The New City School and College Time;

1hours 20 min Marks: 44 11a

i.Temperature and number of moles are kept constant in:
(A) Boyle’s law (B) Charles’s law (C) Avogadro’s law (D) Dalton’s law of partial
pressure
ii. The order of the rate of diffusion of gases NH3, SO2, Cl2 and CO2 is:
(A) NH3 > SO2 > Cl2 > CO2 (B) NH3 > CO2 > SO2 > Cl2 (C) Cl2 > SO2 > CO2 > NH3
(D) NH3 > CO2 > Cl2 > SO2
iii. The deviation of a gas from ideal behaviour is maximum at:
(A) -10o C and 5.0 atm (B) -10o C and 2.0 atm (C) 100o C and 2 atm (D) o C and
2.0 atm

iv.The covalent radius of Cl-atom is:

(A) 99.4pm (B) 80pm (C) 70pm v(D) 66.4pm
v. Which element has highest ionization potential:
(A) Li (B) Be (C) B (D) C
vi. Carbon atom in methane in hybridized:
(A) sp3 (B) sp2 (C) sp (D) dsp2
vii. Molecule in which the distance between two carbon atoms in the largest is:
(A) C2H6 (B) C2H4 (C) C2H2 (D) C6H6
Viii. Glucose can be converted into ethanol by an enzyme:
(A) Lipase (B) Zymase (C) Sucrose (D) Urease
ix.The unit of the rate constant is the same as that of the rate of reaction in: (A)
First order reaction (B) Second order reaction (C) Zero order reaction (D) Third
order reaction
x. Which enzyme catalysis urea?
(A) Invertase (B) Zymase (C) Urease (D) Lipase
2- Write short answers to any (12) of the following questions.

(i) Draw isotherms of a gas at two different temperature.

(ii) Derive Avogadro's Law from KMT of gases.
(iii) Write two applications of Dalton’s law of partial pressure.
(iv) The rate of effusion of an unknown gas A through a pinhole is found to be 0.279 times the rate of
effusion of H gas through the same pinhole. Calculate the molecular mass of the unknowngas at STP.
(v) What is Joule Thomson Effect?
(vi) Give the units of Van der Wall’s constant ‘a’ and ‘b’.
(vii) Explain unit of pressure.
(Viii) Define octet rule. Give two examples of compounds that do not obey this rule.

(ix The atomic radius is greater than catconic radius. Explain.

(x Ionization energy decreases down the group, although nuclear charge increases. Explain.
(xi) There is no bond with 100% ionic character. Give reason.
(Xii Explain paramagnetic character.

(Xiii Explain the term bond lenght.

Long question 5x2=10

3. Explain CH4, NH3, and H2O with VSEPR theory.

4.Explain arhenius equation.