cARBONYL CoMPOUNDS canbonol nda 2 Mdehydes —( R CHe) ~ Kehr ( KER) Methods 9 preparation :- ALDBAYDES (AEH) KETONES (REOR) vr Oxidation 9 I Ae w oxidetion 9 2 dobds:- Ka READ +Hy ra 20 rip ° bmi Po nila 08 pee in aated are "eit Hd St) lpg A we) Boondysis 9 of Kea: © setiyain AK a.erry or 0; A-CoO-k 9 HROR \) UzenrtyoIe 7 me sep -n b Rete OT PRCA An eho 0:0 4 ngeacen-i, 2 > CASE Woe em 9 2 Ae ‘ods ne a Fe ln PN Aarne ta 4,3 Dinca t2- Oe om nt Seip ses me Ag te) P| Be aK yim, 9 ( yt Bide anbtobhe cage soci cy) untbs rreo0 (Fenuctne. - ) “RY ® por GR . GR . ar big nm. wecem + RMX > Ae NgA CaN + RMX alan yr car I Ae “cle Ye Rem t yt yl RLOR ENS YP olde Ketone Rodenmnds Redution — | Revtin 9 Aid Assia i Da ay for debs Dede codon , J! P4-BaSty Red +R d3a2 eGR Rid +A, “aaate MENT AG TE + ob ask 1 dinpisctte odoin = tH-c-4 +4, Segge +nd 4 ‘lnk pestle F acnped+ Cyl > 4% oe [Partin 4 Didtd eda AE 1p ee ds? Bed + 2nd] Benge Arid BeateBogyhoo co nitrile” ne AMdehy dan WD Ay! sya, R-L2N Akane nitrile qe asczN +r Sales CougeneNd Bihan nibile w Acetonitrile salad we sen ye Pangpnifrile DEBAL-A cave + Wa) —7 RB 4 RCHo CAZNH — aR? i Athy imine He caycno a Eten imine SAsero Benapbehyde a inebyp) at La Di-isebuf Aeniaivin Aya det CAH, CN 0 PROM CAA CAD we Agfa Ch CAZUA py eH ON PCs CH Cy -, CHD Aja ” Cash, 6 As —_ CAC Ay CHO ° cat, prpanel eH Benzafeehyde oO , GecHo Metheds. 9 prepratisn:- O Efond Henrction- CAs en (ocnoned,) eho Grr Cy Ae Tate Bogiaiyl eb cH (0444Hs) > n0; * co @) + (cas ro — Cy PP Ce) Thue AatiS bie 0) sith dein Abninntion 9 Tevere : Gh Oo 9 O TA yy Guattermann — Kerk eatin ad, atts a Co) +o wP oud, Baz Bledtrephile 2 n$-0 tm CoribocetionBlefrephile = n-Lz0 Portingh Cenibo ction erin phoprtin cotton compound He. Aetrcfesise Meatime F Atdehyde Koha te luc ic addin neste Ne ? | V& eo Aw pez? = “n? “Ss Ne * Hil nese, 9 Trg lavas nnn BOE WK Afdehydis om Mam Hentive Then Ketna funda rucleophilic dition heactiod , — cxplrited 4Y w Stoic fart Fete fart rite, wo Shoic Fn : Ry ne mane, onl per? R =d aldehyde Keb Aw ioe crpndiog aed ohio cre tenn NP wr asl at fack Gd Eetnnic fator (+2 ete) A,@ 9 R We ce Re P Adela Keto. Rentihy found, OK MegNh dak on Aechaphilic addition Contaryl catibey Ate gays (9) fede Fe Ang F cAbugf oda da th +E eet: ( € donno yous)a Alef pp Uy ee -- du hp FE ete. ( € drafig pmups) campritively Aus 7 Ve hig pratent om Hene Ketone ote kab Hokie Cahbrn Ketones, Aurivily shan. GAs, 4 SH: “Veo 7 Oy , zo ? Broo oh o> Noo i nn? H ca fo 7 Ghs os A Armedic mldehpe & Ket ote [at Mende four —nechaphific. addin de = «bet