Calculate the [H’] Of a solution containing 0 01M CH,CICOOH and 0.002 M CH,CICOONa. Ka for CH,CICOOH = 136 x 10°§ | 2 The self ionisation constant for pure formic acid, K = [HCOOH] [HCOO'] has been estimated as 10° at room temperature. The density of formic acid is 1.22 gicc. The percentage of formic acid molgetiles in pure formic acid converted into formate ion is (0.02% (B) 0.04% (C) 0.06% (0) 0.08%. 4. Whighrdoes not react with NaOH or which is not acid salt? (bYNaH2PO NayHPO3 (C) NagHPO, (D) NaHCO Which of the following are acid-base conjugate pairs: "@YHONO, NO>- (B) H30*, OH {OxCHgNHg*, CHaNHo ore So 5. In the following reaction 3+ 7 a [cuH.o), (on) ][AH.0), > [cutti0), }* + [a\,0), (oF)] a) ®) © ) (A)Ais an acid and B the base {Bis a base and B the acid ) Cis the conjugate acid of A, and D is the conjugate base of B (0) Cis the conjugate base of A, and D is the conjugate acid of B Ted yaad Conon Saiabad | + Nerayanagude + Diguepenger * fuatpaly, Miyapur Prccio-cerrvony * prron-aeseatea‘SP.WBVI(A)-CH(LE)-90 ke > ks 7. and STATEMENT-2: The [H’] furnished in 1° step of dissociation exerts common ion effect to reduce 2"! dissociation and so on. 445 Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement~ (8) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct Explanation for Statement—1 (C) Statement-1 is True, Statement-2 is False (©) Statement-1 is False, Statement-2 is True 8 STATEMENT-1 : pH of aqueous solution of acetic acid increases with dilution. and STATEMENT-2 : The degree of ionization of acetic acid increases with dilution (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement—1 (8) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct Explanation for Statement—1 (C) $tétement-1 is True, Statement-2 is False 8. STATEMENT-1 : For heavy water, D0, the dissociation constant is one-fifth of that of HzO at 25°C. The pD (pD = —log[D")) of pure heavy water will be less than pH of pure water. and STATEMENT-2 : Dissociation constant depends upon nature of electrolyte (A) Statement—1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (8) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct Explanation for Statement—1 (C) Statement-1 is True, Statement-2 is False {BY Statement-1 is False, Statement-2 is True DAY-25 a SLEEVE nn] 1 Calculate the [H"] and [OH] in the following solutions : (i) 0.02 M HCI (ii) 0.005 M NaOH,‘sP-WB{VIA)-CHIIE) 91 jae the pH of solution on obtained by mixing 10 ml of 0.1 M HCl and 40 mi of 0.2 M H:SOs 100 ml of 0.1 MHC! and 9.9 ml of 1M NaOH. A solution of HCI has a pH = 5. If one mi of itis diluted to 1 litre, what will be the pH of the resulting solution?sP.waqvinA-CHOE}92 with SmI water assuming Calculate the pt of ho solution made by mixing 60m of 001M Ba(OH) with 50m 7 complete ionisation Which fhe following aids i stvonger than benzoic acd (K, = 6:3x10"*)? (a) A(K, =1.62«10") (8) Bipk, =6) Ley Clek, = 4) (0) D{k, = 1.010") 7. When NHCt is added to solution of NH,OH (A) Only the concentration of OH” ions increases _{ByOnly the concentration of OH” decreases (€) The concentaion of NH; ions detteases (0) the concenzaion of NH; as wellas OH" ions increase. 8. STATEMENT-1 : On increasing temperature pH of H,O decreases and STATEMENT-2 : At high temperature water become acidic. (A) Statement-t is True, Stalement-2 s True; Statement-2 isa correct explanation for Statement-1 {@) Stalement-1 is True, Siatement-2 is True; Statement-2 is NOT a correct Explanation for Staterment-1 ‘Statement-1 is True, Statement-2 is False (0) Statement-1 is False, Statement-2 is True. TAL ij airabad Conars Saliabad , ¢ Nargyanaguda + Dilsukhnagar” + Kukatpally enema * pingSpllSP-WBIVIN(AY-CHIIE) $3 calulate forthe reaction x 4H0" == HA+H,0 ir ka valve for the acid HA is 1x 19° A Aspirin tablet contains 324mg of asprin kg= 3x 10". What is the pH of the soluti solution in water. {acetyl salicylic acid CgHgO.) a monoprotic acid having ion if two aspirin tablets are dissolved to prepare 300mI of 3. Find the concentrations of H’, HCOs” and CO; in a 0.01 M solution of carbonic acid if the pH of solution is 4.18. Ky = 4.45 107 Kp = 4.69 x 10SP-wecyAycHiE-e4 