ORGANIC CHEMISTRY reactions- [esa] ALUoHOLS & PHENOLS R The bond length te paend is Mighty tus than that of mithand. Explain B. Explain the methanivm o preparotuon a, aldol fom alkene QR. Hy disbovation oti dahon 2 ae Mao = + GBI), > Oe or ane SEBS 4 6H, Com, chy -0), BH Oty Ge Ha Ho Blow, tt 2 hr CH oe — Cone cry - 4), a = Paspan-t-ol 0, of QR Radartion Olde & kunt with allah de Ho Reno + t, C4 > Remon — HHO + RNG X —> ReHOMax —“25RCHL0H atglon)x Reor’ Nala , p- cw r! k - Reno + KMgx > R- Cw nongy BS Ga ae wo ett R- cH on + Mglorx i a ; : ia » Coms ht & Commeial preparation 4 Rok + Rrgk — RE OMX Tung fe 14, 1 _& Revo E24, Riot’ —“ > penon + oH a] + 4 tae ae . arti oe Malou) x t i Rk Q. hom Grignond maganle : eh oo oe = bmg ok pero t RG [-¢- fo @ Addue. [hve \ Ma Con)» + 70H E@Preponctaon sf phanst B Mudaele om highly, soluble i» 2 ‘hom hole anes on s weaken «tala iL - A se QReaution gj aleohlt with Gask Ho + vaon eats (2) He a nlovobenzene Plums dp-o- 4 INQ —> 2R-0- No + He Sedans alkoxt trom bensint sulfonic acid S0,H on ay a | CHS304) 2 Noel Go- c-on + ant 72 Gag goa, Fae. i ° Ke nt aw, on s pare Bement, Phancl tek- bukylatusha Lt’ Sulbomie Kuamvinium- tek oud baboifds | oH ono hom diazonium salts 7 ce 3 + ana —> 2 + Ha NHy nrd on L Nano ate fio Nake cancun wort ~ on ona Bennene Phenol a Naor @ [0] + HO diaw mum Sout Sodum Phenoxide etn Cumnene a, 1 on =f 9-0-# ‘2 “Os = ) + Gio cH, RC Puspane Pland if ieop ore GExp loon the bedang ip ode ain 8 Baling point devant ite inoaan im branilulny - Explain “ & alent Q Kurd howe compart tiuly bah botlong point than eft erp oashle_ mame pork 4 alisha & phenst trocar wilhG reichtty abishas in tm the mda fost> 5 thy ? ne OsB les! & Phenele one brnstd aide Tuotiby osbincbse.com ae qoep otatked to an aromatic ming & mor aude than XY qoup aitauad # aK oll 2 OR) whe . yk yore | 4 phenol mare : @ Dey craton Q. Estudfy cakion a | fi 1 Guon 8S cH, = tH? Ay[eeo-n + Soom == Av] Rowe! + Ho? abvohrel ote woalin on tHe on, ae cH, “HF cH on +Hio ' a fy[Reon + (e-t),0 =—= pv[Rocon + Roow ah : ofs odechel uid anhydride ete gag (PRCT OS ae cr C=, oR +Ho an[econ x rtcoct Pyidine Arvocoe + HE oluch oud ete aud @: Muchonuim 4 daly drain chlevide thant Q halyloton colieylic aud ae ete wine an eal q) (pon cr + (aigte),0 .