Professional Documents
Culture Documents
SAND83-2622
$~4~/C1
RV
Printed April 1984
Otmar Stuetzer
-Prepared by
Sandia National Laboratories
Albuquerque, New Mexico 87185 and Iivermore, California 94550
for the United States Department of fnprgy
under Contract DE-AC04-76D",OTh9,. i
I.
Lw
\Y /
'4.
N4 7-.
'r4!ld
, •i:,:IV
....
ai:
4. .
U,,ISNULEAfREGULATORY COMMISSI
SF29OQ
C8-81)
NOTICE
This report was prepared as an account of work sponsored by an
agency of the United States Government. Neither the United
States Government nor any agency thereof, or any of their em-
ployees, makes any warranty, expressed or implied, or assumes
any legal liability or responsibility for any third party's use, or the
results of such use, of any information, apparatus product or
process disclosed in this report, or represents that its use by such
third party would not infringe privately owned rights.
Available from
GPO Sales Program
Division of Technical Information and Document Control
U.S. Nuclear Regulatory Commission
Washington, D.C. 20555
and
National Technical Information Service
Springfield, Virginia 22161
NUREG/CR-3263
SAND83-2622
RV
Otmar Stuetzer
Printed: April 1984
Prepared for
Office of Nuclear Regulatory Research
U.S. Nuclear Regulatory Commission
Washington, DC 20555
Under Memorandum of Understanding DOE 40-550-75
NRC FIN No. A-1051
ABSTRACT
iii, iv
CONTENTS
Page
EXECUTIVE SUMMARY 1
I. INTRODUCTION 4
V. CRACKS IN CABLES 59
1. General Comments 59
2. Preliminary Tests 60
a) Long Cables 60
b) Cracks in Stressed Bends 62
c) Maintenance Accident 62
3. Ongoing Systematic Tests 65
a) Dynamic Cracking 65
b) Static Cracks 66
VI. CONCLUSION 69
REFERENCES 71
APPENDIX A A-1
V
ILLUSTRATIONS
Figure Page
vi
ILLUSTRATIONS (cont.)
Figure Page
28 Density Distribution 50
33 Crack Experiments 64
vii
LIST OF TABLES
Table Pa•e
2 Creep Shortouts 38
5 Preexperiment Averages 53
6 Crack Statistics After Heating to 2250C
Over 5 Days 61
A-i Cable Test Parameters (27) A-2
viii
ACKNOWLEDGMENTS
ix
EXECUTIVE SUMMARY
I
temperatures for long periods. Creep distances can be preci-
sion measured by X-raying at regular intervals.
Systematic creep experiments (Section IV) are presently per-
formed on cable samples that are bent in a U-shape over a
4.8-mm diameter support rod with each cable end supporting a
1-lb weight. After 7 months, no situation approaching short-
out has been identified. It was found that the most severe
creep deformation occurred at a temperature of approximately
125 0 C. Apparently, at higher temperatures, polymer embrittle-
ment proceeds so fast that it effectively inhibits creep.
2
(2) Cable overhang over edges with small radius of curva-
ture does not exceed 10 m (creep shortout condition).
AlL
" iI 'V•./
-
3
1. INTRODUCTION
4
generalize the results to other cable types by correlating
the observed cable damage with the rather well-known materials
deterioration. Analytical extrapolation to other geometries
and to a variety of mechanical stresses is accomplished by
correlation to. and then generalization from. simple scaling
models. With this approach, it was feasible to limit the
number of experiments to 84 temperature-time value pairs per
year. The number of tests for each value pair (6 precision
creep measurements and 40 crack tests) was chosen so that it
is large enough to be statistically significant.
5
In the following sections the essential details of the work
performed to date will be described. In Section II, litera-
ture data and preliminary experiments will be discussed; it
will be shown that purely electrical breakdown is unlikely
for the cable type under consideration. In Section III,
arrangements used to obtain creep and cracking data are
described, together with calibration and correction methods.
Section IV concerns creep measurements and the results of a
first-order (two-dimensional) creep analysis. In Section V.
the cracking data obtained are analyzed. Section VI summa-
rizes the results and discusses possible and probable conse-
quences.
6
II. PURELY ELECTRICAL FAILURES
7
if any, purely electrical failures have occurred even in
cables exposed to reactor-containment environment for long
periods.1,s
8
70 70
I
IB
I
I
I
I
I
I
I
E 60-
E
0
50s-
Iv- 401-
EPR
0 30 -
o PE INSULATED CABLE FREQUENCY: 50Hz
W o XLPE INSULATED CABLE TEMP.: R.T.