4, Does the pH increase, decrease, or remain the same on addition of each of the following 7 (@) LIF an HF solution’ (b) KI to'an Hi solution (c) NH,C! to an NH; solution 5. Phenol(CgH,OH,K, =1.3x10") is @ weak acid used in mouthwashes, and pyridine (CHAN, =1.8:10")is @ weak base used as a solvent. Calculate the value of Ky for neutralization of phenol by pyridine. Does the neutralization reaction proceed very fer toward ‘completion 7 M HCI. Calculate the concentration of S* and HS” fons in solution contains 0.1 M HS and 0. S 4a ay 1.3% 10°, solution, For HzS, Ka; = 10” and KazSP-ANBIVIYA)-CHIIE)-95 consider the tation of 60.0 mL of a 0.100 M solution of the protonated form of the amino acid (nee (AAO 20510 *®) with 0.100 M NaOH. Calculate the pH after gaaton of 2808 ofthe flowing volumes of base ® oom ©1250. (©) 50.0mL (4) 750.0 mL (e) 100.0 mL What will be the resultant pH when 200mi = 20) is mixed with § 300m! of an aqueous solution of NaOH. on shea solution of HCI. (pH = 2.0) is mixe 4 Asolution of 0.01M concentration of NH,OH is 2.6% dissociated. Calculate the pH of the solution. —e@ Hyderabad CentersSSPLNBIIALCHIE}6 10. 4) Calculate tho pH of a 0.001 M solution of benzoic acid, the Ky being 7.3410 ee solution at that {(b) 0.2 M solution of Ba(OH), is found to bo 90% ionized at 25 'c. Find the pH temperature CVE TT 12 “The percentage ero in hyrtium fon concentration made by neglecting the ionisation of water in 1 x10 M NaOH is (A) 1% (8)2% (C)3% Ae Given Hays (HON) = 45.2 kd mol & AHxe(CHsCOOH) = 2.1 ksfmol (8) pka (HCN) = pKa (CH;COOH) pKa (HCN) > pKa (CHjCOOH) (©) pa (HON) < pka (CH,COOH) (O)pka Hon) = “S17 pka (cH,COOH) TT I TS UT CORE 13, ‘of the folowing isfare true about alkanty ? (A) AS metal hysroxdes ae water-soluble onic ols, most fair bases 14 (8) Akaline earth oxides, such as CaO are weaker bases than corresponding hydroxides 10.289 of ime (CaO) in re water gives a solution of pH = 12 (0) 10°” M NaOH solution has pH value 7 100ml of 05 M hyéazl acl (HN 18x 107) are mixed. Which ofthe following is (are) true for te final solution ? pit]? rfe]-26e19* — ofoew ]-asrit0® (yr ]-tantt 610°) and 400 ml of 0.1 M cyanic acid (HOCN, K 16 STATEMENT - 1 : pH of HCI solution is less than that of acetic acid solution of the same concentration ‘and STATEMENT - 2 : In equimolar solutions, the number of titrable protons present in HCI acid is less ‘than that present in acetic acid (A) Statement-1is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct Explanation for Statement-1 (C) Statement-t is True, Statement-2 is False (0) Statement-1is False, Statement-2is True. fenced Co aSP-WE(VIVA)-CH(E)S7 calculate 1 qpthe degree of hydrolysis 7 Of a decinormal KCN solution at 25 °C. The dissociation constant of HCN so 72x10" and ionic product of water is 10-4 {ithe pH valve ofthis solution, ‘Also find 1 Calculate (i) the hydrolysis constant of NH,CI and (i Ser tn 2nd (i) the [OH] ia a 0.4 Mi NHLCI soliton Tee gy cages ch pst ogra acme area 4:10” ard that of CH,COOH is 1.810" (ji) also calculate ts pH value. prea igs eee ‘°ilsukhn a + nave 6 Nwp + maaan eset, satatag + NennaaSP.WBQVIVAFCHIE) 100 ee TT fares id and strong base is dissolved in Fydrelyais is reverse process of neutralization. When a salt of @ strong ac aa Hyd ton romans neal since no Rydro}yss takes place, but when 2 salt of weak aci trong Pareto ig NaCN is cissolvod in water, the solution is basic due to anionic hyerolysis CN 4 H,0.¢HNC-+OH ‘ opr ic due to cal Similarly, aqueous solution of a salt of a weak base and strong acid is acidic due h amt ouuton of he salt of a weak acid and weak base may be acidic, basic of neutral depending on be ‘ain strengths of weak acid and weak base, Hydrolysis constant Ky and degree of hydrolysis It = (forthe salt of weak acid and strong base) K, ereretcted as h= Xt ond Kk, = Cc K, Where C is the concentration of salt. ‘The pH of a salt in water can be calculated using the above expression, 7. The amount of NH,Clto be dissolved in 500 mito have pH = 4.0 (Ke of NH,OH = 1.0.x 10"), is a)O1M b)1.0M c) 10M. d)0.01M 8. _pHofa0.5M aqueous NaCN solution (pKy of CN’ = 4.70) is aya b)95 0105 118 