( + ot ycooH| abun ix Sere : Explain cakyl soli coud tentang Q. oridalow Sadieaie i if C-h —R- © OH oud Renn CE R- Q Reauken | alte ttth hydrogen hodlade . Reon + He —> RX +H? Ree Whey gd on peton rts Rew Qhurer Tests Umportamee da : : Cay CH = 08 = O0H ie Q beatin wth Phaphwus trihalde . v CH ar = cH ~ Oto 3R-0W + PK3 —a $@-x +H3POs Pee > Pridininm Chlove chyomat&Q-Puporotion 6 ketone prom 2 olihl pe gt OH gc! mae ox 4 OsB osbincbse.co”™ 8.04 A alichdl tn the prone A Copper cakalyat oh ReH ow Hs reno ey 9H T13k ©), x ie ay , en R-o-R | -w-e As bar acrr 1 By ue 2,4,6-Taibromeplensl Hs te chs Lidwate ppt) O- Coon —H> CH,- c= cH, | ' S13k cn, |g. kolkes veaction ow Q- Nitvoten oa Nao a a oe en a be eel eo Phunst — dedhinawn salicylic aid ans er le pices a. 0- nib phenel 893. Cransr) Prva phund f& Beimer - Hanae veauhon (major) on ons a Oo ayeon an oe | QHows te repurste onthe & parm dora 4] | nihve prundl ? [oe i? . eno - (He _— Q- Reaction 4 ao with UmeHno, sal lddny “anc HNOS ies Q. Raaukon 4 phend uth tene rust at Si-O Aare Sed (ptote acd) G. O%m 8 phenol ow | Na Ov, 04, leat nation tet, [° © 8 on ow 1,804 i By ey ° “aE ake Bencoguinone ByA lommusiat preparation A muthand 040° co + aH, P20 eno Jeo- sovatm ros & Q- Wmmunual prop q Ethane Cathe. + ho SES yo GHa% Glucose Fauctese ymase, ri 2GHOW + 202 ae AMINE & & Parp aration A armins Wy ommenolipir 4 alkyl hrodi des Nat Pee emer ve Nie see Sa osbincbse.com ay Ae : R-NH—> ANH fs Rn Ry Nix ° 2 2 Cqnontneay, ammonivune tal) ao f-iye + Naok —> R-NM + not Ndx Q. Raducion 4 nibiiles te peep ant ammonite ep tals ge cH, He Q.Redulisn 4] ahroles P A in Po ae ty, TE, RL M0 Gabriel- Phtholinude Q . ion ; y " ~ one! KH Poo N ae Oe 2NooH ic a \ ve Seok foe . "QMelfmann Bremamide desredatin reaction R- F_un, + By + qNaou —> R- WH, t Najo, + 2NaBy t He Q Te ovdin 4 boiking pews A Womanic anaines ane F293. thy 7 Retna ix tae tmpoataner A pky value 2 Q: Miphate anuius am aongu base than ammonia. Explain QR: Rromotic anun arn weaker Than ammonia Expl QR Compont the baric propetitn BL Ukanoumints & ammonia Cag & vopow, QR Gmpau the barie properties f orylamins & ammonia « ae Q. Atkylodncn Qa anes Nag t We —> RIN x” Q. heylolean | Cy 4 ie ! Base yee ‘ Gio Wwe Fd "GH NT ee > GH -N ~c -cy p ae 4 ° Hees a 4 Eth ansmnime N- Ela ethanamide x Bone. a 4 Hut GEN: < Ge 4 GG "s 1 ° GH, ° ool, i . N,N- Di etlayt ethanamide -e- Ws " Ne phenyt Uharamade CAcetanitide) -N “ spe — Oy ee Coot GHe F Qh NaH Tt Gn aly 3 _ 4 $ ° Bena narine a. Benzonylahon veowion, Ha CAs, 4g GM, CO ——> Ot, NH OO GH 4 Hethanamamnc Benronyl N- nuttluyt benain amide WordsCn arma reation 4 REN, + CHU + KOH ——=> R-NC + BkU + 3H,0 Houganider] rbylanuinu Q. Reakion with hipou oud : Nanos sata | 2 won tnd uct Re NH + HNO, aie [e~ wifi] nanos Soy MH Me Ge - Nee + Natt + dH.o net bordline Benzene digzonium bhovide Q-Reation wilh Asad sulphone! dlovide - HU - 64 —> &_ ie Sie t 4 N- a aes © sulphonate Cs in odkobi ) n fo ace FSbea te at BN Ghy — tt ee ° ony bo ay N,N- di Huy beneenc