Test-01 Chapters: Complete syllabus Std 12: Chemistry Date : 05/02/24 ‘Total Marks:100 Subjective Test ‘Time: 03 Hour Section A @ Choose correct answer from the given options. [Each carries 1 Mark] {s0] 10, u What is the molarity of a solution prepared by dissolving 7.1 gram Na,SO, in 100 mL. water? (A) 05M ® 2M (© 02M ©) 0.05M ‘The vapour pressure of benzene is 75mm and that of toluene is 22 mm at 20°C tempreture. The solution prepared by mixing 78 gram benzene and 46 gram toluene then, what will be the partial pressure of benzene in the mixture ? (A) 25 @) 50 © 100 O75 ‘What is the molality of 2.05 molar aqueous solution of acetic acid ? The density of solution is 1.02 gram/ml. W Lu4M ®) 328M (© 228M (D) 044M When 20 g of naphthoic acid (C,,H,0,) is dissolved in 50 g of benzene (K = 1.72 K m7), a freezing point depression of 2 K is observed. The Van't Hoff factor is A 05 ®1 2 O3 What is the mole fraction of the solute in a 1.00m aqueous solution ? (A) 0.0354 ®) 0.0177 017 1.70 ‘What is the values of AG, equilibrium constant K and Eq for the spontaneous reaction ? WW) 4ve, < 1, -ve ®) ~ve, > 1, 4ve 5) ve, < 1, ve () ~ve, < 1, -ve If A°CH,COONa = 91 Sem? mot", ATIC determine A°CH,COOH, ( aecr ®) A°Nacl (eH (D) A°CICH,COOH 462.2 S.cm® mol", then choose correct option to Find out molar conductivity of AgCI at infinite dilution. Given, AS, = 133.4 (AgNO,); A@ = 149.9 (KCD; AZ, = 144.9 S cm? mot! (KNO,) (A) 140 S em? mot!) 138 S em* mot? (©) 134$ em*® mot! —_(D) 132 $ cm? mol! Metals A, B and C has reduction potentials, 0.34 volt, -0.80 volt and ~0.46 volt respectively. So give order of their capacity as reducing agent. C>A>B BA>B>C (OB>C>a D)C>B>A How much faraday current is required for reduction of 1.5 mol Cr,0,- to Cr? 15 F Bor (O6F O3F For the non - stoichiomette reaction 2A + B ~ C + D, the following kinetic data were obtained in three separate experiments, all at 298 K. Initial Initial Initial rate of Concentration | Concentration | formation of C w ®) (mol 179) 01M O1M 12% 10> 01M 02M 12 10% 02M o1M 24 x 103 The rate law for the formation of C is w Kap — @ Sf = KAI of =KaB =o $= KAR BH12 14 15, 16. 1. 18. 19. 20, 1 If the rate constant for a first order reactions K, the time (0) required for the completion of 99% of the reaction is given by (A) = 2.303/k B) t= 0.693/k (©) t= 6.909/k (D) = 4.606/k ‘The rate constant for a first order reaction is 4.606 x 10-5 s"!, The time required to reduce 2.0 g of the reactant to 0.2 g is (A) 500 s ®) 1000 s © 100s ©) 200s 1) the slope of Anhenius plot (Ink v/s) of frst onder reaction is- 5 108 K The value of Ba ofthe reaction is : Choose the correct option for your answer. [Given R = 8.314 J K! mol!) (A) 166 kJ mol! (B) -83 kJ mol! (©) 41.5 i mol? (D) 83.0 kJ mol! ‘At 298 K temperature the activation energy for the reaction X, + Yq -> 2X¥ + 20 KJ is 15 KJ. What will be the activation energy for the reaction 2XY > X, + ¥, 7 (A) +35) ®) 85K) ©-5K) (D) -15 KJ What is the oxidation number of Ti, whose magnetic moment is 1.73 BM? w+ ® +2 ou Da The outer electronic configuration of Gd (Atomic no, 64) is (8) af 5a 62 @ 4 5a 62 (© af 5d! 62 D) af 5a 6% Match the catalyst to the correct process. Catalyst Process @ Til, |@ Wacker process (b) Pdcl, | tid) Ziegler Natta polymerisation (© CuCl, — | tii) Contact process (@ V,0, | Gv) Deacon's process W @ > Gi, b) > Gi), >, @>O B @ > ii, & > OC > W, @ > Ww © @ > Gi, 6 > H, © >, @ 50 DM @ > GH, b > 0, © > Ww, @ > Gi Match the metal ions given in Column-I with the spin megnetic moments of the ions given in Column-II and assign the correct code Column - IL @ V8BM Gi VBBM iy) J3BM Gv) JBM JI5BM cod ww wo wd @ B i) wo w a Oo a Gi Ww Ow @ Ww Gi Zr (Z = 40) and Hf (Z = 72) have similar atomic and ionic radii because of (A) Lanthanoid contraction (B) Having similar chemical properties (©) Belonging to same group (©) Diagonal relationship ‘What is the IUPAC name of K,[Ni(CN),] complex ? (A) Potassium tetracyano nickelate (D B) Potassium tetracyano nickelate (ID (©) Potassium tetracyano nickel (ID ) Potassium tetracyano nickel (1D22. 23. 