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II PU Chem All District Preparatory QPs 2024
II PU Chem All District Preparatory QPs 2024
PREPARATORY EXAMINATION-2024
SUPER COLLECTION OF QUESTION PAPERS FOR
By :
MOBILE : 9738237960
CHEMISTRY
SUPER COLLECTION OF QUESTION PAPERS FOR
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chandu
ou=education,
email=chantalawar2006@g
mail.com, c=US
Date: 2024.02.21 18:13:50
+05'30'
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Instructions:
(i) The question paper has Five parts. All the parts are compulsory.
(ii) Part - A carries 20 marks. Each question carries one mark.
60
Part B carries 6 marks. Each question carries two marks.
79
Part -C carries 15 marks. Each question carries three marks.
Part - Dcarries 20 marks. Each question carries Five marks.
23
Part- E carries 9 marks. Each question carries three marks.
38
(iii) In part - Aquestions, first attempted answer will be considered for awarding marks.
97
(iv) Write necessary balanced chemical equations and draw neat labeled diagrams and graphs.
ct
(v) Direct answers to the numerical problems willnot be considered without writing detailed steps and
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scientific units for find answer will not carry any marks.
on
(vi) Use log tables and simple calculator if necessary. (use of scientific calculator is not allowed)
C
PART - A
(c) Cu is oxidized to Cu
A
3. During the electrolysis of molten NaClusing platinum electrodes the products liberated at a anode and
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60
10. Which of the following will not give aldol condednsation?
79
(a) acetaldehyde
(b) phenyl acetaldehyde
23
(c) benzaldehyde (d) 2-methyl pentanal
38
11. Sodium salts of carboxylic acids are converted into hydrocarbons by
97
(a) Dehydrogenation (b) decarboxylation
ct
(c) dehydration (d) dehalogenation
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12. Methyl amine is a stronger base than aniline due to
on
(a) -Ieffect (b) + Ieffect (c) + Reffect (d) Reffect
C
13. The amine which cannot be prepared by Gabriel pthalimide synthesis is
(a) methanamine (b) ethanamine (c) aniline I: (d) propanamine
TT
14. Glucose on oxidation with nitric acid gives
A
D
(a) saccharic acid (b) gluconic acid (c) glyceraldehyde (d) n-hexane
VA
II. Fill inthe blanks by choosing the appropriate word from those given in the brackets:
O
PART -B
B
III. Answer any Three of the following. Each question carries two marks. 3x 2 =6
B
A
21. Write any two differences between ideal and non-deal solutions.
K
26. What are non-essential amino acids? Name naturally occurring a-aminoacid. Which is not optically
active.
60
) |Co(NH, ), Br lso, () [Co(NH, ), SO, JBr
79
23
31. On the basis of VBT. Explain hybridization geometry and magnetic property of Ni(CN),
38
97
32. Explain crystal field splitting in octahedral complexes using energy level diagram.
2x3=6
V. Answer any TWO of the following. Each question carries Three marks.
ct
33. State Henry's law, write its Mathematical forn. How does Henry's constant varies with the solubility?
ta
on
34. Explain the construction and working of standard hydrogen electrode with neat labeled diagram.
C
35. (a) Define limiting molar conductance.
I:
(b) Write the equations for the reactions taking place at anode and cathode for lead storage battery.
TT
36. Derive integrated rate equation for zero order reaction.
A
PART - D
D
4x5= 20
VA
VI. Answer any FOUR of the following. Each question carries five marks.
37. (a) Explain SN2 mechanism with an example.
SA
(3 +2)
() aqueous KOH (ii) alcoholic KCN
N
O
H,SO,B
A
413K
C
A+H,C,H,OH
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B
H,so4
443 K
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the products.
(b) Write equation of the following reaction and mention
R
(3 + 2)
Friedel -Craft's acetylation of anisole.
U
process.
B
(3 +2)
(i)Phenol to 2, 4,6 trinitrophenol. (ii) Phenol to benzene.
