THE INDIAN PUBLIC SCHOOL - CAMBRIDGE INTERNATIONAL Mock Examination CANDIDATE PE so 92 NMORISHwenTe) CANDIDATE pa A ae CENTRE i | f ae = = | numper =|! | Sys le NUMBER | © eS Grave 10_/9 5 january 2024 CHeMusTRy (062042) 1 Hour 15 Minutes Paper 4 Theory (Extended) ‘You must answar on the question paper. No additional materials. areneedad INSTRUCTIONS © Answerall questions. © Use a black or dark blue pen. You may use an HB pencil for any diagrams or graphs. * Write your name, centre number and candidate number in the boxes at the top of the page + Write your answer to each question in the space provided, * Donot use an erasable pen or correction fluid. + Donot write on any bar codes, © Youmay use a calculator. = You should show all yaur working and use appropriate units. INFORMATION +The total mark for this paper is 80. © The numberof marks for each question or part question is shown in brackets [ ]. + The Periodie Table is printed in the question paper. f ao For Examiner's Use Q - Oe This document has 16 pages. Any blank pages are indicated. Invigilator’s Signature: TIPSENGCSEMMock ExamiJanuary 2024:Chemisty Ps ET2 4 Element X can undergo the following physical changes. gaseous X WA liquid X a aN Fig. 1.4 (2) (i) Name each of the numbered physical changes shown in Fig. 1.1 4 oe + ..melbn es 3, ay. r condensation ees i BG a ea: (ii) One difference between boiling and evaporation is the rate at which the processes occur. State one other difference between boiling and evaporation, lig Js, belle.....phenemonen.....eraperatien \ 1S. sisforce i Pleromemn, eae i ty {b) Describe the separation, arrangement and motion of particles of element X in the solid state, ae &. = ote NQn.2. iby, labtice,/ en Ps ( |éfotion a ho (c) Element X is a Group Ill metal. It bums in air to form an oxide X,0,, Wie pee equation for this reaction. 3 /x) Op.=2.Xe..O3 ot 2 2 aS \yt 3905-— [Total: 10} XN TIPSENGCSE!Mock Exam/January 2024/Chemisby P4 EXT3 2 Magnesium, calcium and strontium are Group Il elements. (a) Complete Table 2,1 to show the electronic configuration of a calcium atom. Table 2.1 shell ast | 2nd 3rd an | aN number of electrons 2 Sages eee) \ i) (b) Describe how the electronic configuration of a strontium atom is: (i) similar to the electronic configuration of a calcium atom Tt pas....2....uglenece...... ole ben s..T....bor..2 Clee fo § itt IS... akon nce...che.ll. ti different fram the electronic configuration of a calcium atom. \ it... ee. bos é..chalbs taith......2lec hens ft) (c) Calcium reacts with cold water to form two products: = acolourless gas, P, which ‘pops’ with a lighted splint * aweakly alkaline solution, Q, which turns milky when carbon dioxide is bubbled through it (i) Name gas P. Hycltogen Cc. 1 “entity the ion responsible for making solution Q alkaline ofl 7 Sapa ee ee A (iii) Suggest the pH of solution Q. a Roniuricru eengeremeer eat Write symbol equation for the reaction of calcium with cold water. CatfhO2 CaO, eel geen: 2] TIPSEAGCSENMock ExamiJanvary 2024/Chemisty Fé EXT4 (d) Magnesium reacts with chlorine to form magnesium chloride, MgCl, Magnesium chloride is an ionic compound (1) Complete the dot-and-cross diagram in Fig. 2.1 of the ions in magnesium chloride ‘Show the charges on the ions. wie \ Fig, 2.1 3] (i) One physical property typical of ionic compounds, such as MgC, is that they are soluble inwater. ‘ Give two other physical properties that are typical of joric compounds. 