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GI-1

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CORROSION AND CATHODIC PROTECTION Reducing the current density may be accomplished
IN UNDERGROUND PIPING SYSTEMS by reducing the corrosion current. In cathodic
protection systems, a minimum amount of current
INTRODUCTION must be maintained. However, in unprotected or
As restrained pipeline systems become increasingly coated systems, the current produced should be kept
popular, more questions concerning corrosion of to a minimum. This is accomplished by the difference
restrained joints are being asked. This paper is an in potential of the metal components. For example,
attempt to address some of these questions, provide a EBAA Iron’s set screws, MEGALUG® wedges, and
basic understanding of galvanic corrosion, and glands are all made of ductile iron. Because EBAA’s
suggest methods for controlling corrosion. products are made completely of the same metal as
the pipe and the fittings, the effects of corrosion are
THE GALVANIC CELL greatly reduced. Choosing materials which are close
The major corrosion concern in the water works to each other in a galvanic series will reduce the
industry is “galvanic” corrosion. Galvanic corrosion difference in potential. A galvanic series is defined
takes place due to current flow in a “galvanic cell” by the National Association of Corrosion Engineer’s
which is defined as (1) two dissimilar metals, an as: “A list of metals arranged according to their
anode and a cathode, (2) in electrical contact with relative corrosion potentials in some specific
each other and (3) a common electrolyte. A galvanic environment; sea water is often used.”
cell is produced when the pipeline components come
in contact with the soil. In such a cell, one of the Another way to reduce the current density is to
metals, the anode, corrodes away and the other metal, increase the area of the anode with respect to the
the cathode, is protected. The rate of the corrosion is cathode. For this reason, T-bolts in a pipeline should
dependent on the current and the current density, be slightly cathodic to the rest of the system. If the T-
which are functions of galvanic potential difference. bolts were anodic to the pipeline system, they would
corrode at a very rapid rate since the area of the
However, most useful metals are alloys created by anode, the bolts, would be very small in comparison
combining elements with different galvanic to the cathode, the pipeline. By the same principle,
potentials. Alloys alone meet the first two the sacrificial anodes should be sufficiently large.
requirements for a galvanic cell; which is why a
single metal will corrode when exposed to an The practice of using Cor-Ten bolts with follower
electrolyte. Therefore, most corrosion control glands for mechanical joints is an example of slightly
methods attempt to separate the metal from an cathodic bolts being used. Cor-Ten bolts are slightly
electrolyte or to control the corrosion current. This cathodic to ductile iron in most cases. This choice
paper will deal mainly with controlling the corrosion reduces the current density in the anode both possible
current. ways. Since in most cases Cor-ten is only slightly
cathodic, the potential difference is small which
MATERIAL CHOICE keeps the amount of produced current small. Also by
The simplest method for controlling the corrosion making the bolts cathodic, the pipe and the gland are
current is the selection of the structural materials. In anodic. Since the pipe and the gland have a much
the water works industry, the selection of the pipeline larger area than the bolts, the current density in the
and appurtenance materials is very important in anode is small compared to the cathode.
preventing a corrosion related failure.
Sometimes, stainless steel T-bolts are used in
The rate of corrosion and the current density, the pipeline joints. This would seem to be a practical
amount of current per unit area, are proportional. solution to corrosion and in fact, the bolts do not
Therefore if the current density in the corroding corrode in most environments. However, in studies
metal, the anode, is reduced, the rate of corrosion will by the Cast-Iron Pipe Research Association in which
be reduced. The current density can be reduced in stainless steel bolts were used, the areas of contact
two ways: reduce the current flow or increase the between the bolts and the glands were severely
area of the anode with respect to the cathode. corroded. This was due to the great difference in
galvanic potential between stainless steel and iron.
SACRIFICIAL ANODES effective corrosion protection, the system must be
In a corrosion cell, current flows from the anode carefully maintained. It is important that the current
through the electrolyte to the cathode. Cathodic and the anodes are continually monitored for both the
protection methods attempt to control the direction of impressed current and the sacrificial anode systems.
the corrosion current. One such method is the use of a Cost is another factor one must consider when using