9. Degree of hydrolysis of 0.01 N ammonium acetate is (K, of CH,COOH =10° = K, of NH,OH) a)1% b)2% ©) 10% d)12% 02 mole of BOH (Ky = 3 *10°) med |p| pr=PY +109 [A] — log [HA] (A) | with 0.1 mole of HySO, e) eee 0.2 mole of BOH (Ky = 3 x 10°) mixed he PX 4 (®) | wi'02 mote of HA (K,=2x 10°) (a) | pi= PrsPvoae 02 mole of NAOH mixed with 02 mole of (C) (HA (K,=2 x10") (R) 0.2 mole of KOH mixed with 0.4 mole of (©) | HA (K,=2 x 10%) (&) [MEER Taya Cos Salabad + Naaynagute ve Diaukanager 4 areas ee mccoy, * Mapusp.nBivivAPCHTENO% A independent fanoentration 0K, + OK, eatin nich ofthe following gives a buffer solution wh y oOMre a OH EE ‘when equal volumes of the two solutions are mixed (t)0.10M HF and 0.10 M NaOH (c)0.20M HF and (010M HC! and 0.20 M NaF : HE anda 10M NaOH Hyderabad Centers oo Sette Memampae Oe” + tag, + py mM,‘SP-WB(VIYA)-CH(IE)-102 2 Compare the effect of adding 0. H’ to 1L of formic acid — formate buffer in which the moles of H’ to 1L i ‘concentration of HCHO, and CHO,” are each 1M. Determine the pOH of a solution after 0.1 moles of NaOH is added to 1L of a rte enn 0.15 MCHsCOOH and 0.2 M CH;COONa. Assume no change in volume. o You need a buffer solution that has pH = 7.00. Which of the following buffer systems should you choose ? Explain. (a) HsPO, andH,PO; —(b) H2PO, andHPO{” (c) HPO2- and PO}SsP.WB(VINAPCH(IE)109 solution i prepared volo 3H-O) and making the THY 6 9. of acotle acid and 13.6 9. of sodium acotale (oll volume 10250 mi, Caeulato () te pH ofthe solution AM Hlto it k i dion of (eA Sange on adtiton of 1 my a or 8x10" tos solution of acetic acid, solid sodium acetate is added gradually. When x mole of salt is added, H has a certain value. If y mole of ic met aiocbnandy. y salt is added, the pH changes by 0.6 units to previous pH. ‘solution of weak base BOH was titrated with 1 M HCI. The pH of the solution was found to be (J904'and 9.14 after the addition of § ml and 20 ml of the acid respectively. Find the dissociation Constant of the base. pee — pa yaw Care Saba aguda e Diaukmagar + Kusaipaly, + My Riccar * afebeeue rwoweroe poe peel stnSSP.NBIVIYAHCHIIEHIO4 8 wath 0.200 M NaOH. How many mie of base are tion of 40.0 mL of 0.250 M HF eine following points cn an tt era a {a) After addition of 10.0 mL of base {b) Halfway to the eq 1 Mor base {c) Atthe equivalence point (d) After addition of 80. a a 10. pee ir oe (peomcint mare soo When equal volumes of 0.1M CH,COOH and 0,05M Ba(CH:COO)z are mixed, the resulting solution ‘shows maximum buffer capactty. gy.yz pH of a midure of 1M benzoic acid (pK, = 420) and 1M sodium benzoate is 4.5. In ‘300m buffer, benzoic acid is b (A) 200ml (8) 150m! sey 0omt (0) 50m! Fear or excitement, generally causes one to breathe rapidly and it Concentration in blood, In what way wilt change the pH of Shear {anu te Gocreane oes (A) pH will increase (8) pH will decrease {OFNo change (0) pH will adjust to 7 “The [NHJ ina solution thatés 0.02 M NHs and 0.01 M KOH. KD(NHs ) = 1.8 x 10 in M lb) =1.8x4 (A) 18x10 shen (C)9x 10° , Daan? ‘ti yaeabed Coos Saltabed + Narayanaguda + + Kukatpally —¢ Miyapur‘SP.WB{VIVAYCHIIE)-105, information can be derived from the fast. a0H ar xd to an aqueous via oP, containing 1.0 nmol ne 2a whan 1.5n mol of NaOH ae aged oan 2 4 sol =103 ition is fount to bo noutral ? of HsPO, = 10 J ak (BY, of HPO, - 10 PO, = 10°” oH {) none of those re ne pH of @ solution of 0.10 M CHaCooH, increases when which of the following substances is ‘ ? ase _ (B)HCI0, AT 004 (0) KC03, a flask om Tt mL of 0.100 M HOAc. To prepare a buffer with pH = pK, which of the ing samples of barium acetate wey30.00 mL of 0.400 MBa (Ores Solution should be added to the flask? 