CBSE ‘3° Meyitrereye tio} Question Ensuring Maximum Marks EAA through a Systematic Approach, Sas Preparation Assessment Zone Latest Sample Paper & 2023 Examination Paper. Proficiency Building Zone 15 Sample Papers in 3 Stages; Foundation, Proficiency & Excellence Level Exam-Eve Special Zone ° Chapterwise Quick Revision Notes & arihant One Additional Exam Pattern Sample Paper SUCCESS AND NOTHING LESS a TTT LSCBSE Exams 2024 | {Succeed | olan) el le Sede Papers = | Warihant | abhi Kaushik ; Arihant Prakashan } Ashe kau oe j (Schoo! Division Series)Arihant Prakashan (Schoo! Division Series) All Rights Reserved % ©Publisher ‘No part ofthis publication may be re-produced stored In a Yetrieval syste o by ay ‘means electronic. mechanical photocopying, recording, scanning, web or otherwie {wthout the written permission ofthe publsher, Arthant has obtained athe information Inthis book from the sources believed tobe reliable and true. 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Section 1 Section 2 Preparation Proficiency Assessment Zone Building Zone Latest CBSE Sample Paper and 2023 15 Sample Papers grouped in Three Board Question Paper, analysing your ‘Stages with the purpose of upgrading preparation on different angles, your practice in gradual manner. completing the paper within time, Stage I: Foundation Level (3 Sample understanding ‘what is exactly asked in Papers with Guided Solutions) the question’, answers as per ‘Stage Il: Proficiency Level (7 Sample eeariners expectation sfx Papers with Solutions at the end of paper) ‘Stage Il: Excellence Level (5 Sample Papers without Solutions) Section 3 pL Exam-Eve Special Zone Itis very important to utilize the day before the exam efficiently. This Section has Exam-Eve Revision (Chapterwise Quick Revision Notes) and Exam-Eve Practice, an additional sample paper, helping students to revise efficiently and engage in last- minute practice. 8y following this plan, you can enhance your preparation, improve understanding of the subject and can be sure of performing well board examination.cere mapa Sita a el oe Navigation Details Section 1 PREPARATION ASSESSMENT ZONE ta —_————————— Latest CBSE Sample Paper 38 CBSE Examination Paper 2023 3a Section 2 PROFICIENCY BUILDING ZONE = STAGE! Sample Question Paper 1 Sample Question Paper 2 Sou Sample Question Paper 3 en = STAGE II Sample Question Paper 4 596 ‘ample Question Paper 5 __ Toaur Sample Question Paper 6 Bh Sample Question Paper 7 ~ orth Sample Question Paper 8 —_ 1024 ‘Sample Question Paper 9 114-1001 Sample Question Paper 10 12513 ™ STAGE Ill sample Question Paper 11 13646 ‘Sample Question Paper 12 " sa) Sample Question Paper 13 148-153 Sample Question Paper 1414-154 ‘Sample Question Paper 15 160-165 a Section 3 EXAM-EVE SPECIAL ZONE 16721, al i Exam-Eve Revision 169201 Exam-Eve Practice 20821Course Structure S.No. ' 10 nit th nitty Marks | Periods Solutions | ? Electrochemistry iz i Chemical Kinetics o ; 4 and / Block Elements 1 ay Coordination Compounds a ; Haloatkanes and Haloarenes ‘8 o Alcohols Phenols and Ethers a z Aldehydes, Ketones and Carboxylic Acids | s Amines wo | 6 Biomolecules ‘3 7 Total a Solutions 10 Periods Sita tanteyetbtession of concentration of solutions of solids in quid, slubilty of gases in iquids sola dearest rece Ris reactive towards nucleophilic addition half order w..t‘P’ and zero order w.rt reactions, why? ‘Q.. What is the unit of rate constant for (b) Write the structure of the product formed when ‘his reaction’? acetone reacts with 2,4-DNP reagent. i Or Convert the following. 18. A5% solution of Na;SO4 -10H,0 (molecular weight = 322) is isotonic with (2) Benzene to mrnitrobenzaldehyde 2% solution of non-electrolytic, () Bromobenzene to benzoic acid non-volatile substance X. Find out the 21. (a) DNA fingerprinting is used to determine molecular weight of X. paternity of an individual. Which property of DNA helps in the procedure? 19. (a) Arrange the isomeric dichlorobenzene in the increasing order of their boiling point and melting points. ™Section C This section contains 7 questions with internal choice in one question. The following questions are + short answer type and carry 3 marks each. (b) What structural change will occur when a native protein is subjected to change in pH? 22. (a) Write the formula for the following (b) Does ionisation isomer for the following coordination compound. compound exist? Justify your answer. Bis(ethane-1,2-diamine)dihydroxidochro HgICo(SCn),4] mium (Ill) chloride (c) Is the central metal atom in coordination complexes a Lewis acid or a Lewis base? Explain.23. (a) Can we construct an electrochemical cell with two haif-cells composed of ZnSO, solution and zinc electrodes? Explain your answer. Calculate the i'm for Cl ton from the data given below XmeMiga,) = 288.6 S em?mol! and Xowdtg?*) =106S cm?mott The cell constant of a conductivity cell is 0.146 cr ', What is the conductivity of 0.01 M solution of an electrolyte at 298 K. if the resistance of the cell is 1000 ohm? ) © 24, Write the name of the reaction, structure and IUPAC name of the product formed when (a) phenol reacts with CHCIs in the presence of NaOH followed by hydrolysis. (b) CH3CH.CH(CHs)CH (CHs)ONa reacts with C:H5Br You are given four organic compounds 4, B, Cand D. The compounds A, B and C form an orange- red precipitate with 2, 4-DNP reagent. Compounds 4 and B reduce Tollen’s reagent while compounds C and D do not. Both B and C give a yellow precipitate when. heated with iodine in the presence of NaOH. Compound D gives brisk effervescence with sodium bicarbonate solution. Identify 4, B, C Section D ‘The following questions are case-based questions. Each question has an internal choice and carries 4{1+1+2) marks each. Read the passage carefully and answer the questions that follow. 29. Crystal Field Splitting by Various Ligands Metal complexes show different colours due tod-d transitions. The complex absorbs light of specific wavelength to promote the electron from t2, to e, level. The colour of the complex is due to the transmitted light, which is complementary of the colour absorbed. The wave number of light absorbed by different complexes of Cr ion are given below. Complex Wt sbsorbed 0") Seemed (Simo cea, 13640 163 (cro, 17830 2» Tere 7680 29 26280 ms 26. 27. 28. Answer the following questions. (a) Or ) (©) Chemistry Class: and D given the number of carbon atoms in’ |¢ three of these carbon compounds is three while one has two carbon atoms. Give an, explanation for your answer, When sucrose is hydrolysed the optical rotation values are measured using a polarimeter and are given in the following table sno. Time (hours) Specific rotation — (a) Account for the two specific rotation values, (b) What is the specific name given to sucros, based on the above observation? (c) One of the products formed during the hydrolysis of sucrose is a glucose, that reacts with hydroxylamine to give compound A. Identify compound A. ‘An organic compound A with the molecular formula (+) C4HgBr undergoes hydrolysis to form (+) C4Hg OH. Give the structure of A and write the mechanism of the reaction. The rate constants of a reaction at 200K and 500K are 0.02s"' and 0.20s” respectively. Calculate the value of Eg. (Given : 2.303 R= 19.15 JK“'mol) Out of the ligands 4, B, C and D which ligand causes maximum crystal field splitting? Why?| Which of the two, A or D will be a weak field ligand? Why? Which of the complexes will be violet in colour? [CrAg]*~ or {CrBg}** and why? (Given: If 560 - 570 nm of light is the colour of the complex observed is violet.) If the ligands attached to Cr3* ion in the complexes given in the table above are watef, cyanide ion, chloride ion, and ammonia (not in this order). Identify the ligand, write the formula and IUPAC name of the following. () [CrAgl (ii) (rc)iSucceed Latest CBSE Sample Paper 30. The lead-acid battery represents the oldest rechargeable battery technology. Lead acid batteries can be found in a wide variety of applications including small-scale power storage such as UPS systems, ignition power sources for automobiles, along with large, grid-scale power systems, ‘The spongy lead act as the anode and lead dioxide as the cathode. Aqueous sulphuric acid fs used as an electrolyte. The half-reactions during discharging of lead storage cells are At anode, Pb(s) + SO} (aq) —» PbSO4(s) + 2e" At cathode, PbO>(s) +4H"(aq) + SO} (aq) +2e° —> PbSO,(s) +2H 20 There is no safe way of disposal and these batteries end - up in landfills. Lead and sulphuric acid are extremely hazardous and pollute soil, water as well as air. Irrespective of the environmental challenges it poses, lead-acid batteries have remained an important source of energy. Designing green and sustainable battery systems as alternatives to conventional means remains relevant. Fuel cells are seen as the future source of energy. Hydrogen is considered a green fuel. Problem with fuel cells at present is the storage of hydrogen. Currently, ammonia and methanol are being used as a source of hydrogen for fuel cell. These are obtained industrially, so add to the environmental issues. : mSection E 31. Attempt any five of the following. (a) Which of the following ions will have a magnetic moment value of 173 BM? se, 18, Ti", Cu’, zn?