(yong a oo
| eas ah ais aia
SD) te-b 3h + > He -EB) > the-h,
to, be ba by
Mger * ® sowgene 2 Had 2 +?
only those alcolols at can form 2
B Bigytes Hold substrate stalole carbocation readily debydrates. ‘Wis correct
woteaies in suitable position but not *R’.
from active site go feageut 12) Any metal hat caw douate electroy easily Liketate
Waeovles feact easily. Both “a! th gps Proms acid. Bot af has wore tedvetion
ange ate cottect aud Ri is poteutial = copper canwot liberate fly frou acid.
cortect explaivation of W'. Both A’ aude ate cottect aud ‘eis cortect
explaivation of 1.
'®) ouly Pawides exhibit AoPemann browamide teacton , Secondary amines ate wore vasic
thon Pomines tn aqeoos solution. Both A‘ and‘e! ate ¢1ve and “R'is correct explaination
gx.
1a) dve to differeuce in ligands , stfoug Field ligand lice ci paits oupai fed electron
wuete aS weak field ligand lite _H,0doss vot pair vupaited electious “2 Dove +o
aifpefence iu momer of uupaited electrons
) wafto ed] » [Pe Geni cto, sop
6 ara on
ee Este a en | NON N | Ba ENO NO ZNO
a-Blowo octane pt Tiavsition State octaut-a-ol
“ f ©
it Jaf Ay 5 “SA_+ allt Br.
Hy
“oH Pent-a-e.
3) Resection poteutial of HBTs wlote yan Mg." a8) 2ate of reaction = —L_ afa05]
2a) cowtd--_1_d{pog] = doa] given _ df b0,) » aexiome' dfpros] » ad Los]
teat) dt dt at t a = fats] = Leena!) = bax Mal,
=
gate of teaction= Ratio a change in couceuttation of Teactautts of products iv given
time.
fate of teaction % slow step. Rabe of Teaction = * fo]? 5
R w
a ca Ow “A on mt) =
# ay esoy ae? couceuttated +
RosENMOWD'S REDvCTON. CANID2AROS REACTION. Beugpicacid — Bevgyl alcohol
9S
Cli, Hg Br
¥ °
° 1
nt Oho
A hvorage tate of seaction= (6-5 — 0-4) = 1O°winote! = Lana] = tate of prodvation of 193.
10 it
a2) loss of Seondaty and tettaty stvdwe G proteins = Denatuiation of piotelus.
ai) )Molewle with less sietic Wiudrance oudergo sw seacton. = (-Bromopentaue.
eed
e
4) Hotecole with cuital c-atou.= optically active = 2-Biowo-2-u0vuyl butane.
ii) notewle Hat om form stale airene (alkene with wore somlet of x-Aydtogen atows)
oudetgo Préliuination fasies.
oO
a) Daton a co + 11,0. Fofwic acid ondergo dekyatation to fom catbou movoride
ain aud watef.
ii) neu voutAReD 2EUNSEY REACION.= chlorination ocevt on x catbon atom in presence
PF chilotive and fed phosplofoos to fot u-cilotoacetic acid.
ctigeoot_+ dy SetP , cicncoon + AOL
» tte hy 0) ci ovelg + HI > cio + aT
ae-> ca ad ety oe a8) Because tet molar forces g attach
2 Acetone ave bforeH do1wA easily.
m= a2 21000 _ = 113 wol/tg. 2g) Becwse water is weat Field ligand and
40 A440
cyano is strong Field figaud 7 $0 woth t2. e-
couiplexes differ Ta mombet 6} oupalted electous. so [uicad] is gfeen, but pod] is
cintess because a absewe Q vupolted electron. witarl4d 2a®
wywtofot |
30) HOFEMABD BPDMAMIDE PEACTION-
Hemctg-E wl, t+Wa0H + Big ——y prac, + WACO, + BABI + aHz0
Propanamide Bthy) amine
ETL AMINE _- METHADE
CH CHa Wit, t WANE, 445 cage Be Hs POR 5 ctte-citg + Wyh
8%
d
DIA2Z0TIZATION
Ti) Amwine ~ AceTADILIOE. +- Acetylation of auilize..
