TAREA 3 TERMOQUÍMICA AMBIENTAL

a)
m x = 100 kg + m8
m3= 0.3*mx
m2 = 0.7*mx
m5 = m2*0.6 = (0.7*mx)*0.6 = 0.42 mx

C6H14O2N + 2O 2 -> NH4 + OH- + CO2 + C5H7O2N + H2O

1 𝑚𝑜𝑙 C6H14O2N 18 𝑔 𝐻20

0.42 mx C6H14O2N ( ) *( ) = 0.0572 mx H2O
132 𝑔 1 𝑚𝑜𝑙 𝐶6𝐻14𝑂2𝑁

m 6 = 0.0572 mx H2O
m9 = 0.0572 mx H2O + 0.3*mx = 0.3572 mx
m8 = 0.15*m9 = 0.15* 0.3572mx = 0.05358 mx

mx = 100 kg + 0.05358 mx
mx = 105.66 kg

b) CH4 + 2 O2 -> CO2 + 2H2O

105.66 kg * 0,7 * 0,4 biogas * 0,5 = 14.8 kg

50% CH4
14.8 kg biogas ( 100
) = 7.4 kg CH4
1 𝑘𝑚𝑜𝑙 CH4 1 𝑘𝑚𝑜𝑙 CO2 44 𝑘𝑔 CO2
7.4 kg CH4 ( 16 𝑘𝑔 𝐶𝐻4 ) *(1 𝑘𝑚𝑜𝑙 𝐶𝐻4)*( 1 𝑘𝑚𝑜𝑙 𝐶𝑂2)= 20.35 kg CO2
c) Masa molar C6H14O2N
𝑔
C = 12.01 𝑚𝑜𝑙
𝑔
H=1
𝑚𝑜𝑙
𝑔
O = 16 𝑚𝑜𝑙
𝑔
N = 14.01 𝑚𝑜𝑙
𝑔 𝑔 𝑔 𝑔 𝑔
C6H14O2N = (6* 12.01 𝑚𝑜𝑙) + (14* 1 𝑚𝑜𝑙) + (2* 16 𝑚𝑜𝑙) + 14.01 𝑚𝑜𝑙= 132.07 𝑚𝑜𝑙

Moles de C6H14O2N en 100 kg

1 mol C6H14O2N
10000 g ( 132.07 g
) = 757.174 mol C6H14O2N

Se necesita 1 mol de O2 por mol de C6H14O2N, es decir, se necesitan 757.174 moles de O2.

20 % de exceso

O2 requerido = 757.174 mol * 0.20 = 151.435 mol O2

32𝑔
151.435 mol O2 ( 1 𝑚𝑜𝑙 𝑂2)= 4845.92 g
1 𝑘𝑔
4845.92 g (1000 𝑔) = 4.85 kg O2

d)

zm = 0.40
𝑎𝑡𝑚 ∗ 𝐿
0.4 ∗ 184.3 𝐾 ∗ 0.082
𝑣= 𝑚𝑜𝑙 ∗ 𝐾 = 0.131 𝐿
46.02 𝑎𝑡𝑚 𝑚𝑜𝑙