* (©) In order to protect iron from corrosion, which one will you prefer as a sacrificial electrode, Ni or Zn? Why? (Given : Standard electrode potentials of Ni, Fe and Zn are -0.25 V, -0.44 V and -0.76 V respectively.) Or If the problem of storage of hydrogen is overcome, is it still a "green fuel"? Despite being the most abundant element in the Universe, hydrogen does not exist on its own, so needs to be extracted from the water using electrolysis or separated from carbon fossil fuels. Both of these processes require a significant amount of energy which is currently more than that gained from the hydrogen itself. In addition, this extraction typically requires the use of fossil fuels. More research is being conducted in this field to solve these problems. Despite the problem of no good means to extract. hydrogen, it is a uniquely abundant and renewable source of energy, perfect for our future zero-carbon needs. Answer the following questions. {a) How many coulombs have been transferred from anode to cathode in order to consume one mole of sulphuric acid uring the discharging of lead storage cell? (b) How much work can be extracted by using lead storage cell if each cell delivers about 2.0 V of voltage? (I F = 96500 C) (©) Do you agree with the statement-"Hydrogen is a green fuel.” Give your comments for and against this statement and justify your views. Imagine you are a member of an agency funding scientific research. Which of the following projects will you fund and why? (a) Safe recycling of lead batteries (b) Extraction of hydrogen The following questions are long answer type and carry 5 marks each. All questions have an internal choice. (©) The second ionisation enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Mn. (d) Give two similarities in the properties of Sc and Zn. (©) What is actinoid contraction? What causes actinoid contraction? (0) What is the oxidation state of chromium in chromate ion and dichromate ion? (g) Write the ionic equation for reaction of KI with acidified KMn0,.8 Preparation Assessment Zone 32. (a) What is the effect of temperature on the solubility of glucose in water? (©) Ibrahim collected 10mL each of fresh water and ocean water. He observed that one sample labelled F froze at 0°C while the other Q at -1.3°C. Ibrahim forgot which of the two, P or Qwas ocean water. Help him identify which container contains ocean water, giving rationalisation for your answer. (©) Calculate van't Hoff factor for an aqueous solution of Ks(Fe(CN)gl if the degree of dissociation («) is 0.852. What will be the boiling point of this solution if its concentration is I molal? (Ky = 0.52 K kg mol) Or (a) What type of deviation from Raoult’s law is expected when phenol and aniline are mixed with each other? What change in the net volume of the mixture is expected? Graphically represent the deviation. (b) The vapour pressure of pure water at a certain temperature is 23.80 mm Hg. If1 mole of a non- volatile non- electrolytic solute is dissolved in 100g water, calculate the resultant vapour pressure of the solution. Hints & Solutions 1. (b) 0.1 MHCI solution have highest conductivity at 298 K. Conductivity is highest for strong electrolyte. It decreases with dilution, 20 ° This reaction is an example of crossed aldol condensation reaction. 7 ‘3. (4) Fat soluble vitamins can be stored in our body. eg. Vitamin A, D, E and K. 4 mcnicme—C—cr 2 cH, S-ucthypént Sen -2-one a cH,cH. C;H;NO, exists in three isomeric forms, the — isomer ‘A’ has the highest melting point o} three. ‘A’ on reduction gives compound ‘B! with molecular formula C7HoN. ‘B' on treatment with NaNO> /HCl at 0-5 °C to fe compound’'C’, On treating C with HsPO,, it gets converted to D with formula C7Hg, whie on further reaction with CrO2Cl; followed: hydrolysis forms ‘E’ C7H,0. Write the str of compounds A to E. Write the chemical equations involved. or (a) Account for the following. (i) N-ethylbenzenesulphonyl amide is soluble in alkali. (ii) Reduction of nitrobenzene using Fe and HClis preferred over Sn and HCl. (b) Arrange the following in (i decreasing order of pK values GgHsNH,, CgHsNHCHs , CgHsCH)NH,, CHsNHp , NH3 (ii) increasing order of solubility in water (CyHsC1, CoHsNHp, CoHsOH (iii) decreasing boiling point HCOOH, CzHsOH, CH3NH> , CH,0CH, 1 cer 5. (b) Statement (b) is incorrect as carbon magnesium bond is polar in nature. 6. (a) The correct match is (i)-(r), (i)-q,(iti-p. () The lowest enthalpy of atomisation is of Zn. As it has no unpaired electrons in 3s or 4s-orbital i) In 3d-series the maximum oxidation state is shown by Mnasit has 5 unpaired of electron in 3d-orbita.{Succeed Latest CBSE Sample Paper (ii) tn the ground state of Se, tt has one electron in the Ad-subshell, but in its common oxidation state it has no electron int Ad-subshell, Hence, tt does ‘not form coloured compounet 7. (b) Molecularity is a theoreti applicable to elementary reacti reaction, it has no meaning, 8. (©) Water 9 @) or 2 pens thunal I concept. It is For complex. CHO The 2-phenyl ethanol is a primary alcohol, and primary alcohols do not produce turbidity at room temperature 10. (a) Initial concentration of A= 1.5 M Final concentration of | A=0.75 M, Time = 1205 [R= [8] _ 150-075 t 120 For zero order reaction, k = =%75 000625 mol L's“! 20 LL, (a) The given reaction occurs because of the activation of benzene ring by the methoxy group . 12. (Q) The given graph is for atomic radii, Atomic radii decrease with increase in atomic number. However, at the end of the series, sizeof elements increases due to the increases in the magnitude of repulsive forces between electrons, 13. (¢) (A) is true but (R) is false. The correct (R) is : The bond between C—Ois broken when alcohol reacts as electrophiles. 14. (b) Both (A) and (R) are true but (R) is not the correct explanation of (A). 15. (b) Both (A) and (R) are true but (R) is not the correct explanation of (A). Each enzyme contains an active site which has specific shape and size. 16. (a) (A) is false but (R) is true. As during electrolysis of aqueous copper sulphate solution using copper electrode, copper is deposited at cathode. 