ee ee ee ee werd o ty ob) PU ee @ aldehydes Ketan Y Addition 9 Hen : @ Addifin 9 MENS nae + Ase Os +HON —> 4, An See 0 THEN a am mate | wen natedeebrle. Aatam Aarne mer eyorrdyattin Cae 40H conn dakic acid 4 fret wr Addefion 9 sodfin, biglphite (Na A509) Beth atderydn & Kets Fath ohife ny Arline products Sih Lediwn bigulplite. A oH on As, 08 Neco tNaASh ELT FO, ns sauen mesort epee By on SEND AO Ne “co emity ae eC chs A, Atdehyde so: og : mca” ta (hike crystafoe. , Porwrd Hendin i Mone fovured Medonish: sdehyda oo + a8, = 0) we ait, SA) hy gt at ky AA WN a \sne a) Additin $ OR: 9 Refer ohh PM AaLLon fleck &y eri DS Ap { condensation “is , nis . ie, ae ot Anh ie? are J Me ny Oy, = “hes awn Biawnal “ai “A hs ® Nexo AnH 9 22M _ ” chy hy Archit, peat BN yee7 rnin Amn With prtimay_ainine> yp . bp RR cope AYER 2 eamer | ROA 4 ten > Seon-rR a “ amine . mm napon > Mybogl oR fea) nan tra 4 rin, A Gls > asd AB MMe OA gy, 4 sy-Dinibr (el pot h -. ASA ConA, semenbogpae PAs antioxdut in Abn inte HA Aydroxd ani. > A Ms, Ab, An _ § \¢ SN-OH N ry aN ef +A a " ° " a Ox “ fie, a fort, OXI Me, - leh Ae ce: a nothin feta — AeteAdoxime. Aepxiine wil Hydnegine + “ Hy y chy, Ren Bas > we 7A My ern 4? wee Sey dn ON alabaie Cretore bydeagert- “rydrnagne with Phenyd Ayabagin. * Ch hy Ay eh + Ay NAGI AaNeniiglls) | C INGHs 2 ea NA Ute 4 hs Outed teh ye or Acetone. phenzh Phenyl tydrngee Aydt with 24- Dirifrephengk Kyte sue (3,4 - NPD oy L Bophihs neg lems HS ON SNM ° Broad pont(2 -onPD ms} ae one of At: NH 4 % sN-NH OE NO» 4 ag” or g Ny poet pend _ Dutaldeds de aie 24h DOP ne Duy “yn Korbgon one tend th rede ane rete else pra) WA Semicnbrzide:- “a eyieng> By cnc) crit eamenn nn, A . seach gts a Ano “im Bertin OR AAAS | tat, ot teat 4 ¢ a Raa A a RoH Ry ve roti ew ye? ead w on “gn Ne! “\ “fe 3% ay? be 4m te fon tel asi RO Nom, Hench 4 cyfic Patek ” Meeted Reduction - 9) Pekan cl cep inh — alot’inh adhe . ‘on Lithy Nabi, m Ini Naess oA Reon 42 RA Ay, AH Ke C4 R ea +) 4 RCHoH enn ae ded tke hy [alcdd | Kefous on Aedet on * AldeAydy * neduction ge fie Setanelay Ate Prinny And : he, rh te Tey xy Henny coo tH? " ER det oy om nal 44 ately. we) ny > Ckmengon Heofuction:- eee pero ebb a Ra: A ose . A 4y 4 Ree, +0) md Ache R 449 - aq Al Kent “exo +) 1) RA + A a(Kane. os + ay 9 hth, the + ; bn tH Bb Sy a Effet. Auch pre ane. puetedelehyle wf -Kibhnwrib Reduction. Yeso 9 ANeso Ap RA: NAN » Ke ehyoe : / “AP Ry ral | Ay, wg, 5 By on wit Ser ee ge no ge Rey tM RR try aKa Aken. 4 ty Ann, 3 Mm whe £ > Tirta Boone) eon Kou | ORE [rrtecaed ope as > Che cyy > heen tty +L