Document No / Rev Level

Material Safety Data Sheet

SK-RnD-MSDS-01 / 00 2

Kartindo Rubber Industri, Kode Pos : 20351

Jl. Bangun Mulia No.43 Dusun VII, Desa Puji Mulyo-Sunggal
Deli Serdang, Medan, Sumatera Utara
Telp : +62 (61) 42776399
Fax : +62 (61) 42773532
Website : www.kartindorubber.com

1. IDENTIFICATION OF THE SUBSTANCE

Product Brand Name : Gum Cord
Description: Serves as a repair material for tyre retreading

2. COMPOSITION / INFORMATION ON INGREDIENTS

Non-vulcanized rubber compound, made from natural rubber.

Blend contains : Aromatic oil CAS.No:64742-04-7

3. HAZARDS IDENTIFICATION

Carcinogenicity, Specific target organ toxicity after repeated

exposure Chronic or long term aquatic hazards

4. FIRST-AID MEASURES
Eye Contact : Flush eyes with plenty of water for at least 15 minutes. Seek
medical attention if pain or redness persists.
Skin Contact :In case of contact, immediately rinse skin with plenty of water.
Remove contaminated clothing and shoes. Wash clothing before
reuse. Clean shoes thoroughly before reuse. Wash exposed areas
thoroughly with soap and water. Leather articles should be
discarded. If irritation seek medical attention.
Inhalation : If inhaled, remove person to fresh air or open air area. If victim
has difficulty breathing, give oxygen. If the victim is not
breathing give artificial respiration \ or cardiopulmonary
resuscitation. Get medical help.
Ingestion : If swallowed in a potentially hazardous amount, contact immediately
doctor. Do not induce vomiting unless directed by medical

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5. FIRE-FIGHTING MEASURES

Extinguishing Media : Carbon dioxide, dry chemical powder and

6. SPILL AND LEAKAGE MANAGEMENT PROCEDURES
foam. Material limit flash point burning: Min. 425 ° F or 218 ° C.
Decomposition of hazardous materials: Carbon monoxide.
a. Personal precautions, protective equipment and emergency procedures:
Extinguishing
Keep allprocedure
sources of ignition and hot metal surfaces from spills (if any possible).
a. Carbon dioxide: Spray it at the base of a fire upwind.
Explosion-proof electrical equipment is recommended. Keep away from contact
b. Dry chemical powder: Spray it on the base of the fire upwind.
c. Foamwith spilled
or foam: product.
When in a Keep in direct
container spraycontact
foam onwith
thethe product.
inner wall For large amounts of
spills, immediately isolate spill area and keep away those who do not concerned
Do not apply to burning
from the liquids,
area of the spill.downwind and if personal
Use appropriate only a spillage.
protective equipment, including
Spray on the base of
respiratory the fire until
protective everything is covered with the
equipment.
wind.b. Environmental precautions
Special protective equipment for fire-fighters: In the event of fire in an area relatively
Stop spill / leak (if possible). Prevent entry of spills into sewers, drains or seepage
closed, so people doing fire-fighting must use self-Contained Breathing Apparatus (SCBA).
into the soil. Use water to minimize environmental contamination and reduce
disposal requirements.
c. Procedure Notes
Report the spill in accordance with the established systems and procedures.
If a spill occurs, it is estimated that it can enter waterways or stream areas
river, immediately report it to the authorized officer.
d. Methods and materials for containment and cleaning up
Absorb spill use sorbents, sand, loam and other fire retardants. Clean and dispose of
at a disposal site that has been determined by local regulations.

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7. HANDLING ANDSTORAGE

a. Precautions for safe handling.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Make sure the container is closed. Use only in a well-ventilated area. Keep away
from combustible
a. Control parametersmaterial, fire, electricity or other sources of heat. To avoid fire &
b. explosion, dissipate static electricity during transfer by grounding and bonding
Exposure limit:
containers
 Mineral and equipment
oil mist: TLV-TWAbefore transferring
5 mg / m3 material. Use explosion proof electrical
 Polycyclic(ventilation,
equipment Aromatic Hydrocarbons:
lighting andTLV-TWA 0.2 mg / m3Wash thoroughly after
material handling).
c. handling.
Biological exposure
b. indicators Data not
Storage Steps
available.
Keep in a separate and allowed area. Keep container in a cool, well-ventilated area.
d. Control required
Keep container tightly closed and sealed until ready for use. Avoid all possible sources
e. Ventilation
of the
If fire product
(sparks or
is flames).
used in a relatively closed room, it must be equipped with an
exhaust fan. Ventilation and equipment used must be explosion proof.
f. Practice self-control, including personal protective equipment
g. Eye and face protection
Use chemical type
goggles.
h. Skin protection
Use chemical resistant gloves that comply with the standard and should be worn
whenever handling chemical products (if the risk assessment indicates this if necessary)
i. Respiratory protection
Wear respiratory protective equipment if airborne concentrations have exceeded the
Threshold Value.
j. Hygienic measures

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9. PHYSICAL AND CHEMICAL PROPERTIES

CHARACTERICSTICS TEST RESULTS

Organoleptic (physical form, color, etc.) Liquid, dark brownish

Smell Odorless

Odor threshold Data Not Available

pH Data Not Available
Melting point / freezing point -6 - 50 oC at 101,325 kPa *
Boiling point / boiling range 200 - 640 ° C at 101,325 kPa
*
Flammability Not flammable
Flash point Min. 425 oF or 218 oC
Evaporation rate Data not available
The values for the lowest / highest Data not available
flammability and explosion limits
Steam pressure 1 hPa at 20 ° C *
Vapor density Data not available
Relative density 1054.6 kg / m3 at 15 ° C
Solubility:
- Solubility in water - Not dissolved
- Solubility in other solvents - It's late
Partition coefficient (n-octanol / water) -0.0012

