General Chemistry 1 Final Exam Spring, 2014 (1/2)

감독자인
계열/학부/학과: 학번: 고유번호: 성명:
수업요일 및 담당교수명: ( , )요일 ( )교수 자필서명:

H He <주의 사항>
Li Be B C N O F Ne 1. 답은 지정된 자리에 반드시 영문(English)으로 기입할 것.
Na Mg Al Si P S Cl Ar 2. 시험 시간은 60분임. 400점 만점 (full score = 400 pt).
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 3. 문제지는 1장(2면)임. 연습지 및 영한사전 사용 불가.
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 4. 12-15번은 풀이과정을 반드시 밝힐 것. (단위, 유효숫자에 유의)
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 5. 계산기 사용 무방하나 빌려 쓰지는 못함.
Fr Ra Ac

1. Write ‘T’ for true statement or ‘F’ for false statement in ( ). ( D) The electron configuration of a particular diatomic species is
− 2 2 2 4 2
[5 pt for right answer, 3 pt for wrong, and 0 pt for no answer] (s2s) (s*2s) (s2p) (p2p) (p*2p) . What is the bond order?
(A) 3.5 (B) 3 (C) 2.5 (D) 2 (E) 1.5
( T) The energy of electromagnetic radiation increases as its
frequency increases. ( B) In which of the compounds below is there more than one
( F) An electron in a 2s orbital can have the same n, l, and ml kind of hybridization (sp, sp2, sp3) for carbon?
quantum numbers as an electron in a 3s orbital. I. CH3CH2CH2CH3 II. CH2=CHCH3
( F) A chemical bond will form if the energy of the aggregate is III. CH2=CH CH=CH2 ― −≡−
IV. H C C H
higher than that of the separated atoms. (A) II, III (B) II only (C) III, IV (D) I, II, III (E) III only
( T) As the electronegativity difference in the bonding atoms +
( C) The hybridization of Cl in ClF2 is .
increases, the ionic character of the bond increases. 2 3 3 2 3
(A) sp (B) sp (C) sp (D) dsp (E) d sp
( T) The size of a cation is always smaller than its parent atom.
( T) A bonding molecular orbital (MO) is lower in energy than the ( D) The molecules in a sample of solid SO2 are attracted to each
atomic orbitals (AO) of which it is composed. other by a combination of .
( T) The triple bond consists of a s bond and two p bonds. (A) London forces, H-bonding
(B) H-bonding, ionic bonding
( F) Methane (CH4) exhibits stronger hydrogen bond interactions
than ammonia (NH3). (C) covalent bonding, dipole-dipole interactions
(D) London forces, dipole-dipole interactions
( T) Liquids with large intermolecular forces tend to have high
surface tension. (E) none of these
( F) Hydrogen bonding is a type of London dispersion force. ( E) Which is true about p-type silicon?
(A) It is produced by doping Si with P or As.
2. Choose the correct answer and write it in ( ). [8 pt each] (B) Protons are the mobile charge carriers.
( C) The quantum number is related to the shape of atomic (C) It does not conduct electricity as well as pure Si.
orbitals. (D) All are true.
(A) magnetic (B) principal (C) angular momentum (E) None is true.
(D) electron spin (E) none of these ( B) In the unit cell of sphalerite, Zn2+ ions occupy half the
( E) Which of the following atoms would have the largest second tetrahedral holes in a face-centered cubic lattice of S2− ions.
ionization energy? The number of formula units of ZnS in the unit cell is:
(A) 6 (B) 4 (C) 3 (D) 2 (E) 1
(A) Mg (B) Cl (C) S (D) Ca (E) Na
( E) Which one decreases as the strength of the attractive
( C) Which of the following atoms or ions has three unpaired
intermolecular forces increases?
electrons?
2− 2+ (A) the heat of vaporization (B) the normal boiling temperature
(A) Al (B) O (C) N (D) S (E) Ti
(C) the extent of deviations from the ideal gas law
( E) What is the driving force of the formation of a stable binary (D) the sublimation temperature of a solid
ionic compound, MgO? (E) the vapor pressure of a liquid
(A) enthalpy of sublimation (B) ionization energy ( C) To sublime a compound that was collected at P = 1.0 atm and
(C) electron affinity (D) bond dissociation energy of O2
T = 100 K by referring the phase diagram, you should:
(E) lattice energy
( C) What is the molecular structure of SF4?
(A) tetrahedral (B) square planar (C) see-saw
(D) trigonal bipyramidal (E) octahedral
( A) Which is false about the molecule O2?
(A) It is diamagnetic. (A) Increase P to 1.5 atm and then increase T to 300 K.
(B) The bond order is 2. (B) Increase T to 300 K, keeping P = 1.0 atm.
(C) The total number of electrons is 16. (C) Lower P to 0.5 atm and then increase T to 200 K.
(D) It is a homonuclear diatomic molecule. (D) Increase T to 300 K and then lower P to 0.5 atm.
(E) The bond distance is larger than that of N2. (E) Not possible.