8525.00 mL of 0.200 M Ba (OAc)y sd oF 0.100 M Ba (ORc)p (0) 100.00 mt of 0.100 M Ba (OAc) Whi of the following mixtures can act asa butler? (a) NAOH + CHCOONa (1 : 1 molar rato) “EYCrgCOOH + NaOH (2 + molar ratio) _FACHGCOOH + NaOH (3 1 molar rato) (0) CHyCOOH + NaOH (1: 1 mola rato) i pees of (NH4)S0, to 0.1 M NH ‘OH ion concentration will decrease (8) H50" ion concentration will decrease (C) pH wil increase H wil decrease bei 4. Towhich of the following, addition of water would not affect the pH (A) 300 ml of 0.2 M CHsCOOH + 100 mi of 0.2 M NaOH 200 mi of 0.2 MCH;COOH + 100 ml of 01 M NaOH {C) 100 ml of 0.2 M CHsCOOH + 200 mi of 0.2 M NaOH {97100 ml of 0.2 M CH;COOH + 100 ml of 0.1 M NaOH 12 Which ofthe following in aqueous solution do not considerably change in pH when relatively small volumes of strong acid or strong alkali are added ? _Ariture of sodum carbonates sodium hydrogen carbonate BVA mixture of sodium ethanoate and ethanoic acid {C)A mixture of sodium sulphate and sodium chloride _JDYA solution of ammonium acetate 41. _Bufer solution A of a weak monoprotic acid and its sodium salt in the concentration ratio x: y has pH = (pH. Buffer solution B of the same acid and its sodium salt in the concentration ratio : x has pH = (pH)s. If (pH). — (pH): = 1 unit and (pH), + (pH), = 9.5 units, then 15 (e)% =2.36 SPE y 162 (0) pk, =5.25 " STATEMENT-1 : An aqueous solution made by adding CH;COOH and CH,COO"Na’ to water in nok rato, nzuheren, >> m,n sion can take mre a than base wihout geting pl ‘changed substantially. STATEMENT2: A good burs made when conceit ofa and base fers substantial in . * buffer solution. er Saiamad —¢Narayanaguda + eten * Mabie + Kukatpally 6 Miyapur penmanants* oy aESSP.WB(VIYA}-CH(E}-106 ct explanation for Statement-1 [-1 is True, Statement-2 is True; Statement-2 is a corre ean ® Stern t a True, Slalement-2 is True; Statement-2 is NOT a correct Explanation for Statemerit-1 AE) Stoement-t is Tue, Statomen-2 is False {D) Statement-1 is False, Statement-2 is True ts as ab 13, STATEMENT - 1: A mixture of the solutions of a weak acid and its sodium salt act ter solution d STATEMENT 2 : Tho pH ofthe solion doesnot change substantially when small amount of aig or base is added to the bulfer. (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement—1 (8) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct Explanation for Statement-1 {C) Statement-1 is True, Statement-2 is False (0) Statement-1 is False, Statement-2 is True. 14. STATEMENT - 1 : Ifa weak acid formed and in that buffer pH = pk, and STATEMENT — 2: Since, in solution [weak acid] = [conjugate base] (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement—1 (8) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct Explanation for Statement—1 (C) Statement is True, Statement-2 is False (0) Statement—1 is False, Statement-2 is True 18. STATEMENT-1 : The pH of an aqueous of CH;COOH remain unchanged on the addition of CHsCOONa and GTATEMENT-2 : The ionization of CHsCOOH is supressed by the addition of CH;COONa (6) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement—1 (8) Statement-1 is True, Statement—1 Statement-2 is NOT a correct Explanation for (C) Statement—1 is True, (0) Statement—1 is Fal is exactly half neutralized by strong base, then buffer solution is Statement-2 is True; , Statement-2 is False Statement-2 is True CCR SOON} 1 16. Match the following 500 mL 0.2 M NaOH is added to 50 mL Buffer sol | 0.1 MCH,COOH © [oon 500 mL 0.1 M NaOH is added to 500 mL H = pK, orf ® | 0.1 MCH,COOH (a) | PIT PRS oF By 500 mL 0.1 MHClis added to 500 mL-O.7 Sal © a tHe (R) | Salthyaroiysis p) | 500 mL 0.05 M HCI is added fo 500 mL 7 ©) 0.1 MNH.OH (8)_| PH> Sok, ae ‘Mt Hyderabad Gomes 7 re en Piatt * Nafyanagud + Dilsukhnagar rotateSP.WB(VINAY-CHIIE) 107 solubility product of PbBr, is 810° owolity of the salt. the salt is 80% dissociated in saturated solution, find t Le Chateliler's 1 ep erease on Sia Aas esate ‘Ag,C0s in water “ Increase on addition of AgNO; (@ Decrease on adn of NazCO, Cees acon of Ns 4 Atwhat minimum pH will 10 mol of Al(OH); 90 into solution (V = 1 L) as AKOH).” and at what maximum pH it will dissolve as Al”? Given ‘AI (OH)c == Al" + 40H Keg = 1.3 x 10 Al(OH) =A + 30H” Kyp = 5.0 10° A an gaara Co Me uaa gute Dimas + Narayan “pigoinager * fa Salabad °c Miyapur,‘SP-WB(VI(A)-CHIIE)-108 MEE) 4. The precipitate of CaF, (K,, — 1.710 ") is obtained on mixing equal volumes of (A) 10 ‘Ma?’ and 10 * ME (8) 10 7MCa® and 10? MF (©) 10 °MCa? and 10? MF (0) 10 °MCa?’ and 10 * MF 5. The pH of Mg(OH), is 10.45 at 25°C. The solubility product of mmgansium