201- A EPR INSULATED CABLE
I . I I I I I
10 I(
I I
5
I m
104 5 10 5 106
9
Table 1
60 Hz Breakdown Field and Standard Deviation for Various Materials
at Different Temperatures (After St. Onge. Ref. 15)
11
BREAK DOWN VOLTAGE
23 - FOR 10 CABLES (EPR)
• T= 225 C
22
U)20
I-
.j •
0 18
-31%
1 66 >
I-
.,I 14 -
0
> 12
0 10
8 0
Il.
I I I I I I i, I I I
1 2 3456 7 8910
CABLE NUMBER
12
1.0°
0.0
XLPE
uwL
2w.. 1015
5
olX10 4 5X10 4 1X10 5 5x10
0
| |
0.54=L
EPR
wt 1015
0 14
5X10 4 j1xO
__Ira
0 Ix10 4 5x10 0
>uJn
DOSE RATE (rads/h)
13
E
3
C: 103
wU
0 3
z
102
7CD
3
101
0
.3
-j
100
. 3
10-1
3.5 6.0
EMICAL SPRAY
CHVC
-RATED
I VOLTAGE & ICURRENT
!!I I
-,______6.
Figure 4. Insulation Resistance in Steam and Chemical Spray Environment (Flame Retar-
dant EPR) (After Murata, Ref. 18)
10-3
(A)
z
w
w
-j 100%
1%
1%
15
is current dependent, the second depends on the applied volt-
age. The cable presently under investigation. AWG I14. has a
conductor resistance of 0.00828 ohms/m at room temperature.
At 1000C. this value is increased by-a factor of 1.43. At
the maximum rating. 20 A. the cable current causes heat gener-
ation of 4.74 W/m at 1000C, and somewhat more at higher tem-
peratures. The installation has to be able to carry this heat
flux away, and usually is amply dimensioned to do this.
Therefore, dielectric losses may add a comparable amount of
heat generation without undue consequences. To be conserva-
tive. we will stipulate that dielectric heat input will not
exceed 20% of the permitted current heat generation. Dielec-
tric losses are therefore limited to 0.95 W/m for the present
cable.
16
The two examples above may have involved cables of above
average quality. At Sandia. for some EPR power and control
cables, lower values of R have been measured than for these
examples. A conservative value for a safe temperature is
1900C. Permitting a minimum resistance of 0.24 Mohm-m at
1900C. scaling as described leads to a minimum resistance of
1.3 Mohmom at 1756C. Values in the neighborhood (but below)
this figure have so far been only observed on control cables
of one manufacturer. As control and signal cables work at
much lower voltages than the above discussed power cables.
thermal runaway is not a problem for the former. Neverthe-
less, addition of a leakage vs temperature test to qualifica-
tion procedures may be helpful for selection of the best
cables.
17
4. Other Phenomena
While radiation is applied, the conductivity of insulating
materials is enhanced due to additional carrier generation.
This phenomenon should be independent of temperature but
could conceivably cause excessively high currents during
accidents. Figure 6. taken from a paper by Murata et al.,*s
shows measurements on EPR cables aged in a variety of ways.
Resistivity varies by less than. a factor of 2. and is not
proportional to the dose rate. Extrapolating to a dose rate
of 10 Mrad/h, dose rates comparable to those expected in an
accident, indicates that a parallel resistance of more than
100 MO would appear across a 1-km length of cabling. At
higher temperatures, the effect would be overwhelmed by
thermal-carrier generation.
The influence of humidity on cable resistivity is observable
but small. Measurements by St. Onge et al. (Ref. 15, Figures
4-3 and 4-5) show an order of magnitude increase in conduc-
tivity for XLPE under extreme humidity (soaked cables) com-
pared to dry conditions. A somewhat smaller increase is shown
for EPR. The measurements quoted above (e.g., Figures 4 and
5) include the influence of humidity.
5. Summary
The above discussion has been brief. A more comprehensive
study of basic electrical breakdown mechanisms and of litera-
ture data has been performed and many more preliminary tests
have been evaluated. 2' We believe it has been adequately
18
0 Mrad
O%-os-- NO
-b. 1100 HEAT
3 - -- M TOTAL 200 AGING
-4--
mmm" DOSE 0AFE
00 AFTER
__
HEAT
H00
w 10 4 - 200 AGING
z
3 EPR
!1 3
z
10 2 ,
0 0.1 0.5 1.0
Figure 6. Effect of Dose Rate on Insulation Resistance (After Murata et al., Ref. 18)
shown that a purely electrical failure is highly unlikely up
to temperatures of 1900C. The discussion now turns to elec-
tromechanical phenomena.
