FULL TEST-1

Date: 23/02/2024 Time: 3 hours

Subject: Chemistry (Class-11) Total Marks: 70

General Instructions:
1. This question paper consists of 35 questions in 5 sections-A,B,C, D and E.
2. All questions are compulsory. However, an internal choice is provided in some questions.

SECTION-A (18 Marks)

The pair of ions having same electronic configuration is; (1)
1. a) Cr3+ , Fe3+ b)Fe3+ , Mn2+ c)Fe3+ , Co3+ d)Sc3+ , Cr3+
Identify the pairs which are not of isotopes? (1)
2.
a) 6 X12, 6 Y13 b)17X 35, 17 X 37
C) 6X14, 7Y14 d) 8X4 , 8X5
Which of the following order of energies of molecular orbitals of N2 (1)
3.
is correct?
a) (π2py) < σ2pz < (π∗2px≃π∗2py)
b) (π2py) > σ2pz > (π∗2px≃π∗2py)
c) (π2py) < σ2pz > (π∗2px≃π∗2py)
d) (π2py) > σ2pz < (π∗2px≃π∗2py)
The volume of gas is reduced to half from its original volume. The (1)
4. specific heat willbe;
a) Reduce to half b)Be double
b) c)Remain constant d)Increase four times
Bohr atomic model can explain (1)
5.
a) the spectrum of hydrogen atom only
b) spectrum of an atom or ion containing one electron only
c) the spectrum of hydrogen molecule
d) the solar spectrum
Boron is a non-metal and is placed under group 13 and period. How (1)
6. can boronform bonds with other elements?
a) By sharing 5 electrons b)By sharing 3 electrons
c)By sharing 2 electrons d)By sharing 1 electron
For the reaction C(s) + O2(g) → CO2(g) (1)
7.
a) 𝗈H >𝗈U b)𝗈H < 𝗈U c) 𝗈H = 𝗈U d) None of these
Stable form of C may be represented by the formula: (1)
8.
a) C b)C2 c)C3 d)C4
What is the order of the metallic character down the group? (1)
9.
a) It decreases as new shells are added to the element
b) It increases as electrons move away from the nucleus
c) It increases as new atoms are added to the same shell
d) It decreases as the effective nuclear charge on the electron
increases
 The IUPAC name for the compound given below is: (1)
10.

a) 1-chloro-2-nitro-4-methyl benzene b)1-chloro-4-methyl-2-nitro

benzene
c)2-chloro-1-nitro-5 methyl benzene d)m-nitro-p-chloro toluene
In which of the following pairs, the ions are iso- electronic? (1)
11. a) Na+, Mg 2+ b)Al 3+, O – c)Na+, O 2– d)N3-, Cl-
Element X forms a chloride with the formula XCl 2, which is solid (1)
12. with a high meltingpoint. X would most likely be in the same group
of the Periodic Table as:
a) Na b)Al c)Mg d)Si
Which of the following statements concerning the quantum numbers (1)
13. are correct?
a) Angular quantum number determines the three
dimensional shape of theorbital.
b) The principal quantum number determines the
orientation and energy of theorbital.
c) Magnetic quantum number determines the size of the orbital.
d) Spin quantum number of an electron determines the orientation
of the spin ofelectron relative to the chosen axis.
14. (1)