nyaroxide woul be (A)224<10°"M (B)3.36« 10" MPC) 1.12% 107M? (D) 5.60 x 2 6. Calculate the pH at which Mg(OH), begins to precipitate from solution containing 0.1 M Mg” ions, sp for Mg(OH)s is 1.0 x 107 (aya (6)9 (5 ce AMAR cccASSERTION~ REASONING TYPE, «islam 7. STATEMENT ~ 1: The solubility of AgC! in water decreases if NaCl is added to it and STATEMENT - 2 : NaClis highly soluble in water where as AgCI is sparingly soluble (A) Statement-1 is True, Statement-2 is True; Statement-2 isa correct explanation for Statement-1 ©) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct Explanation for Statement—1 (C) Statement-1 is True, Statement-2 is False (0) Statement-1 is False, Statement-2 is True 8. STATEMENT ~ 1: In third group of qualitative analysis, NH,Cl is added to NH,OH medium and STATEMENT ~ 2: This is to (A) Statement is True, St (8) Statement-1 is True, Statement-1 (C) Statement-1 is True, Statement-2 is False (0) Statement-t is False, Statement-2 is True. Convert the ions of group into their respective chlorides. 'atement-2 is True; Statement-2 is a correct explanation for Statement-1 Statement-2 is True; Statement-2 is NOT a correct Explanation for DAY-32 [ee ee EE Key for StF 2 = 2.8 x 10° at 25°C. How much NaF should be added to 100m! solution of 0.016M Sr* ions to reduce its concentration to 2.5 x 10" M? ~ FC iydorabed Coniors a mittens * MatRnggede + Diuktnagar 6 ukatzaly 6 MiyapurSP-WBIVIVA}-CHIE)-109 jeate the solubilly of magnesium phosp ‘8 ein rated solution. Given : Ksp pong UIMMg) org teen ert ee eee and M(P) = 31.0 g mol " a (a : ine hydroxide, Zn(OH)(k,, — 4 1% 10°17), is nearly insoluble in water, but is more soluble in strong 2 tase because Zn forms the soluble complex ion Zn( OH)” (ky = 3:10") ye (Kr = What is the molar solubility of 2n(OH), dissociation of water.) in pure water ? (You may ignore OH" from the self ‘M.30°C, the solubility of AgzCOs (Ki, = 8x 10") would be greatest in one litre of (A)0.05MNa,CO, —(B)O.05MAgNO, —_(C) Pure water (0)0.05 mK.co, 5 MOH), has ky, 4 x 10" and solubility 10 M. The value of xis a @)2 (0/3 (04 ‘ Zn satis mixed with (NH,).S of molarity 0.021M. The amount of Zn? remains u D ins unpreciptated Athi sohtton i of 2ns = 4.51 x oy) ee (A)1.677 x 10% g (8) 1.767 x 10g (C)201x 10g (D) none of these "RITIGE Hyderabad Convers ——___ + Soar” + un + livapue‘SP.AWBIVIVA)-CH(E)-110, 7. sly in equilibrium’ with g ou (8) 0 iy gcd ns Ces ASC acai in? ee 7-2[80% |+2[60%] (A\[Aa' ] +2 [Bas ] = 2[S0% }+3[Por " 21-508 [PO ] eed aed] [oa (0e")-(o0t IL ila INOs to it, w A solution consists equal concentration of NaCl and NazCrO« (On adding AGNOs 10, which ofp, following facts is true. Ky (AQCi) =1.710- Ky (AggCrO, ) = 2x10" (A) CrO;? ions are precipitated first (C)CI ions are precipitated first (0) solubility of AgzCrO, increases in presence of AGC! (@) both Cr0;? and Clare precipated together = 17x10" When equal volumes of the following solutions are mixed, precipitation Of CaF2 (Kp = 1.7 x 10) gy will occur only with - pease (A) 10% MCa® and 10% MF (8) 105 Mca and 7 (C) 10° M Ca” and 10° MF (0) 10° M Ca” and 1 1¥ mili mol of Ni? is added to 100m! of a solution containing solid AgrS in equilibrium with ‘Ag+ and S” ions. What wil happen [ksp(Ag,S)=4x10“®, Ksp (NiS) = 10°] (A) Nis will precipitate (8) More AgzS will dissolve (C) More Ag2S will precipitate (0) no change is observed 12, STATEMENT-1 : Addition of siver ions to a mixture of aqueous sodium chloride and sodium bromide solution wil ist precipitate AgBr rather than AgCl and STATEMENT 2 : Kep of AgCI < Kep of AgBr. (A) Statement—t is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (8) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct Explanation for Statement-1 (C) Statement-1 is True, Statement-2 is False (0) Statement-1 is False, Statement-2 is True STATEMENT-1 : Solubility of BaSO, in 0.1 M Na;SO, is 10° M hence its Ky is 10°" and STATEMENT-2: because for BaSO, Key = (5) (A) Statement-1 is Tru, Statement-2 s True; Statement-2is a correct explanation for Statement-1 8) 1 Is Tne, St tM ©) Satement-1 is True, Staement-2 is True; Statement-2 is NOT a correct Explanation fo (C) Statement-1 is True, Statement-2 is False (0) Statement-t is False, Statement-2 is True "WAG Hyderabad Contany —— — Saltabad | + Narayanagude s Oteannacare moore” "memesucte menanaage’ ¢ Kukatpally 4 — iyapur reams * lad teaee‘SP-WBIVI(A)-CHUE)-111, the pH at which an acid indicator with Ka © changes colour when the indicator calculate ty tion is 10° M. Also report the pH at which coloured ion is 80% present 1 goncentral Bromophenol blue is an indicator with a K, value of 5.84 x 10° » ir it aot a pH of 484 7 40°. What % of this indicator is in its basic 2 3. Calculate the pH at whic! is1x10-°M han acid indicator with K, = 110° changes colour when the indicatorSPAWB(VI)(A)-CH(E)-112 ji low. The pH curve of the titration of weak acid with a strong base, is given bel 4 : Rh om ! >| ‘Volume of Tra (beso) Now choose the incorrect option among the following a) pH at point 'P' = le [4,]. where Ag is the intial concentration of weak acid 2° 2 7 (weak acid) ) pH at point '9"= p*: — jog Leak acid) (salt) Cc) pH at point 'R ae oe +Log[sait] " 2 tye ts - Pao 4) pH at point get 3 los[dase] 5 Getithe colour of the indicator Hn (colourless) wil be visible only when is ionized form (pink) is 25% happen (ake ton: Suppose Hin (pK, = 8.0) is added toa solution of prt ae Predict what will happen. (Take log 2 = 0.3) (A) pink colour will be visible (8) pink colour will not be visible (©) % oftonized form willbe less than 25% (0) % of nized fons mn’ more than 25%. 6. The value of indicator constant depends upon (A) temperature (8) pH (C) nature of indicator (0) Poh 7. Dissociation of an indicator can be considered as, Hin=H* +In- Colours of Hin and In- are diferent. Which statement is correct ? A) Solution assumes colours of Hin when pH = Pe (®) Solution assumes colours of in when pH = Pest (C) Solution assumes colours of Hin’ when pH = Pret (©) Solution assumes colours of in~ when pH = PySSP-WBIVINAY-CHOE)-13 eee —— SS aro 20 ation no & suggested. and STATEMENT-2 : pHis reached easily to 8.3 and pink colour isnot seen. S] Statoment-1 is True, Statement-2 fs True; Statement-2is a corect explanation for Statement-1 {8} stotement-1 Is True, Slatement-2 is True; Statement-2 is NOT a correct Explanation for Statement—1 {© Siatement-1 is True, Statement-2 is False (0) Statement-1 is False, Statement-2 is True AAA TASTER GBPGUESTIONS 18D) ead passage 1: pad soution is defined asa solution whose [Ht] > [on Base solution has jou >|H |. During acid-base ations, pH ofthe mixture will change depending on the amount base added. This variation is shown in the Brot f@ph by making plot between pH vs volume of base added. These arephs are known 28 tiation canes 100 mL of 0.1 M Hs A (Ky, =10°, Ky 0-7) is tiated against 0.1 M NaOH. The firation curve is as follows. ‘Volume of NsOH (mL) added —— 4 Whats the pH at point A? (a)3 4 (0) 6 10. What would be the ph if more of NaH, Ais added to the tration mixture at point C? (a) 11.0 (@) 102 (C97 (077 11. What will be the change in pH from point B to point C? (a)28 (8)32 ()46 (0)0.04 Passage 2: Pssage 2: ion acid & base react rapidly to neutralize each olher. Equivalence pont s 2 point at wri Poe aes the base (or oxidizing agent and reducing agent) have been added in equiaient quantities. The fat pont Is the point at which the tration stops. Since the purpose of the indicator is to stop the titration dose to the point at which the acid base were ‘added in equivalent quantities, it is important that the Re othe poo end pon be as cose a8 posible. The fdeaor must change enous 6 pH close Heese eo arr the salt of the acid and base. Significantly, the pH changss Toe rapidly near the tauvalence point. The exact shape of a titarion curve depends on K, and K, of acid and base 2 {s titration curve of HCI against KOH, The pH at equivalent point is The following curve represent er ae (a3 (Bs uphine the titration curve below and answer question. ear ma rrccnnmagar + Kokataly + My er oneukhnagar + Kuba + Miyapur sortbod © Narayanaguda —* -DNGone Seite: * “rma2040 60__—80, Volume of acid added(mL) ® a son oer may ner oy NaOH —(C) HCé by KOH (0) NH, by HNO, “ Cy Matyorange eyeramatyal (C) Methyl red (0) All of these 15. Trepk at equivalence Potts a on DAY-34 rr 1 Consider the titration of 60.0 mL of 0.150 M HNOs with 0.450 M NaOH. (a) How many milimoles of HNO; are present at the start of the titration? (b) How many milters of NaOH are required to reach the equivalence point? (c) What is the pH at the equivalence point ? (4) Sketch the general shape of the pH titration curve. eee _ IAG Hyderabad Gentes Salons Nanya a eee re rrowainsn * Miyapur‘SPAVB(VIVAYCHIE)-15, é SINGLE CORRECT az ae Met orange gives red colour in {A)KOH solution ——_(B) HCI solu (C) Na,CO, solution (D) NaCr solution EES ME ‘hich of the following statements about a weak acid strong base titration is/are correct? (A). The pH after the equivalence point of the weak acid strong base titration is determined by using the Ke expression for the conjugate base. Oa baflersluon of weak acid an is conugete base i formed befor the equivalence is re (C). The pH at the equivalence point of a weak monoprotic acid strong base titration is equal to the pH at the equivalence point ofa strong acid—strong base titration, (0). The increase in pH inthe region near the equivalence point ofa weak acid strong base tiation is grater than the pH change in the same region of a strong acid strong base titration ‘An acid-base indicator has K, = 10°. The acid form of the indicator is red and basic form is blue. Which of the following is/are correct? (A). At pH = 4.52, solution is red (8). At pH 5.47, solution is blue. {C). At pH = 6, solution is 75% red (0). At pH = 8, solution is 75% blue. What is general criteria of choosing a suitable indicator for a given titration? (A). The inidcator should have a broad pH range. (8). pH at the end point of titration should be close to neutral point of indicator (C). The indicator should have neutral point at pH = 7. (0), The indicator must show a sharp colour change near the equivalence point of titration point. Which of the following are true for an acid-base titration? (A). Indicators catalyse the acid-base reactions by relasing or accepting Hons. {B). Indicators do not significantly. affect the pH ofthe solution to which they are added (C). Acid-base reactions do not occur in the absence of indicators (0). Indicators have different colours in dissociated and undissociated forms ‘tthe end point, there is @ sharp change of colour inthe indicator. Tis happens because the (A). pH at end point changes sharply. (6). Structure of the indicator changes. (C). Colour of indicator is adsorbed by water. {0), Dissociation constant of acid and base differ by 10 Dissociation of an indicator can be consider as, HIn=H’ +In- Colours of Hin and In” are diferent. Which statement is correct? (A) Solution assumes colours of Hin when pH =P. (8) Solution assumes colours of In” when pH Post (©) Solution assumes colours of Hn” when pH (0) Solution assumes colours of In- when pH =F, ras erat Centers ayonaguda "+ isukmagar + ,Kukatpally # | Miyepat saltabed + Netayenaae moose pvecmat exonsSPAWBIVIVAL-CHUE}116 8 9. 10. During the titr (A) phenolphthalein is used to de 'Na,CO, Is neutralized. (8) Methyl orange is used to (C) Methy! orange is us CO, and an inert substance against h) ation of mixture of NaOH, Nay i point when NaOH Is fetect the enc ydrochloric acid: completely neutralized and half of detect the final end point. ‘od to detect the first end point halen is used to detect the final end point (D) phenolphi Match the Column ~ | with Column — I Column - | (Indicator) (A) Phenolphthalein (8) Phenol red (C) Bromo cresol green (0) Methyl orange ‘Match the Column ~ | with Column — Ik ‘Column - | (Titration) (A) Strong acid versus strong base (B) Weak acid versus ‘strong base {C) Strong acid versus weak base (D) Weak acid versus weak base ‘Column = II (Type of titration) (p) NaQH+HCe (q) H,SO, +NH,OH (() CH,COOH+NH,OH (6) KOH+H,SO, Column = I (Indicator used) (p) Methyl orange (3-4.4) (q) Methyl red (4.3 - 6.3) (9) Phenophthalein (8 - 10) (5) No suitable indicator‘SP.WBIVINA)-CH(SCC)48 ANSWERS ee} DA\ 1 2A 3 4 AG0 5 8 ABD i a 8 8 DAY-25 1 i [H"] = 0.02 M; [OH] = 5 x 10° M ii) [H"] = 2 x 10" M; [OH] = 5 x 10°M. 2. 