17. (a) Given : Half-life of X =12 he Half-life of ¥ =16hr Time = 2 days = 48 hours For first order reaction, Half-life of X after 2 days = 4 4 Amount of X left after 4 half lives = 4 of initial value half-life of Yafter 2 days = =3 Amount of ¥ left after 3 half lives =" of initial value - Ratio of Ne = 1:2 w (0) For the reaction, P+Q—» R Rate = kP}"[QI" = Kp General formula for determination of unit is mol! "17's! é fue So, for 5 order reaction, unit is mol? L-"/*s w 18. Molecular mass of Na,SO, -10H,0 = 322 For isotonic solution osmotie pressure is same. “m (Na,S0, 10 HO) = x (non-electrolyte) * iC\RT = CRT For NazS0, 10 H,0, = = x 322 3x5 [where, M =molecular weight of non-electrolyte] =429g ‘Thus, the molecular weight of non electrolyte is 42.9g, @ 19. (a) m-dichlorobenzene < 0 -dichlorobenzene < p-dichlorobenzene. ‘The p-isomer have high melting point as. ‘compared to o- and m-isomer. This is due to the symmetry of p-isomer compared to m-and o-isomers. (ara) (b) The resonance structure of haloarenes are “EL * ‘The electron density in haloarenes increases more at o- and p-positons than at m-positions. Hence, electrophilic reactions occur at o- and P-position. The halogen atom has the tendency to withdraw electrons due to which electron density on benzene ring decreases (-I-effect ) and the ring gets deactivate. Hence, eletrophilic substitution in haloarenes ‘occurs at a slow rate aw10 20. (a) prnitrobenzaldchyde is more reactive towards, the nucleophilic addition reaction than p-tolualdehyde as —NO, group is electron withdrawing in nature. Presence of nitro group decreases electron density. Hence, facilitates the attack of nucleophile Presence of —CH, leads to + I-effect as CH, is electron donating group. a ® No, No, NHNH, NH=(CHy)s cH,Coct, + 7 ‘cetone) ON seDNP reagent ON @ or (a) Benzene to m-nitrobenzaldehyde (b) Bromobenzene to benzoic acid eg Dryer Bromabensene MgBr co, wie Benzo acid (1) 21. (@) A sequence of bases on DNA is unique for a person and is the genetic material which is transferred to the individual from the parent. This helps in the determination of paternity. (1) (b) When a native protein is subjected to change in pH, the denaturation of secondary and tertiary structure of protein takes place. Whereas the primary structure remains intact. @ 22. (a) [Cr(en),(OH),] Cl or [Cr(H,NCH,CH,NH;),(OH),]CL @ () In the given compound ionisation isomers are not possible. This is because ionisation isomers are possible by exchange of ligand with counter ion only and not by exchange of central metal ion. @ (©) The central metal in coordination complexes is ‘act as a electron pair acceptor, Thus, it behaves as Lewis acid. a 23. (a) Yes, we can construct an electrochemical celf the concentration of ZnSO, in the two half-cell is different, the electrode potential will be different making the cell possible. (©) Given, Avgoygct ,) = 258.6 S.cm* mol”? w 25. 26. “= Chemistry Class) Rgynyg?s) * 106 8.6m mol Naawiects) ™ % nent?) * ery 1066220), Auch = 763 Sem? mol" ‘é (©) Given, cell constant, G* = 0.146 em" Resistivity, R= 1000 ohm Also, G = kx R n-2 oa A610 “Sem! (a) Phenol reacts with CHCl, in the presence of NaOH followed by hydrolysis form 2-hydroxy benzaldehyde. This reaction is known as Reimer-Tiemann, on cHo NAOH, + CHCl pata Phevat "hydroxy bemzallehyde (6) Alkoxide reacts with alkyl halide to form on This reaction is called Williamson's synthesis, (CHCH;CH(CH)CH(CHg)ONa + C,HsBr —> CH,CH,CH(CH,)CH(CH,)0C,H, 2-ethoxy-2-methylpentane (1) According to the question, A, Band C, contain carbonyl group as they form an orange-red precipitate with 2,4-DNP reagent. A and B reduces Tollen’s reagent, thus they are aldehydes. Cis a ketone as it contains carbonyl group but does not give positive Tollen’s test. As C gives positive iodoform test , thus it is a methyl ketone. B gives positive iodoform test, thus it is an aldehyde. Dis a carboxylic acid , as it gives brisk effervescence with bicarbonate solution. Since, the number of carbons in the compounds A, B, C and Dis either three or two, therefore B is CHyCHO.s this is the only aldehyde which gives a positive iodoform test. ‘The remaining compounds A, C; and Dhave thee carbons. ‘A=CH,CH,CHO, C=CH,COCH, ; D=CH,CH, COOH) (a) Sucrose is dextorotatory but after hydrolysis, gives dextrotarotory glucose and leavorotatory fructose. Since, the laevorotation of fructose (-92.4° is more than dextrorotation of glucose (+52.5°), the mixture is laevorotatory. @ (b) The hydrolysis of sucrose brings about a change it the sign of rotation from dextro (+) to laevo(-) and the the product is named as invert sugar. (1)i Succeed Latest CBSE Sample Paper cu cH =N—on | sont (©) (CHOH), > (CHOW), CH,OH CH,OH oxime The product A is CH =N—OH. (CHOM), | CH,OH w 27. ‘The structure of Ais CjHsCH—CHs, ! @ cH, @) ‘og oe | 0.02 2.303R| 200 500. ata) 200% 500 E log 10 =. * Bal 1915 200% 500 a 6383) mol 29. (a) Energy is directly proprotional to the wave number . Maximum energy of light is required for an electron to jump form tz, to €, in case of (Crd, a Or Aweak field ligand causes the splitting of energy orbital (et, ande,) with minimum extent Hence, A is a weak field ligand on the energy required is minimum, @ (b) For [CrB,]**, wavelength of light absorbed =—_a7351m, 13640 Preparation Assessment Zone nN Thus, Fo [CxB,]"" complex is violet in colour. (4) (6) A=CI (weak field ligand ), B= 1,0, C= NH, D=CN (strong field ligand ) (i) [CrCIg]’ = Hexachloridochromate (111) ion (ii) [Cr(NH, )]"*=Hexaamminechromium (11) ion (2) 30. (a) As, 2 Faradays (or 2 mol ) have been transferred from anode to cathode to consume 2 moles of H,S0, Therefore, 1 mole of H,SO, required 1 Faraday of electricity or 96500 coulombs a (0) Given , E° = 2V, n-2, F = 96500 Wray = —RFE® =~ 2 96500% 2 = ~ 386000 J Then, 386000 J of work can be extracted using lead storage cell when the cell is in use. a (© Both Yes and No should be accepted as correct answer. Hydrogen is a green fuel. On combustion it emits water vapour and leaves no residue in the air However, at present there is no green method to obtain hydrogen. It is obtained by electrolysis of ‘water which use electricity obtained from fossil fuels. @ Or (a) Safe recycling of lead batteries. Lead batteries are widely used batteries but their disposal is an issue because currently, these are being thrown into landfills and no safe method of disposal or recyling exists. Research on this project will lead to reducing the pollution and health hazards. (b) Fuel cell is a clean source of energy but the current problem is obtaining/extraction of hydrogen. Research on this project will reduce the pollution problem and find a sustainable solution. @ ‘34. (a) Among the given option, Ti?* and Cu* have 1 unpaired of electron. Thus , their magnetic moment is 1.73 or V3. (©) Zine can be used as sacrificial metals as, it is more reactive than iron and lose its electrons in preference to iron. This prevent iron from losing. its electrons and becoming oxidised. (©) Electronic configuration of Mn* = 34°4s" Electronic configuration of Cr” =3d° As Cr” has stable half-filled electronic configuration thus, it requires more ionisation energy to remove electron from stable configuration whereas, Ma” hhas 1 electron in 4s" which can easily be removed. ‘Thus, its ionisation energy is less (@) Se in its common +3 oxidation state has no clectron in 3¢-orbital and Zn has no unpaired electron in its 3d-orbital in either its atomic state fr ionic state. Thus, both Sc and Zn form colourless compound and are diamagnetic(©) The radii of trivalent and quadtivalent ions of actinoids contract slightly with increasing atomic number. This contraction is known as actinoid contraction. This results from poor shielding experienced by 5f-electrons. () The oxidation state in chromate ion [Cr,0;"} and dichromate ion [Cr,0"] is +3 and +6 respectively. (8) 2Mn0, +10f +6H* —+ 2Mn** +8H,0+51, (5) ‘32. (a) The solubility of glucose in water, increases with increase in temperature. a (b) Qis ocean water because due to the presence of salts it freezes at lower temperature (depression in freezing point). @ (©) Degree of dissociation of K,{Fe(CN),] =0852 Ky =052K kg / mol K,[Fe(CN),] gives 4 ions in aqueous solution i=1+(n-1)0 +(4-1)*0852=3556 ym =3556%052x1=185C 100 +1.85C =10185°C @ Or (a) The negative deviation is expected when phenol and aniline are mixed with each other. The net volume of the mixture will decrease, (AV =0) due to stronger intermolecular interactions. ‘Mole faction iat Hao tend url »p. 1. diagram for solutions showing negative ‘deviation from Raoult’s law ay (b) Vapour pressure of pure water = 2380 mmHg Amount of non-volatile electrolyte solute =1 mol ‘Amount of water =100 g ‘We know, relative lowering of vapour pressure 3 EP) ary oT and =O nm, =100/18 =555 xy=—_ = wos mem 565 p= 238 mmHg Relative lowering of vapour pressure = 25-2 -onis 23 2380~p =0428 p=238-0428= 2337 mmHg (24) 33. Chemistry C2: 7 Compound having molecular formula C;H,NO; 1 oH, Q J exists in three isomeric forms (o. p and mere No, forms). ‘Among these 3 forms, (A) p-methyinitrobenzene bay point due to greater symmetr; a eee Porth Sa/HIC i reduced to C-H,X ie. (p-methylbenzenamine) (B). (B) on treatment with NaNO/HCI forms diazorsem ax{ > 4 « ‘NO; a a o ° i ca we, a . - F o e 3 Or (@) (@) The hydrogen attached to nitrogen in N-ethylbenzene sulphonylamide is strongly acidic in nature due to the presence of strong electron withdrawing group. Le. sulphonyl group. ‘ Hence, itis soluble in alkali a (Gi) Reduction of nitrobenzene using Fe and HO is preferred because FeCl, formed during reaction get hydrolysed to release HCL ‘Thus, only a small amount of HC! is requ! to initiate the reaction. 