20
III. TEST INSTRUMENTATION
2. Cable Tensioners
21
- A
.5.4
.5-4
0
I
54)
0
'-f4
0
.5.4
I s,
4~ t ALI
4 4
27
I-I
I
OA
22
+8.64V, 130A
- TOTAL
PIPE I
95 0 C
PIPE III
1650C
PIPE II
135°C
1=
23
'Ali 4 AIM
IEW.
1%, I'
I
•i•i
•iiIi i •i•i
I
ý,
tN
1~
O
O
26
CABLE
CON~DUCTOR
lI
-.3 D
d
SOURCE
NOT TO SCALE
Uncertainty
050
10
28
3. Special Apparatus
For cracking experiments, cables have to be bent reproducibly.
Figure 13 shows a simple jig developed for this purpose. A
movable lever, connected to a vertical post, wraps the cable
around a cylinder 12-mm in diameter. It usually took about
10 seconds to bend the cable into a hairpin structure: uni-
formity of motion was attempted.
29
Alt
30
IV. CREEP SHORTOUT
1. General Comments
A cable is stretched by an applied force. F. over a surface
with a radius of curvature. r. At elevated temperatures, the
metal wires will creep through the softened polymeric insula-
tion and cable jacket: after some time, metallic contact
between cable wires or between the wires and the cable support
may occur. The present discussion is limited to the simplest
case where the cable consists of a single wire surrounded by
an EPR insulator and a Hypalon jacket.
The situation of concern involves large compressive strains
with values approaching unity. There is. however, nothing in
the literature concerning such large strains. As a result.
an essentially experimental investigation backed by computer
modeling was undertaken. To introduce basic concepts, an
attempt will be made to first draw conclusions from existing
pertinent data for small-strain situations.
The low-strain behavior of polymeric 2materials including rub-
ber has been thoroughly investigated. 4 Even the long-term or
"aging" phenomena of these materials are subjects treated in
textbooks. 2 9 Unfortunately, most published work is limited
to temperatures below transition temperatures, which means
that only the lower regions of the temperature range of pre-
sent interest are covered. (For EPR the transition tempera-
ture is not well defined, and the transition is not severe
since only a small percentage of the polyethylene incorporated
into the compound shows a crystalline melting point: the
"transition" lies between temperatures of 700 and 900C.26)
At low temperatures and low strain rates, creep is a linear
function of applied stress, a, and a function of a time
dependent "creep compliance." J(t), or its inverse, the creep
modulus, M(t). The creep strain, c, is given by
c =i a J(t) a/M(t) (1)
31
T_ I I I I
00
a. 40 YRS
w 10-2-
1 DAY 0I
0. 02
0 i0~ 3
10-31B.
i
7
i fI I II I I :,
I I I II r
n = dt/dJ (2)
33
75 *
0
60
0.
A
45 A
0
0.
30
IL
IL 15 L
ILI
0-
10-1 100 101 102 103 104
TIME (hours)
34
sizes and shapes of cable and supports. A second supporting
geometry (sharp corner) is shown in Figure 19. For determina-
tion of stress from some known stretching weight, an effective
support area must be estimated. For the geometries in Figure
18, the effective area. A, should be proportional to the wire
radius, rw, and the curvature radius of the support, rs.
such that
A = krwrs (3)
35
10:1
(9
b) a)
36
5
oN
CO b
a. 0.5 -
II
Creep Shortouts
39
(a)
(b)
Figure 21. Cut Through a New Cable (a) and a Cable Stretched
by 0.9 kg at 125-C for I Day (b)
40
Table 3
Remaining
Thickness
(c) (mm)
Avg: .0020 0.117 0.170 0.97 0.77 0.86
/77777777777
Nominal-stress: 14 MPa
SUPPORT Exposure time: 1 day at 1906C
~6
LL
0
040
cl)
UJ + 3
z
020
4 1
U)
(fl 0 8 24 48 72 96
EXPOSURE (HOURS)
60
I
U)
50
LL
0 40
30
+
20
10
0
0 24 4852
EXPOSURE(HOURS)
42
0.7 I I I I I I
0.5 K 0i.
a0
0
0*
0
%
%STRAIN =1
C] 0.86 kg WEIGHT
0. 6
40
0.3
() see,
0
0.
IL 0.2
2
1250C
(0
0 0.1 190 0 C
b
I I I I
0.0
I 2 3 6 14
43
exact cause of the compliance decrease is (perhaps strain
hardening or compacting). The phenomenon is beneficial
because the lower compliance delays shortout.
