Multi Assertion ple Choi Fa ie and Type Questions Solutions IR MULTIPLE CHOICE QUESTIONS Each question has four options (a), (b),(c) and (4). | Choose the true option. | 1. Inwhich of the following, physical state of solute and | solvent is liquid and solid respectively ? @ Solution of sugar in water | (Zinc amalgam | (6) Solution of Naphthelene in benzene (@) Brass 2. What is the physical state of solute and solvent for a | solution of camphor in N, gas ? @ solid, gas © solid, tiquid © 2s, solid @ gas, gas 3. To convert molarity into which of the following unit of | concentration, does not require density ofthe solution ? (@) molality (® normality | (© mole-fraction —(d) Yewiw | 4. Which ofthe following unit of concentration doesnot | depend on temperature ? @ Volume percentage (6) Molarity © Molality (@ Normality } 5. Onwhich factor, the solubility of gasin liquid depends ? | (@ Temperature (©) Pressure of the gas | © Nature of solute and solvent @ All of the above | 6. In which ofthe following specific condition, CO, gasis filled in cold drinks, and in soda water ? (2) at high temperature and high pressure 51 (at low temperature and high pressure (©) at low temperature and low pressure (@) at high temperatire and low pressure 7. Inwhich condition, Henry's law is applicable ? (@) ideal behaviour of gaseous solute at high pressure and low temperature. (b) gaseous solute neither associate nor dissociate in solution. © gaseous solute react with solvent. @ applicable in all the above conditions. 8. Duet which reason, O, gas liberates from the blood of | tissues of animal bodies (@) less temperature of tissues . (©) partial pressure of oxygen gas is more in tissues. (© pantal pressure of carbon dioxide is less in tissues. (@) partial pressure of oxygen gas is less in tissues. 9. Solute + solvent = solution; A,,,,H>0. What would bbe the change in solubility of substance on increasing the temperature at equilibrium ? @ Increases (©) Decreases (© Remains constant (d) Can’t be predicted 10. Which of the following is a colligative property ? @ vapour pressure (©) osmotic pressure () boiling point (@) all the above ‘UL. Moist air is an example of ............. Solution. (@ gaseous (0) liquid (©) solid @ colloidal i a52 | CHEMISTRY-x11 swett auesnon mrets 12. Which of the following pai . Fees rornaee oFsokacas fre oar @ Chlorobenzene-chloroethane @) Benzene-toluene (© Acetone-chloroform @ Water, HCL 13. How many grams of NaOH needed to prepare 250ml of01 Meohiten a @ ig (®) 10g © 4 @& ar oe following solution is isotonic with fluids @ 0.2% (wNYNaCl —(b) 0.9% (w/V)NaCl © 0.18% (w/V)NaCl_ (a) All of the above. ‘A solution of sulphuric acid in water exhibits (@) negative deviation from Raoult’s law (©) positive deviation from Raoult’s law (©) ideal properties @) the applicability of Henry's law. Which colligative property is used to determine molecular weight of biomolecules such as protein ? (@ Osmotic pressure (®) Depression of freezing point (©) Elevation of boiling point (@) Relative lowering of vapour pressure. 17. Two solutions have different osmotic pressures. The solution of higher osmotic pressure is called (@) Isotonic solution ()_Hypotonic solution (©) Isotopic solution (d) Hypertonic solution 18. Naphthalene is soluble in ether or benzene because + (@) dipole-dipole interaction is equivalent (®) London forces are equivalent 1s. 16. Zs ‘ASSERTION AND REASONING TYPE QUESTIONS DIRECTION: For questions given below, two statements are £iven tne dabelled Assertion (A) and the other labelled Reason (R).Select the correct answer from the codes (A),(B), (C) and (D) as given below. (A) Both assertion and reason are correct sta correct explanation of the assertion. ements, and reason is the (6 Hydrogen bond formation @ Tonic int sion are equivalent. 19, Which of the following isapplicnle forthe sols cof gases in liquid. : (@ Increases Wild increase in Lemperatre gy pressure. (& Decreases with inerease in temperate gy © Increases with decrease intemperature ard ingray in pressure. : (ay Decreases with deorease in temperature gq jncrease in pressure. ap. afewo substances A and B BAVE PA :P5 = 1: ang have mole faction in solution 1:2, then mole factigg ‘of A in vapours is @ 03 0,025, © 02 » @02 21. Ethylene glycol is added to water as antifreeze. It will (@ decrease the freezing point of water in winter an jncrease the boiling point of water in summer, © only decrease ‘the freezing point of water (©) only increase the boiling