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10. STABILITY AND REACTIVITY

a. Reactivity
11. TOXICOLOGICAL INFORMATION
Polymerization of hazardous materials does not form.
Complete and comprehensive account of the toxicological / health effects
b. Chemical Stability
a. Acute toxicity : Oral: LD50 5000 mg / kg bw (mouse)
Stable under normal conditions.
Dermal: LD50 3000 mg / kg bw (rabbit)
c. Possibility of hazardous reactions
b. Skin corrosion / irritation : Data not available. Not expected to corrode or irritate
Reactive with oxidizing agents, acids, alkalis, nitrates, chlorites, peroxides
the skin. This statement comes from compounds or products which have similar
d. Conditions to avoid
structure or composition.
Heat, fire or conditions that can generate static electricity.
c. Serious eye damage or irritation : Data not available. Not expected to cause
e. Incompatible materials
damage or irritation to eyes. This statement comes from compounds or products
Oxidizing agents, acids, alkalis, nitrates, chlorites, peroxides
which have similar structure or composition.
f. Hazardous decomposition products
d. Respiratory tract / skin sensitization : Data not available. Not expected to cause
Carbon monoxide (CO), carbon dioxide (CO2), nitrogen and sulfur oxides
respiratory sensitization or sensitizationskin. This statement comes from compounds
(NOX, SOX), particulate, aromatic, VOC.
or products that have similaritiesstructure or composition.
e. Mutagenicity in germ cells : Data not available. It is thought that it is not a
mutagen in germ cells. This statementderived from compounds or products that

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similar structures or compositions.

f. Carcinogenicity : May cause cancer.
g. Reproductive toxicity : Suspected to interfere with fertility or disturbances in the
fetus.
h. Specific target organ toxicity after a single exposure : Data not available. It is
expected that it is not toxic to specific target organs after a single exposure. This
statement comes from compounds or products that havesimilarity in structure or
composition.
i. Specific target organ toxicity after repeated exposure :
- Oral LOAEL (rat): 125 mg / kg bw / day
- NOAEL Dermal (mice): 30 mg / kg bw / day
- NOAEL (rabbit): 500-1000 mg / kg bw / day Causes damage to organs
through prolonged or repeated exposure.
j. Aspiration Hazard : May be harmful if swallowed and enters the airway / airway.
k. Information about the route of exposure : Skin contact, swallowed
l. Symptoms related to the physical, chemical and toxicological characteristics :
Data not available. There has been no further examination.
m. Delayed and immediate effects and also chronic effects from short and
term exposure long : Data not available. There has been no further
examination.
n. Numerical measure of toxicity : Data not available. There has been no further
examination.
o. Interactive effects : Data not available. There has been no further examination.
p. If specific chemical data are not available : Data not available. There has been no
further examination.
q. Mix : See numerical measure of toxicity.
r. The mix versus the constituent ingredients : Data not available. There has been no
further examination.
s. Other information : Data not available. There has been no further examination

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12. ECOLOGICAL INFORMATION

a. Ecotoxicity
13. DISPOSAL CONSIDERATIONS
Short term toxicity to fish:
Method
- LL50of(4disposal
days) 1 g: Avoid
/ L spilling, draining and contact with soil, drains,
drains sewerstoxicity
Short-term and sewers. Disposal
to aquatic of this product, dilution and any treatment
invertebrates:
the- EL50
product
(48must be in
hours) accordance
35.9 mg / L with the provisions of the local government.
Short-term toxicity to aquatic invertebrates:
- NOELR (21 days) 100 µg / L
- LOELR (21 days) 1.1 mg / L
Toxicity to algae &
cyanobacteria:
- EL50 (72 hours) 18.8 mg / L
b. Persistence and degradability
Data not available. There has been no further examination.
c. Bioaccumulative potential
Data not available. The details regarding the toxic effect relate to the
concentration nominal. There has been no further examination.
d. Mobility in soil
Data not available. There has been no further examination.
e. Other detrimental effects
Data not available. There has been no further examination.
 Document No / Rev Level

Material Safety Data Sheet

SK-RnD-MSDS-01 / 00 2

14. TRANSPORT INFORMATION

Not
15. classified
REGULATORYas a hazardous material for transportation. Keep away from material Food
INFORMATION

a. Environmental, health and safety regulations for these products

16. OTHER INFORMATION
- Regulation of the Minister of Industry Number 23 / MIND / PER /
4/2013 concerning Amendments
The data provided here is based on current knowledge and experience
On the Regulation of the Minister of Industry Number 87 / M-IND / PER /
from9/2009
this Material Safetythe
concerning Data SheetGlobal
System is to describe the product
Harmonization in terms
of Classification and
Labeling
of security of Chemicals
requirements.
- Regulation of the Director General of Manufacturing Industry Base No. 04 / BIM
/PER / I / 2014 concerning Technical Guidelines and Guidelines for the
Supervision of Harmonized System Implementation Global Classifications and
Labels on Chemicals
- Government Regulation of the Republic of Indonesia Number 74 of
2001 Concerning Management of Hazardous and Toxic Materials
- Minister of Manpower Decree No 187 / Men / 1999 concerning Material
Control Hazardous Chemical
- Regulation of the Minister of Health of the Republic of Indonesia Number 70
of 2016 concerning Industrial Work Environment Health Standards and
Requirements
- ACGIH. 2016. TLVs and BEIs