sacrificial anode. A sacrificial anode is an anode a cathodic protection system. In both the
electrically connected to the system to be protected. aforementioned methods, the anodes will require
The sacrificial anode will corrode and therefore, the replacement at some period of time. The current must
cathodic system will be protected. The basic idea is be maintained in an impressed current system. The
to force certain parts to be cathodic or anodic with equipment needed to maintain these methods must be
respect to the other in order to control the current considered. Also, the soil must be tested in order to
direction. If a sacrificial anode is chosen that is determine the amount of current needed to provide
anodic to every metal in the pipeline system, the optimum corrosion protection.
anode will corrode while the pipeline is protected.
OTHER CONSIDERATIONS
A prime example of a sacrificial system is the use of Several factors should be carefully considered during
magnesium anodes in connection with the pipeline the design of a corrosion control system. One such
system. The magnesium is buried in the ground consideration is the environment. For a pipeline, the
within the same electrolyte as the pipeline. The environment would consist of the soil and anything in
pipeline and the anode are electrically connected, and the soil such as other pipelines, buried cable,
as the magnesium corrodes, the pipeline is protected. minerals, and water. Be aware of other current
sources. A stray current source can affect the amount
The magnesium should be alloyed to prevents passive of protection a corrosion control system can provide.
layering. A passive layer is an oxide film that forms In an unprotected system, stray currents can increase
naturally on the surface of most metals. This passive the rate of corrosion. Economic and life requirements
layer becomes a protective coating on an anode and are two more things to be considered. Usually,
prevents further corrosion. If the sacrificial anode pipelines are designed to last many years, so enough
does not corrode, the protection current is not corrosion protection should be provided to insure the
produced. If this happens, the pipeline will begin to pipe and its components will last. Also, keep in mind
corrode. the pipeline material to be used, including special
coatings or polyethylene wrap. The effects of
IMPRESSED CURRENT SYSTEMS polyethylene wrap and coatings are discussed in
Another form of cathodic protection is an impressed Connections™ bulletin GI-3. Whichever method you
current system. In this system, an external source, not choose, the corrosion protection system should be
the galvanic reaction, forces the direction of the economically justified.
current. The positive terminal from a power is
connected to the anode and the negative terminal is SUMMARY
connected to the cathode. The pipeline is connected Galvanic corrosion continues to be a major concern
to the negative terminal and consequently becomes in the water works field. Therefore material choice,
cathodic. It is very important that the positive such as EBAA Iron’s all ductile iron joint restraint,
terminal be connected to the ground bed anodes, the becomes important. Also since the environment
material to be corroded. If the positive terminal is changes from job to job, a corrosion control system
connected to the pipeline, the pipeline will become must be designed for each individual situation. Each
anodic and corrode. Several different current sources corrosion control met hold should be considered
are available for use in impressed current systems. carefully based on the soil type and other important
Batteries, DC engine-generators, and thermo-electric factors.
generators all provide direct current. Alternating
current sources such as a power line may be used if a REFERENCE LIST
AWWA Manual M27; External Corrosion- Introduction to
rectifier is used to convert the current to direct Chemistry and Control, 1st . ed., American Water Works
current. Alternating current will not provide any Association, Denver, CO, 1987.
protection since the pipeline would be anodic or “Corrosion in Underground Restrained Piping Systems,” EBAA
cathodic depending on the direction of the current. Iron Inc. Technical Bulletin.
NACE, NACE Basic Corrosion Course, 11th Printing, National
Association of Corrosion Engineers, Houston, TX, 1980.
The biggest advantage in cathodic protection systems
is its effectiveness. However, in order to provide
EBAA IRON – Your Connection to the Future.™ GI-1
9-93

This is one of a series of CONNECTIONS reports addressing design and application subjects. If you would like copies of
other reports or a listing of available reports contact your EBAA Iron representative or call EBAA Iron Sales at (800) 433-
1716 or fax (254) 629-8931. EBAA’s engineering group can be reached at (800) 633-9190 or fax (254) 629-2079.

Copyright © 1994 EBAA IRON SALES, INC.


P.O. Box 857, Eastland, Texas 76448 USA PHONE: (254) 629-1731
CALL TOLL FREE: 800-433-1716 TELEFAX: (254) 629-8931
contact@ebaa.com http://www.ebaa.com

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