point of water @ beused for cleaning the radiator in a car 22. Which of the following option is correct fora ‘homogeneous mixture of liquid A and B, whic shows positive deviation from Raoult’s Law. | (@ A-B interactions are stronger than interaction between A-A and B-B. (© BB interactions are weaker than interaction off) A a (@) B-B interactions are stronger than interaction off A (®) Both assertion and reason are correct statements, D4] reason is not the correct explanation of the assertion (©) Assertion i correct, but reason is wrong statement (D) Assertion is wrong, but reason is correct statemett Solutions are homogeneous mix Solvent determines the physicel in which solution exists.“g pout 24, Assertion (A) + Molality is den Reason (R) 25, Assertion (A) Reason (R) 26. Assertion (A) Reason (R) 27, Assertion (A) Reason (R) 28, Assertion (A) Reason (R) 29. Assertion (A) Reason (R) 30. Assertion (A) Reason (R) 31. Assertion (A) Reason(R) ined as Aumber of issolved in one litre Molality ig temperature, The ‘solubility, ‘Of a solid in atic Sienifcamly affected by wap independent of If the dissolution process j endothermic, the solubility should decrease as per Le Chateliers Principle, ‘The solubility of gases increase with increase of pressure, Raoult’s law gives the relation between pressure and solubility of a gas in @ solvent. Aquatic species are more comfortable in cold waters rather than in warm waters. The solubility of gases in water increases with decrease of ‘temperature, To avoid bends, the tanks used by scuba divers are filled with air diluted with helium. Helium is very less soluble in blood even at high pressure. Solubility of gases in liquids decreases with rise in temperature, Dissolution of gas in liq exothermic process. For any solution, the partial vapour pressure of each volatile component in the solution is directly proportional to its mole fraction, The solutions, which obey Raoult’s law over the entire range of is an concentration are known as ideal | solutions. Ifthe intermolecular attractive forces between the A-A and B-B are nearly ‘equal to those between A-B, this leads to the formation of ideal solution, + Most of the solutions are nearly ideal | in behaviour, sawete QUESTION pavers CHEMISTRY-XII | 53 32, Assertion (A) Reason (R) 33. Assertion (A) Reason (R) 34. Assertion (A) Reason (R) 35. Assertion (A) Reason (R) 36. Assertion (A) Reason (R) 37. Assertion (A) Reason (R) 38. Assertion (A) Reason (R) + Amixture of chloroform and acetone forms s solution with negative deviation from Raoult’s law. + Chloroform forms hydrogen bonds with acetone. : Azeotropes are the binary mixtures having the same composition in liquid and vapour phase. + The components of an azeotrope can be separated by fractional distillation. + The solutions, which show a large positive deviation from Raoult’s law form maximum boiling azeotrope at a specific composition. Ethanol-water mixture containing 95% ethanol by volume form minimum boiling azeotrope. + Relative lowering of vapour pressure is equal to the mole fraction of the solute. Relative lowering of vapour pressure is a colligative property. + The boiling point of a solution is always higher than that of the boiling point of the pure solvent in which the solution is prepared. + The elevation of boiling point depends on the number of solute ‘molecules rather than their nature. + Blood cells collapse when suspended in saline water. + Osmotic pressure is a colligative Property. + Measurement of osmotic pressure is widely used to determine molar masses of proteins, polymers and other macromolecules. 3 As compared to other colligative Properties, the magnitude of osmotic Pressure is large even for very dilute solutions. 39. Assertion (A) : 0.9% (mass/ volume) sodium chloride Reason (R) solution, called normal saline solution is safe to inject intravenously. + The osmotic pressure associated with the fluid inside the blood cell is equivalent to that of 0.9% (mass/ volume) sodium chloride solution,54 | CHEMISTRY-X11 suwuz quesnon press 2 [FS MUUTPLE aioice auesnons 29. (A) bs Mason is the correct explanation of a 1 @® 2@ 2 40 assertion. es e and reason are correct sta 5. @ 6 & 7.® Re 30.6) a a not the correct explanation gh x2@ 0106 %L@® 120 - P 3@ 4O 6@ 6@ sre awe jscorrect, but reason is Wrong state 1.@ BO WO _2@ q assertion and reason ATE COFTECt state 2 @ 2® 20) Boh sae pecometeranation ofthe aya (3 assexton ano nessoume re ovesrons 23. (B) Both assertion and reason are correct statements, but reason is not the correct explanation of the assertion. 