Avlphonanatde Q How ton you idurtidy and sepuate 12,3 mistine 4 amin 2 Q: Brominabiew na telwoe syn o eS + 3 Hey ‘a 2/46 -Tri bromo anil Goble ty) Q: Puparabion QGurstidGd ancline Wann 6 - Ory i ay NL bye) oe 7 ae” Biycoon pe ethananade aN Mihai Wide) Capeba docs Norton wth acckanlide gine mane rubst Gated pro oF Q. Nualuon wits walt oe : an ey nts tases (e) - @) . | Sk < ee ee cste) nett) ') |} osbincbse.com To gk menotubstinattd produc : NHCOCKs, ce ae rh oUt oe Que)ee, HNOs, W804) on Ht ait 28ek Acotwntlid te Coe Fi io niho anon Pe pulro acctanelade + + . oh oe 's nih NH tS RK aa ASHIK, ©) . see yee ; ic $044 oy, Sudpha L Frsi tter om wd Q aiding doer nik undergo Friedl crafts Athen «tab 2 see All the Best L-- +Preparation of Haloaeens Fon alcohel. D R-of + Hel ante, pac +H0 2) R—OM + NaBr + Hyso, ——> @-Br #Natisay +O 2BR-O + PX3——> 3R-x + Hy POs 4) R-0H +PCl, —> R—cl + Pocl, + HCl DROW HRels—>-R- red Pim, py 2 R-on + ene On Soc, —> Rel +50, +Hel Pouparation ef haloalkane from aleohol by using Thionye chlefde (© From hydrocostbens Free valical halogenalion cHycHach, cHy 6 S/o tO, crcn, ch cH + er hak cusens cles (© From Abkens Addition of hydogun bends - ee He —e [Aas FNOK eS ATS a Roch acy + Hx Neelam py cts & RCH cH, + H-Br 8 Powttde gen cer Cant! markovetKov's Addéifen of halogens Bw A Noa + By Ht, Breet er H7~ MH Vic -dibromfde. (@D Halogen Exchangp : D ForRalstiin ouectfon -(Poepanation of dodeatRans ) — | 2 Swords stadtion - ( Prepaxation of ALkyt | Fluondele) oo ee | oO NaNO, tHX Co inka gE ae Bangine. ditigentom atic Towlene, HALOALKANES & HALOARENES Replacement of the dia gonkomarp Pd aA does net ouquixe pre prusene: ef capsous habide and, of dame by Shosith ie dfagosium cat with potautum indie wie x “pel Kr of Ne e)Sotbility of halealkons Sr wate - why? ©) pera Loman af dfhabobengine have high matting pt compar do thd: ofthe and mata Byo mex. why ? 8) The beilfng pt of Brome haleatRanes ecwas Laken branching om? ©) Expat SW, Csubstitusfon nuctiophihe Biomelular) mechamin ©) Expuat ez +Nax —> H3c—-Br +AgF —> H3c—F +A98r chy S ns ony +a gee + | cHetotaulow ” p-Haloteulene| Reaction wit» mutads CHS cH Br + Mg dou ethan cits cH, Mg Br gitgnond ouagiet | Potepanatfin of hyde carbon from qrignonal | R-MgX + H20 —> RH + Mg (on) | | Weds ouacten | PRX FaNa dy et RoR + 2Nax Auiny Bok necmony do awet even dacs of meoritine rem gefgnard ocagent- 9) why aut halidis ane onbumily Las sunctive che words nuckophili subatthtion suactton Replacment of hydroxy group el on DNAoh 623K ,200atm SNgOnezakaes amet > A on DNaon 443% a Noa. cl on Nf. iy Natl) 365 & Ney we Mon nen et on "0, Ho, Ng os 2 Wewn 3 " a0 0s. ae