5 (b) (i) Higher the pK, value, weaker is the base. Decreasing order of pKyvalue is C(HNH, > CJH,NHCH, >NH, >CgHsCH,NH,> CH3NH; (ii) Increasing order of solubility in water. C,HsCl C3H,OH > CH,NH,> CHO SECBSE 2023 neti men Time : 3 hrs Max. Marks : 70 4. This question paper contains 35 questions. All questions are compulsory. 2, Question paper is divided into FIVE sections, Section A, B,C, D and E 3. In Section-A, Q. no. 1 to 18 are Multiple Choice Questions (MCQ) carrying 1 mark each. 4 In Section-B, @. no. 19 to 25 are Very Short Answer (VSA) type questions carrying 2 marks each. 5. In Section-C. Q. no. 26 to 30 are Short Answer (SA) type questions carrying 3 marks each. 6 In Section-D, Q. no. 31 and 30 are Case-Based Questions carrying 4 marks each. 7. In Section-E, Q.no. 31 to 32 are Long Answer (LA) type questions carrying 5 marks each 8 There is no overall choice. However, an internal choice has been provided in 2 question in Section-B, 2 question in Section-C, 2 questions in Section-D and 2 question in Section-E. mSection A 1. Acompound undergoes complete tetramerisation in a given organic solvent. The van't Hoff factor is (40 (e025 (0125 (a) 20 2. The half-life for a zero order reaction equals 2k Lk R R = Le, cas a ® OF OR OF OF (where, Ris the initial concentration.) 3. Which of the following structures represents a-D - glucose ? — _ iH H H 0, OH “Ke Dh Ko») OH OH OH iH iH OH H OH 4. The ions of metals of Group 12 (Zn, Cd and Hg) have completely filled d-orbitals and so they (@) behave like semiconductors (b) are very high melting solids (©) do not behave like transition metals (@) behave like super conductors 5. [Co(NHg);NO3] SO, and [Co(NHg)sSO4)NO3 exhibit (@) linkage isomerism (b) ionisation isomerism (© optical isomerism (@ coordination isomerism. 6. Reaction of 1 phenyl -2-chloropropane with alcoholic KOH gives mainly (@) 1-phenyl propene (b) 3-phenylpropene (©) phenyl propan -3-ol (@) 1- phenyl propane -2-ol10. i When diethylether is heated with excess of Hl, it produces (a) ethanol (©) todoform (6) methyl iodide (d) ethyl iodide . The reduction of ethane nitrile with sodium and alcohol gives (@) 1- aminopropane (b) 1- aminoethane (©) ethanoie acid (¢) ethanamide . How many faradays are required to reduce 1 mole of MnO, to Mn?* ? 4 3 6 @s5 In a reaction, the initial concentration of the reactants increases four fold and the rate becomes sixteen times its initial value. The order of the reaction is (20 35 1s 2s On hydrolysis, which of the following carbohydrates gives only glucose ? (@) Maltose (b) Sucrose (c) Lactose (@) Galactose Deficiency of which of the following vitamins causes pernicious anaemia ? (@) Vitamin B, () Vitamin B, (©) Vitamin By (@ Vitamin By» CgHsCHO + CHgCOCHg a, CgHsCH =CH — COCH3 ‘This reaction is known as (a) Aldol condensation (b) Cross-Aldol condensation (©) Cannizzaro’s reaction (@) Friedel-Crafts reaction m Section B 19. ‘An alkyl halide (4) of molecular formula C@HjgCl on treatment with alcoholic KOH gives two isomeric alkenes (B) and (C) of molecular formula CeHy2- Both alkenes on hydrogenation given 2, 3-dimethyl butane, Write the structures of (4), (B) and (C). 14. _ Chemistry Class). jy In which of the following does the central atom exhibit an oxidation state of +3? (@) K,INKCN)) WK [FACNg} (©) [FCO 1 (@) (CueNH)P* 2 Direction (Q. Nos. 16-18) In the following question, 2 as Assertion (A) is followed by a corresponding Reason (R). Use the following keys to choice the appropriate answer. 15. 16. 17. 18. {a) Both (A) and (R) are true, (R) is the corre explanation of (A). (b) Both (A) and (R) are true, (R) is not the 2 correct explanation of (A). (6) (A) is true, (R) is false (a) (A) is false, (R) is true. Assertion (A) When NaCl is added to water,, depression in freezing point is observed. Reason (R) The lowering of vapour pressure of a solution causes depression in the freezing point. i Assertion (A) A,, for weak electrolytes shows a sharp decrease when the electrolytic solution is diluted. Reason (R) For weak electrolytes, degree of dissociation increases with dilution of solution. Assertion (A) Zr and Hf have almost identical radii. Reason (R) Both Zr and Hf exhibit similar properties. Assertion (A) Monobromination of aniline can be conveniently done by protecting the amino group by acetylation. Reason (R) Acetylation decreases the activating effect of the amino group. What type of deviation from Raoutt’s laws shown by a mixture of ethanol and acetone! Give reason. Or Define azeotrope. What type of azeotrope § formed by negative deviation from Raoult’ law? Give reason.i Succeed CBSE 2023 Examination Paper 21. Name the cell which (2) was used in Apollo space programme. () is used in automobiles and inverters. () is suitable for hearing aids and watches (€) does not give a steady potential and is used in transistors. The rate constant for the first order decomposition of NOs is given by the x10" following equation, log k = 236 - 2 aoe Calculate £, for this reaction. [R=8314)K* mol] Write the mechanism of the following reaction. CH, =CH, +H,0—#, cH,CH,OH Section C 26. (a) Write hydroboration-oxidation reaction with an example. (b) Write the products of the following reaction. /OCHs Ce (©) Why is p-nitrophenol more acidic than phenol ? Or (a) What happens when phenol reacts with 1. Cone. HNOg and 2. CHCl, in presence of aqueous NaOH followed by acidification ? Write equations only. (b) Why does the reaction of CH3ONa with (CH), —Br give 2-methyl propene and not (CHy);C—OCH,? 27. Account for the following. (a) Benzyl chloride is highly reactive towards Sylreaction. (b) (¢)- Butan-2-ol is optically inactive, though it contains a chiral carbon atom. (©) Chloroform is stored in closed dark coloured bottles. 28. Answer any three of the following questions. (a) Explain the type of hybridization in IFe(CN)g]*" on the basis of valence bond theory . (Given : Atomic number of Fe = 26) 24. 25. 29. 30. Preparation Assessment Zone 5 Write the products of the following reactions cHO ocr “cone NOH, o oy + H,NNH—CO—NH, 4+ Or Do the following conversion in not more than two steps. (a) Toluene to Benzoic acid (b) Benzaldehyde to 1-phenylethanol Write IUPAC names of the following coordination entities. (2) [Co(NHs),CKNOz)ICL__ (b){PtClx(en)?* (b) Draw the geometrical isomers of [PtCl,(en),|** ion. (c) [NiCl, is paramagnetic, while [Ni(CO),] is diamagnetic though both are tetrahedral. Why? (d) Name the type of isomerism when ambidentate ligands are attached to central metal ion. Give one example of ambidentate ligand. If benzoic acid (M =122 g mol) is associated into a dimer when dissolved in benzene and the osmotic pressure of a solution of 6.1 g of benzoic acid in 100 mL benzene is 6.5 atm at 27°C, then what is the percentage association of benzoic acid ? (Give, R = 0.0821 L atm K* mol”) The following data were obtained during the first order thermal decomposition of C7HsCl at a constant volume. CoH sCl(g) —+ CoH (g) +HCl(g) Experiment Time(s~') Total Pressure (atm ) 1 ° 4 2 100 06 Calculate the rate constant. (Gives, log 2 =0.3010 , log 3 =0.471, log 4=0.6021)mSection D ‘The following questions are case-based questions. Read the case carefully and answer the questions that follows. 31. Living system are made up of various complex biomolecules like carbohydrates, proteins, nucleic acids , lipids, ete. Carbohydrates are optically active polyhydroxy aldehydes or ketones or molecules which provide such units on hydrolysis . They are broadly classified into three groups - monosaccharides, oligosaccharides and polysaccharide. Monosaccharides are held together by glycosidic linkages to form disaccharides like sucrose, maltose or polysaccharide like starch and cellulose. Another biomolecule : proteins are polymers of a-amino acids which are linked by peptide bonds. Then, amino acids are called essential amino acids. Structure and shaps of proteins can be studied at four different levels ie. primary, secondary, tertiary and quaternary each level being more complex than the previous one. Answer the following questions. (a) What is the difference between a glycosidic linkage and peptide linkage? (b) Which amino acids are called essential amino acids? (c) What are the common types of secondary structures of proteins ? Write any two forces which stabilise the secondary and tertiary structures of protein. Or (c) Define denaturation of protein with an ‘example. During denaturation which structures of protein lose their biological activity ? 