24. (D) Assertion is wrong, but reason is correct statement. 25. (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. 26. (C). Assertion is correct, but reason is wrong statement. 27. (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. 28. (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. fs MULTIPLE CHOICE QUESTIONS Each question has four options (a), (b), (c) and (4) ~ Choose the true option. 1, Reduction reaction means .. (@) the addition of oxygen @ the removal of hydrogen (©) the gain of electrons @) the loss of electrons. “Assertion iscorrect, butreason is Wrong “Aseerton is wrong, but reason is COTTeCtstatemey, ‘Both assertion and reason are correct statements, recon snot the comect explanation of the aseg 6. @) Both asetion and reason are correct statements, y 36.8) reason isnot the correct explanation Of the assertog Both assertion and reason are correct statem bot reason is not the correct explanation of ty assertion. +38. (A) Both assertion and reason are correct statemen, » eetreasn ste cect explanation of the aceon, Both assertion and reason are ‘correct ‘and reason is the correct explanation of the assertion. 3. © 34. ©) 35. ®) 37.8) 39. (A) Electrochemist : 2. Oxidation reaction means .... (@) the loss of electrons (&) the addition of hydrogen (© the removal of oxygen @ the addition of electrons,How many moles lectonsae ded vhen 25 mole 1,07 reduced in Ce*7 7 (@ 125 (ON 15 @0 4, How many mole of MnO, reduced to Mn by the addition of75 mole of eleetonsin Mao; ? (25 os @1s 75 5, For an electrochemical cell, 7 wae Mg|Me™o| [BF |B] Pt, what willbe the change in cell potential, when concentration of solution of cathode increase at constant temperature 7 (@ increases ®) decreases (©) No change occurs (@) Big =EOq 9. For which of the following compound, a graph of molar conductivity and (molarity) is obtained straight line ? @ ca © NHOH (©) HOOOH @ givenall tree When same electric charge is passed through electrolytic cells containing aqueous solutions of CuSO,, AgNO, and NiSO,, then what would be proportion of moles of metal obtained at different cathodes respectively ? (@ 2:1:2 ® (Q 11:2 @ 8, What would be the change in pH ofthe solution, when electrolysis of aqueous solution of CuSO, is carried cout in presence of inert electrodes ? (@ pH increases (6) pH decreases (©) nochange inpH — (@) can'tbe predicted Inanexperiment of electroplating, 4 Aclectric current is passed for minutes. Hence, ‘m' g Agis deposited at cathode. If 6 A current is passed for 40 s, then what amount of Ag is deposited at cathode? (@)2m @4m (© m2 @ m4 10. What is the value of Egg? 3M) at 25°C? Eggs “2369 (@) 236897 ~ (0) -23689V (©) 288V (@ -238V |« How many gram of Ais obtained, if $.0 F quantity of electricity is passed through aqueous solution of | AgNO, ? [Atomic mass of Ag = 108 u } swyne cusmon wats CHEMISTRY-XI | 55 (@ 200g () 5408 (© 180g @ 1358 12. 2.5Sm'=. Sem: @ 2% OS (© 002s @ 025 1 13, Which ofthe following is equal to 7p ? @p Onc 1 @G OF 14, What i the numberof electrons required to deposit 1g 15. stom of Al (atomic mass=27) form a solution of AICI, ? @ Imo (@) 2mol © 3m @ Arno For the reduction of silver ions with copper metal, the standard cell potential is 0.46 V at 25°C. The value of standard Gibbs energy AG® will be: (@ 9.015 © 9905 © 4s @ 8008 16, Standard electrode potential for Sn‘*/Sn™* couple is +0.15 Vand that forthe CP*/Crcouple is-0.74 V. These two couples in their standard state are connected to make cell. The cell potential will be = @ +1.8V (+119 © +089 (@-039V 7. Standard electrode potential of three metals X, Y and Z. are -1.2V, +05 V and—-3.0 V respectively. The reducing power of these metals will be : @ X>Y>Z ® Y>Z2>x (© Y>x>Z @ 2>x>¥ 18, If the E&, for a given reaction has a positive value, v. 20, Kohlrausch’s law states that at : then which of the following gives the correct relationships for the value of AG® and K,, ? @ AG°>0;K,<1 (6) AG°>0;K.