Another probably related, and also helpful, phenomenon con-
cerns breakdown fieldstrength. With the insulator and jacket
thicknesses decreasing, the electrical breakdown voltage
should decrease. This does not appear to be the case. As
Figure 24 shows, breakdown voltages measured for 18 cables at
225 0 C do not vary significantly with the thickness of the -
remaining layer. The explanation for this may be that mechan-
ical compression near the support improves the insulating
material (e.g., by removing bubbles, closing microcracks. and
densifying the polymers). Using an experimental facility
developed by K. Gillen,2 6 a 5% density increase was mea-
sured for EPR samples removed from a location just above the
support point. Cable breakdown in the support region there-
fore becomes less likely with increasing exposure: breakdown
along flaws at other locations remains unaffected.
A third phenomenon further decreasing the breakdown probabil-
ity has been observed. Over long times, and probably affected
by vibrations, the "unfavorable" wire strand position (shown
in Table 3. (a)). appears to be unstable. The cable tends to
twist towards the more stable position indicated at the bottom
of Table 3. The wire now sinks in more slowly, and shortout
at the support is delayed.
This work demonstrates the complexity of creep shortout.
Long-term extrapolation from short-time tests is difficult
under the circumstances.
3. Systematic Experiments
As a consequence of the considerations in Sections I and II
and backed by results of the preliminary tests, a long-term
experimental effort has evolved, which is continuing. The
part pertaining to creep phenomena, particularly creep short-
out, will be discussed here.
a) Program -- In the main test facility described in
Section II, 6 experiments are being conducted in heat cham-
bers maintained at 750, 1000. 1250, 1500. 1750. and 225 0 C. A
seventh experiment is taking place in the open at room temper-
ature. In each test, creep versus time is measured by X-ray
observation of the gradual reduction of insulator thickness
in 6 cable samples. Each cable is hung over a 4.8-mm diameter
steel rod and the cable-ends carry 0.45-kg lead weights. For
three of the six cables in each test, an ac voltage of 480 V.
between cable wire and support, generates an electrical field
tending to pull cable wire and support together. The small
mechanical stress of about 3 Pa (0.4 x 10- psi), which
increases rapidly with decreasing distance, induced by the
44
I I
w 0
NO
,1 SDEFORMATION
1 0.q- 0
I-. 0 0
-,J 0
N
0
0 SLEEVED CABLES
2 0 WIREHANGER Ii, 225°C
WIREHANGER III, 225°C
0 WIREHANGER IV, 2250 C + HEAT SPIKE
1.01-
QZ
ILl 2250 C
W
I I
0.1'
0.01 0.1 1.0 10.0
REMAINING THICKNESS (mm)
45
voltage also causes 120 Hz mechanical vibrations. (Figure 10
shows one of the seven tensioning arrangements. Alignment
and correction methods for the measurements have been
described in Section III.)
46
J-\w Jlq\w
2) iJ-\WE 3j-kmc JJW
I. 210501
ý.
q-l
b)
48
w WIRE
-7
IYP4
/ 0
d
No. 1
i Cable Number 1 2 3 4 5 6
2 EPR, measured (mm) 14.0 12.0 12.0 14.5 13.0 11.5
3 Hypalon, measured (mm) 9.0 10.0 10.0 10.5 10.5 9.0
4 Total, measured (mm) 23.0 22.0 22.0 25.0 23.5 20.5
U'
Computer Evaluations
Group Averages
24 EH.T, 1..3 (%) 67.9 75.3 70.9
25 E.H.T. 4..6 (%) 64.5 72.4 67.7
Row 9 gives the values for the measured tilt angle,
a. versus the vertical, indicated in Figure 27.
Proexperiment Averages
Creep compression of the EPR and Hypalon layers are not pro-
portional; EPR is softer and contributes most of the combined
creep strain. Figure 31 shows worst-case EPR thickness-
reduction percentages. The 225 0 C values have the tendency to
approach the critical curve. An explanation is that the
squeezeout of the insulator (see Table 3) may be very rapid
in the beginning before embrittlement slows the process.