32. Amines are usually formed from nitro compounds , halides, amides, imides, etc. They exhibit hydrogen bonding which influence their physical properties. In alkyl amines, a combination of electron releasing, steric and hydrogen bonding factors influence the stability of the substituted ammonium cations in protic polar solvents and thus affect the basic nature of amines, j, aromatic amines, electron releasing and withdrawing groups , respectively increase and decrease their basic character. Influence of the number of hydrogen atoms at nitrogen atom on the type of reactions and nature of products is responsible for identification and distinction between primary, secondary and tertiary amines, Presence of amino group in aromatic ring enhances reactivity of the aromatic amines. Aryl diazonium salts provide advantageous methods for producing aryl halides, cyanides, phenols and arenes by reductive removal of the diazo group. Answer the following questions. (a) Arrange the following in the increasing order of their pK, value in aqueous solution. CaHsNHz, (C2Hs)2NH, (Cos )3N (b) Aniline on nitration gives a substantial amongst of m-nitroaniline, though amino group is 0/p directing. Why ? (©) An aromatic compound ‘4’ of molecular formula C7H,02 on treatment with aqueous ammonia and heating forms compound 'Z ‘Compound ‘B’ on heating with Br, and aqueous KOH gives a compound ‘C’ of molecular formula CgH;N Write the structures of 4, B and C. Or ‘Complete the following relations by giving main products. NHg (a) + Bro(ag)— Nic HBF. ®) (i) NaNO,/Cu, &mSection E 33. (a) Calculate the emf of the following cell at 298K AK(s)|A15*(0.001M)|Ni*7(0.1M)/Ni(s) [Given, Eye. 4 = -L66V, Eq? xy = -0.25V, log 0 =I) (b) With the help of a graph explain why it is not possible to determine Aj, for a weak electrolyte by extrapolating the molar conductivity (Aq) versus C!? curve as for strong electrolyte? Or (a) The molar conductivities of NHj and CI” ion are 73.8 cm*mol! and 76.2 S cm? mol respectively. The conductivity of 0.1 M NH,Clis 1.29107S cm", Calculate its molar conductivity and degree of dissociation. (b) Calculate the half-cell potential at 298K for the reaction. Zn?* +2e-—+ Zn If[Zn?*] =01M and E3,2- 7, --0.76V- ro 34. (a) Account for the following. @ Zn** salts are colourless, while Ni?* salts are coloured. (ii) Cr?* is a strong reducing agent. (ii) Transition metals and their compounds show catalytic activities. 35. (b) Write the ionic equations for the oxidising. action of MnO, in acidic medium with (1) I> fon and (2) Fe? ion Or (a) Name two oxometal anions of the 3d-series of the transition metals in which the metal exhibits the oxidation state equal to its ‘groups number. (b) What is the effect of increasing pHon a solution of K,Cr;0;? (c) Why is Cu* not stable in aqueous solution ? (4) Name a member of lanthanoid series which is well known to exhibit +4 oxidation state. (e) Name two elements of 34-series which show anomalous electronic configurations. (a) Draw structure of the 2, 4 - dinitro phenyl hydrazone of benzaldehyde. (b) Which acid of the following pair is a stronger acid ? Fac (coon or Hc—{) coon (©) Write the chemical equation involved in Rosenmund reduction. (d) Why are a-hydrogen atoms of aldehydes and ketones acidic in nature ? {e) Write a chemical test to distinguish between benzaldehyde and benzoic acid.1. (b) Let the given compound which undergoes complete tetramerisation be A. The reaction is 1A —> Ay or Am ta ‘ Aree ot ° ALter o : ‘ (Sts) coos . 4 k 2. (a) The half-life of zero order reaction is > 3. (a) The correct structure of a-D-glucose is: cH,OH nf on HOP __ Won HOW 4, (0) 2n, Cd, and Hig do not behave like transition metals as they have completely filled d-orbitals. 5. (0) lonisation isomerism. 6. (a) The reaction of 1-phenyl-2 chloropropane reacts with alcoholic KOH to form I-phenyl propene cay he J" wa ee = Gad Ties Jphenyl-2-chloropropane I tephenyl propene 7. (d) The reaction is ethyl iodide, CH,CH,OCH,CH,+ 2HI —+ CH,CH,NH, +H,0 Diethyl ether thy oie 8. (0) CHyCmn 64 (H] Ml CHCH,NH, thane nitrile ‘amino ethane 9. (a) The balanced chemical equation is MnO, 48H" +5e” —+ Mn +440 From the above equation we can see, to reduce one mole of MnO,, 5 electrons are required Hence, 5 Faradays of electricity is required. 10. (a) 4 = KAI" no Kay \ On dividing, Fa, (i) by Ea.) we get 164, A (where x = order of reaction) —{7,=14g 4 16=4" x2 11. (a) Maltose on hydrolysis yields two moles of a-D plucose CygH 201) +H,0 “> 26414,.0, Deiuoe 12. (d) Vitamin By 13. (b) Cross aldol condensation 14. (c)[Fe(C,0,)s}” xt (-2x3=-3 x-6=-3 6-3=+3 15. (a) Both (A) and (R) are true and (R) is the correct explanation of (A). When NaCl is added to water, depression in freezing point is observed due to lowering of vapour pressure of solution. 16. (a) (A) is false, but (R) is true. Because Ay, for weak electrolytes shows a sharp increase when the electrolytic solution is diluted. 17. (#) Both (A) and (R) are true but (R) is not the corres explanation of (A). Zr and Hf have almost identical radii because of the presence of lanthanoid contraction. 18. (a) Both (A) and (R) are true and (R) is the correct explanation of (A). 19. ‘The reaction takes place as follows wiceth, HC CH oy 6 cr, AEA, cH, C=C —CH + an 2, 3imethylbut2ene 2chloro-2-dimethylbutane ® “) HCH WC CH cH,—C—CH—cH, 4 PBB CHC —CH-Cth 2,34imethytbutane "2, 5.dimethylbutl-e* oO{Succeed CBSE 2023 Examination Paper 20. A mixture of ethanol and acetone shows positive ‘deviation because in this case, A— B interactions are ‘weaker than A—A and B—B interactions. Due to this, vapour pressure increases which results in positive deviation Or ‘Aneotropes are binary mixtures having the same ‘composition in liquid and vapour phase and boil at constant temperatures. Azcotropes showing negative deviation from Raoult’s law form maximum boiling azeotropes at a specific composition. e.g. Azeotrope formed from nitric acid and water, Azeotropes showing positive deviation from Raoult's Jaw form minimum boiling azeotropes at a specific composition, eg Ethanol-water mixture 24. (a) Fuel cell (0) Lead storage cell (©) Mercury cell (@ Leclanche cell is commonly used in transistors. 22. A general equation relating log with E, is E, . logk =loga - ae oo) ii) 2303RT oT E, =2x10' x 2303 8314 =382, 942.84 J mol! 23. Mechanism involves in the given reaction is as follows H,0+1 —+1,0° H 4 Mole chat mat 8" ao 24, (0) cHo CH, —08 2 + Come, NaOH —» Demy = or agent “on aan (a) Toluene to aaa AHO" a o ete tthe and 25. (a) Tetraammine chloridonitrito-N-cobalt (I) chloride (&) Dichlorido bis-(ethylene di-amine) platinum (IV) nitrate (@) The addition of diborane followed by oxidation is known as the hydroboration-oxidation reaction. eg. (CH; —CH = CH, + ByHg —> Propene Ditorane cy —CH= Cry 26. Ciy—CH— Gh | H BH, cH, —cH— art, (CH) —CH, —CH),BH————> #0 (CH; —CH,—CH,);B ——> iy y Ins moe 3CH; —CH)—CH, —OH+ B(OH); Propooct, on or + Hers or + cH,Br tomemrthane saga rena (©) p-nitrophenol is more acidic than phenol because nitrogroup san electron withdrawing groop The presence of this group in the para-position decreases the electron density in the —OH bond. So, itis easier to lose a proton . Hence, Para-nitrophenol is stronger acid than phenol Or @) on OH OQ cone-nno,, NOz Ns Pico! NO, 2-4esntropnenol (ene) on on uo + Ag, NaOH + CHCh—> Phenol Salicylic hydroxy benzaldehyde cD) Cray oh cs ¢ 28 +CH,ONa —> CHC CH CH, 2-methylpopene +CH,OH + NaBr Because tertiary alkyl halide is sterically hindered compound in which substitution is not possible. CH,O"Na’* is nucleophile as well as base that's why limination will take place and alkene is formed as ‘major product. (2) Benzyl chloride is highly reactive towards Sy1 reaction because the intermediate benzyl carbocation formed in the slowest step is, stabilised through resonance. (b) (+) 2-butanol is a racemic mixture. It is a mixture which contains two enantiomers in equal proportion and thus, have zero optical rotation due to internal compensation. Therefore, it is optically inactive though it contains a chiral carbon atom. (©) To avoid the formation of phosgene, chloroform is stored away from light and air. In dark coloured bottles, no light can enter. Thus, ‘oxidation of chloroform to phosgene can be avoided. Hence, chloroform is stored in closed dark coloured bottles, 29. 