24 26 27 29 Weite the mame of the reaction and IUPAC name of the product a), Phenol reacts with chloroform in the presence of sodium hydroxide b) Methyl chloride reacts with sodium ethoxide. ©) Phenoxide ion reacts with carbon dioxide An organic compoutid A with indlecular foriula CsH)0> is reduced to a-pénitahe on treatment with ZWHg and HCl, *A? forms a dioxime with hydroxylamine and gives a 00% iodo form test and Tollen’s test Identify the compuund A (write the IUPAC name) and deduce its structure, Answer any three of the following a) Deseribe Glyeosidic Linkage with one example bb), Deseribe Peptide linkage with one example ¢) Describe Phosphodiester linkage with one example dd) What happens when glucose is reacting with Bromine water(write the structure and name of the product) Answer any three of the following a) Convert | bromopropune to 2-bromopropane b) Aniline to phenyl isocyanide ©), Methyl bromide to propan-2-01 d) Alkyl halides, though polar, are immiscible with water. Give reason. 4) Derive an expression for halflife period ofa first order reaction, b) A reaction is 50% complete in 2 hours and'75% complete ind hours. Whatis the order of the reaction? SECTION D The following questions are case-based questions, Each question leas un internal choice and carries 4 (14142) marks euch. Read the passage carefully and answer the questions that fallow. FOR WEAK FIELD (octahedral) @ | configuration Unplired electron | CFSE ia tig 1 4Dg [ot =12Dq i} {a* Hite’ 60g, a __[hetee ~aNgiP For octahedral complexes the energy differcnog Between We and eg is referred as crystal field splitting energy, If CFSE value is larger than the energy required for pairing low spin complexes or spin paired! complexes are formed, LF CFSE value is lesser than Pairing enétgy (P) High spin or spin free complexes are formed, For a given metal ion P is constant. Thus the amount of crystal field splitting is determined by the strength of the ligand field. Tresence of strong field ligands eauses the formation of iow spin complexes and if the ligand field strength is weak, electrons oocupy eg level and thus high spin complexes are produced. When ihe CFSE values are high, electcons absorb more eneryy from visible light and emit the complementary colours of larger wavelensth, 3The following questions are long answer GP€ and carry $ marks each, Two questions have an internal choice. 4) Potassium dichromate ean be prepared fron chromite ore, Givea brief explanation of this 3 uM method. py Name the product(s) firnved when linthandlds are heated! with No? 1 ‘© The size OF the trivalent cations of the lanthaoid series decreases steadily as the atomic number incteases, What is this known 18? 1 GF Or a) Cue ion is mbt stable in aqueous solution. Give reason i ) Calewtate the spin-onty magnetic momen: Value for Ka[MaCly) i {At Noof Mn is 25] «) Why isthe highest oxidation state of a ntl eabibited in its oxide or flupride- only? 1 @) 2n,Cd and Hg are soft and have low me'ting points:compared te other’@ block elements 1 of respective transition series. Give reasot ¢) Name a member of the lanthanoid series Whieh is well known to-exhibit+4 oxidation 1 2 ® placed in 0.9% sodium chlordesolution, will you be able to abserve osmosis? 1 Give reason ) What are azeotropes? Explain with an example. 2 | © A solution containing 30g urea(mola: 738% 6Og/mol) per litte of solution tm water has | the same osmotic pressure 2s a solution ofiglucose(molar mass=180gmol)in water 3 Calculate the mass of glucose present in aRe litre of its solution. Or Or | a) Henry's constant for Oz.and Nz at 303K ae 46.82bar and 88. 84bar respectively. Which 1 | is more soluble at 303K? | b) Explain the positive deviation from Reoulfs Jaw with the help of graphical representation. y 2 ©) 1.00g of a non-slecttolyte solute disso! vellin 50g of benzene lowered the freczing point | of benzene by 040K Find the molar messighthe sobute 2 (Kf for benzene=5.12 Kkgmo!” ) i) Gabriel Phthalimide Synthesis ii)Hofmann bromamide reaction b) With a chemical test, how can you <:-cumguish ‘between (CHING, (CH3):NH, (CH3 » ¢) Convert! 