0.4685 a Eph 30a a 6a7 8B & 6 7 8 a 6 DAY-26 1 1x 10° 2 an a [W']-e6n10-%moit" [roo3 ]=6.75«10-%m [oof ]=478x10-%m 4. (a) pH increases ; (b) no change; (c) pH decreases 5. Ky= 2.3 10"; Knis small so the neutralization reaction does not proceed very far to completion. 6 1.44310 M 7. (a) 4.74; (b) 2.34; (c) 6.02; (4) 9.70; (2) 11.11 8 pH= 113 & 10415 10. (a) pH (b) pOH = 13.55, Ta) 2 B 3 AC 4 AB 6% OC Saifabad + Narayanaguca ""'»Dilsukhnagar + Kukatpaly «MiyapurSP.WBIVINA)-CH(SCC)49 1 (n= 1.39 10% (i) pH = 9.143 2 (5.714x10-" (il) [OH] = 1.322 x 10% 1. 292 2 Ky=3.98x107 3, K, for HCN = 14-4.70=9.30 NaCN + H,0—NaOH + HCN or pOH Alek, -togc- pKa] = 4114 + 0.03010 -9.30) 225 pH= 142.5211 4 Ac 5 ABC 6 oC 7 6 pil 7-4(0K, +108) 4=7-4(5+108¢) 8=14-5-logC 8=9-logc og C= 1 8 1 - pH =7+>(PK, +logC) [14-4.7 +log(0.5)] pH=7+45=115 9. 10" a x10 h=0.01%100=1% 10. A+r;B>s;C>q;D>p M1. A>p.qiBons;C>p.q;Dor 12. False ‘eyaerabad Cons Salfabad | + Narayanaguda "+ + Kukatpally + Miyapur‘SP.WBIVINA)-CH(SCC).20 1. solutions (a, (6), (e) and (@) 2. ap=-0.087 3. pOH=8.48 4. HPO; -HPO? 5. (pH =4.96 (iapH= 0.01 60281 7. Ky = 1.83 x 10° 8. 50,0 mL (a) 2.85; (0) 3.46; (0) 8.25; (4) 12.70 9. DO 10. Tne DAY-30 1 2 6 3 8 48 5 AC 6 BC 7 BC 8 AD 2 BD 10 ABD 1 AC 2 oC 138 4A % 8B 16 A+sBons;CorjDopas DAY-31 4 12.448 gl” 2. (a) AgNOs, source of Ag’; ;equilibrium shifts left; (©) HNO,, source of H:0", removes COZ ;equilibrium shifts right (6) Na,CO;, source of CO% equilibrium shits let; (d) NHs, forms Ag(NH, );; removes Ag* ; equilibrium shifts right 3. pH=4.23 48 5 oc 6B 7 8 8 Cc DAY-32 0.118 gm 2, 2.2% 10°M: 4. 8 6 A 8. ACD 1 c 1 1 3, 5. 7. 9. 1 B oF 80%, 3, When the indicator (Hin) is added to a solution, there exists the equilibrium, Hin——= HY 4 In Salfabad | + Narayanaguda "+ + Kukatpally + Miyapur10. SP.WBIVINA)-CH(SCC)21 colourA colour 8 [H Jf] [Hin] ‘The midpoint ofthe colour range of an indicator Hin the pont at which In- He] =1110%; pH=5 ‘Thus at pH = 5 ofthe solution, the indicator will change is Colour Kun > Point 'S' represents the situation beyond end point at which excess base is present in the titration fask. So ts [ 1,0" ] can be witen as (#,0")= R= (on) pit = p* +tog(base) woo>e 200 Since K,, andK,, are high values therefore point A, K,, and K,, are considered. HASH! +H,A ‘At point C, Na, A is formed, hydrolysis of A°- occurs and hydrolysis of Na,HA is suppressed, (K,, Is considered) due to common ion [ox effect, AY +HO—HA 40H HAD + H,< LA~+OH At point C salt Na,A (salt of W,,/S, )is formed. Since the concentration of NaOH and H,A(0.1) are equal. So the volume of NaOH used at point Cis 3 times the volume of H,A used otal volume of solution = 100 mL (HsA) + 300 mL (NaOH) = 400 mL. MY, (Before) = MV, (After) 0.4100 =M, x 400 on 4 Hence the concentration of salt (NasA) formed at point C my, =°- 0.025 025. ‘eyaerabad Cons Salfabad | + Narayanaguda "+ Dilsukhnagar + _ Kukatpal + Miyapur‘SP.WBIVINA)-CH(SCC)22 1" 12, 13, 14, 18. Using hydrolysis equation for Na,A (using K,, value) pH=1 (ok, +pK, +lo9¢) 2 14 yo4 , = $(14 +7 +0925.10°) = (211.6) =9.7 pH=97 D At point B, Na,HA is formed hydrolysis of HA* is considered and hydrolysis of NaH, is, lon) suppressed (K,, is considered) due to common |OH| effect, HAY 4 HO——=H.A” +OH HA” +H,0—=H,A +0H At point B, salt Na,HA (salt of Wi/Ss) is formed. So the volume of NaOH used at point Bis 2 times the volume of H,A used Total volume of solution = (100 mL +200 ml) = 300 mL MY, (Before) = MLV, (After) 0.13100 =M, «300 ot 4 my, = 4 0033, 30 [Na,HA| = 0.033M 4) pH= 5 (0K, +pK,, +loa¢) Change is pH =9.7 8.76 =0.94 A A D c ‘eyaerabad Cons Saifabad + Narayanaguca ""'»Dilsukhnagar + Kukatpaly «Miyapur‘SP.WBIVINA)-CH(SCC).23 DAY-34 (a) 9.00 mmol; (b) 20.0 mL; (c) 7.00; (4) 8 AB AB Hi Ind +H’ (pK, =5) Ree he a. when pH < pk, (4.62 <5), colour of acid form, ie., red predominates. ». when pH < pk, (5.47 > 5), colour of basic form, i.e, blue predominates. ©. 75% red >|!) _ 078 Hin) 0.25 5 + 1og3 ~5 +-0.48 ~ 5.48 (Hence (c) is wrong) d.is also wrong statement. BD AB AB AB A=psB— C+qD—pas AapqnBorC—pgD—s ‘eyaerabad Cons yanaguda + Dilsuknagar + Kukatpally ¢ Miyapur Saifabad +