30. Chemistry Classy, (a) In [Fe (CN)g]~ Fe?* has d? configuration. 1t ig inner orbital or low spin complex due to strong * field ligand. It undergoes d*sp*-hybridisation and has ‘octahedral geometry. 1 oe al ) as rane (Pench trench) (©) In Ni(CO),, the oxidation state of Ni is zero whereas in [NiCl4]*~ the oxidation state of Niis +2 ‘The presence of CO ligand, which is a strong ligand can pair all electrons in Ni(CO), and ths, is diamagnetic in nature but CI” is a weak ligang ‘and is unable to pair up the unpaired electrons thus [NiCl,}*~ is paramagnetic in nature. (d) The isomerism shown when ambidentate ligands are attached to central metal ion is linkage isomerism. e.g. (Co (NH )s(ONO)] Cl; and [Co (NH3)sNOz]Clz Given, Molecular mass =122g mol! Osmotic pressure of solutio ‘Temperature =27°C Amount of benzoic acid = 61 g ‘Volume of benzene =100 ml. We know that = iCRT ink = er v > x £00821 300 1220 i=05278 eae 1-05278 44 in 1-05 Hence, % association is 94%. For a first order reaction, 4-22 og Pe ) © * pope Att =100, pr =06, py =04 2303), ,/_ 0 100 2(04)-06 2303 =——log 2 100 s k =693x10~*sec™!2 ySueceed CBSE 2023 Examination Paper “Preparation Assessment Zone 2 BA. (a) Peptide linkage is ~CONH— linkage formed From Nernst equation, we have between two amino acids while glycosidic 0059, (0.001)? linkage is an oxide linkage between two 6 op monosaccharides = 141 +0.0295 =1.4395 V () Amino acids that can not be synthesised in the (b) In case of weak electrolyte it is not possible to y and must ned through diet are bedi pels = . pana ugh diet at calculate the molar conductivity at infinite tects resin sieimeat iste by extrapolating the graph because the graph is not linear, it is an exponential graph. So, bree Seca ie ee maximum value at» dilution can not be obtained. drogen bon: vi Is forces are the two forces which stabilise the ad Strong electro secondary and tertiary structure of protein. 47 Or act Or | Due to the temperature or pH change, secondary Po Weak electroyte and tertiary structures are destroyed but primary structure remains intact. This process is called denaturation of proteins. During denaturation, primary and secondary structures of protein loss their biological activity. 32. (a) (CpHs))NH >(C;Hs)3N > CoHsNH2 () In strongly acidic medium, aniline is protonated to give anilinium ion which is meta-directing. Conductivity of 0.1 M NH,Cl=1.29 10"? Sem That’s why aniline on nitration gives a substantial amount of m-nitroaniline. Nt =150 Sem*mol™ Nil /Heat | Br,yKOH a (©) C;H0, +B ——+ | C,H,N =129Scm*mol ! ia ata ewmanite“C) n - a (degree of dissociation) =" COOH —-CONH, = NH Kn O (b) According to Nernst equation Ais +a C+ cu G 0.0591, 10 Bayt aq = 016 Nog tt tee «Bem aine acid 0.0591, or NH, NH, . Br. ne 7152-00591 _y agoy @ C +Brkay— 34. (@) Br (i) Zn** with configuration [As}3d"” has all filled orbitals. Therefore its salts are colourless. . Ni?*with configuration [Ar]3dhas some half Nxt filled orbitals. So form coloured salts. wu, ii) Chromium (1) act asa strong reducing agent © O onan a? OHNO, + NT NAB, + HCL Oo ecmcahe talon sheet ben becomes Cr°* which has more stable half-filled 33. (@) Atanode, 2Al—+ 2Al"*+6e" (Oxidation) (¢3,) configuration At cathode, 3Ni** +6e" —»3Ni (Reduction) (iii) Transition metal and their compounds show Total electrons transferred (n) = 6 catalytic properties because of the following reason Eta = Ecatode ~E tnate = ~0.25 ~(~1.66 V) =141V, (1) due to variable oxidation state. (2) availability of empty d-orbital.(©) ( 2MnO| +101" +16 HY — > Mn” +51, +8H,0. (Gi) MnOg +5 Fe®* +8 H* —> Mn™ +5 Fe™ 441,0 Or (9) MnOj: Mn has +7 oxidation number and group number is 7, CrO}": Cr has +6 oxidation state and group number is 6. (b) K Cr, is orange in colour. On increasing the pH of K C130), the medium becomes basic and as a result it changes into KCrOg, Potassium chromate) which is yellow in colour. yO} + 20H” —> Cro? +H,0 irom) coma) (©) Cu is unstable in aqueous solution and disproportionates to give Cu** and Cu. ‘The reaction is given as 2Cu** (aq) —+Cu* (aq) + Cu(s) Cu** is more stable in aqueous solution because of more hydration energy which compensates to the ionisation energy of copper. (@) Cerium exhibits +4 oxidation state as it attains stable noble gas configuration. (©) Chromium (Cr) and copper (Cu). al Chemistry Cla, 35. (a) Structure of 2, 4-dinitrophenyl hydrazone of benzalde,. No; (Ope =NNH Oy No, w nye-{ coon is stronger acid as compares, c,-€_\-coow due to CF; group, CF; ron, an electron withdrawing group which will stabilise the anion formed after loss of proton while CH; is an elec, donating group which destabilise the anion. (©) Rosenmund reaction ° I 1 C, \ “er __¥2 K Pd-BaSO, Benzaldetyde Benzoyl chloride (@) The a-hydrogen of aldehydes and ketones are acidic ux to the strong electron withdrawing nature of carbonyi {group and resonance stabilisation of the anion (base) formed after loss of proton. (©) Benzaldehyde and benzoic acid can be distinguished by NaHCO; test. On reaction of NaHCO; with benzoic acd it gives the effervescence of CO; gas while benzaldebyie does not react with NaHCO;,erred Chemistry CBSE Class 12 PROFICIENCY BUILDING ZONE This section contains 15 Sample Question Papers grouped in Three Stages; Stage! Foundation Level (3 Sample Papers with Guided Solutions) Stage Il Proficiency Level (7 Sample Papers with Solutions at the ena of paper) Stage III Excellence Level (5 Sample Papers without Solutions) The purpose of 3 stages is upgrading your practice in a gradual manner.ee ome ard © Stage! Foundation Level (With Guided Solutions) SAMPLE QUESTION PAPER 1 Chemistry Instructions Time: 3 hrs Max. Marks : 70 1 There are 33 questions in this question paper with internal choice. Section A consists of 16 multiple-choice questions carrying 1 mark each. Section B consists of 5 very short answer questions carrying 2 marks each. Section C consists of 7 short answer questions carrying 3 marks each Section D consists of 2 case-based questions carrying 4 marks each Section E consists of 3 long answer questions carrying § marks each. All questions are compulsory. Use of log tables and calculators is not allowed. oNowaun mSection A ‘The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. 1. For d‘ ions, the fourth electron enters one x of the e,-orbitals giving the configuration I te), when (c] R-C—COOH (a) 4,>P x (0) 4,

P; ). Hydroboration oxidation of Chemistry Clase Lnpairad electrons form strong intermetallic bond | which are difficult to break immeciately Rate =-K{R}. The negative sign used in the rate expression indicates (a) decrease in the concentration of re } with time. (b) decrease in the concentration of with time. {c) reaction is reversible. {d) decrease in the rate with time. (a) For the given reaction, the negative sign indicatey the decrease in concentration of reactants with time, ‘Which of the following is not correct for amines? (a) Ethyl methylamine cannot be prepared Gabriel phthalimide synthesis. (b) N-ethylbenzene sulphonamide is insoluble in alkali. (c) Amines are less volatile than hydrocarbons. (a) Amides can be converted into amines with same number of carbon atoms by LiAIH, /ether. (b) N-ethyibenzene sulphonamide is soluble in alkali because hydrogen attachéd to itrogen in ‘sulphonamide is strongly acidic and forms a salt during reaction between these two. 4-methyloctene would give (a) 4-methyloctanol (b) 2-methyldecane (c) 4-methylheptanol (d) 4-methyl-2-octanone (@) Terminal alkenes react rapidly with diborane to form primary trialkyl boranes which on oxidation gives primary alcohols, CH, 1 ‘3CH; (CH, ), —CHCH,CH =CH, S11 B#e 4-methyloctane: i (CHs (CH); —CHCH-CH»—CH,7 8 ' a CH HEA, CH CHa), —bHCH,CH.C ‘4-methyloctanol (in general, bydroboration oxidation involves the Cf water according to ant-Markownikott's rule).