oo. ia ql
ton + ARN > ctl, + etigcoolt
HET a a
a
Acetauilide
) Gis wo, a Goll WH, + Hyd Reduction
° 6
7) ota aR
1
wabo, + HCl g aiada /Hcl Oo + Wat
DIAZOTI BATION. SADDHEUER'S REACTION
el
3) ‘ove fo Wote wuizgation of cl ou dilotieu. ji) Holat Conductivity « dilvtion. So 8.005M
Hours acl tas mote molar conductivity. ii) Am= 4 xwoo § = wexigx iGr=125xB
—
coo)
, Rea . 4
ny yo 7896x0 ‘seul! c= 0.00241 M Ams 5xI000. = #-846% oSx10* = 32.26 Sew mol.
© o-o024l
aD/)dniline does nor give friedel-cuaftls reaction ecavse auilive react with
dasic nae
alvuiuiown cilotide. i) pb x_|___égitciotty > Ng 7 ee 2 Gig Cth Nity.
AWN, " 9 ahi — ach)
solvole. A base dve to
acid “H'atom.
g g
aati wh a) eeee oe aENG
ie =
chet chy Che
Tnsobble in base dve to
auseuco. 3 Acs by drogen
arom.
ot
ho; wha Dita
> o sut Hel o. en ” % Bt
water 7
, p
Aniline.
Br a4,6 thibtomo aniline.
D crzettycomt, SA/AeFot , co crow, + QEBT + ALO
Hofman bromamide teaction.
°
Q
Che —__> cH cH, -N—-c—cH, + HC)
@' * pyran 38 { eB
33))) ETAPD PEACTION = chfomyl chlotide teact wita Toluene +0 form mtetmediate
whicn fothet bpouw hydrolysis form Bengaldehyde
tty Ss - cro.
+ ctocl, ——> ee
STEPHEN REDOCTION..> Alkyl Wittile vudetgo teductiou to form imine which is
forther lydrolysed 4o form aldelyde-
clean 5 HCl, ctig-en=wt Ho-a/t ctig-g-t + Nits
:
» Beuzeic add ~ Beugaldehyde 5
of + sod, b-cl thy Pi/zaso4. fs
7 a e. o
i) Sheng ttaloform reaction. 4-owa at ies + eis,
soon + I,
feeto phere,
6
x I
tf) agbon + cy BAP, ye ech, woot _, tg-toety
q Of
oo
ay ene tr = @
Agr Uy CHE FO- aH chy Cts > ce-ch ct coo + Hoc cily—cH~chy
Hott
on Ol
ie tt
ot hg am. oF
Baar = Gas zs” ate fag 48231 dve to pieseuce of ove oupaited.
co a
Oa
D dve to formation 4 ehg0R” ion (orange colovs)
) an, 4 amd fig does ot kave vupaited ‘a! electron , so these ate
Called wou-trausition elemeuts.
i) oo > faQa? ae pe JnGnta) BM eZ
UO Geert) pe 3(3ta) &M n> 3-4BM
fo = (hr) ast au* pe Sngwmay = 3-4.BM
() fwwhh
or
) 9 es doe to tag Malf filled stabiity.
5) Hv"? becavse Hil pole to dorm Hul® = a© (halt eilled coutiguratior).
DTW doe Yo abseuce a vupatred “Selection.
Pe Oo omg
1) amuoy risit + so __» wR + yo to od So
it!) Anos, = Muo, + 0,
3) Toad t= 1Smin we fe b.¢ = log xaxisxen = ag
4600 eso
Foel Cell= Galvanic (ell that couvert chemical enetqy ditectty +o electrical
enetgy by oxidation sf foel.
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