Eft prep Redation by AD [Red preipnis de ~ ed yee a “hh ROOR+ AT Re RAR th? Akae +22 RA, Rey tpt =? I, 7 o , Acyo t ¥AL phaplons akon 4 AM Fy 9 Ay tls + Hy? rope 7% a . +4AT 9 “A FA, q ugh Een vi 2, Onidefion s- etn mil “sige! ay hvy OA ©, DANK yy Pe J papafit « w) 2 cant ee ? coerced Ane /et a ANG, Lo unfbis dove (a)Aldebyh yprgie nese - D unfeis Arve eh nie ear & Eric aad # iit Ly eonpint tent | Conbon arn Bo J caer 4© “9 Cycom Kefme ) ey | Hats + 40 BE ctyeon + « G49 Se tA? prctts fle: PU! GB Duning The oxidation t Vriyrnetrio Ketrnes , 2 -goy ye Hefaind WIA Amsler led Pop Reon R 2» peat + Reo yo se, Fh 4 Fo cee Artis Hy oleae + yeyen * nico Sihwn mison Fat (Tellers tod): & Ginn oy ony Aramaic] silver nitrate 4*fatite Ly Piers Heagert acHo sept 3 —7 Rue + aay + 70 sin ig + a Ms Kefoa de nt Mebpod pleis Fea buoy reve 1 Fafaylery,] +209 aan favo] aay® tytn 4%, pedlge tet gin 4 only ele byes I Antonedic dehyde bt Fusprd tr PAling’s fot elas Atet > oY cuss A BeAiag Aetwtion AfKaline ok. pots toabrtate ot Ketones ob ast Hus pad PeAluge “ast: Rochele Att Reo + act Sona ROW + CUP Ret itt oo Fugen + re Sa cd FH? F 2 Beredit a Tat: Ly finn Beredits S2fiction L tdie sdetin g ei!” vanplexed a Cthrafe enh 5 rm UH F PAlig tol Kets ob nt Pa to RalnsAlig tol sch fe tot> Mi A te a sai dafrined by probing > Ketna & rot aprd MW ink Shured Resrviline + shit Tat Hough f' Cp ov f+ + tddyda abn pk Aur 9 SALA Hear tel: Auetone + Sodio rire prvi + Anat na, [tem] Wire. Hed cvtowecion — Taye Trdg Fest - Aah + o-rdrrobengtdebyde. + NAH + Blue chon gett fendtin vith hy * eno tad | CHcol, + 34> ecoch, + 3nd CASeHp +34, a 64; hes TrieKerpactt dde hyde, Pi doPt0 Abnd nape wih ry e hs tp A + pe, 3 Hy CHa od , yr + Ps wrsa 7 pod, a ts a ales prorfidoe Attin n . a . re proppidee “AMtee. Hafo 2 fot Hertton > Aldehydes & keprs confining CAs gop E a Ade ahead, caning Ch rep porta hen yom Naox Rensen] [Nao + X&y / [ ] ” r 4 «Ba Aw dnt, 6 Noon +Zp CAL, , Jad form tdeboe [ Kedwe. Sehopny / J xX og cation Cah (Hig oo Se OY Ch. hf c- x ogres “Aye Os (x CA, cA A + > “eps * » fo etd 444 3a. chschn, + 22 7 623A + 273A CAsCAD, + 22,7 CZyhe + BAL ‘re + CZ. 5 CHE, + H eon, FNS 74 SAD ; ¢ SNE + FAP oa + yZyt 6 Nay} CHT + Ho A Bia 44 an ep ona + BKsE CHEhe + y Ne + 2E,—7 CATs + “A. fret + HD Flute dp byl, + eNO + 359 cal, + cero tie ym 130 ALDoL CONDENSATION. pe int H Pe ny Aldehyde & Keto voxfaining % my tendin Rk NAH NGS Bal), Y 2 a = a a CA, Ho Hy CH, CHO. (%); crete ecco, 4c) a im ig ot ct One ~~ Pale neice ” AL pol ” 5 bpdnongetored Pei ipa Fanart> Che CA =CH-CHD