‘\psucceed Sample Question Paper 1 8 b 10. The half-life period of a first order reaction is 4 minutes, the time after which 99.9% reaction gets completed is (a) 16 min (b) 8 min (c) 32 min (d) 40 min Sol. (¢) Gven, typ =4min anda =100; a~x=01 Now, ty, = OOS [For first order reaction} 0.693 ne 0 As wotknow that, k= 2503 jog 2303x4100 tog 100 fF 0693 9 “G7 [From Ea.) t = 3988min = 40 min 11. Boiling point of alcohol is comparatively higher than that of corresponding alkane due to (a) intermolecular hydrogen bonding (b) intramolecular hydrogen bonding (c) volatile nature (d) None of the above J. (a) Due to intermolecular hydrogen bonding in alcohols, they exist as associated molecules, Consequently, a large amount of energy is required to ‘break these bonds and, therefore, their boiling points: are higher than that of the corresponding hydrocarbons. (hydrogen bonding is absent in hydrocarbons). 12. Which type of electrolyte are used in A and Be 400} i “ 2 20) 3 ® 0208 XE (mot A 8 (a) Weak electrolyte Strong electrolyte (b) Strong electrolyte Weak electrolyte () Weak electrolyte Weak electrolyte (4) Strong electrolyte Strong electrolyte “estoge! Foundation Level 27 Sol. (a) in the given graph, ‘A’ represents weak electroiyte like CH;COOH as A, increases steeply Cn dition at low concentration region and 'B represents strong electrolyte like NaCl as Ay, increases slowy with dilution. Direction (Q. Nos. 13-16) In the following questions as Assertion (A) is followed by a corresponding Reason (R). Use the following keys to choose the appropriate answer. (a) Both (A) and (R) are true, (R) is the correct explanation of (A). {b) Both (A) and (R) are true, (R) is not the correct explanation of (A) (0) (A) is true, (R) is false. (d) (A) is false, (R) is true. 13, Assertion (A) p-nitrophenol is more acidic than phenol. Reason (R) Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance. (@) Both (A) and (R) are true, (R) is the comect explanation of (A). Assertion (A) In electrolysis, the quantity of electricity needed for depositing 1 mole of silver is different from that required for 1 mole of copper. Reason (R) The molecular weights of silver and copper are different. J. (b) Both (A) and (R) are true, (R) is not the correct explanation of (A). According to Faraday’s law of electrolysis the weight ‘of ion deposited on an electrode is directly proportional to the quantity of electricity passed. So, 1 mole of silver = 19 equivalent of sitver and 1 mole of copper = 2g equivalent of copper. 15. Assertion (A) All naturally occurring a-amino acids except glycine are optically active. Reason (R) Most naturally occurring amino acids have L-configuration. Sol. (b) (A) and (R) both are true and (R) is not the correct explanation of (A), All naturally occurring «2-amino acids except glycine are optically active. Sol. 14.yore 9 optcaty nace because Gye does rot neve @ tos Oterert substituents as shown below eo YP, ™» ~co0n yore 16. Assertion (A) The a-hydrogen atom in carbonyl compounds is less acidic. mSection B This section contains 7 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each. 17. A first order reaction is 25% complete in 40 minutes. (a) Calculate the value of rate constant. (b) In what time will the reaction be 80% completed? Sol. (a) For frst order reaction, ‘The given first order reaction completes 25% in 40 min. Let a=100 a-x=100-25 =75 400 _ 2303, 2303 Wey Ogg gg OO k =0.0072 min-* qQ (b) For 80% completion of reaction, a=100 = 100 - 80=20 k= 0.0072 min~* = 2308. jog 100 _ 293.6min “door 18. A solution containing 25.6 g of sulphur dissolved in 1000 g of naphthalene, whose 2, (a) Give chemical tests to distinguish melting point is 80.1°C gave a freezing point lowering of 0.680°C. Calculate the molecular weight of sulphur, K; for naphthalene is 6.8 K kg mol. w Sol. ath = oma ky pis 25.6 1000 068= 6.8%77 20 aq) 068 a Reason (R) The anion formed alter the loss of a-hydrogen atom is Tesonance stabilised Sol. (6) (A) Seton tad (R) 8 U2. (A) is flee Decay my opekogene 1 cattery CATPOSS 3 Genes, Se fo ard where willbe an 628 oes inform oH" S008 The anion formed atier toss of a-FYFOQEN atom ig resonance statics the suitable haloarene and 39. (a) Namo the 5 -chloroacetophenooe can prepared. {b) Out of chlorobenzene and cyclohexyl chloride, which one has higher dipole moment? Sol. (a) 2-chloroacetophenone can be obtained from chlorobenzene and acetyl chloride in the presenes| of anhyd. AICI o 9 oO Anis. ACs + Feder Cras ‘Acct Soyation a (b)In_chiorobenzene, the Clatom is linked to 4] ‘sp-hybridised carbon atom, whereas in cyciohes chloride, the Clatom is linked to a sp®-hybriisr carbon atom. ‘As, sp-hybridised carbon has more s-character ‘80, it is more electronegative, thus the density of more polar, i.e. it has higher dipole moment. (i between phenol and benzoic acid. (b) Write TUPAC name of CH,—C=C— CH=CH—C—OH , Or Convert the following, (a) Ethyl cyanide to ethanoic acid (b) Butan-1-0l to butanoic acidisucceed Sample Question Paper 1 Sol. (8) Phenol and benzoic acid can be distinguished by ferric chloride test. Phenol reacts with neutral FOC toform ferric phenoxice complex giving violet colouration. 6C4H.OH + FeCl —+ [Fe(OC Hf 46H" + 3Ct Pret ton pnt caren Scout (ap) But benzoic acid reacts with neutral FeCl, to give a ‘buff coloured precipitate of ferric benzoate. SCgH,COOH + FeCl; —> (C,H,COO),Fe + 3HCI Bowe md Fore bonwoate cexmcocredpet) (1/2) (©) «CHy—CmC—CH =H on Hox 2en-4syt-ot acd a) Or caer“, CH,COOH M84, C.H,CONH, Propane aid Se KOH CHaNH, 2.0,H,0H Ain 4 C4,C00H Branocacis (1) Section C 29 (0) CH,CH,CH,CH,OH as CH,CH,CH,COOH fares, Butanoe acs (1) Gommon ~ Selecting the inappropriate oxidising Mistake agent for specific conversion can make the answer incorrect. 21, (a) Account for the following. Pentaacetate of glucose does not react with hydroxyl amine. (b) What happens when oxidation of gluconic acid takes place? Sol. (a) *Pentaacetate of glucose does not react wth hydroxylamine” due to the absence of free CHO group. a) (0) Glucose and gluconic acid, both on oxidation yields a dicarboxylic acid, saccharic acid, Reaction involved is as follows ‘COOH COOH bron, 2288005 Grom, HOH 00H uronic aia Secchane acid (1) ‘This section contains 7 questions with internal choice in one question. The following questions are short answer type and carry 3 marks each. 22, (a) What kind of isomerism exists between [Cr(F,0),Cl, (violet) and ICr(H,0), CIJCl, -H,0 (greyish-green)? (b) Write the formula of diamminechlorido- nitrito-N-platinum (II). (c) Different colours observed in octahedral and tetrahedral complexes for the same metal and same ligands. Explain. Sol. (2) Coordination compound [Cr(H,O)p]Cl, and [Cr(H,0),CI}ClH,0 are solvate isomers, because ‘water is exchanged by chloride ion. This is why both, ‘of them show different colour on exposure to ‘Sunlight, a) (©) The formula is [Pt(NH),Cl(NO)} a) (©) Crystal field spiiting energy in the octahedral and tetrahedral field are closely related as a-(3}s Higher the CFSE, higher wil be the energy radiated ind transition Hence, lower wavelength is absorbed in octahedral Complex than tetrahedral complex for the same metal and ligands. Thus, different colours are observed. (1) 23. (a) What happens if external potential applied becomes greater than Ey of electrochemical cell? (b) Write the relation among the conductivity of a solution in the cell constant and the resistance of solution in the cell. (c) The resistance of a conductivity cell containing 0.001 M KCI solution at 298 K is 1500 Q. What is the cell constant if the conductivity of 0.001 M KCl solution at 298 K is 0146 x10? S cm? Sol. (a) When external potential applied becomes greater than Ey) of electrochemical cell, electrons flow from cathode to anode, i.e. electrolytic cell. @30 (b) The resistance, R of a conductor varies directly with length (/)and inversely with area of cross-section A i ie « # A on Rep eA where p =resisity p = 9A a) (c) Given, conductivity, «= 0.146 10° Sem"! Resistance, 500.02 Cell constant,G* =x xR 146% 10°" x 1500 219 cm" a 24, Write the equation for the following reactions. (a) Conversion of propan-2-ol to 2-methyl propan-2-ol (b) Phenol is treated with Na,Cr,0, in the presence of sulphuric acid. Sol. (a) Propan-2-01 to 2-methylpropan-2-ol on I - cb cry ROMEO, 4 Propan2-ot a Gila oH cH —¢H—ch,|"2 cH —c— Ags ICHy oe CHs| Sroomat CHa —C—CHs CH CHy Adduct 2-methyipropan-2-01 q@ (b) OH Oo N On Ove ow oO serine (Oxidation of phenol is done with Na,Cr,0, in the presence of sulphuric acid and benzoquinone is formed alongwith water. w 25. An organic compound (P) having molecular formula CH ,o0 forms an orange precipitate (Q) with 2, 4-DNP reagent. Compound (P) gives a yellow precipitate (R) when heated in the presence of iodine and NaOH alongwith colourless compound (S). 