Read the instruction given below for Q. No. 16 to Q. No. 18

Two statements are given- one labelled as Assertion(A) and the other as
Reason(R).Read the statements carefully and choose the option that correctly
describes statements A and R.
a) Both A and R are true and R is the correct explanation of A.
b)Both A and R are true and R is not the correct explanation of A.
c) A is true but R is false.
d) A is false but R is true
15. Assertion (A): Electron gain enthalpy becomes less negative as (1)
we go down agroup.
Reason (R): Size of the atom increases on going down the group and
the addedelectron would be farther from the nucleus.
16. Assertion (A): Among the two O-H bonds in H₂O molecule, the energy (1)
required to
break the first O-H bond and the other O-H bond is the same.
Reason (R): This is because the electronic environment around oxygen
is the sameeven after breakage of one O-H bond.
17. Assertion (A): Combustion of all organic compounds is an exothermic (1)
reaction.
Reason (R): The enthalpies of all elements in their standard state are
zero.
18. Assertion (A): Nitration of benzene with nitric acid (1)
requires the use of concentrated sulphuric acid.
Reason (R): The mixture of concentrated sulphuric acid and
concentrated nitric acid produces the electrophile, NO2
 SECTION-B (14 Marks)
19. i. State Heisenberg uncertainty principle. (2)
ii.De -Broglie concept cannot be applied to a moving cricket ball.
Why?
20. Show that for an ideal gas Cp- Cv = R (2)
OR
With the help of first law of thermodynamics and H = U + PV,
prove ∆H = qp

21. For the general reaction: (2)

aA +bB cC + dD
Derive the relationship between Kp & Kc
OR
Find out the value of Kc for each of the following equilibria from the
value of Kp2NOCl (g) 2NO (g) + Cl2 (g) Kp = 1.8 x 10-2 at 500K
22. Consider the following species: N3- , O2- , F- , Na+ , Mg2+, and Al3+ (2)
a) What is common in them?
b) Arrange them in the order of increasing ionic radii.
23. Distinguish between Sigma(σ) and pi(π) bond. (2)

24. Explain with example ozonolysis. (2)

25. On the basis of type of hybridization predict the shape of the (2)
following molecules: (i) H₂C = CH2 (ii) CH3F

SECTION-C (15 Marks)

26. Calculate the wavelength, frequency, and wavenumber of light (3)
wave
whose period is 2.0 × 10-10 s.
27. a)Use molecular orbital theory to explain why Be2 (3)
molecule does not exist?
b)Define the term hydrogen bond
OR
a) State any two limitations of Octet rule.
b) Discuss the shape of PCl5 and BCl3 using the VSEPR theory
28. a) State Le chatelier’s principle. (3)
b) Calculate the pH of the solution 0.002M HBr.
c)
29. Explain why? (3)
a) Ionization enthalpy of nitrogen is more than that of oxygen.
b) Electron gain enthalpy of fluorine is less than that of chlorine.
c) Anionic radius is more than the cationic radii.
OR
Give reason for following:
a)Halogens act as good oxidising agents.
b)A cation is always smaller than its parent atom.
c)Na and Mg+ have same number of electrons but removalof
electron from Mg+ requires more energy.

30. a) Define hyperconjugation. (3)

b) Hyperconjugation is called as no bond resonance. Explain with
example.
 SECTION-D Case Based (8 Marks)
31. Read the passage given below and answer the following (4)
questions:

The rotation of carbon-carbon single bond (s-bond), due to

cylindrical symmetry ofmolecular orbitals long internuclear axis, in
alkanes results into different spatial arrangements of atoms in space,
that are interconvertible. These arrangements arecalled
conformations. However, weak repulsive interaction are present
between the adjacent bonds in alkanes so the rotation of C—C
single bond is not completelyfree and is hindered by a small energy
barriers of 1-20 kJ mol-1. The repulsive interaction between the
adjacent bond is due to electron cloud. The two types of
conformations are very common, i.e., staggered and eclipsed. The
conformation in which the hydrogen atoms attached to the two
carbon atoms are as far apart as possible is called the staggered
conformation. The conformations in which the hydrogen atoms
attached to the two carbon atoms are as closed as possible is
called eclipsed conformation. Any intermediate conformation
between the above two is called skew or gauche conformation.
Alkanes As already mentioned, alkanesare saturated open chain
hydrocarbons containing carbon – carbon single bonds.
Methane (CH4) is the first member of this family. Methane is a gas
found in coal mines and marshy places. If replace one hydrogen
atom of methane by carbon andjoin the required number of
hydrogens to satisfy the tetravalency of the other carbon atom, it get
C2H6 . This hydrocarbon with molecular formula C2H6 is known as
ethane. Thus it can consider C2H6 as derived from CH4 by replacing
one hydrogen atom by -CH3 group. Go on constructing alkanes by
doing this theoretical exercise i.e., replacing hydrogen atom by –CH3
group.
The next molecules will be C3H8, C4H10

i) Draw the confirmation of ethane using sawhorse formula.