K
benzaldehyde.
40. (a) Explain Cannizzaro 's reaction for
compound.
(b) Give the mechanism for the addition of HCN to carbonyl
and ketones. (2+2+ 1)
(c) Mention a test to distinguish between aldehydes acid.
(dry ice) followed b acid hydrolysis gives ethanoic
41. (a) A Grignard reagent X' reacts with CO,compound X'.
Write the chemical equation name the
(3 + 2)
example.
(b) Explain HVZ reaction with
with an example.
42. (a) Explain carbylamines reaction
reaction with an example.
(b) Explain Hoffmann's bromanide (2 + 2+ 1)
(c) Give the IUPACname of C,H,NHCH,.
of
43. (a) What are the hydrolysis products
(i) Sucrose (ii) Lactose
(b) Define
60
(i) Denaturation of protein.
79
(i)Peptide linkage
23
(2 +2+ 1)
(c) Give an example for water soluble vitamin.
38
PART -E
97
3 x 3 =9
carries three marks.
VII. Answer any three of the following. Each question
ct
protein. The osmoticpressure of such
44. 800 cm' of an aqueous solution of protein contains 2.12 g of the mass of protein. (R = 0.0823 L
ta
molar
a solution at 300 K is found to be 3.89 × 10 bar. Calculate
on
barmol K-).
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temperature is 0.850 bar. When a non-volatiBe, non
45. The vapour pressure of pure benzene at a certain grams). Vapour
I:
electrolyte solid weighing 0.5 grams is added to 39 granms of benzene
TT (Molar mass 78
substance?
of the solution is 0.845 bar. What is the molar mass of the solid
A
46. Calculate the emf of the cell in which the following reaction takes place.
D
47. 1M solution of a salt surrounding two platinum electrodes 2.1 cm apart and 4.2 cm in area was found
S
48. Rate constant of areaction at 300 Kand 400K are 0.0345 s and 0.1365 s respectively. Calculate
TI
the activation energy for the reaction. (Given R= 8.314 JK' molr)
A
49. Afirst order reaction has a rate constant l.15 x 10 s. How long will 5 g of this reactant take to
C
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reduce to 3g?
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60
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60
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60
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60
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A
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60
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A
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PU
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60
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A
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A
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60
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A
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A
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60
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A
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60
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PU
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60
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A
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PU
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60
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ct
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PU
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60
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A
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PU
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60
79
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97
ct
ta
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TT
A
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A
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PU
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60
79
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97
ct
ta
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C
I:
TT
A
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SA
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N
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TI
A
C
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B
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R
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B
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60
79
23
38
97
ct
ta
on
C
I:
TT
A
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VA
SA
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N
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TI
A
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B
PU
R
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B
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60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
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N
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TI
A
C
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B
PU
R
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B
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A
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60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
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A
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60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
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N
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TI
A
C
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B
PU
R
U
B
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A
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60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
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B
PU
R
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B
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A
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60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
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B
PU
R
U
B
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A
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60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
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B
PU
R
U
B
B
A
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60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
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60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
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A
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60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
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B
PU
R
U
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B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
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A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
C
I:
TT
A
D
VA
SA
S
N
O
TI
A
C
LI
B
PU
R
U
B
B
A
K
60
79
23
38
97
ct
ta
on
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I:
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A
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VA
SA
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N
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TI
A
C
LI
B
PU
R
U
B
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A
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d. Part-D carries 20 marks. Each question carries 5 marks.
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e. Part-E carries 09 marks. Each question carries 3 marks.
23
3. In Part- A questions,first attempted answerwill be considered for awarding marks.
38
4. Write balanced chemical equations and draw neat labeled diagrams and graphswherever necessary.
97
5. Direct answers to the numerical problems without detailed stepsand specific unit for final answer will
ct
not carry any marks.
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6. Use log tables and simple calculator if necessary (use of scientific calculator is not allowed).
