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A Simple Analytical Method To Estimate All Exit
A Simple Analytical Method To Estimate All Exit
Cairo University
ORIGINAL ARTICLE
A R T I C L E I N F O A B S T R A C T
Article history: The dehumidifier is a key component in liquid desiccant air-conditioning systems. Analytical
Received 16 December 2012 solutions have more advantages than numerical solutions in studying the dehumidifier perfor-
Received in revised form 5 February 2013 mance parameters. This paper presents the performance results of exit parameters from an ana-
Accepted 23 February 2013 lytical model of an adiabatic cross-flow liquid desiccant air dehumidifier. Calcium chloride is
Available online 30 March 2013 used as desiccant material in this investigation. A program performing the analytical solution
is developed using the engineering equation solver software. Good accuracy has been found
Keywords: between analytical solution and reliable experimental results with a maximum deviation of
Dehumidifier +6.63% and 5.65% in the moisture removal rate. The method developed here can be used
Regenerator in the quick prediction of the dehumidifier performance. The exit parameters from the dehumid-
Liquid desiccant ifier are evaluated under the effects of variables such as air temperature and humidity, desiccant
Analytical solution temperature and concentration, and air to desiccant flow rates. The results show that hot humid
Structured packing bed air and desiccant concentration have the greatest impact on the performance of the dehumidi-
Desiccant cooling fier. The moisture removal rate is decreased with increasing both air inlet temperature and des-
iccant temperature while increases with increasing air to solution mass ratio, inlet desiccant
concentration, and inlet air humidity ratio.
ª 2013 Cairo University. Production and hosting by Elsevier B.V. All rights reserved.
Introduction handles the latent load, while sensible cooling handles other
load portion. Traditional vapor compression equipment
Ongoing increase in the air-conditioning load which is the sum overcools air-stream to provide cooling and dehumidification.
of the sensible and latent load represents 20–40% of the overall Air-conditioning operates at a temperature colder than the
energy consumption in a building [1]. Dehumidification supply air dew-point temperature, so the supply air needs
reheating before entering the space to ensure indoor air
quality. Liquid desiccant dehumidifier is used as an alternative
* Tel.: +20 1005852335. to the conventional air dehumidification systems. An energy
E-mail address: mahgoub.m@gmail.com savings, relative to conventional vapor compression systems,
Peer review under responsibility of Cairo University. of up to 40% can be achieved by using a desiccant assisted
air-conditioning system [2]. One-dimensional differential heat
and mass transfer models are well established and were
frequently used to study the performances of packed bed
Production and hosting by Elsevier
dehumidifiers and regenerators. A theoretical model for a test
2090-1232 ª 2013 Cairo University. Production and hosting by Elsevier B.V. All rights reserved.
http://dx.doi.org/10.1016/j.jare.2013.02.002
176 M.M. Bassuoni
Nomenclature
column with LiBr solutions was developed by Factor and column has been developed, based on the Runge–Kutta fixed
Grossman [3]. The interface temperature and concentration step method, to predict the performance of the device under
were assumed to be the bulk liquid temperature and concentra- various operating conditions. Good agreement was found be-
tion. Overall, heat and mass transfer coefficients were utilized. tween experimental tests and the theoretical model. Davoud
The model was validated with the experimental results. For and Meysam [16] presented a new analytical solution of heat
CaCl2, LiCl and cost effective liquid desiccant solutions and mass transfer processes in a packed bed liquid desiccant
(CELD), the individual phase heat and mass transfer coeffi- dehumidifier. They results revealed that design variables such
cients were calculated and correlated for various packing mate- as desiccant concentration, desiccant temperature, air flow
rials [4,5]. Analytical expressions of the air and desiccant rate, and air humidity ratio have the greatest impact on the
parameters in the counter flow dehumidifier are provided by performance of the dehumidifier. The liquid flow rate and
Stevens et al. [6]. Within the model, the analytical solution of the air temperature have not a significant effect. Furthermore,
the air enthalpy and liquid desiccant equivalent enthalpy, the effects of air and liquid desiccant flow rate have been re-
which expressed the capability of the combined heat and mass ported on the humidity effectiveness of the column.
