JEE

JEE MAINS Test 11

Discussion 12/06/2022

(Chemistry)
IIT
BY: Ram Niwas Sir
Jee-Main Test - 11
Discussion

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1. The ratio of number of -bond to -bond in N2 and CO molecules are

𝟏
1 2.0, 2.0 2 𝟐,
𝟐
𝟏 𝟏 𝟏
3 , 4 ,𝟐
𝟐 𝟐 𝟐

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2. The state of hybridisation of central atom in dimer form of both BH3 and
BeH2 is

1 sp2, sp 2 sp3, sp2

3 sp3, sp3 4 sp2, sp3

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3. For H3PO3 and H3PO4, the correct choice is

1 H3PO3 is dibasic and reducing agent

2 H3PO3 is dibasic and non reducing agent

3 H3PO4 is tribasic and reducing agent

4 H3PO4 is tribasic and reducing agent

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4. Which of the following does not show geometrical isomerism

1 1, 2−dichloro− 1−pentene 2 1, 3-dichloro- 2-pentene

3 1, 1-dichloro- 1-pentene 4 1, 4−dichloro− 2−pentene

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5. Which of the following nitrogen atom is maximum basic?

1 b 2 a

3 c 4 All are same

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6. Major product of the following reaction is
Na
Isopropyl chloride ⎯⎯⎯⎯ → Product
Dry ether

1 2

3 4

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7. What is compound Z?
NaCN H3O+ CH3CH2OH
CH3CH2CH2Br ⎯⎯⎯→X ⎯⎯⎯
heat
→ Y ⎯⎯⎯⎯⎯+ →Z
H

O
||
1 CH3 CH = CHCOH 2 CH3CH2CH2CH=NOCH2CH3

O
||
3 CH3CH2CH2CH(OCH2CH3)2 4 CH3 CH2 CH2 COCH2 CH3

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8. In diamond, carbon atom occupy fcc lattice points as well as alternate
tetrahedral voids. If edge length of the unit cell is 356 pm, then diameter of
carbon atom is

1 77.07 pm 2 154.14 pm

3 251.7 pm 4 89 pm

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9. A sample of an ideal gas is expanded 1 m3 to 3 m3 in a reversible process for
which P = KV2, with K = 6 bar/m6. Work done by the gas is

1 5200 kJ 2 15600 kJ

3 52 kJ 4 5267.6 kJ

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10.Fe2O3(s) may be converted to Fe by the reaction
Fe2O3(s) + 3H2(g) ⇌ 2Fe(s) + 3H2O(g)
for which KC = 8 at temp. 720°C
What percentage of the H2 remains unreacted after the reaction has come to
equilibrium?

1 ≃ 𝟐𝟐% 2 ≃ 𝟑𝟒%

3 ≃ 𝟔𝟔% 4 ≃ 𝟕𝟖%

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11. CH3–CH2–O–CH2–Cl can undergo which substitution reaction

1 SN2 only 2 SN1 only

3 SN1 as well as SN2 4 None

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12.

1 2

3 4

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13. Which of the following will give different osazone than the other three ?

1 2

3 4

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14. Which of the following option show correct matches
Column-I Column-II
(a) Precipitation of colloidal sol (p) Peptization
(b) Purification of colloid (q) Coagulation
(c) Gold Number (r) Desorption
(d) Formation of colloidal sol (s) Dialysis
(t) Measure of protective power

1 a-q, b-s, c-r, d-p 2 a-s, b-q, c-p, d-r

3 a-r, b-s, c-q, d-t 4 a-q, b-s, c-t, d-p

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15. 3 moles of FeSO4 are oxidised by "a" mole of K2Cr2O7 in acidic medium
whereas 3 moles of FeC2O4 are oxidised by "b" mole of K2Cr2O7 in acidic
medium, the ratio of "a" and "b" is

𝟏 𝟏
1 2
𝟑 𝟐

𝟏 𝟏
3 4
𝟒 𝟓

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16. The rate constant of a first order reaction is 3 × 10–6 per sec. If the initial
concentration is 0.10 M, the initial rate of reaction is

1 3 × 10–7 Ms–1 2 3 × 10–6 Ms–1

3 3 × 10–5 Ms–1 4 3 × 10–8 Ms–1

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17. 7.6gm KBr in 1250 ml solution was found to have an osmotic pressure of
1.804 atm at 27°C. Calculate degree of dissociation in % (Atomic weight
K = 39, Br = 80)

1 45.4% 2 58.4%

3 4.64% 4 80%

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18. Oxide of an element A is used in the manufacturing fire clay bricks and this A
not react with water but its oxides dissolve in NaOH then A is

1 Mg 2 Be

3 Na 4 None of these

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19. In [Ni(NH3)4]SO4, the E.A.N. of Ni is

1 34 2 35

3 36 4 37

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20. Which one of the following octahedral complex will not show geometric
isomerism (A and B are monodentate ligands)

1 MA5B 2 MA2B4

3 MA3B3 4 MA2B2

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21.How many P–O–P linkage (s) are present in 𝐏𝟒 𝐎−𝟒
𝟏𝟐 ?

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22. [X] = Number of reaction in which final product is aldehyde. Find out X.
LiAlH
(i) SnCl +HCl
(a) Ph – C  N ⎯⎯⎯⎯⎯
2
+ →
(b) Ph – C  N ⎯⎯⎯→
4
(ii) H3O

(c) (d)

aq.KOH
(e) (f) Ph – CHCl2 ⎯⎯⎯⎯ →

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23. How many number of lone pair is present in catechol ?

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24. 99% of a first order reaction was completed in 32 minutes when 99.9% of the
reaction will complete.

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25. An electrolysis of a oxytungsten complex ion using 1.10 A for 40 min
produces 0.838 g of tungsten. What is the charge on tungsten in the
material? (Atomic weight : W = 184)

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26. How many isomers are possible for the following molecule?

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27. For the reactions, 2A + B → C,
H = 400 kJ mol–1 and S = 2 kJ K–1 mol–1
Calculate temperature above which reaction become spontaneous?
(considering H and S to be constant over the temperature range)

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28. Sulphur trioxide is prepared by the following two reactions
S8(s) + 8O2(g) → 8SO2(g)
2SO2(g) + O2(g) → 2SO3(g)
How many grams of SO3 are produced from 1 mole S8?

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29. Number of moles of ammonia obtained when one mole of Mg3N2 react
with water = x mole and number of lone pair present in XeF4 at central
atom = y, find (x + y) =

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30. H3PO2, H3PO3, H3PO4 sum of basicity of ........ is

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THANK YOU