Pf: 2-enaf (Croley) Mehanibn > 1 , 2 @ AetHo + va) > thyeno + %? uctdde hyde Combanion © 6 sfigiliged bf Redoene Len ser Ay G > aeeecl o) P Wo a ° tek Qncio + Cy E-Heh0 Canbahirh 4 3 2 onts dike ANuc|uaphi w P i chy CAH + 40 —% Hy CHC yo + OM ALP o| -Ayo Chy CHS CH-6 AO Crefan aldehyde * 4 4 of Cage 4 + CHD ~ Cat 2CH CAD7 4 ~ A CHty sCHCHD cagede + Apncaw so oF rH 99 cay +O nts —¥ tly C— Cty cochs én a z » Qahn. KaTOL al-4g t ‘7 Diace tne ch ch, oe Ch- ots chy e Masel ox ide - Se + Reve *; Asx, a cacoths chy ny predate enemas eae AEAOLH, ic Croibed olde endengection: ® yupe * poe ce ye x ype bbls keh ater oe Ahowld tee KA ? 4 CAycHe + Chg H,CAD 4 LPtedete Earl Propane tiga t Menem hy As eH CD f dd Paarl Zzos “el etnarel B dA D products Off =>t-¢tHo ; + -cHo De Ay ae cont tM propane| zB zZ & -—CAD - - a Ay eG Ay ce + A “ ay coped A CHy dd (thar prepowl [rtedecta A Etaard propor ? ach + React 4 Ae = HCHO ye i Prrmeldelge ir per: czar bn eA ee Hens spat Aap ch? Dn an le a 4 - ® @2a . o0G Ay EMg-tysca-6- Gls go She vet He Ha? GMS SAPS 4 Atotrohs nolh.gw Ghe-C vot tyerieece ye gis criecn ge A Alefapherae ° Dengdehple if Lae kA 1, se iplenyl prep-aer-tont— claigen- schmidt corde notion - / b cnased odd cn denrtion oho Artomedic. aldehyde 3 diptic dehyde on Ke te. 4 thy-gae + Anon eg tHscH-thd Bory Quetale byte Cinnanaddedyde- ” aie pe + Rene Gls th ocn-en Hs jf Begrlaactne Burgfolahyee Andon Camiaere Meaction -- Dy adehy te Roving no AA on Heafion with anc: bag (om an Kot) urderge ap opeittonatin »} @O NaH __. qo > Heo ers Heo + CH:PH wo Hyo/At weno 29 econ "9 Aeort Ly Heal Perel pece Hy dl yet j) KY action 4 & GAs cho 5 Ggbigeorn + Seg ae "5 Borgel debyle ‘efit Berapic, oA etd Gis cno + 0) Hl, OgAy vot] 44 aire + aw) fA, wes? H . Hedonist: d e . eb tH ton 4 wy i, porn dehyde D ° i ° ide (4 ” whey len Tr A eG porrecde hy de Rate Atoms oD 2 oO n-b-n + bon A 4 Pumice aud | oA yeerH Meta cadMeta tcAd Crossed Cormigye Mention: Ly bly the ehfforent_ add ys faving te Z- Trformdfe ya, i'r Jeotion - wee ©) 4 on 9 Adebydor is thal ely at Pebpaldehyde. K AcHO + GAstho “ty Heo} + Us prow — Brengeeyle™™® frend Bensf Ath Of me me & Ach , fn produ % posite Os Nal + Gprb-eho Sh guy + sche t ch nal yt oxidised - GAs Ao > « can es patie Lay CHy ® Iaffvrdecula Camigzte seation Mon $4 DialdeAyae Fevig 0 4A o CHD KOH, ood Lao Ap/at CH,2H 00H we) chp KoRwn) oe tho Agfa C Linee) ce gee Cine Aut VAs (Bi) Dnforned canine? Hentivn = X- Ketraldehydis “havi % a ant Ke Top 1) Na “rk _— op 0 hac GA — a C00 f ae + 7 WO H0/ HF I oF siete lags eet ‘ Kepe wad