>1 (© AG°<0;K,>1 @ AG®<0;K, <1 When 0.1 mol MnO3° is oxidised, the quantity of electricity required to completely oxidise MnO} to Mn0; is: (@) 965006 © 9650¢ © 2%96500C @ %50C (@ infinite ditution, each ion makes definite contribution to equivalent conductance of an= 56 | CHEMISTRY suwote avesnon res electrolyte depending on the nature of the other ion of the electrolyte © infinite dilution, each ion makes definite Contribution to conductance of an electrolyte whatever be the nature of the other ion of the electrolyte . © infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte, whatever be the nature of the other ion ofthe electrolyte @ finite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte 21. The molar conductivity of NaCl, HCland CH,COONa atinfinite dilution are 126.45, 426.16 and91 Sem? mot! respectively. The molar conductivity of CH,COOH at infinite dilutions: (@) 201.28Sem*mol" (6) 698.28 Sco mol (© 390.71Sem?mot (@) $40.48 Sem molt 3 ‘ASSERTION AND REASONING TYPE QUESTIONS DIRECTION: For questions given below, two statements are given - ‘one labelled Assertion (A) and the other labelled Reason (R). Select the correct answer from the codes. (A),B), (Cand (D) asgiven below. (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. (8) Both assertion and reason are correct statements, but reason is not the correct explanation of the assertion. (© Assertion is correct, but reason is wrong statement, (D) Assertion is wrong, but reason is correct statement. 25. Assertion (A) : The potential difference between the two electrodes of a galvanic cell is called the cell potential. Reason(R) : Cell potential is measured in volts. 26. Assertion (A) : Cu does not dissolve in HCI. Reasom(R) : The value of standard electrode potential for copper (E® 2...) is positive. + Lithium ion is the weakest oxidising agent. 21, Assertion (A) Reason(R) : Lithium has the lowest electrode potential. 30. Assertion (A) : a Limiting molar corantiity of NH,OH/ 79 hi 4 15 QvH,0H) isequal 10: @ xenjow+ A, (NH,CD--A,, (HCI) & A,onHc)+ Nj, (NAOH) = A, (NaCI) fo Ky (sH,CD+ Ae (NAC) A, (NOH (@ A, (NAOH)+ A, (NAC) + A, (NH,Ch solation of which of the following co ee f electric current? js the best conductor of (a) Acetic acid, CH (0, (6) Hydrochloric acid, Fo) (6 Ammonia,NH, _() Fructose, C,H,,0, 24, Anclctrocemical cel behaves like an electrolytic when (@) Boea=Eenerat ©) Besa” Fest @E,y=0 @) Eosema,2+ 2, 31. Assertion(A) : If, E2,, > 0, the reaction is feasible | Reason (R) be stored in a zinc pot. 32, Assertion (A) : Ions are the carriers cof current in | internal circuit of the cell. | Reason(R) +; Electrons are the carriers of cuedtit} the external circuit ofthe cell.33, Assertion (A) The relationship between Gibbs free ‘energy of the cel] teaction in a talvanic cel s rp the emf of the cell Reason (R) ‘34, Assertion (A) + Conductivity aways decreases with (one ‘concentration i.e. on ilution for both str aa rong & weak + Number of ions decreases on Reason (R) Per unit volume lution, 435, Assertion (A) : strong electrolytes increases on dilution, Reason (R) : On decrease in concentration i.e. on dilution, mobility of ions increases. 36, Assertion (A): Increase in molar conductivity for savers auesron neces CHEMISTRY | 57 Reason(R) _: Direct current is used for measuring fmon(e)s resatance of an electrolytic solution. P 31. Assertion (A) : Conductivity of CH,COOH decreases on dilution. + The number of ions per unit volume decreases on dilution. 38, Assertion (A) : During electrolysis of molten NaCl, ‘Na metal is produced at anode while Cl, gas is produced at cathode. + Inert electrodes do not take part in ‘chemical reaction but act as source oF sink of electrons. 39. Assertion (A) : When acidulated water (dil. H,SO, solution) is electrolysed, pH of the solution remains unaffected. Reason (R) _: During electrolysis of dil. H,SO, solution,the amount of H® ions Reason (R) Reason (R) weak electro is more than that of reduced is compensated by the H” strong electrolytes.. ions produced by oxidation of H,O. Q ANSWERS =~, ULTPLE CHOICE QUESTIONS | 30. (A) Both assertion and reason are corect statements, and reason is the correct explanation of the LQ 20°30 40 seein 5 6@ 26 &® 31. @) Both assertion and reason are correct statements, 20 0@ LO. ne leer ingot the conect cxphauation of the 13, @ 14.0, I@, 160 32. @B) Both assertion and reason are correct statements, 1@ BO BO me but reason is not the correct explanation of the 1.0 20 BO OE ete FB ASSERTION AND REASONING TYPE QUESTIONS 25, (B) Both assertion and reason are correct statements, but reason is not the correct explanation of the assertion. 26. (A) Both assertion and reason are correct statements, ‘and reason is the correct explanation of the assertion, 27, (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. 28. (C)_ Assertion is correct, butreason is wrong statement. 29, (D) Assertion is wrong, but reason is correct statement, 33. (D) Assertion is wrong, but reason is correct statement. 