transfer process, is first calculated. Then, the solutions of the Heat and mass transfer coefficients were used to numeri-
air humidity ratio and desiccant equivalent humidity ratio, cally solve most models in the literature. This paper proposed
which expresses the capability of moisture transfer, are given. a simple analytical model of the bulk heat and mass transfer
Finally, the air and liquid desiccant temperature can be calcu- processes in a cross-flow liquid desiccant air dehumidifier.
lated according to the above enthalpy and humidity ratio cal- An empirical correlation for calculating the dehumidifier effec-
culated result. A method for finding the analytical solution of tiveness introduced by Moon et al. [17] is used to perform the
the coupled heat and mass transfer performance for the dehu- analytical solution of the presented model with acceptable
midifier and regenerator was reported before [7,8]. Analytical accuracy. Comprehensively, this model is used for studying
solutions of the air enthalpy and desiccant equivalent enthalpy the effect of operating parameters on the whole dehumidifier
field within the cross-flow dehumidifier/regenerator were given performance. The analytical solution shows good accuracy
[9,10], where the air and desiccant are not mixed breadthwise when compared with reliable experimental data available in
(which means the transfer processes of the air and desiccant the literature.
are both two dimensional). The enthalpy field gained from
the analytical solutions compares well with numerical solu- System description
tions, and the analytical enthalpy efficiency compares well with
experimental results of the cross-flow dehumidifier. Based on energy and mass laws of conservations, the proposed
Researchers [11–13] have developed mathematical models analytical model has been developed as a tool for evaluating
of the coupled heat and mass transfer processes in the dehu- the performance of a cross-flow liquid desiccant air dehumid-
midifier or regenerator, and most of the models were solved ifier. This model describes rationally the bulk coupled heat and
numerically. In Liu et al. [14], an experimental study of the mass transfer processes taking place inside the dehumidifier.
performance of the cross-flow dehumidifier was done, which From Fig. 1, the strong desiccant solution is supplied to the
has been less studied than the counter flow dehumidifier, dehumidifier at suitable concentration and temperature. At
although it is more applicable in practice. The moisture re- the same time, process air flows continuously across the dehu-
moval rate and dehumidifier effectiveness were adopted as midifier. Due to the vapor pressure difference between air and
the dehumidifier performance indices. The effects of the dehu- desiccant solution, the process air is dehumidified. The dryer
midifier inlet parameters on the two indices were investigated. the exit air is, the higher the rate of water vapor absorbed by
Correlations have been proposed to predict the cross-flow the strong desiccant solution which leads to weak desiccant
dehumidifier performance, which give results in good agree- solution at the dehumidifier exit. The following initial param-
ment with the present experimental findings. The results from eters should be assumed during calculation procedure: concen-
studying the performance of a counter flow liquid desiccant tration and temperature of desiccant solution at dehumidifier
dehumidifier were presented by Koronaki et al. [15]. A heat inlet, mass flow rate of inlet desiccant, humidity ratio, temper-
and mass transfer theoretical model of an adiabatic packed ature, and mass flow rate of inlet air.
Liquid desiccant cross flow air dehumidifier 177
of air which in thermal equilibrium with CaCl2 solution at the concentrations from the plot digitizer are fed to the presented
interfacial area in C, and it is assumed to be equal to the des- model, and the results are shown in Fig. 2. According to these
iccant solution temperature Ts. results, good agreement between the experimental data of
The partial vapor pressure on the surface of CaCl2 solution Moon et al. [17] and the analytical results of present study is
(pv) in mm Hg is calculated using the correlations introduced achieved. In all cases, the most of predicted values for MRR
by Gad et al. [19]. Constants of Eq. (12) and its operating are higher than the experimental values, and the discrepancy
range are shown in Table 1. may be due to the assumptions made in the analysis. However,
ðbo þ b1 XÞ the maximum deviation in MRR is +6.63% and 5.65%.
