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Study of The Magnetoelastic Effect in Nickel and Cobalt Thin Films at GHZ Range Using X-Ray Micros
Study of The Magnetoelastic Effect in Nickel and Cobalt Thin Films at GHZ Range Using X-Ray Micros
X-ray microscopy
Marc Rovirola,1, 2, ∗ M. Waqas Khaliq,1, 3, † Travis Gustafson,4 Fiona Sosa,1 Blai
Casals,2, 5 Joan Manel Hernàndez,1, 2 Sandra Ruiz-Gómez,6 Miguel Angel Niño,3
Lucı́a Aballe,3 Alberto Hernández-Mı́nguez,7 Michael Foerster,3 and Ferran Macià1, 2, ‡
1
Dept. of Condensed Matter Physics, University of Barcelona, 08028 Barcelona, Spain
2
Institute of Nanoscience and Nanotechnology (IN2UB),
University of Barcelona, 08028 Barcelona, Spain
3
ALBA Synchrotron Light Source, 08290 Cerdanyola del Vallès, Spain
arXiv:2312.15269v1 [cond-mat.mes-hall] 23 Dec 2023
4
Department of Physics, Norwegian University of Science and Technology (NTNU), 7034 Trondheim, Norway
5
Dept. of Applied Physics, University of Barcelona, 08028 Barcelona, Spain
6
Max Planck Institute for Chemical Physics of Solids, 01187-Dresden, Germany
7
Paul-Drude-Institut für Festkörperelektronik, Leibniz-Institut im Forschungsverbund Berlin e.V., 10117 Berlin, Germany
(Dated: December 27, 2023)
We use surface acoustic waves of 1 and 3 GHz in hybrid piezoelectric-magnetic systems with
either cobalt or nickel as a magnetic layer to generate magnetoacoustic waves and directly image
them using stroboscopic X-ray magnetic circular dichroism imaging. Our measurements visualize
and quantify the amplitudes of both acoustic and magnetic components of the magnetoacoustic
waves, which are generated in the ferromagnetic layer and can propagate over millimeter distances.
Additionally, we quantifiedy the magnetoelastic strain component for cobalt and nickel through
micromagnetic simulations. We obtained a drop in the magnetoacoustic signal at 3 GHz suggesting
a speed limit for the efficient magnetoelastic coupling in our hybrid devices.
I. INTRODUCTION acoustic waves (SAWs) [11, 12], which are strain waves
propagating at the surface of a solid. SAWs generate
There is an increasing interest in manipulating mag- an oscillating strain in both space and time which can
netization dynamics to create low-power consumption create an oscillating magnetic anisotropy field on a mag-
devices capable of transmitting and encoding informa- netostrictive material [13, 14]. This dynamic anisotropy
tion efficiently [1]. A challenge lies in effectively creat- field may induce a magnetization variation with the same
ing and controlling magnetic excitations in nanodevices. wavelength and frequency as the SAWs and the exci-
The most common way to manipulate magnetization typ- tation may propagate up to millimeter distances [15].
ically involves the use of magnetic fields. However, this These hybrid waves are referred to as magnetoacoustic
approach has several downsides, including issues with waves (MAWs) and have been studied in a wide range of
non-locality, and challenges with integrating controllable materials by measuring acoustic attenuation as a func-
magnetic fields into micrometer-scale devices. Other tion of the magnetic state [16–20] or by direct imaging
approaches explore interactions of conducting electron’s using magneto-optic Kerr effect (MOKE) [20, 21] or X-
spin [2, 3], lattice phonons [4, 5], or ultrashort light pulses ray magnetic circular dichroism (XMCD) [15, 22]. Using
[6] with magnetic excitations. Promising alternatives the same principles, more recently also Néel Vector waves
have been proposed, such as the use of strain. The field have been observed in antiferromagnetic CuMnAs [23] by
of straintronics [4] studies strain-induced effects in solids X-ray linear dichroism (XMLD).
and special attention is directed to magnetic materials as SAWs are typically generated by means of interdigital
a promising alternative for reduced energy-consumption transducers (IDTs) deposited on piezoelectric substrates.
devices [7]. Strain couples to magnetic states through IDTs are interlocking arrays of metallic electrodes that
the magnetoelastic (ME) effect, which is the change of can excite SAWs up to GHz frequencies. IDTs are used in
magnetic properties due to mechanical deformation. This electronics as delay lines and filters and their integration
effect has already been proposed and used in many appli- into micrometric devices is well-established [24]. SAW-
cations [5] including the reversing magnetization of pat- based technology can be efficiently integrated into low-
terned nano-magnets [8, 9] or inducing a phase transition power devices since the SAW amplitude depends on the
from antiferromagnetic ordering to ferromagnetic order- amplitude of the oscillating voltage applied to the IDT
ing [10]. instead of the current.