34. (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. 35. (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. 36, (©) Assertion is correct, but reasons wrong statement. 31, (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. 38. (D) Assertions wrong, but reason ig correct statement. 39, (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion,AS MULTIPLE CHOICE QUESTIONS Each question has four options (a), (b,(c)and (2, Choose the true option. 1, Rate of reaction is defined as: (@) decrease in the concentration of a reactant © increase in the concentration of a product (© change in the concentration of any one of the Teactants or products per unit time (@) all the above three are correct 2. For the reaction: 2A +B—>3C, instant rate ofreaction is: ( +144 a8)_ 1c) 2 dt a aa, © 24442) _ 340 3. The rate of reaction of spontaneous reaction is generally very slow. This is due to the fact that (@) the equilibrium constant of the reaction is less than 1 (©) the activation energy of the reaction is large (© the reaction are exothermic @ the reaction are endothermic 4. For the reaction, 4A + B +» 2C +D. Which of the following statement is not correct ? (@) The rate of formation of C and D are equal (6) The rate of formation of D is same as the rate of consumption of B (©) The rate of appearance of C is twice the rate of disappearance of B (@ The rate of disappearance of B is one fourth of the Chemical Kinetic, rate of disappearance of A 5, For thereaction A+B + C—> Products, Rate = [B)!"{C). The order of reaction is : @3 @1 © 56 @ 116 6. A zero order reactions one whose rate is independ, (@ volume of reaction vessel (© concentration of reactants (© temperature @ pressure of light 7. The rate constant of a reaction changes when (@ pressure is changed (®) concentration of reactants changed (© temperature is changed @ a catalyst is added 8. A reaction involving two different reactants canneverbea} (@ bimolecular reaction (6) unimolecular reaction (© firstorderreaction (d) second order reaction 9. The rate law of a reaction is rate = KA]? [B). doubling the concentration of both A and B the rate’ will become : @x (@ & @4r O% 10, Ifthe order ofreaction is zero. It means that: (©) rate of reaction is independent of temperature, (the rate of formation of activated complex is 210 © the rate of decomposition of activated complex is 2210. q @ rate of reaction is independent of the concentrate of the reacting species. 11. Following mechanism has been proposed for tb#)} reaction :2A+2B—>D+E, ‘| Step 1: A+2B + 2C+D(slow) Step2:A+2C—>E (Fast) The rate law expression for the reaction is : @ rate=K{A}[BP (6) rate=K [APBY{C] (© rate=K{A][BF (d) rate=K[A][B] Kayaost 12, In the reaction A ~> B. When the concentration of Ais changed from 0.1 M to 1 M, the rate of reaction increases by a factor of 100. What is the order of reacties with respect toA? (@ 10 1 @2 @3 13. The rate constant of a reaction has same units as the rate of reaction. What is the order of the reaction ? (@) Three (b) Two (© One @ Zero 14. The rate constant of reaction is 3 « 10° bar! sec" ‘What is the order of the reaction ? @ One () Two (© Three @ Zero of the following statements is not correct about the molecularity of a reaction? (@ Molecularity of a reaction is the number of ‘molecules in the slowest step. (® Molecularity of a reaction can never be zero. (© There is no difference between order and molecularity ofa reaction. @ Molecularity is always a positive whole number. 16. Increase in the concentration of the reactants leads 1o the change in : (@ heat of reaction (6) threshold energy (© collision frequency (@) activation energy wun quesnon raens CHEMISTRY-XI | 59 ion 2A-+B —» Products is expressed my ease If Ais present in large excess, the ‘order of the reaction is @3 2 @1 @o 18. The activation energy of a reaction is zero, The rate constant of the reaction : (@) increase with increase of temperature ()) decrease with increase of temperature © decrease with decrease of temperature 19, The rate of reaction 2A + B-> Product is expressed as: Rate = K [AJ[BF. The active mass of A is kept constant ‘and that of B is doubled. The rate of reaction will : @ increase two times (6) increase four times (©) decrease two times (d) decrease four times. 20. The half-life period for a zero order reaction is equal to 0.693 = OF © ip 2.303 (Rl oF Ox (where [R]pis initial concentration of reactant and kis rate constant.) 