Eludi phd Substitutfen suactfon ©) Halogen ctem en benzene shag 3 extho Porn Sucking a Compare to bengne Maloarnuus shows bas euuctivity fo wards Cldwophihe substitution otaction Helo ea Anhya Feds, at gy ty 4-dTedulorcben-| cMajen OsB a osbincbse.com * cy 1,2. = Dichlorsbenye coined WD) Nodbuckion el a HNO; NOs. one Haldy I= chloro 2 -nibrobengene CM Snes) Pe 4 chtorobengtre slplente add Cmajer>©) Fadedal crayt ouactfon al 4 el FCu3C| Annya Alls om - O 1 Gero -2 - Methyl te- cus oa chloro reny fav) vmidhal 1 1 = chloro =~ mathy! kensene. S 3 a major) CO Hye — el Arka Ally i cl cae cM cere 2 dhloroacitoprenore Caen) oes A> Chievo axtto phenome Major) Reaction utth metals Wud - Fitting suaction a z CY a ee Bate, (CTs wax F biting ouactfen a co ana Bey ether, ee DPphanyt ETHERS Paiponabion of ether :CHydlgdntin of alionet) Pouporalon of Aine | 3 e iat chance :on a cHscton — oO Naot —> cus Hs, ee +e iets bth sutonanee of antiel- eMichontem af pouponation of, ether by ddd °) Expiale se % ob alcoho Hatogunatfon ootts octs ons EMancie act bd Actiole iz me! + Cis Br —> a, P-romoanisele 9-Bremepaciele pibeari i major? Crainen) F SedidumotRovtds haloalRane Fetedd Graft atkytalion suactten ae fo Ochs gen fy do Ge + ASE —cay—s ewe prethsmmarscigel oo 1 cs +cngel MEE a 1° sodfumabkextde | sPheloatrane s-tienyeaiine 4. xen | CHtaor) cmaser)ocns ons cls cee + Chycoel MS cy fy Ethanoy! Ontos a-Mathoxy cach cuite phenome A> wshory Cui) dadaphenene (Mager) Nibuation cs oc oct He, Nos ror a a-Niroontsel ea Cate) A= Niboantiole Cran? Roo-R'+hx —> A-X + ROH ee All the Béshensj | Aldehyde, ketone, Carboxylic acid Prapavalum of ab dehyele md ketone | © ay oxidaten of abchol RcH,oH ——> RCHO (alcohol) . [eet RoCH> ik =e eee oH (ec alehe i @ By clehychogensian of aleehel cu RCHO R CHOH BK Ren oR: ce So ee | Bien au * OH ¢ | From hy clrocar bons '® by ozonolysis of athena 2 CH. CH StH, ¢ C3 — 7 cH, | (am cH, CHO+ HcHoc 224 Hee | @ cH He, ° c= cH, +977 ¢ cH, 7 | CH CH CSch 4 H- OH. ages HPht, cH. CCH 2 333K 3 ale ay aldehyde cua (oy Pol- fun [oy Bengog| eta, chine From nibules ond esters Cstephan's veacln] Ren + snel, tHe > Rc = w4-BS RCH Reachen by Dien L-H ROW fi Ron OMHE Bs ecHo © t,0 > what is Re Full form ob Dibni-H [Refer teat} orsz. S46) * Eslens are Healuceel aldehydes euith B1SALH ye CHC qe C— 0-GHs 3 CH | cH | HcHo + c=o eznthee] Chg © by ‘hydeakion of zlkynes CH=CH +H- OH ay & hy i l Odierno n,o a H| VY a He CHie c-H| Fa om hy clro Carb ond @use & choml cMoni de Letard neackon) i cHt@crondl,)) [oye cr0,cl Or chromium Gorn plex ‘ : Bemgaldelyde @ oo cH3 \) 4,679, +CH. 1,cO}O [Chremi? oxidi) > 473-283, Coyne Léengylidene