54
l100 _ _ _Cables)
L225°C- -- 7 5 oc25°C o 2SOC
m A Imý1OO°C • 75 0C
- - 125 0C o 1OO°C-
CO a 125 0 C -
(1) A 150°OC
LUI
z A 1750C
od 0 225°C--
C10
cc 40
year
1 100 10
1000 10,000
EXPOSURE (DAYS)
w 40
z
2 30
z
20 100%x t 0 .4 8
10
10 30 60 90 12!0150 210
EXPOSURE (DAYS)
Lfl
2'0
10
10 30 60 90 120150
EXPOSURE (DAYS)
58
V. CRACKS IN CABLES
1. General Comments
Cracks in the insulator-jacket protection of a cable may lead
to electrical shortout. especially during an accident when
the combination of humidity, contaminants, and spray may form
conducting paths to ground or to another crack.
Experiments have been performed during this investigation
that show that the existence of a crack through jacket and
insulator does not always lead to an immediate shortout. even
if the cable is immersed in a conducting liquid. The condi-
tions under which a short does not occur, even though cracks
are present, are very complex and not completely understood.
For the present discussion a criterion will be that cracks
penetrating to the inner conductor may cause a shortout and
are considered as a "failure".
59
2. Preliminary Tests
60
Table 6
Experiment I II III IV
Number of cables 10 10 10 5
Load per cable (kg) 1.6 0.34 0.34 0.34
Environment Dry Dry Humid Humid
(Heat Spike)
Average number of
cracks per cable 4.6 1.9 2.3 1.6
Standard deviati6n 40% 34% 21% 154%
Average width
of cracks (mm) 0.9 1.1 1.6 0.1
Standard deviation 27% 51% 42%
Integral crack
width (mm) 4.2 2.1 3.7 0.16
(Est.)
Insulator cracks
(percentage) 77% 35% 67% 0
61
cable wire; this phenomenon has often been observed when
cooled-down cables are disassembled.
Cracks parallel to the axis are generated by circumferential
stresses. Measurements have shown that the outer Hypalon.
jacket tends to shrink more than the inner EPR material.
This enhances the circumferential stress and may explain why
parallel cracks almost always occur only in the jacket and do
not penetrate the insulator.
b) Cracks in Stressed Bends -- In this test, 35 cable
samples made of EPR/Hypalon were exposed to a thermal treat-
ment in which the temperature was slowly increased over a
period of 5 days to 2250C in steps of 250C. The cables were
stretched over a sharp edge with weights of either 1.6 kg or
0.34 kg each. Half the experiments were performed in a dry
atmosphere; for the other half, the humidity ranged between
95% and 100%. In the last experiment, a one-hour heat spike
of 2650C was applied before the normal heating sequence.
Listed in Table 6 is the average number of observed cracks.
the average width of the cracks, and the integrated crack
width per cable. Also given is the percentage of cracks which
reached the conductor (through cracks). It was observed that
the formation of cracks increased strongly between 2000C and
225 0 C. The cracks were formed and counted before the system
had time to cool noticeably. Some cracks may have deepened
in the subsequent cooling period. One crack in experiment III
was found to have healed after cooling.
The most severely stretched cables, those in experiment I.
clearly exhibited the largest number and the highest total
width of cracks. It is not clear why the average crack width
was very low in this experiment. The presence of humidity
during the relatively brief aging experiments does not seem
to have noticeable influence. The addition of a heat spike,
simulating a temporary overload, had strong impact. It
resulted in very tiny cracks (or crazing) which did not pene-
trate to the conductor. This inconsistency (and some of the
observations above) may be related to the adhesion of the
insulator to the center wire. In the first three experiments.
the three cable components (jacket, insulator, wire) stuck
inseparably to each other after cooling. The heat spike in
test IV led to easy separability of the three.
c) Maintenance Accident -- The many data in literature
describing the influence of temperature and radiation exposure
on materials properties have almost always been taken after
cooling to room temperature. The results therefore may not
be descriptive for what happens at high temperature, but
should be applicable for correlation with crack generation at
room temperature, i.e., during "maintenance handling" of aged
cables. A "maintenance accident" was simulated by bending
cable samples around a mandrel. The mandrel diameter was
62
usually approximately equal to that of the cable; this cer-
tainly constitutes a severe overtest.
e + (4)
For the cable used, p for the Hypalon jacket has an aver-
age value of 2.4 mm, and for the insulator, 1.9 mm. If the
cable is bent over a 4.8-mm-diameter mandrel (r = 2.4),
strains of 0.5 and 0.4, respectively, are created. It is
customary to normalize strain values to the original room-
temperature breaking strain. eo, which is about 3.5 for
these materials. Cracks should therefore become likely when
e/eo equals 0.15 for the jacket (Hypalon) and 0.10 for the
insulator (EPR).