1 conduct. .electicily.....nrhen.....melten 6 ent 2 MANE HOI. lathe aarge nett {e) Aqueous silver nitrate is added to aqueous magnesium chloride. Awhite precipitate forms, (@ an ionic equation for this reaction. Include state symbols. Agibagat Wyclogse eG a Ay Ce. ai) Fo tal [Total: 15) ‘TIPSENIGCSE/Mock Exami January 2024/Chemisty Pa EXT5 3. Coppers a transition element, It has variable oxidation states. {a) State two other chemical properties of transition elements which make them different from Group | elements, ant Yeac tne. 2 (b) When copper(I!) oxide is heated at 800 °C it undergoes the reaction shown by the equation. 4CuQ — 2Cu,0 + 0, (i) Identify the changes in oxidation numbers of copper and oxygen in this reaction. Explain in terms of changes in oxidation numbers why this is a tedox reaction — change in oxidation number of copper: from .2.+...6... to... 80.14 change in oxidation number of oxygen: from 24,8... to... PBRZ*. cxcnetin .copper..go... ecuadused.and...O2egRen ger oxydiged. t " eas ete ich, a ee Calculate the volume of oxygen, measyred at r-tp., which is formed when 1.60 9 of CuO reacts as shown in the equation. (3) 4Cu0 — 2Cu,0 + 0, 4 2a Ae 4 TIPSE/IGCSEINock Examisaruary 2024/Chemisty P& EXT6 (c) Copper metal is obtained when scrap iron is added to aqueous copper(II) sulfate. (i) The reaction between iron and aqueous copper(II) sulfate is a displacement reaction. State why this displacement reaction takes place. Dic te beets e Ayan. ts. mee, Reso te TRA... Cf Lo Sood MED od BEB... A sulbtern iN Copper (ii) Write a symbol equation for the reaction between iron and aqueous copper(II) sulfate. Fes. Ca SO RRS cb EH i oT (iil) A displacement reaction is one rpetfoa tot obtaining copper metal from aqueous copper(II) sulfate. Identify another method for obtaining copper metal from aqueous copper(II) sulfate. lec tial ( [1] [otal 11] TIPSE/IGCSE/Mock Examiseruary 2028/Chemisiry P4 EXT4 Sulturic acid has many uses (a) Sulfuric acid is a strong acid (0. Detne the tor ac \\ A. pveton...dexeks.f. atte a fll (ii) Define the term strong acid, lsspion) \ 4. snltion. toll... pl. ie i Sok eaceditentt) (b) Dilute sulfuric acid is used to make salts known as sulfates. ‘A method consisting of three steps is used to make zinc sulfate from zinc carbonate. step 1 Add an excess of zinc carbonate to 20 cm® of 0.4 mol/dm dilute sulfuric acid until the reaction is complete. step 2. Filter the mixture, step 3 Heat the fitrate until a saturated solution forms and then allow it to crystallise. (i) Suggest two observations which show that the reaction is complete in step 1 5.2 Fo, measence. eS. 2 TF, Hoxe....i6...0p..1008.,.pxecipiste ore Ail. the.. SwiFuVic. acid is reaches mg (ii) State why itis important to add an excess of zine carbonate in step 1 Te...enguse.....all. Ho. sulisic, Na,SO, + 2H,0 {i) State the colour of methyl orange in aqueous sodium hydroxide. blue... ’ ae 1] (ii) Determine the concentration of the dilute sulfuric acid in g / dm® using the following steps. Calculate the number of moies of aqueous sodium hydroxide added to the conical fiask 25 5 = 7 === 0.200 = 0005 We00 PL nm © Calculate the number of moles of dilute sulfuric acid added from the burette. S| | oa 0200.28. mol * Calculate the concentration of the dilute sulfuric acid in mol / dr’. O.0025 O-iga® ae Zee QUEL co mold? + Calculate the concentration of the dilute sulfuric acid in g /dm*. o.p07s ¥ 24+ 8246 = 0. 2S + (2:25. gdm? 4) [Total: 14] TIPSENGOSEMock ExamiJeruary 2024/Chemistry PA EXT40 & Astudent investigates the progress of the reaction between dilute hydrochloric acid, HCl, and an +88 of large pieces of marble, CaCO,, using the apparatus shown in Fig. 5.4 gas syringe dilute hydrochloric acid an excess of large pieces of marble Fig. 5.1 (a) Agraph of the volume of gas produced against time is shown in Fig. 5.2. 