8 Es" [ASSERTION AND REASONING TYPE QUESTIONS : DIRECTION: For questions given below, two statements are given one labelled -Assertion (A) and the other labelled Reason (R). Select the correct answer from the codes (A), B), © and D) asgiven below. (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. (B) Both assertion and reason are correct statements, but | reason is not the correct explanation of the assertion. (©) Assertion is correct, but reason is wrong statement. (©) Assertion is wrong, but reason is correct statement. 21. Assertion (A) : Hydrolysis of an ester follows first order kinetics. Reason (R) : Concentration of water remains nearly | constant during the course of the reaction, 22, Assertion (A) : The feasibility of a chemical reaction ‘can be predicted by thermodynamics. Reason (R) A reaction with AG <0, at constant ‘temperature and pressure is feasible. chemical reaction, R—>P Atk] a When expressed in terms of concentration, the unit of rate of reaction is mol L's“. “The representation of rate of reaction in terms of concentration of the reactants is known as rate law. Rate law for any reaction cannot be predicted theoretically but must be determined i Yo 25, Assertion(A) : The molecularity of a chemical reaction is the sum of powers of the concentration of all the reactants in the rate law expression. The molecularity of a chemical reaction is a theoretical concept. ‘The unit of rate constant for an nth ‘order reaction is (mol L~! "5", ‘The unit of rate constant for an 2nd order reaction is mol Lt s', 23, Assertion (A) = Fé Rate of reaction = Reason(R) = 24, Assertion (A) : Reason(R) = Reasoa(R) 26, Assertion (A) Reasom(R) =‘of more than three a colliding simultaneously why Gasket re with Proper orientation is very For a first order reaction, tyq is independent of [R]. 29. Assertion (A) + The order of a reaction is sometimes altered by conditions. + Hydrolysis of ester is a pseudo first ‘order reaction when water is taken in large excess. 30. Assertion (A) : The overall order ofa reaction, which has the rate expression; Rate=HA) (BPs $(1+3). Reason(R) = The order of a chemical reaction is the sum of powers of the Ae Probability ofmolecularity being | tow. 31, Assertion (A) Reason (R) 32. Assertion (A) Reason (R) 33. Assertion (A) Reason (R) 34, Assertion (A) 26. (©) Assertion is correct, but reason is wrong statemey 27. (A) Both assertion and reason are correct satemeny, and reason is the correct explanation ofthe a 28. (A) Both assertion and reason are correct statement | concentration of the reactants in the esoe ny rate law expression. : “QCANSWERS, & MULTIPLE CHOICE QUESTIONS LQ 26 36 4@ S@ 60 720 8) assertion. 9@ WM 10 126 B@ 40 6.0 6© and reason: 170 BM 90 20@ & ASSERTION AND REASONING TYPE QUESTIONS, 21. (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion, 22. (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. 23. (B) Both assertion and reason are correct statements, but reason is not the correct explanation of the assertion. 24, (B) Both assertion and reason are correct statements, ‘but reason is not the correct explanation of the assertion. 25. (D) Assertion is wrong, but reason is correct statement. | 29. (B) Both assertion and reason are correct state but reason is not the correct explanation of it assertion. 30. (A) Both assertion and reason are correct and reaso assertion. 31. (B) Both assertion and reason are correct statemenls | but reason assertion. 32, (B) Both assértion and reason are correct statements bi reason isnot the correct explanation ofthe asset 33. (A) Both assertion and reason are correct stalemes and reasonis the correct explanation ofthe asset 34, (A) Both assertion and reason are correct statemens and reaso1 assertion. + Order ofa reaction isan ex quantity. + Order of @ reaction can bg even a fraction, to + Order is applicable to ¢, well as complex reactiong molecularity is applicabie elementary reactions, ¥ fy + For complex rection, ord by the slowest step ang ..'8h molecularity of the slowesr sth, same as the order of the c!P& reaction, ver + Fora zero order reaction hale is diretly proportional to gy) concentration of reactant (Ry iy + Forazeroorderreactionhatting i) is expressed as typ = Be Rate of reaction increase ease in temperature, + The increase in temperature in the number of effective collisions 8 Wi is the correct explanation of the: nis the correct explanation of tit | is not the correct explanation of te n is the correct explanation of