In Figure 33, the time needed for EPR and for Hypalon to reach
the values e/eo = 0.10 and 0.15. respectively., is plotted
versus inverse temperature. The data are extrapolated from
Reference 31 and supported by Sandia measurements on similar
EPR and Hypalon compositions. 2 6 The extrapolation is justi-
fied in Reference 22. Five standard cables were aged at 1860C
for 8, 16. 32. and 48 hours and for longer periods. As indi-
cated in Figure 33. the jacket exhibited cracks after 32
hours. The insulator did not crack until after 300 hours.
The experimental results are certainly compatible with the
model developed.
63
NEUTRAL
FIBER
o eI
Figure 32. Model for Equation 4
TEMPERATURE (C)
225 186 147 108
I I
- BENDING
CRACKS A
100
U
w
O NO CRACKS
0
a. 10
/ CRACKS
IJACKET:
(1 DIAMETER
BENDS)
wu
* CRACKS
(HALFINCH
MANDREL)
INSULATOR:
* NO CRACKS
A CRACKS
64
Some earlier observations for a 225 0 C exposure are also indi-
cated in Figure 33. During the experiments I through III
described in connection with Table 6. straight as well as
prebent cables were exposed to temperature treatment with no
axial stress applied. The cables remained a few hours at
2250C and were then bent (or unbent) after cooling. The bend-
ing radius was 6.4 mm in these experiments. According to
Equation 4. cracking should occur for e/eo = 0.08 (Hypalon)
and 0.06 (EPR). The graphs for these values would lie just
above the respective plotted lines in Figure 33. Jacket
cracks were observed as shown. The insulators did not crack
because the exposure did not last long enough.
After removal the samples are bent in the jig shown in Figure
14, and the cracks are counted. There are always many more
surface cracks observed in the Hypalon layer than cracks
extending through to the wire (through cracks). Also, per-
pendicular cracks outnumber parallel cracks. Data obtained
up to now are plotted in Figure 34. Groups of 6 samples were
65
taken from the heat chambers at the indicated times, bent and
analyzed. Shown in the graph are the number of through
cracks, with perpendicular cracks in the top graph and paral-
lel cracks at the bottom. Figure 34 shows that, for 2250C
exposure and bending over a 12.7-mm mandrel, through cracks
appear before one month of exposure. At 1750C, through cracks
appear at about a month. The number of cracks grows rapidly
with time. Data for the 1500C exposure are still too few to
exhibit a clear trend. At still lower temperatures no cracks
have yet occurred. As expected, the scatter in the data is
substantial.
The cracking model predicts that an e/eo ratio of 0.04 or
less is needed for cracks to start in the EPR layer. i.e., for
through cracks. In Figure 33, the e/eo = 0.04 line would
lie somewhat above the plotted 0.1 curve. The starting times
for cracking at 2250C and 1750C taken from Figure 34 are com-
patible with the model plot in Figure 33.
b) Static Cracks -- As reported in Section IV. all 225 0 C
creep experiments under voltage shorted out temporarily after
an exposure of 2.5 months. The X-rays (see example in Figure
35) show striations not present in other pictures; in addi-
tion. the Hypalon layer has lifted off the support. The stri-
ations appear to be associated with cracks.
Inspection of the samples reveals that after the long, high-
temperature exposure the polymers are completely embrittled.
Temperature cycling, mechanical vibration naturally present
and caused by the ac field, and asymmetric stress distribu-
tion lead to cracking. It is suspected that during the crack-
ing process vapors and fluids in polymer pockets are freed
and permit a surface breakdown discharge3 2 along the crack
walls. The discharge cleans the contamination and the insu-
lator is functional again. Further observations are needed
to verify this explanation. Repetition of the 2250C experi-
ments is planned.
66
70
U-.'
CC 60
00
2.40
-I
cc~ 3
Ow
IL2w
0Q10
Icc
I-t-
0
2 3 4 6
EXPOSURE (MONTHS)
70 II I I I
. 150oC
(0 60 U *1750C
A 225°C
045
60
40
M4
40 F-
&U
rz
<0-
301-
40 A
20-
101-
I -- I I I I
0 A 0
1 2 3 4 5
EXPOSURE (MONTHS)
67
* SL
691
(I) Insulating (instead of metallic) caps on conduit corners
will eliminate creep shortout to ground; so will mechan-
ical load relief (tying) for downhanging cables.
70
REFERENCES
71
15. H. St. Onge, et al., "Research to Determine the Accept-
able Emergency Operating Temperature of Extruded Dielec-
tric Cable." EPRI Report EL 983. November 1978.