a |r,o* diacetada) [Benga Idehydle) by hy obrolysis iy ouch, 8 Bengal Chess Cie or": Toulon. co, Hel 4 Mee cucl Preparation of Kélones © From Rey) chlorides aac + cdel, — RK, Cal + ang cxyel | ae a + Rca (di abky|Cadmiut | acy? chboni de —_ adc a +cdel, | | |O Fram nibs Led CEN +H, 15M 8" aNtigBe Che Hy eth P EH CH CH ~ Gu. ° Hot | He Gi —_! : | Ba By Side chaim ¢Morinalin fo owed Ho 2 0) ajak 65 Ci phony! ree © From benzene 9 Substi tied benzene A q [o) tv —C-I ; c Pinhyelrowd con adel; ~ tries 5 (0) te | Addehyoles and ketoney ane Soluble un eJaler. Tastity ? [Re Per noe boo k}the 6P of abdchyds and kalne arz higher ham hy dro Gx bons amd etters of Comparable molecular maifes | Refer note book) Aldelydls oe generally more qeeackive han kilos in nucleophilic acllilen reach - Sustily. CReber role) Reaction of bydaogen Gyamicle with kelma and abd ehycle Hen + on ===! cw + Ho : cw Sexo + me l= | — - Non Tetrahedlral Cy anohydain dntsrmesliate pddibims of Sodiam by clogen Selphile \ N ages frat \ seu = NaHso, == rans es How Ke above neachon elp im +e purifiahin ofp oH alle hy les pdsidin of alcohols eit alilehy de i Re " u ao» are “ fans R-cH +H,0 ety oT Ho ee Hemniace tol Acetal Reaction of ketone evith ety bons glycol RY cu, - OH Hed gas i po cz0 + | 4 . — chen Ala 7 \ | +H,0 R den, os tyler glycolAddit ch ammonia and its cerivatves 4 \ Ne . = —zZ ——!/c —» c= N-2z emeia AN = >, bg +H,0 iz —p abky! aryl on wy Co Hua | NHCONH, che Re ductim to alechol e-cHo +H, PL, eenjow / R-Co-p' Mable » p_ cue 1 on ec) i ‘ A emmensen's teclu cim, Wwelff kiskner reduction zn-Hy_ \ H cso STS ‘cy, tho} \ Wits Way No fe C= NN y ae ae a > eater: Z oe wt den Sel -oridaline a abd e bye R-~cuo £292 5 g-coon Oaidalon of ketones YS ee ca ! R~CH~ C-— CH.—-R ——*—> RCOOH + RCH, COOH ao 2 (ey cleavage 4 G =0, bonal) + , R-CH,cooh + RC OOH C6y cleavage of o-6, bod) Toullen's Test 2 R-CHO + Lng evn) + 30H —> RCO0” FAAGH+AH,O + ANH, Fe Along 5 Test R- CHO + ACU + 50H” —> RECO + Cu,0 + 3,0 (Real Brown pp E]aidan o Hetifl kelns =, Sab farm taackion i R= c—cH, NeO% 5 R-C— ona 4 CHK [xecl, 87,1) Reactin olue te o¢-H o @ ; Ul ' tu ue I ) > —o— com OH CH ce Abd cnlnsaion sel) bey ene See CH= CH CH -cho > is ty =Ike 8 a bys a CH,-CH= ChH-CHO natal) [Alldel cenclensalion ey Gross Alldol Gmden saben a MD CH CH= eH — CHO H G CHCHO + CHZCHACHO - ao~ cHe Clr CH -CH a 5 Sel# aldol produck -cH=c—CHo = CH, -CH= 04-1 CH,-CH iF CHO + CHg- CHy-CH= cH -che chy ae Cress Abele! Conolon scion Ganizar Readum " H H _ ) oF aot eo + ime kon “95 He coon + HH em < \ : “ , ok i H methano) peesOH Na | Conc . fear + : a Ee Se ane he a sent eer kibic Substhuten cdl