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PART - A
C
I. Select the correct option from the given choices.
I: 1 ×15 = 15
TT
1. Aquatic species are more comfortable in cold water rather than in warm water. This is due to
A
60
c) ammonium nitrate solution d) silver chloride solution
79
11. Carboxylic acids exists in dimeric form even in vapour phase due to
23
a) Hydrogen bond b) peptide bond c) ionic bond d) metallic bond
38
12. The state of hybridization of orbitals of Nitrogen atom in amines is;
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a) sp2 b) sp3 c) sp d) dsp2
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13.Benzene diazonium chloride reacts with phenol to form p-hydroxy azobenzene in
on
a) acidic medium b) neutral medium
C
c) basic medium d) both acidic and neutral medium
I:
14. Thiamine is a chemical name of;
TT
II. Fill in the blanks by choosing the appropriate word from those given in the brackets:
S
17. The number of molecules taking part in the elementary reaction is called _______.
A
C
19. The poisonous gas formed when chloroform is exposed to air and lightis ________.
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PART - B
U
B
III. Answer any three of the following. Each question carries two marks. 3 × 2 = 06
B
A
21. How does theboiling point of solvent varies, when a non-volatile solute is dissolved in it? Give reason.
K
22. Define order of a reaction. For which order reaction the unit of rate of reaction and rate constant is same?
23. What are chelate ligands? Give an example.
24. Write the general equation for Finkelstein reaction. What is the role of dry acetone in this reaction?
60
79
32. Drawthe energy level diagram for the crystal field splitting in tetrahedral complexes. Write the relation
between Δ0 and Δt for the complexes having same metal, the same ligand and metal-ligand distances.
23
38
V. Answer any two of the following. Each question carries three marks. 2 × 3 = 06
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33. Write any three differences between ideal and non-ideal solutions.
ct
34. State Kohlrausch’s law of independent migration of ions. Mention two applications of it.
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35. Explain the experimental determination of conductance of electrolytic solution by using Wheatstone
on
bridge.
C
36. Derive integrated rate equation forfirst order gas phase reaction.I:
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PART - D
A
VI. Answer any four of the following. Each question carries five marks. 4 × 5 = 20
D
b. Define stereocenter? How many asymmetric carbon atoms are there in 2, 3-dichlorobutane?(3+2)
O
39. a. An aromatic hydrocarbon ‘A’ having molecular formula C9H12 is oxidised in the presence of air gives
B
compound ‘B’. The compound ‘B’ is treated with dilute acid gives two organic compounds ‘C’ and
A
K
‘D’. The compound ‘C’ forms white precipitate ‘E’ with bromine water. Write the chemical reactions
with names of A, B, C and E.
b. Give an example for unsymmetrical (mixed) ether. (4+1)
40. a. Write the chemical equation for the reaction whenbenzaldehyde is slightly heated with acetophenone
in the presence of dilute alkali. Give the IUPAC name of the product.
b. Explain Rosenmund reduction with an example.
c. Alpha (α) -Hydrogens of aldehydes and ketones are acidic. Give reason. (2+2+1)
60
b. What is Zwitter ion of an amino acid? Give its general structure.
79
c. Name the hormone responsible for the hypothyroidism? (2+2+1)
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PART – E (PROBLEMS)
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VII. Answerany three of the following. Each question carries three marks. 3 × 3 = 09
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44. 100 g of liquid ‘A’ (molar mass 140 gmol-1)was dissolved in 1000 g of liquid ‘B’ (molar mass 180 gmol-
ct
1
).The vapour pressure of liquid ‘B’ was found to be 500 torr. Calculate the vapour pressure of pure
ta
liquid ‘A’ if the total vapor pressure of the solution is 475 torr.
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45. The boiling point of benzene is 353.23K. When 1.8g of non-volatile solute was dissolved in 90g of
C
benzene, the boiling point is raised to 354.11K. Calculate the molar mass of the solute. (Given K b for
I:
benzene is 2.53Kkgmol–1).