72
30. H. M. Gilroy, "Thermal Oxidative Cracking of Polyethylene
Insulation," Bell Telephone Laboratories Report, 1974.
73
APPENDIX A
A-i
Table A-i Cable test parameters (27)
A. Materials:
Insulator Composition n = 3
Binders 2
Additives 2
Processing 1
Jacket Composition 2
Additives 1
Processing I
Wire Material 2
B. Geometry and Forces Wire Diameter 1
Insul. Thickness 1
Jacket Thickness I
# of Strands 2
Bending Radius 4
Applied Stress 2
Flaws I
C. Circuit Voltage 1
Load Impedance 2
Frequency 2
Off/On Percentage 2
D. Aging Exposure Temperature To 3
Rad. Rate Ro 3
Humidity ho 2
Exp. Time to 1
A-2
heat conductivity and separation). The compilation will serve
its present purpose, however.
A-3
DISTRIBUTION:
ASEA-ATOM CEA/CEN-FAR
Department TQD Departement de Surete Nuclealre
Box 53 Service d'Analyse Fonctionnelle
S-721 04 B.P. 6
Vasteras 92260 Fontenay-aux-Roses
SWEDEN FRANCE
Attn: T. Granberg Attn: M. Le Meur
J. Henry
ASEA KABEL AB
P.O. Box 42 108 CERN
S-126 12 Laboratorie 1
Stockholm CH-1211 Geneve 23
SWEDEN SWITZERLAND
Attn: B. Dellby Attn: H. Schonbacher
Dist. 1
Commissariat a 1'Energie Atomique Furukawa Electric Co., Ltd.
ORIS/LABRA Hiratsuka Wire Works
BP NO 21 1-9 Higashi Yawata - 5 Chome
91190 Gif-Sur-Yvette Hiratsuka, Kanagawa Pref
FRANCE JAPAN 254
Attn: G. Gaussens Attn: E. Oda
J. Chenion
F. Carlin Gesellschaft fur Reaktorsicherheit (GRS) mbH
Glockengasse 2
Commissariat a l'Energie Atomique D-5000 Koln 1
CEN Cadarche DRE/STRE WEST GERMANY
BP NO I Attn: Library
13115 Saint Paul Lez Durance
FRANCE
Attn: J. Campan Gesellschaft fur Reaktorsicherheit (GRS) mbH
Forschungsgelande
Conductores Monterrey, S. A. 8046 Garching
P.O. Box 2039 WEST GERMANY
Monterrey, N. L. Attn: S. Gossner
MEXICO
Attn: P. G. Murga Health & Safety Executive
Thames House North
Electricite de France Milbank
Direction des Etudes et Recherches London SWlP 4QJ
1, Avenue du General de Gaulle ENGLAND
92141 CLAMART CEDEX Attn: W. W. Ascroft-Hutton
FRANCE
Attn: J. Roubault ITT Cannon Electric Canada
L. Deschamps Four Cannon Court
Whitby, Ontario LIN 5V8
Electricite de France CANADA
Direction des Etudes et Recherches Attn: B. D. Vallillee
Las Renardieres
Boite Postale nO 1 Imatran Voima Oy
77250 MORET SUR LORING Electrotechn. Department
FRANCE P.O. Box 138
Attn: Ph. Roussarie SF-00101 Helsinki 10
V. Deglon FINLAND
J. Ribot Attn: B. Regnell
K. Koskinen
EURATOM
Commission of European Communities Institute of Radiation Protection
C.E.C. J.R.C. Department of Reactor Safety
21020 Ispra (Varese) P.O. Box 268
ITALY 00101 Helsinki 10
Attn: G. Mancini FINLAND
Attn: L. Reiman
FRAMATOME
Tour Fiat - Cedex 16 Instituto de Desarrollo y Diseno
92084 Paris La Defense Ingar - Santa Fe
FRANCE Avellaneda 3657
Attn: G. Chauvin C.C. 34B
E. Raimondo 3000 Santa Fe
REPUBLICA ARGENTINA
Attn: N. Labath
Dist. 2
Japan Atomic Energy Research Institute NOK AG Baden
Takasaki Radiation Chemistry Beznau Nuclear Power Plant
Research Establishment CH-5312 Doettingen
Watanuki-machi SWITZERLAND
Takasaki, Gunma-ken Attn: 0. Tatti
JAPAN
Attn: N. Tamura Norsk Kabelfabrik
K. Yoshida 3000 Drammen
NORWAY
Japan-Atomic Energy Research Institute Attn: C. T. Jacobsen
Tokai-Mura
Naka-Gun Nuclear Power Engineering Test Center
Ibaraki-Ken 6-2, Toranomon, 3-Chome
319-11 Minato-ku
JAPAN No. 2 Akiyana Building
Attn: Y. Koizumi Tokyo 105
JAPAN
Japan Atomic Energy Research Institute Attn: S. Maeda
Osaka Laboratory for Radiation Chemistr3r
25-1 Mii-Minami machi, Ontario Hydro
Neyagawa-shi 700 University Avenue
Osaka 572 Toronto, Ontario MSG 1X6
JAPAN CANADA
Attn: Y. Nakase Attn: R. Wong
B. Kukreti
Kraftwerk Union AG
Department R361 Oy Stromberg Ab
Hammerbacherstrasse 12 + 14 Helsinki Works
D-8524 Erlangen Box 118
WEST GERMANY FI-00101 Helsinki 10
Attn: I. Terry FINLAND
Attn: P. Paloniemi
Kraftwerk Union AG
Section R541 Rheinisch-Westfallscher
Postfach: 1240 Technischer Uberwachunge-Vereln e.V.