Flectrop' NO, CHO Oe. HIN 03 /H2 8 te> a R73 -298k fe ritho bengal ehyele m= elo Bengal dely 258 osbincbse, com |CARBOXYLIC “ACIDS Re The rbonytie cadbon ik Wes dbuophiaie than coubenyt cauhen Explain Q.Buparition J carboxylic ads fom Primary abishele & oleh des @ aon alk KMade Mot an (ur) O04 pi teioe cn, (on,) coon as jones reas an B Decanie oud 5 L- Decanst : osbincbse.com tise.com | a Pru aration A eubonytie aude fem odkafl lenrunts oS Oo” "ety =, qj - = cor ae" aa) 7 Rot ¢ wou _Stindy, — kow > a S are aud ReooH, Benesie avid @ Pruponctuen from wabuls een Hi ovol” 5 gp 2 ny ——> Reon 0 . 82, cath + NHS 6 GH, CONH, Ethonele Ethanamide el YQ con, if cooH Cm Os g a 3 Benranamide bape 1Q Prap aration 4 carboxylic aide fom Srignand reag onl 2 Hao" tema-x + oFcso PM» poh — > Rewer ether +[Q-trom auyl habidn & anhydrides @, Geplin wager A phe a | “ fov eae aye acide Keook + / hn o lks, pend or AEE Ree |g. Caplin the higher avidly waborylic audi as comp anid ty prencly (G%e),0 BPs aqucort Benreic anhydride Benzeie avid ic onl Q. Gaplain the eat sf Ho v Gi toocoek, => GH C#OM + CH,C0OH Subceheanti on the Benreit Bars g ondazytic avid ee Benreie othaneic iia aa | 8 ee 8 Exslain the ek § QR thom elon Sudatitunt group on Bentsic H, o i: : Cr TY cayenne orkydede wv . ° englbentoate iBoade he ery atid Z 14 shot, a : Gy CH, O4.000 CH << om, wasn + atoH | le, 7 wtonate Ho ° ° Eyl but on ate AI ty wet fem Cehgcat co, WOH SNe Bukanaic oud Pitcanti« an hydride @- Carbonic andy ane wighe heey Urypwids than aldehy das, ketones | & erin alice 9] crmp anable mole ualan mart - Tat liby QRaadion wilh metals & alkalis 2k + ana ——> aRcronle + Hy Sodiaan Gaborsplati Reooh + nlaok ——» kwon F ML? Reon + Natco, —» Revdme + Mo tO,@: Catwifieation fi " 1 Rtook + Roy <== Rtook + H,° eit Q Methenim q buinficlon | Crboxglie. ouds Q: Reattion with Pus, PU, & 80d, Reooh + PU, ——5 Rout Pou, se RA BRcooH + PUL,—> BRO CL + Hy Po; | Reoon + Sou, —» Roou + Sot Hu QRroken with Mmmoma 4 GAvooH + NH, = Uy ONM, Sig tromenium oulan, LOH ag @ | oo Or = Oo =the” \A | Frnmoniu Benvarnide | benroate, A a0 cont, —S> Cont, or + ANH, — = ko Conta, coor Geri: Phital amide Derm arrasine | | — NH | phthalic Sheng | s ° tl Ce Plthodk nude Q. Redudon tiny Leiber or 4p chy of Reoon Hot Decanh on im alanis Cas a’ ony tok Rooona oe ee Na, Co,Q. Halo genakion Hall- velhond - ie veatkion Rot eno elt Phosphewout_y Rc - coo —> - caabanylic ad \ = bed (x su, br) Q Halagenadaon : Ring Aubstitetion wnt 4 coor cone: HNO Cl ner ne ¥ cone Hs50y, monitebenraic aid coor oot i a sb, SB Q O.. 580, | m- Brmdbenvie aud QBenrsic arid dou nok undye Fatedid - crate reacHon. Explain