lnðpv Þ ¼ ðao þ a1 XÞ ð12Þ
Ts þ C
Results and discussion
The above mentioned analysis shows the dependence of the
absorption process, air dehumidification, on operational
After the validation of the analytical model with the experi-
parameters such as air inlet humidity and temperature, inlet
mental results, an extensive theoretical investigation was con-
concentration and temperature of the desiccant solution, and
ducted to examine the effect of various operating parameters
air to desiccant solution mass flow rates. The proposed math-
on the adiabatic dehumidifier performance. The parametric
ematical model is constituted from coupled algebraic equa-
study includes the effect of air inlet humidity ratio and temper-
tions integrated with the correlation from Moon et al. [17].
ature, air to solution mass ratio, inlet desiccant concentration,
A program for the analytical solution is developed using the
and temperature on the exit dehumidifier parameters. Table 2
engineering equation solver software. The inlet parameters
provides the operating conditions considered for all cases in
for both air and desiccant solutions are introduced into the
the parametric analysis. The effect of each five parameter is
program, and then, the exit parameters of the desiccant solu-
studied, while the other parameters are held constant.
tion and process air are calculated.
Effect of inlet air humidity ratio
Validation of mathematical model
The effect of inlet air humidity ratio (ya1) on the moisture re-
Before evaluating the effect of various operating parameters moval rate, dehumidifier effectiveness (MRR, ey; respectively),
on the performance of the adiabatic air dehumidifier, the val- and the exit parameters from the dehumidifier; air humidity ra-
idation of the developed analytical model should be achieved. tio, air temperature, solution concentration, and solution tem-
For this purpose, reliable experimental data from Moon et al. perature (ya2, Ta2, X2, and Ts2, respectively) is shown in Fig. 3.
[17] were selected. A plot digitizer program is used to extract As illustrated, when the inlet air humidity ratio is increased,
point data from Moon et al. [17]. The obtained inlet desiccant MRR, ya2, and Ts2 are increased, while ey, Ta2, and X2 show
no significant effect. To a great extent, the partial vapor pres-
0.001 sure is the governing factor of the mass transfer occurs be-
tween process air and desiccant solution. As the inlet air
Moon et. al. [17]
humidity ratio increases, the partial vapor pressure of air also
Present study
increases which in turn enhances the difference between the
partial vapor pressure in the inlet air-stream and that on the
desiccant solution surface resulting in an increase in the mois-
0.0008
ture absorbing capacity of desiccant solution. This increase
MRR, kgv/s
Table 2 Operating conditions for the cases considered in the parametric analysis.
Cases Inlet values for the parametric analysis
ma/ms ya1 (kgv/kgda) Ta1 (C) X1 (kgd/kgs) Ts1 (C)
Fig. 2 0.64 0.02157 30 0.33–0.43 30
Fig. 3 1 0.016–0.026 40 0.43 20
Fig. 4 1 0.018 26–40 0.43 20
Fig. 5 1 0.018 40 0.33–0.43 20
Fig. 6 1 0.018 40 0.43 26–36
Fig. 7 0.25–2 0.018 40 0.43 20
38
MRRR
ya2
0.6 Ta2
0.02
Ts2 36
10, kg v /s & ya2 , kgv /kgda
X2
Ey
& X 2 , kg d /kg s
Ta2 &T s2 , oC
0.5 34
0.016
32
εy
MRR*10
0.4 0.012
MRR
30
εy &
( a/m
(m ms=1
1, Ta11=40°°C ,T
Ts1=2
20°C
C, X1=0.43
= 3)
0.3 0.008 28
0.0
016 0.02
2 0.0
024
ya1, kgv/kgda
Fig. 3 Effect of ya1 on dehumidifier parameters (MRR, ey, ya2, Ta2, Ts2, X2).