1 2 3 4 5 6 7 8 9 10 11 12 13 14 Total
50 112 24 20 10 18 20 10 18 10 43 16 29 20 400
 General Chemistry 1 Final Exam Spring, 2014 (2/2)
3. Arrange the correct order for the following questions.[8 pt each]
+ 2+ 3+ 2− −
(1) ionic radii for Na , Mg , Al , O , F
3+ 2+ + - 2- 10. Which of the following are paramagnetic? ( O2- B2 )
( Al ) < ( Mg ) < ( Na ) < ( F ) < ( O ) − 2−
O2 O2 B2 C2 N2 F2 P2 [10 pt]
(2) ionic character of LiF, NaCl, LiI, HCl, IBr
11. Using the molecular orbital model, for the following diatomic
( IBr ) < ( HCl ) < ( LiI ) < ( NaCl ) < ( LiF ) + −
species; CN CN CN , assuming that their energy levels of p2p
and s2p are similar to that of N2 molecules.
(3) boiling points of KNO3, CH3OH, C2H6, Ne
( Ne ) < ( C2H6 ) < ( CH3OH ) < ( KNO3 ) (1) Write electron configurations, bond orders and magnetic
properties. [27 pt]
+ 2 2 4
4. For the ground state electronic configuration of mercury, Hg, CN (s2s) (s2s*) (p2p) B.O. = ( 2 ) ( dia )magnetic
[5 pt each] 2 2
CN (s2s) (s2s*) (p2p) (s2p)
4 1
B.O. = ( 2.5) (para )magnetic
(1) how many electrons occupy atomic orbitals with n = 3? (18e-) − 2 2 4 2
(2) how many electrons occupy d atomic orbitals? (30e )
- CN (s2s) (s2s*) (p2p) (s2p) B.O. = ( 3 ) (dia )magnetic
-
(3) how many electrons occupy pz atomic orbitals? (8e ) (2) Place the species for bond length and bond energy. [16 pt]
(4) how many electrons have spin "up" (ms = +1/2)? (40e-) − +
Bond length: ( CN ) < ( CN ) < ( CN )
+ −
5. The successive ionization energies for an unknown element are Bond energy: ( CN ) < ( CN ) < ( CN )
I1 = 896 kJ/mol, I2 = 1752 kJ/mol, I3 = 14807 kJ/mol, I4 = 17948
kJ/mol. What are the best fitting group number for this 12. The temperature dependence of vapor pressure can be
representative element? [10 pt] represented by the equation below. Determine the boiling point of
Group ( 2 or 2A ) water at the top of Mount Halla where the atmospheric pressure is
608.0 mmHg. The molar heat of vaporization of water is 40.7
6. Draw a Lewis structure for the following molecules as shown in kJ/mol, the gas constant is 8.314 J/K·mol. The normal boiling
the example. [9 pt each] point of water is 100.0 °C. [16 pt]

[Example] NH3 P1 = 608.0 mmHg in

Draw lines for bonding pairs and dots for lone pairs. All oxygen ln(760.0/608.0)=40.7×103/8.314×(1/T1-1/273.1)
atoms in the following molecules have two lone pairs of electrons.
T1=367 K (= 94°C)
(1) H2SO4 (2) ClNO

13. Answer the following questions about the phase diagram.

(1) Three phases. [9 pt]
A = ( solid )
B = ( liquid )
C = ( gas )
7. (1) Draw two Lewis structures with formal charges for the O3
molecule. [10 pt]

―O ]↔[ ―O=O
(2) D = ( triple ) point [10 pt]

[ O = O O ] E = ( critical) point

[ ] ↔ [ ] (3) What is the phase change you will observe? [10 pt]
(2) Is the O3 molecule linear or bent?(VSEPR) bent [5 pt] Expt 3: Phase A - ( solid/liquid/gas mixture ) - Phase C
Expt 4: Phase B - ( intermediate(=supercritical) ) "fluid"
(3) Is the O3 molecule polar or nonpolar? polar [5 pt]
3
14. Iron has a density of 7.86 g/cm and crystallizes in a
23
8. Select all the polar molecules in the following list of molecules. body-centered cubic lattice. (NA = 6.02 × 10 . Atomic weight of
OCl2, KrF2, BeH2, SO2, SO3, NF3, IF3, CF4, SeF4, KrF4, IF5, AsF5 Fe = 55.85 g/mol. Use cell diagonal = sqrt(3)*d = 4r.
OCl2, SO2, NF3, IF3, SeF4, IF5 [10 pt] (1) Calculate occupation ratio in percentage. [10 pt]
bcc: 2 Fe atoms per unit cell.
9. Consider the structure of glycine, the simplest amino acid: Volume of the bcc unit cell = d3
3
Volume of actually occupied = 2 Vsphere = 2 (4/3 p r )
3 3
= 2 (4/3) p ( 3/4) d = 0.68 d √ 3
68 % ∴
(2) Determine the atomic radius of iron. [10 pt]
[6 pt each] 3 23
Volume of the unit cell = d = {2 × 55.85 / (6.02×10 } / 7.86
-23 3
(1) Indicate the hybridizations at each N and C atom in the = 2.36 × 10 cm
molecule. C1 ( sp2 ) C2 ( sp3 ) N ( sp3 ) -8
d = 2.87 × 10 cm r = d × ∴ √
3/4 = 1.24 × 10-8 cm
(2) What is the total number of bond(s) in the molecule? ( 10 ) (= 124 pm = 0.124 nm = 1.24 Å).
(3) What is the total number of p-bond(s) in the molecule? ( 1 )
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