The ME effect can be used to generate spin waves— Magnetic imaging techniques based on MOKE [25, 26]
collective excitations of magnetic order—through surface or XMCD [15, 22, 27] bring the opportunity to directly
measure MAWs and thus study the effect of the cou-
pling between strain and spin waves both in space and
∗ marc.rovirola@ub.edu in time. Recent experiments have shown that the ME ef-
† mkhaliq@cells.es fect is as efficient in dynamic processes up to 500 MHz as
‡ ferran.macia@ub.edu is in static processes [27], thus fueling the idea of using
2
SAWs in magnonic applications. One of the key ques- top-center depicts an XMCD image that highlights the
tions in this field is whether the ME remains efficient at magnetic contrast on the Co magnetic domains, accom-
higher frequencies, which are characteristic of magnetic panied by faint traces of residual SAWs on the LiNbO3
resonances. due to thermal drifts in subsequent images (and thus dif-
In this paper, we study MAWs at 1 and 3 GHz in nickel ferent SAW propagation velocities). The top-right corner
and cobalt thin films using stroboscopic X-ray photoe- depicts a 2-phase-XMCD image, which consists of captur-
mission electron microscopy (XPEEM) combined with ing two XPEEM images with a 180-phase shift in SAW
XMCD imaging. Our analysis reveals that both nickel for each X-ray helicity, followed by a subtraction between
and cobalt exhibit MAWs across a wide range of mag- both phases and helicities. This method enhanced both
netic fields, each material displaying different profiles and the magnetic and piezoelectric contrast while eliminat-
amplitudes. With the help of micromagnetic simulations, ing static contrast such as magnetic domains, enabling
we are able to quantify the strength of the magnetoacous- a clearer measurement of MAWs. Figure 1(b) shows the
tic coupling for both magnetic materials at the studied two opposite phases of the SAW, tensile and compres-
frequencies. sive. Figure 1(c) shows the directions of the SAW, the
magnetic field, and the X-rays. The SAW and the mag-
netic field are at 45◦ with respect to each other to exert
II. EXPERIMENTAL METHODS maximum magnetoelastic torque, whereas the SAW and
X-rays are perpendicular to each other in order to detect
the magnetization changes in the y-direction as repre-
Thin films of nickel (Ni) and cobalt (Co) with a thick-
sented by the dashed lines.
ness of 20 nm were grown on the acoustic path of several
SAW delay lines by e-beam evaporation. The delay lines
consist of pairs of unidirectional IDTs deposited on piezo-
electric lithium niobate (128Y-cut LiNbO3) substrates, III. RESULTS
see Fig. 1 [28]. The IDTs are designed to generate SAWs
with frequencies of 1 GHz and 3 GHz for the Ni sam- An initial characterization of the samples was per-
ples and 1 GHz for the Co ones. These frequencies are formed to study the angular dependence of their acoustic-
conveniently selected to match the synchrotron repeti- ferromagnetic resonance (a-FMR) at 1 GHz. The experi-
tion rate (499.654 MHz), thus allowing for stroboscopic ment consists in placing our hybrid device (see, Fig. 1(a))
images. To generate SAWs, we excite the IDTs with an between the poles of an electromagnet and measuring the
oscillating electrical signal of the appropriate frequency transmitted acoustic signal, S12 , with a vector network
that is transformed into strain through the inverse piezo- analyzer at different angles between the SAWs and the
electric effect [11]. Notice that SAWs are limited to a in-plane magnetic field. In contrast to FMR, where an
substrate depth on the order of the SAW wavelength [29], rf-magnetic field is used to drive the magnetization into
corresponding to 4 um and 1.32 um for 1 and 3 GHz, re- resonance, a-FMR uses the periodic strain field of the
spectively. Within this depth region, the SAW causes a SAW to induce magnetization precession by modulating
periodic modulation of the crystal lattice in the substrate the effective magnetic field of the sample. Additionally,
and on any thin film deposited on its surface. The SAW the non-zero wave vector of the SAW has to be taken
propagating through the hybrid device generates a peri- into account in the determination of the resonant mag-
odic effective magnetic field in the ferromagnetic film as netic fields and frequencies [17].