3 ™; Identify (P), (Q), (R) and (S). Write do, the reaction for their formation, Or An unknown aldehyde ‘A’ on reacting with alkali gives a B-hydroxy aldehyde - which loses water to form an unsarura,_ aldehyde, but-2-enal. Another aldehyde ‘B’ undergoes disproportionation reaction in the presence of conc. alkali to form produc, C and D.C is an aryl alcohol with the formula C;H,O. Identify A and B Wn, the sequence of reactions involved Sol. P=Pheny\ acetone Q =2, 4-dinitropheny! hydrazone R=Methy iodide S =Phenyl acetic acid 9 ot q CHy—-C—CH, HN—NH> Ais CH,CHO (ethanal), BisC,H,CHO (benzaldenyce) OH noo | 2 2CH,CHO = CHEHCH.CHO =. ‘eran a: {succeed Sample Question Paper 1 26. A simplified version of nucleic acid chain is as shown below. Base { Base 1 on se remem r Sugar— (a) Write the main structural difference between nucleoside and nucleotide. {b) How do two nucleic acid chains bond with each other? (c) Name the bases present in DNA. ‘S01. (a) Nucteosides contain onty sugar and a base, whereas nucleotides contain sugar. base and a phosphate group as wel a) {b) Two nucleic acid chains are held together by hydrogen bonds between pairs of bases, (1) (©) There are four nucleotides, or bases, in DNA: adenine (A), cytosine (C), guanine (G), and ‘thymine (1). a 27. An alcohol having formula C,H,O reacts with HBr and forms products. Write the name and structure of both products and the mechanism of the reaction. Sol. Te involved chemical reaction is CH,CH,OH—= .CH.CH.Br+ H,0 oes Choose wert) ‘The mechanism of the given reaction is as follows ‘Step 1 HBr —> H” +B8r- mSection D Sol. ‘Step 2 Protonation of alcohol CH, —CH, OH + H"—+ CH, — CH,—OH, Proonaied cohol Stop 3 Nucleophiic attack of Br t Be a Hy — Ot, 5,2 reacton ~? ar) CH —CH, On, }. Prove that time required to complete 3/4 of a first order reaction is twice its half-life period For first order reaction, rate constant First condition Completion of 3/4 reaction a 23100275 4 2.303, tye 2 Thus, tye =e 4 100 2308, _ 1966 tye tye k ® ‘Second condition When reaction is half completed = 0689 @ ok a) From Eqs. () and (i 386/k tye ” 0683/ tye =2xty2 ‘Thus, time needed to complete 3/4 of reaction is twice its halt-ife period. @ ‘The following questions are case-based questions. Each question has an internal choice and carries 4{1+1+2) marks each. Read the passage carefully and answer the questions that follow. 29. Crystal field theory is a theory that describes the breaking of the degeneracy of electronic orbitals that occurs in transition metal coordination complexes, most often as a consequence of the presence of ligands. Crystal field splitting energy (CFSE) is the parameter that is used to correlate a variety of spectroscopic, thermodynamic, and magnetic properties of complexes. The essential feature of crystal field theory is that there is a competition between the magnitude of the CFSE and the pairing energy, which is the energy required to accommodate two electrons in one orbital.The eneray sphitting shown schematically im the hgure given below Sy a. —_ ins a Be Me Be Wrereoe tes Seon Ocmal tes Answer the following questions. 4a) On the basis of this theory, write the electronic configuration of d* system in terms of fy, and ¢, if A,< P. Or White the electronic configuration of the central atom K, [Fe(CN),] w.tt crystal field theory. (@) What is the crystal field stabilisation energy for high spin d‘ octahedral complex? (c) How does the magnitude of the splitting decide the actual configuration of -orbitals in an octahedral field for a coordination entity? ‘= For scoring maximum marks, mention TEBE Point about the strong field ligands and weak fields. tified Sol. (a) it 4, Pare called strong field ligands q . Electrochemical cell potentials have no simple relationship with temperature depend on the interplay between the sip and magnitude of the isothermal - temperature coefficient, dE4T, and on the magnitude of the reaction quotient, Q. An electrochemical cell is said to act reversibly if the net cell reaction is reversed when the current through the cell is made to flow in the opposite direction. When no current is being drawn, such g cell is in a true equilibrium state. When ¢, no current is being drawn from a reversible cell, the potential difference across its terminal, or open-circuit potential, is known as the electromotive force or emf of the cell. The emf of any particular reversible cel is a quantitative measure of the tendenq of the cell reaction to occur and may be related to the free energy change for ths gy process. The Daniell cell is a type of Tt electrochemical cell invented in 1836 by John Frederic Daniell, a British chemist 3 and meteorologist, and consists of a copper pot filled with a copper (I!) sulphate solution, in which is immersed an unglassed earthenware container filled with sulphuric acid and a zinc electrode. Several scientists performed experiment that used a Daniell galvanic cell workin in different electrolyte concentrations fo comparing results with the theoretical values calculated by the Nernst equatio The cell potential decreases drastically when the Cu’* concentration was reduced and the temperature was above 80°C. In addition, temperature indirectly has® influence through the activity coefficients, ionic strength and dilution’ the solution.* seeceed Sample Question Paper 1 Answer the following questions. (a) An electrochemical cell generally consists of a cathode and an anode. Where is the reduction takes place? (0) What is the effect of increase in concentration of zinc ions on the electrode potential of zinc electrode for which E;,2-2, equals -076V? (c) How does the reduction potential increase w.rt. Nernst equation? Or Imagine you are a member of a project based on electrochemical cell and you are asked to construct an electrochemical cell. What will be its main four components? Sol. (a) Cathodes are usually metal electrodes. tis the electrode where reduction takes place. o (0) According to Nemst equation. the electrode potenial of zinc depends on the concentration of zinc ions. 2303AT Faye tn = Eat an? gp OO} Hence, electrode potential will increase with ‘increase in concentration of Zn®* ions. a (a) Anode An electrode where oxctsnon occurs (0) Cathode Ar etecrade where recucton conus (©) Bectrviyte An 2iecrahe s 2 charged mobile en that tunctons as 2 concuceng meum When dssoNec 17 poisr solvents such ss water an secroyie proc.ces ens resuting nan electrically conducing solution (@) Salt-bridge A sat-cnage connects he oncanon {and reduction haNes of an stecrachemca csi completing the elecrochemcca! crout. & contans a saturated sat sokton such as KO. @ mSection E The following questions are long answer type and carry 5 marks each. All questions have an internal choice. ‘31. Attempt any five of the following. (a) Why Mn’* is more stable than Fe** towards +3 oxidation state? (b) Why the enthalpy of atomisation is lowest for Zn in 3d-series of the tansition elements? (c) Identify the metal in MO,F and justify your answer. (4) Explain why transition metals form a large number of complexes. (e) Why the E° value for the Mn®* /Mn** couple is much more positive than that for Cr** /Cr** couple? (0 Complete the following. 3MnO}- +4H* —> (g) Which of the following cations are coloured in aqueous solution and why? Se™*, v**, Tit", Mn? Mn? having hatt-iled o-orbitais will be more stable than Fe’ as ¢ has nat fitea d-crotats a (0) Zinc has completely fled Corbis. which lenis &s Tendency to form metalic bonds Thus. ¢ requires feast enthalpy to get atomsed a (MOF SMOOF MOF Let the oxidation state of M's x xX+3x(-2)2 (0-0 0 x= +7, 18. M's cucaton state of +7 Hence, the gren compound is MnO F a (@) Transition elements form a large number of ‘complexes due fo the comparatively smaer Ses ‘of the metal ons, ther high ion charges and the availabilty ofc-orotats fer bond formaton (1) (@) The value of Es. ox S negaine 04) son al we 19 eura stabaty of nadie