ii) Arrange the following in the increasing order of boiling point:
a)Pentane b) 2-methyl butane c) 2,2- dimethyl
propane

iii) What happens when alkyl halide is treated with sodium in presence of
dry ether.
iv) Give one example of functional isomerism

32. Read the passage given below and answer the following (4)
questions:
Branched chain hydrocarbons: In a branched chain compound
small chains of carbon atoms are attached at one or more carbon
atoms of the parent chain. Thesmall carbon chains (branches) are
called alkyl groups. For example:
 In order to name such compounds, the names of alkyl groups are
prefixed to the name of parent alkane. An alkyl group is derived
from a saturated hydrocarbon byremoving a hydrogen atom from
carbon. Thus, CH4 becomes – CH3 and is called methyl group. An
alkyl group is named by substituting ‘yl’ for ‘ane’ in the
corresponding alkane. A reagent that brings an electron pair to the
reactive site is called a nucleophile (Nu:) i.e., nucleus seeking and
the reaction is then called nucleophilic. A reagent that takes away
an electron pair from reactive site is calledelectrophile (E+) i.e.,
electron seeking and the reaction is called electrophilic.
Electron Displacement Effects in Covalent Bonds The electron
displacement in an organic molecule may take place either in the
ground state under the influence ofan atom or a substituent group or
in the presence of an appropriate attacking reagent. The electron
displacements due to the influence of an atom or a substituent
group present in the molecule cause permanent polarisation of the
bond.
Inductive effect and resonance effects are examples of this type of
electrondisplacements. Temporary electron displacement effects are
seen in a molecule when a reagent approaches to attack it. This type of
electron displacement is called polarisability effect.

(i) Define the term electrometric effect .

(ii) Give one example of +I and –I
(iii) Draw the resonating structures of aniline.

SECTION-E (15 Marks)

33. a) The enthalpy of formation of methane at constant pressure (5)
and 300 K is – 78.84kJ. What will be the enthalpy of formation at
constant volume?

b) State and explain Hess’s law of constant heat summation.

OR
The equilibrium constant for a reaction is 2. What will be the value
of ∆G°?

c) State and explain First law of thermodynamics. (Give mathematical

expression)
34. a) Calculate the maximum work obtained when 0.75 mol of an (5)
ideal gas expandsisothermally and reversible at 27°C from a
volume of 15 L to 25 L.
b). i. Why standard entropy of an elementary substance is not zero
where as standard enthalpy of formation is taken as zero?
ii. Under what conditions will the reaction occur, if
(i) both ∆H and ∆S are positive
(ii) both ∆H and ∆S are negative
 OR
a) In a process, 701 J of heat is absorbed by a system and 394 J of
work is done bythe system. What is the change in internal energy
for the process?

b) Give reason for the following:

(i) Neither q nor w is a state function but q + w is a
state function.
(ii) A real crystal has more entropy than an ideal
crystal.
(iii) Mention the conditions for a reaction to be
spontaneous at constanttemperature and
pressure.

35. An alkyl halide C5H11Br (A) reacts to ethanolic KOH and produce (5)
an alkene ‘B’, which then reacts with Br2 to produce a compound
‘C’, which goes through dehydrobromination and gives an alkyne
with ‘D’. On treating with sodium metalin the presence of liquid
ammonia, one mole of ‘D’ produces one mole of the
sodium salt of ‘D’ and half a mole of hydrogen gas. Complete
process of hydrogenation of ‘D’ produces a straight-chain alkane.

Identify A, B, C and D from the given and also mention about the
reactions involved.
OR
What happens when benzene is treated with
i) Br2 in presence of anhydrous AlCl3
ii) Conc. H2SO4 at 330K
iii) Mixture of cone. H2SO4 and com. HNO3 at 330 K
iv) methyl chloride presence of anhydrous AlCl3
v) Ethanoyl Chloride in presence of anhydrous AlCl3

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