24, 25, 26. a. 28, 2, 30, 3. 2. 33. M4 ‘What is the oxidation no. of (Cr(NH,),Ch]" ? (A) +3 ®) +2 On D0 Which of the following octahedral complex does not shaw geometrical isomers ? (Where A and B are unidentate ligand) (A) [MA,B,I ®) (MA,B,] © [MAY D) [MAB] Which complex possesses facial and meridian isomers ? (A) [CoWNH,),Ch] ®) (CoNH,),CLJC! (© [Coten),)Cl, () [CowNH,) CHCl, Which complex contains 4, values is the minimum ? A) [CriCN),)- (B) [Co(NHy),]3* (© [Coch (D) [Crd1,0},) Chlorobenzene reacts with sodium metal in presence of dry ether to prepare diphenyl the name of the reaction is. (A) Fittig reaction (B) Wartz-Fttig reaction (© Sandmeyer reaction D) Gattermann reaction Im Sy? reactions, the correct order of reactivity for the following compounds CH,Cl, CH,CH,CI, (CH), CHC and (CH,),CCl is (A) CH,CH,Cl > CHCl > (CH,), CHCI > (CH,),CCL (B) (CH,,CHCI > CH,CH,CI > CH,CI > (CH,),CCL (©) CHCl > (CH,),CHCI > CH,CH,Cl > (CH,),CC1 (0) CHCl > CH,CH,Cl > (CH,), CHCI > (CH,),CCL Chlorination of toluene in presence of light and heat followed by treatement with aqueous NaOH gives. (A) o-cresol B) p-cresol (C) Mixture of o-cresol and p-cresol () Benzoic acid Which of the following compounds has the highest boiling point ? (A) CH,CH,CH,Cl ®) CH,CH,CH,CH,CI (©) CH,CH(CH,)CH,Cl (D) (CH,)¢ CL 3-methylbut-I-ene on reaction with HBr gives (as major product) ? ( (CH,), CHCH,CH,Br ®) (CH), CBrCH, CH, (© (CH,), CHCH Br CH, ©) (CH,), CCH, Br Pick the correct group of the following having decending order of its acidity. (A) m-nitrophenol > p-nitrophenol > 0 - nitrophenol (B) o~nitrophenol > m~nitrophenol > p-nitrophenol (©) p-nitrophenol > m -nitrophenol > 0-nitrophenol (D) p-nitrophenol > o-nitrophenol. > m -nitrophenol Wo, ‘Cumene +? 00 and (¥), What is X and ¥? Gi) H,0, (A) Toluene, Propene ) Toluene, Propy! chloride (C) Phenol, Acetone (D) Phenol, Acetaldehyde BeG)-ocHs ant Hg o Ope asco © © veo CHoH 0) Ook antcryse Zn Powder, » CHCl, , Allaline, 7 wnat is 7.7 Phenol ‘Anhy.” " KMnO,35. 36. a. 38. 3%. 40, 41 2. AICly (A) Benzaldehyde ®) Benzene (© Toluene (D) Bensoic acid Complete the reaction. cH, - GH—cH,-0-cH, cit, +1—A> Cis (A) CH ~ CH -CH,OH + CH,CH, (8) CH, ~ GH CH, +CHCHOH Hs CH (©) CH, - CH -CH,OH +CH,CH,! ) Cy - CH -CH, -14CH,CH,OH Hs Hs Which compound will not give Cannizzaro reaction ? (A Benzaldehyde ®) 2-methyl propanal (C) p-methoxy benzaldehyde (D) Formaldehyde What is the IUPAC name of compounds ? (A) 2-methyl-3-bromo hexanal (8) 3-bromo-2-methyl butanal AN (C) 2-methyl-3-bromo butanal (D) 3-bromo-2-methyl pentanal Br Which product will obtain in below reaction? catecay 20/1880, ~HS0, wo on — @ CH,-cHO (© CH,-Ccoon (D) CH- Ch on on In the reaction, cH,coon HAs , , PCls ,p_Ale. KOH ¢ The product C is (A) Ethylene (B) Acetyl chloride —_—_(C) Acetaldehyde (D) Acetylene What is the IUPAC name of the organic compound formed in the following chemical reaction ? (CaHsMgBr, dry Ether DIO." (A) pentan-3-o1 ) 2-methylbucar Acetone ol (C) 2-methylpropan-2-ol (D)_pentan-2-o1 What is A and B in following reaction respectively, NH, NaNO, , (4) HBF , HCl, 278K (A) Phenol and benzene (B) Nitrobenzene and chlorobenzene (©) Nitrobenzene and fluorobenzene (D) Benzene diazonium chloride and fluoro-benzene What is product A in following reaction ? Nenci NH + 4Lw Yellow dye ow» Ops-x-meO) Ops-825)Nip © Gpn-n(Oy wo Oyx-{Opnn 43. What is the correct rate for increasing basic character of following compounds ? NH, NH, NH, NO, CH, o am om @ = 54.6 Sem? mot! Give one example of each for Swarts reaction, Wurtz reaction and Finkelstein reaction of alkyl halide. Write the reaction mechanism of dehydration of ethanol in presence of acid to form ethene. Give conversion in three steps : Nitrobenzene into chlorobenzene. Write the answer of the following questions. [Each carries 4 Marks] (16) Derive an equation of rate constant and half life for first order reaction, INi(CN),}% is square planar while [NiCI,]* is tetrahedral. Explain. Write Kolbe and Reimer Tiemann reaction of phenol, Write the self aldol and cross aldol products of ethanal and propan.