TT
46. At 298K, the EMF of the cell: Mg(s) |Mg2+(Q)||Ag+(0.01)|Ag(s)is 3.022V. Calculate the value ‘Q’.
A
D
47. The resistance of 0.01M acetic acid solution is found to be 2220Ω, when measured in a cellhas two
SA
48. For a first order reaction, the half-life period is 120 min. Calculate the time required to complete 90% of
N
the reaction.
O
49. The rate constants of a reaction are 2 × 10-2s1 at 300K and 8 × 10-2 s1 at 320 K. Calculate the energy of
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A
Marks
Chapter/ Content
VSA VSA VSA VSA SA
domain/ Unit/ SA (02 SA (03 SA (02 SA (03 SA (02 SA (03 SA (03
(01Ma LA (01 LA (01 LA (01 (02 LA
Theme Marks) Marks) Marks) Marks) Marks) Marks) Marks)
rk) Mark) Mark) Mark) Marks)
6 0
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Physical Chemistry
213(NP)
Solutions 14 13 1 - 1 (T) - - - - - 1 1 - - - 1 (NP) -
Electrochemistry 14 14 1 - 1 (T) - - - 1 (T) - - - 38 - - 1 - 2 (NP) -
Chemical Kinetics 14 13 1 - 1 (T) - 1 1 - - - 9-7 1 (NP) - - - 1 (NP) -
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Inorganic Chemistry
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The d & f - Block
12 11 1 - 1 - - - 1 - - 1 - 1 - - -
Elements
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I :-
Coordination
12 12 - - 2 - 1 1 1 - - - - - - - -
Compounds
Organic Chemistry TT
A
Haloalkanes and
10 09 1 - - - 1 - D - 1 - 1 - - - - - -
V- A
Haloarenes
Alcohols, Phenols
SA
12 12 1 - - 1 1 - 1 - - - - - - - -
and Ethers
Aldehydes, Ketones
14 14 1 1 - 1 S
and Carboxylic Acids N1 - - - - - - 1 - - - -
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Amines 08 08 1 - -
T- I 1 - - 1 - - - - 1 - - -
Biomolecules 10 09 1 1 - A1 1 - - - - - - - - - -
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Total Teaching 09 04 LI
18 15 07 04 09 15 01 04 09 05 03 00 12 00
Hours & Marks
120 115 B
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46 35 19 15
Total Questions 49 09 02 06 03 07 02 03 03 01 02 03 01 03 00 04 00
R
U
1. Weightage = Total marks/Number of teaching hours = 115/120 = 0.96 (i.e., 0.96marks for each hour)
B
2. Choice = out of 49 Questions only 35 Questions are to be answered.
Note: T = Theory; B
NP = Numerical Problems; VSA = Very Short Answer (MCQ’s and Fill in the Blanks); SA= Short Answer; LA = Long Answer
A
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Collection Of Question Papers For POCKET MARKS 70/70
GENERAL GUIDE LINES:
1. Questions should not be vague and ambiguous. Answers should be availablein the prescribed NCERT text book or based on the contents in the
prescribed text book. 60
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2. Intermixing of questions of different units is not allowed. 5 marks question may be framed as (3+2) as far as possible.
23
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3. Avoid questions from:
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a. Drawings involving 3D diagrams
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b. The boxed materials with deep yellow bar in the text book are to bring additional life to the topic and are non-evaluative.
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4. Questions on numerical data given in the form of appendix, numbered tables containing experimental data and life history of scientists given in the
chapters should be avoided.
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C
5. Frame the questions in such a way to strictly avoid ½ mark evaluation (or avoid value points for ½ marks.).
I:
6. While framing Physical chemistry units (Unit 1, 2 & 3) questions for Part -A, B and C should not be Numerical problems. The Numerical Problems of
TT
these Units should be framed only in Part-E. This division is done to make for the students to learn and attempt to solve the Numerical Problems.
A
D
7. Application and HOTS (Higher Order Thinking Skills) questions can be selected from any chapter without changing the weightage of the chapter.
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