MRR 36
ya2
0.7
Ta2
Ts2
MRR*10, kg v /s & y a2 , kg v /kg da
X2
0.016
Ey 32
0.6
& X 2 , kg d /kg s
T a2 &T s2 , oC
28
0.5
0.012
εy
0.4 24
0.3
(ma/ms=1, ya1=0.018 kgv/kgda ,Ts1=20°C, X1=0.43)
0.008 20
24 28 32 36 40
Ta1, oC
Fig. 4 Effect of Ta1 on dehumidifier parameters (MRR, ey, ya2, Ta2, Ts2, X2).
180 M.M. Bassuoni
34
MR
RR
0.014 ya2
0.6
6 Ta
a2
Ts
s2
/k da
X2
2
k v/kg
Ey
y 32
0.013
/ & y a2 , kg
εy & X2, kg d/kg s
Ta2 &T s2 , oC
0.5
5
0.012
k v/s
30
0.4
4 MRR*10 kg
MRR*10, 0.011
28
(ma/ms=1, ya1=00.0188 kgv/kgda
d ,
0.0
01
Ts1=200°C, Ta1=40°C
C)
0.3
3
0.32 0.34 0.36
6 0.38
8 0.4
4 0.42 0.4
44
X1, kgd/kgs
Fig. 5 Effect of X1 on dehumidifier parameters (MRR, ey, ya2, Ta2, Ts2, X2).
decreased, but Ta2, ya2, and Ts2 are increased, while X2 has no Effect of inlet desiccant concentration
significant change. This may be explained as follows: as the in-
let process air temperature is increased, the temperature of the Fig. 5 shows the effect of inlet desiccant concentration (X1) on
desiccant solution inside the dehumidifier is increased which in the MRR, ey and the exit parameters from the dehumidifier;
turn increases Ts2, Ta2 and the partial vapor pressure on the ya2, Ta2, X2, and Ts2. When X1 is increased, MRR, Ts2, and
desiccant surface. When the desiccant surface vapor pressure X2 are increased, but the dehumidifier effectiveness and Ta2
increases, the potential of the absorption process is decreased are slightly changed. When X1 increases, vapor pressure on
causing air to become more humid (i.e., low Dya) and in turn the desiccant surface is reduced leading to low ya2 which in
low MRR. On the other hand, the reduction in Dya is greater turn increases MRR. As shown from Table 2, the inlet air tem-
than the decrease in (ya1 yeq) which leads to low ey. When perature is higher than the inlet temperature of the desiccant
Ta1 is increased from 26 C to 40 C, both MRR and ey are de- solution resulting in high Ts2. Both ya2 and yeq are decreased
creased by about 11.6% and 11.8%, respectively, but Ta2, ya2, but at different rates which means that the numerator of Eq.
and Ts2 are increased by a percentage of 31.58%, 9.5%, and (9) is to some extent smaller than its denominator; so, ey is
6.8%, respectively. slightly reduced. Increasing X1 from 0.33 to 0.43, MRR, Ts2,
0.016
MRR
44
ya2
Ta2
0.8 0.014 Ts2
MRR*10, kgv /s & ya2, kgv /kgda
X2
Ey
40
εy &X2, kgd/kgs
Ta2 &Ts2, o C
0.012
0.6
0.01 36
(ma/ms=1, ya1=0.018 kgv/kgda,
X1=0.43, Ta1=40°C)
0.008
32
0.4
0.006
28 32 36
Ts1, oC
Fig. 6 Effect of Ts1 on dehumidifier parameters (MRR, ey, ya2, Ta2, Ts2, X2).
Liquid desiccant cross flow air dehumidifier 181
0
0.7 50
0
MRRR
ya2
Ta2
Ts2
εy &X2, kgd/kgs
Ta2 &Ts2, oC
0
0.5
MRR*10,
0.01 30
0
MRR
0
0.4
Fig. 7 Effect of ma/ms on dehumidifier parameters (MRR, ey, ya2, Ta2, Ts2, X2).
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