D-8757 Karlstein Postfach 10 32 61
WEST GERMANY D-4300 Essen 1
Attn: W. Siegler WEST GERMANY
Attn: R. Sartori
Kraftwerk Union AG
Hammerbacherstrasse 12 + 14 Sydkraft
Postfach: 3220 Southern Sweden Power Supply
D-8520 Erlangen 21701 Malmo
WEST GERMANY SWEDEN
Attn: W. Horell Attn: 0. Grondalen
Dist. 3
United Kingdom Atomic Energy Authority 1200 G. Yonas
Safety & Reliability Directorate 1234 J. Chang/G. J. Lockwood
Wigshaw Lane 1800 R. L. Schwoebel
Culcheth 1810 R. G. Kepler
Warrington WA3 4NE 1811 L. A. Harrah
ENGLAND 1811 R. L. Clough
Attn: M. A. H. G. Alderson 1812 K. T. Gillen
1813 J. G. Curro
Waseda University 1815 R. T. Johnson
Department of Electrical Engineering 2155 J. H. Gover
4-1 Ohkubo-3, Shinjuku-ku 2155 G. J. Simmons
Tokyo 2155 0. M. Stuetzer (10)
JAPAN 2321 D. McKeon
Attn: K. Yahagi 2341 M. B. Murphy
5200 W. C. Myre
6200 V. L. Dugan
6300 R. W. Lynch
6400 A. W. Snyder
6410 J. W. Hickman
6420 J. V. Walker
6432 D. D. Carlson
6440 D. A. Dahlgren
6442 W. A. Von Riesemann
6444 S. L. Thompson
6445 B. E. Bader
6445 L. D. Bustard
6445 C. M. Craft
6446 L. L. Bonzon (20)
6446 W. H. Buckalew
6446 J. W. Grossman
6446 D. B. Hente
6446 F. V. Thome
6446 F. J. Wyant
6447 D. L. Berry
6449 K. D. Bergeron
6450 J. A. Reuscher
6450A J. Bryson
6452 M. Aker/J. S. Philbin
7550 F. W. Neilson
7551 B. D. Hansche
7551 D. G. Sample
8424 M. A. Pound
3141-1 C. M. Ostrander (5)
3151 W. L. Garner (3)
Dist. 4
URCFORM 33US ,.UCLCAR REGULATORV COM•ISSION. PEPOO?T fVMER dA aAp..eh, T7DC. POP We be d. ,I
t 33) - NUREG/CR-3263
BIBLIOGRAPHIC DATA SHEET SAND83-26222
March. 1984
6 AUT"MOtSI 7 DATE REPORT ISSUED
11SIPD%DR,•a% ORGANIZATION %A•E AN• MA'LnNQ ADDRESS lInIcIe Zp Cowoe 12. TYPE OF REPORT
Office of Nuclear Regulatory Research
U.S. Nuclear Regulatory Commission
Washington, DC 20555 12t PERIOD COVERED,,m,."pl
•3 S.JP.LEMEETAMo NOTES
Unclassified S
* U.S. GOVERNMENT PRINTING OFFICE:1984-776-0271 4303
BLDG. NAME REC'D
ORG. BLDG. NAME REC'D ORG.
BY* BY*
9 .IAIR
___________jN555057
us %•RC
ijRK-OIV
BRANjCH CiI[EF
JF E:ý;LNE•E'VIG
4 3R
.... UIHT QUALjFICAT[O
?-343-'G OC 20555
IA SH IN:,G T0":