1 (@)Aniline to 2.4,6-Trinitro aniline (i Aniline to p-Bromoaniline | 33 a) Write chemieaf equations for 2 Or 1 Answer the following or 1 1 fa) CHsNH2(CHs):NHACH):N.HCOOH( deoreasing order of boiling point) 6) CHNH>(CHs):NH(CHs)sN.NH) «!i compounds in gaseous staetincreasing endet of Ky values) ©) Aniline, Ethanamine, p-nitro anilin p-Atiisidine ( decreasing order of Kb values) 3 4) Convert nitrobenzene to benzamid i ¢) Convert ethanamine fo N-Ftbyl ethonamide 1 o seegeseesanessenes es10 u 12 13 Reactivity order of halides for debiydrohalogenation is a) RF RCL> RBE> RT b) R-[> R-Br > RCL> R-F co) Rel >RCI> R-Br> RF d) RR > R-I> R-Br > RCI Which of the following oxidation states is the most common among the lanthunoids? a) 4 b2 eS dy3 When initial concentration of the reactant is doubled, the halflife period of a zero order a) Is halved ) is doubted c)is tripled Wd) remuins unchanged Aniline ina set 6f reactions yielded a product X Aniline (treated with NaNOwFICl) — A(treated with CuCN) — Bitreated with Ha/Ni) > C(treated with HNO) xX The structure of the product X would be a) CcHsNHOH ‘b)CcHSNHCH3CHs — c)CsHSCH:NH2 = dCsHsCH20H1 What is formed when a primary alcohol tincer20es catalytic dehydrogenation? a) Aldehyde b) ketone oyalkene @) alkane During the kinetic stady of the reaction, 2A + B= +D, following results were obtained: Run [Al/imolL* | (Biinot* Thidal rate of formation | | of D/molL'min'* i 1 Of G0x 10" T 03 | a 72% 10" | i 03 of AR x IO | W 04 | oF 2.40 x 10> | Based on the above data which one of the following is correct? a) Rate -K{AP(B) bh) Rate =k[A [BP b) Rate =K{ANB] @) Rate =K{AIB] The compound which does not react with sodiumvis a) CH:COOH b)CHsCH(OH)CH, ey GsHsOH —_d) CHsOCHs Which one of the following has most acidic character? a) MnQ b) MnsOx cy MnOa @) Mm0> Question number 13 to 16 are two statements Labelled as Assertion (A) and Reason (R).choose the correct options given below a. Both A and R are true and Ris the correct explanation of A b. Both A and R are true but R is not the corregt explanation of A. ¢, Ais true but R is false. d, A is false but R is true Assertion(A) :p-nitro phenol is a stronger aoig than @-mitro pheol Reason(R): Intra molecular hydrogen bonding makes oMho-isomer weaker than para-isomer, 1FOR STRONG FIELD(etatiedral) | conteenratte Tnpuired electron | CFSE a [ee = Da (2 _ tee (apy i ee 7: ac: 0 2aDpSP (i) Atomic number of Co is 27. Calculate the CFSE value of the complex Ks (Co(CN).] with the help of the given table, i) The ligand present in a homoleptic oetaliedral coordination compound is Bromido, The central metal ion present is Cr*,caloulate the number of unpaired electron(s) and the CFSE value, with the help of table given above. [Atomic number of Cr is 24] (iii) a) In the above/table in case of d® configuration for weak field, one P is added with -4Dq where as for steong field with 24Dq SP is added. Give reason for the change in the value of P in eithet cases, b) A coordination complex is blue in colour. Comment on the CFSE value of this complex compared to a Red coloured coordination complex. values for various ions are given in the table reaction. | Std reduction potential (E° value in \ Vals) [Fg t 22 E: 287 [92 aD de dEO ie | za" eH) O76 [Ke oK@) [Bs a 0) aes I e+Ag(@tl [iz When two half cells that differs in their? valnes are coupled, Redox reaction takes place and the energy released can be direetly used 19 p known as electrochemical cells. lons with mote ne: of less negative electrode potentials, Charge of one mole electrons is kirow a one Faraday( app.96500C) Eleetroplating isan application of clectrolysis where ictal fs deposited over another metal. 11) Inthe given table ddentify the strongest Oxicising agent and strongest reducing agent >p) Caleulate the amount of charge required to deposit 2mol Zine from zine chloride solution. roduce electrical energy. Such cells are c) why electrolysis of Nal gives fe Where aSNaF gives Oz insteall of Fs (ive reduction potentials ean reduce ions:[ PBISCHEM KENDRIYA VIDYALAYA SANGATHAN ERNAKULAM REGION PRE BOARD EXAMINATION ‘Max Marks- 70 Hrs CLASS-XIL CHEMISTRY (043) General Instructions: Read the following instructions carefully a) There are 33 questions in this question peper with internal choice, b) SECTION A consists of 16 multiple-choice questions earryitig '! mark exch. c) SECTION B consists:of 5 very short answer questions carrying 2 marks each. ) SECTION C consists of 7 short answer questions carrying 3 marks each. ce) SECTION D-eonsists of 2 case-based questions carrying 4 marks cach. f) SECTION E consists of 3 long answer questions carrying 5 marks each. g) All questions ate compulsory. h) Use of log tables and calculators is nbt allowed SECTION A The following questions are multiple-choice questions with one correct answer. Each question carries I mark. There is no internal choice in this section, 1 Molar conductance of Ba** and Cl’ ions are 127 and76 ohm’ teni*mol” respectively: The 1 molar conduetance of BaC at infinite dilution is a) 1395 b) 1015 ©) 203 4279 2 Anacy! halide is formed when PCls reacts with an 1 a) Carboxylic acid b) amide ‘galeohol ester 3 Which of the fallowing is nota fat soluble vitersin 1 a) VitaminD ——_-8YVitamin Beomplex c) Vitamin Ad) Vitamin E 4 t H gas, Latm Pd/c,ethanol ‘The correct structure of the product A is o oH co Se 4 } } }