ergo me ducfion skefrypile: Abstiton enctive q. Aimdic sale ; gry men dinestoy lm te > Prin Bago Supe oe tt One“f Hs tH- CAO, da nt undone — atdel candengation. As Fabby de “uy an * cdc , ds rt ndings — Counigre mention 4, oO, td wep ts pete tay p el AK nue ¢ coho — end, t Here Tisthenko eatin Aleta fn TB rales With om Bop % HH undete comigyr Heackon feacfisn with AY] ynininan cHhoxide- Lew formed aad ¢ cnbrafic sod onbine ap fin Eston. at (264s), 4 ad CH, © HO CA, coe HLH, etay| ache [ ACAD » Hs! je cngninns| ene Te penkin condensation *- CAsconls igen + (Chae) 0 ER Gl ed = CA Anonnfic atipho tic 4, B walatuneed aldehyde f aud aby rice annafic aed 4 1 2aagenyae ‘aad Aa. wy pene nee b “ny a Bema aely de Aue anhyebide Cinnamic 94 Med orp Toe KH [tegen > atin cern | A xt Bengein condenda tion a oe ic Mehyhs elon cnup hog fim - Aydorny Ke fne. t in prsoe 9 KOA t 4 q KEN i A a - who ig bi 2- Gus OAs Gat OF GAs we) ols - & A Pengin Prema debyde ZL z Claisen vndenhation - by peattin Sv Fw esfon wm Bain wd ik frm Po keh alow © p-dikefm 8 prise ) bg “ NaoR Ps nc ptsliy : 2 - Y,- 6-0GMs 7° coche + Bieta aye OG Ett acetal —— @) @) ( B- Keto eto Es Baty, Aufracede esfn CEA aupavtele) %) chet + Hehcactt a) thy te a4 A a A2, ” “ Cages + Herts tb Ge ° ° Eta outte Acetone Autyl much (am) (Redon pe dikedaw * Bayo villgar oxidefion :- ongpnie prnic oxide Afdehyla —9 carbene al repos > ESTO CF, coon (TH Fhohe powry aus aud) 4 Spy Caer ( pony ben zie aad) ¢-000H1 Al , MCPRA 2 ’a PR > FR > ph 7 Me 7h ated Pp “ts A PzC-00%) t- no cen Mee oer” hr 0 Hy ° w Cyl km, “pHs m -Chs Dd A C445 Ho t BACA,- 6-0 alls a Gylig EA ty 9 O45 4s a He/miy , ; eo eae eo B-agebony Esty 5 | “Ae H cate pages Mish FH gatas 4 %,B- whenatad EST He # Oxidation bY Se” a O, cHeg. ee) {Oth 5a o a4 n aaypxed a AH 64 3 © a Soe th Gt Mygehs 9 rs 0 “ Ne a A JS ” S - OG ee a eH CAy 6 Hh Ms oy ty G 4? eH, Tb mene neafive Tr ~Aa ee e peniodic oxidaion aH potindic. onic it cham 65 oo rep pe EN yk HCHD CHO on Poriinclelthy de EMylo fy °40) CH oA a Chor By 5 ch, nero a “Hen go ” ape ) acon o chal on Prone aud Gl te: —> HeHo } nd Oh panmdeAyde. Preto oh a Hen + Huey + Or va OD . at dontfreee + Op yo, ha rene + 2 Ave Prima) Date pak snd Zmpe tot renttin 3 ayer Bilphtc ccho| CA, fe cA, i in WR OA i Ww Reaction Wi iz, /s CHA cat CHy AD CH, a E 4 J cen AE, (<2) = li “ages at =a cA, ta CHy Ch t AL 1 ——_ _ i (ata Ga-L CH, m Ch» 4 * A Dod papant Lanprepal iodide | Retin 8K = KHSO, tne: Hay > Dehydration 1 a toy tHD wap 5? 2th “> A Thon 6 42 | t ba °H “” (4 i (CA, d ApH cH a DiulanHol ein aren’