150: volume of gas produced/cm® 0 50 100 150 200 250 300 350 400 time/s Fig. 6.2 (i) State how the shape of the graph shows that the rate of reaction decreases as the reaction progresses. Th. nati... beeper ull... higha....fie..vale..of rewchion..Abthe...onk Fhe...gtah...ie. 035 stagiX 1 er. (il) Suggest why the rate of reaction decreases as the reaction progresses. \ The......concentatin....of .reachants.. Ailece.. ack cle eC ty Deduce the time at which the reaction finishes 4 é 200 sti] “TIPSENIGCSEMock Exam/Janvary 2024/Chemisty P4 EXT" (b) The experiment is repeated using the same mass of smaller pieces of marble. All other conditions are kept the same. Draw a line on the Fig. 5.2 to show the progress of the reaction using the smaller pieces of marble, RI {c)\ The original experiment is repeated at a higher temperature. All other conditions are kept the same. The resulting increase in rate of reaction can be explained in terms of activation ‘energy and collisions between particles. (i) Define the term activation energy. ‘Te...emowat....of. gtagy aacded. ie bvagk. the bands he haeate TP, 1 Explain why the rate of a reaction increases when temperature increases, in terms of activation energy and collisions between particles, -lOlen. fompreroduse....cctesese, Fe..jnkesnal hogy alke..ingdases...s fe pacheles moWiS,.. ale. veswlBag.. In. A.hrightd..munnDEen.2F...ewstests| CB. if ben S ear —— : 31 [Total: 10} TIPSENGCSEMock ExamiJanuary 2024/Chemisty P EXTfollowing two alcohols are members of an homologous series and they are isomers. CH; — CH; — CH, — CH, —OH and (CHs),CH — CH, — OH Explain why they are isomers. (ii) Deduce the structural formula of another alcohol which is also an isomer of these alcohols. CHe CHEH, ~ x oy = “TIPSE/IGCSEMock Examisanuary 2026/Chemistry Pé EXT8 {c) Copper(tl) oxide can oxidise butanol to liquid X, whose pH is 4 mineral wool soaked in butanol copper(II) oxide liquid x formed by oxidation of butanol, @) Gi &-Prdacsivna. enangano ten Which homologous series does liquid X belong to? —eothnaylic acid State the formula of liquid X. Ce SE (1) TIPSENGOSEMock ExemiJanuary 2026/Chemistyy Pa EXT14 (a) The alcohol ethanol can be made by fermentation. Yeast is added to aqueous glucose. CoHzOs(aq) > 2CzHsOH(aq) + 2C0,(a) Carbon dioxide is given off and the mixture becomes warm, as the reaction is exothermic. The graph shows how the rate of reaction varies over several days. rate of | reaction time (i) Suggest a method of measuring the rate of this ae (ii) Why does the rate initially increase? ¢ [Total: 14] ‘TIPSEIIGCSEINock Examiseruary 2024/Chemistry P& EXT15 7 There are two types of polymerisation, addition and condensation. {a) Explain the difference between these two types of polymerisation. () ‘Some plastics, formed by polymerisation, are non-biodegradable. Describe two poliution problems that are caused by non-biodegradabie plastics. TIPSEIGOSE/Mock Exaridanuary 2024/Chemisty Pa EXT18 (<1) ainssaid pur aimyesediaay woos ye lip pz S| 26 AUe jo @jou @uO Jo AUINION Ou, splouyoe sprouequey beat | scion nage | | aa ae SH | ug | 8s io eee ie ag | Mm xa | ov uw | 5 [ joquiss smoye ‘Swrowl9fa JO SICH] DONA PUL TIPSERGCSEMNock Exar January 2024/Chemisty P& EXT19 {c) The polymer known as PVA is used in paints and adhesives. Its structural formula is shown below. a ee ee OCOCH; OCOCHs Deduce the structural formula of its monomer. x (d) A condensation polymer can be made from the following monomers. a) HOOC(CH.),CQOH and _HLN(CH;)eNH, Draw the structural formula of this polymer. Hoo bn \co-Meten,) NH y— [3] [Total: 6] TIPSENGCSE Mack ExamWJaruary 2026/Chemistry P4 EXT