a result of the ME effect. The coupling between magnetization and SAWs can
The experiment was performed at the XPEEM exper- generate MAWs under certain conditions of the external
imental station of the ALBA Synchrotron Light Facility magnetic field. At resonance, significant energy is trans-
[30]. A schematic representation of the setup is shown ferred from the SAW to the magnetic system, resulting
in Fig. 1(a). Details on synchronized SAW strobo- in SAW attenuation and phase shift that are detected in
scopic XPEEM measurements and the upgraded setup to the S21 measurement [16]. The SAW attenuation results
support > 500 MHz excitations can be found elsewhere are presented in Fig. 2 as a function of the applied field
[31, 32]. Since the metallicity of Ni and Co shields the magnitude and angle (in both cases, the magnetic field
piezoelectric field of the LiNbO3 substrate, only changes was swept from negative to positive values). In both
in magnetization can be observed in the areas covered by samples, a large attenuation is observed, regardless of
the ferromagnetic films. To resolve these changes, two the angle, at a fixed magnetic field that corresponds to
XPEEM images with different light helicity, circular right the magnetization-switching field of the film. In addi-
and circular left, were subtracted to obtain an XMCD im- tion, Ni (Fig. 2(a)) shows the typical four-fold shape
age, in which the contrast variations are directly related with large attenuation between ±30◦ and ±50◦ , and a
to the in-plane magnetization of the samples. The in- maximum around 45◦ where the ME torque is the largest
sets of Fig. 1(a) display the three imaging modalities of [16, 33, 34]. As the angle between SAW and the magnetic
the setup. The top-left corner depicts an XPEEM image field exceeds 50◦ or drops below 30◦ , the attenuation de-
with clear SAWs contrast on the LiNbO3 , accompanied creases, reaching the minimum ME torque at 0◦ and 90◦ .
by a weak contrast of magnetic domains on the Co. The In contrast, the SAW attenuation for Co (Fig. 2(b)) is
3
FIG. 1. (a) Schematic of the experimental setup. The thin film of either nickel or cobalt is grown in the middle of the acoustic
path. The cobalt sample can only be excited at 1 GHz by either IDT. The microscope (XPEEM Objective) is operated at 10
kV with respect to the sample to accelerate the electrons excited by the X-rays. From this setup, we can obtain XPEEM and
XMCD images. The magnetic field is applied in-plane at an angle φH = 45◦ relative to the SAW propagation direction. (b)
Normalized schematics of SAW strain phases, compressive and tensile. The difference in piezoelectric voltage between each
phase is labeled as Vpp , from which the strain components can be determined. (c) Representation of the direction of SAW,
magnetic field, and X-ray. In this experiment, the SAW and X-ray are perpendicular to each other. The horizontal dashed
lines represent the change in magnetization projection captured with the X-rays.
B. MAWs in Cobalt
IV. DISCUSSION
FIG. 3. (a) XMCD image of Ni showing the MAW driven at 1 GHz. (b) XMCD image of Ni showing the MAW driven at 3
GHz. (c) Experimentally determined MAW profiles at 1 GHz (black curve) and 3 GHz (green curve). the red and blue curves
are fittings to a sinusoidal function. (d) Dependence of the MAW amplitude on the external magnetic field. The left axis
represents the excitation at 1 GHz, while the right axis represents the excitation at 3 GHz.
achieve amplitudes approximately equal to 0.1, compa- is obtained for Co. The found values for the magnetoe-
rable to Ni, which could make Co an interesting mate- lastic constants at 1 GHz are similar to those reported in
rial for straintronics, due to its low damping and high the literature [15, 27, 40–42]. Additional measurements
magnetization saturation. At 3 GHz SAW excitation, we at 3 GHz SAW excitations show a clear decay in MAW
found a reduction in the efficiency for the MAWs in Ni efficiency suggesting a drop in the phonon coupling be-
that requires decreasing the magnetoelastic constant (to tween SAW at the piezoelectric substrate and SAW at
∼ 0.3 MJ/m3 ) approximately a factor of 10 compared the ferromagnetic thin film. Our study provides valuable
with 1 GHz excitation. Although our model does not ac- insights into the coupling between strain and magnetiza-
count for direct transfer of phonon angular momentum tion dynamics at the GHz frequency and may guide the
to magnetization [33, 43], which might be dependent on development of more efficient acoustic spintronic (strain-
frequency, we consider that a plausible explanation for tronic) devices.
the drop in efficiency at 3 GHz could be related to a
frequency dependence of the strain transfer efficiency be-
tween LiNbO3 and the Ni film. ACKNOWLEDGMENTS