < 1000 ppm; A2: < 5000 ppm; A3: < 10000 ppm
Ensure adequate ventilation. This can be achieved by local
exhaust extraction or by general ventilation. (EN 689 - Meth-
ods for determining inhalation exposure). This applies in par-
ticular to the mixing / stirring area. In case this is not sufficent
to keep the concentrations under the occupational exposure
limits then respiration protection measures must be used.
Environmental exposure controls
General advice : Do not flush into surface water or sanitary sewer system.
pH : Not applicable
Flash point : 76 °C
Method: closed cup
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Solubility(ies)
Water solubility : insoluble
Solubility in other solvents : No data available
Viscosity
Viscosity, dynamic : Not applicable
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
The product is chemically stable.
10.3 Possibility of hazardous reactions
Hazardous reactions : No hazards to be specially mentioned.
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Acute toxicity
Not classified based on available information.
Components:
xylene:
Acute oral toxicity : LD50 Oral (Rat): 3.523 mg/kg
4,4'-methylenediphenyl diisocyanate:
Acute inhalation toxicity : Acute toxicity estimate: 1,5 mg/l
Test atmosphere: dust/mist
Method: Expert judgement
m-tolylidene diisocyanate:
Acute inhalation toxicity : LC50 (Rat): 0,107 mg/l
Exposure time: 4 h
Test atmosphere: vapour
Skin corrosion/irritation
Not classified based on available information.
Components:
Skin sensitisation
Not classified based on available information.
Respiratory sensitisation
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
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12.1 Toxicity
Components:
Urea,N,N''-(methylenedi-4,1-phenylene)bis[N'-butyl-:
Toxicity to fish : LC50 (Brachydanio rerio (zebrafish)): > 250 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..
Product:
Additional ecological infor- : There is no data available for this product.
mation
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European Waste Catalogue : 08 04 09* waste adhesives and sealants containing organic
solvents or other dangerous substances
14.1 UN number
Not regulated as a dangerous good
14.2 UN proper shipping name
Not regulated as a dangerous good
14.3 Transport hazard class(es)
Not regulated as a dangerous good
14.4 Packing group
Not regulated as a dangerous good
14.5 Environmental hazards
Not regulated as a dangerous good
14.6 Special precautions for user
Not applicable
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH - Restrictions on the manufacture, placing on : Conditions of restriction for the fol-
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SAFETY DATA SHEET
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the market and use of certain dangerous substances, lowing entries should be considered:
preparations and articles (Annex XVII) Number on list 3
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of ma-
jor-accident hazards involving dangerous substances.
Not applicable
Volatile organic compounds : Law on the incentive tax for volatile organic compounds
(VOCV)
Volatile organic compounds (VOC) content: 3,46 %
If other regulatory information applies that is not already provided elsewhere in the Safety Data
Sheet, then it is described in this subsection.
Health, safety and environ- : Environmental Protection Act 1990 & Subsidiary Regulations
mental regulation/legislation Health and Safety at Work Act 1974 & Subsidiary Regulations
specific for the substance or Control of Substances Hazardous to Health Regulations
mixture: (COSHH)
May be subject to the Control of Major Accident Hazards
Regulations (COMAH), and amendments.
Other regulations:
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Sikaflex®-221
Revision Date 13.07.2020 Version 7.0 Print Date 13.07.2020
Take note of Directive 92/85/EEC regarding maternity protection or stricter national regulations,
where applicable.
15.2 Chemical safety assessment
No Chemical Safety Assessment has been carried out for this mixture by the supplier.
Further information
Classification of the mixture: Classification procedure:
Resp. Sens. 1 H334 Calculation method
STOT RE 2 H373 Calculation method
The information contained in this Safety Data Sheet corresponds to our level of knowledge at the
time of publication. All warranties are excluded. Our most current General Sales Conditions shall
apply. Please consult the product data sheet prior to any use and processing.
GB / EN
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