Answers & Solutions (Seet00 ) —<$<$<$@$@ @ @ <<< SEE (Advanced) RRB 10, 10.4 10.2 103 10.4 10.5 106 10.7 ATOMIC STRUCTURE san © PE =~ 27.2% Zw nv 2 1 PE=-27.2% — =-302eV 3 (©) In the given figure if line ‘E’ is in visible region then line belonging to ultraviolet region will have more energy than ‘E’ i.e. line A “ Let n be the number of photons emitted 12400 ‘6000 = n=6.5* 10" x 1.6 x 10°" x n= 60 x 10 x 60 « 60 ® De-broglie wavelength 6.6210 10 (A) For Li?*, n= 6 ton=3 For H, the similar transition is 2 to 1 For He®, the similar transition is 4 to 2 2 Energy of 4 orbit of He* = -13.6 * 77 = -3.4 0V ) h Pmev ~~) h = Jace © equation (i) & (i) we have 2m,eV = 2*4*m, x 2eV, v ‘Scanned with CamScannerAnswers & Sobattoms (Sectho I) mg, IRE (Advanced) - RRB ck 10.8 (A,B) nF @ — 18, 28? 2p", 38? Spt, Sd*, 4s? (+m=0 > t= 0,m=0 i, s-subshell Cetm=a-t i ‘one orbital of p. ¢=2,m=-2 ie. — oneofd-orbitals hence there are 13 or 14 electron as in d-orbital it may be one or two electron having m = -2. 10.9 (0) mo 2e (e/m), a Amy 4x1840m, = — (e/m), = 9680 10.10 (A,C,D) These are the fact. 10.11 (A.C) z as aleueete won} = XER 108% 5 Wave length of 2% line of lyman series of H-atom 1 36 Wy Rx 2 (1-3) sar- Baxs- 10.12 10.13 ‘Scanned with CamScanner a. PPPPPPPPPLEs ffs SSbhfAhBSASe Answers & Solutions (Section). —<$<$<—$< $= & @ @&=&©£ ———_—_—"_ JEE (Advanced) - RRB ca 10.14 (A,B,C) ~» (a) Co™ : 15? 25? 2p* 38? 3p* 3d* => » = 4 unpaired electrons 2. y= (4(4+2) = /24 =4.9BM (b) Number of radial nodes = n-¢—-1 Number of radial nodes in 3p orbital = 3—1-1= 1 (©) Number of electrons with (m = 0) in Mn (18?2? 2p* 3s? 3p? 3d°) ior 3p (2) + 3d (1) = 11 (d) Orbital angular momentum for the unpaired electron in V* lies in 3d orbital. ». £= 2 8 (2) + 28 (2) + 2p (2) + 38 (2) + os Orbital angular momentum = /@(@+1) 32 = 75 ® 10.15" (Bc, D) @ 10.16 (A,B,C) Since B is in infrared region and A has more energy than B hence it will have lesser wave length i.e ultra . violet, visible or infrared region. B 10.17 (A,c,D) number of photons emitted = 6 > n= So, —>— =6;n=4 > 2 excited state is 3% orn = 4 > photon having highest energy will ge 4 —> 1 > . 14 15 So, its energy will be = 13.6 [=~ gz} = 19.6% 4g = 12.75 » when it is incident on plate having work function 8 eV then KE = 12.75-8 = 4.75 » KE will be equal to this value or may be less if electron is inner electron. So option (B) is correct. Option (A) is incorrect because all photon have equal velocity which is 3x 108mis. } (C), (0) alos incorrect because number of nodes in n** & (n—1)" shall are 6 (Radial node) & 3 (Angular node) respectively. 10.18 (B,C, D) Transition is taking place from 5 —> 2 => An=3 3(3+1) Hence maximum number of spectral line obsrved = ae (C) number of lines belonging to the baimer series = 3 (0) Also we can see that number of lines beloging to paschen series =2 10.19 (A) Specific charge depends on mass of ion, which is different for 10.20 (C) ec can wai-c 6.6210 an 91x10" x4x3.14x10" = as uncertainty in velocity is very high so we canot 10.21 (0) Binding energy of Il excited state (1 ‘Scanned with CamScannerAnswers & Solutions (Seco) SEE (Advanced) - RRB oc 10.22 (B) fs : Energy of photon = “w 10.2 eV = (H)y_,4 = (He"), 42 80, species is He* ion : 10.23 (A) | excitation potential = 10.2 Z? = 162 V 11 excitation energy = 12.092? = 12.09 x 182 « s92 ey 102 10.24 (8) Few — [Ar] 3a fT) Mn2* ~ [Ar] 3d5 TH11 Cr+ — [ar] ad¢ ve far] 3a clearly Mn?" has maximum number of unpaired electrons therefore it has highest magnetic moment. 10.25 (Cc) Magnetic moment = /n(n+2) = 3.873 = number of unpaired electronn = 3 2M — [Ar] 36°48? [TFT {] 111] [ff] therefore Mn should be in + 4 3° 4s 10.26 (0) There is two unpaired electron in Ti?* 10.27 (D) Moe - ta 36° [TTT T 10.28 (C) CPL LILLIES SASSER ERRAARBRR 6.6x10- Te = 242 pm. 9.11094 x3x10% 1031 (8) 1032 @) 1033 (Cc) 10.31 to 10.33 S=1 t=0 ets mv ‘Scanned with CamScannerD Answers & Solutions (Section-1) a EE (Atvanced) - RRB > U=-2,-1,0,+1, +2 (fort=3), No. of subshel No. of orbital = 7. > No. of electrons = 28. > S=3 t=0,5,8 ) 44 U=- >. > (fort=0), =-3,-2, -1, 0, 1, 2,3 (fort=5), 2-2 7 5 3 1139 5 79 GL Be 2222 Be 2 2 22 (tort=8) : No. of subshell = 3, No. of orbital = 19. No. of electrons = 76, (1,0), (2,0), (3, 0), (4,0), (2,3). Energy order of (S, t). For Atomic No. 24 (S +t) rule. There is no electron in S = 2, t= 3 10.34 (A-q,r); (B-p,s); (C-p,s, t); (D-q) eg? (A) BE. of He* atom = 12:9*2 2,3 ni Hence it can be 13.6 ev, 3.4ev both (B) In 7 + 3 transition an = 7-3 =4 4(4+1) maximum number of spectral line observed = sen. 10 Itis line of paschen series hence infrared region (C)5+ 1 = 10 lines, out of these transitions 5 > 4, 5 > 3, 4 3 transition will be in infrared region and 2 -> 1 will be in U.V. region. (D) series limit of Balmer series is the last line having 3.4 ev energy. 10.35 [A-q,r,s] [B—p,r,t];[C~p, 4,1, 8]; (0-1, 8]. (A) Co : 1s? 2s? 2p® 3s? 3pS 3d® 's0 No.of fully filled orbitals is 10. no. of unpaired electrons = 4 So, magnetic moment is greater than 3.87. no.of electrons with n +1 = 3. i.e. 3s, 2p are eight. no. of electrons with m = 0 may be 11or 12. (B) Sc": 1s? 2s? 2p® 3s? 3p® no. of fully filed orbitals is nine. no. of unpaired electrons = zero. no. of electrons with n+1= 3, ie. 3s & 2p are eight. no. of electrons with m = 0 are ten. (C) Cr+: 18? 2s? 2p8 3s? 3p® 3a3 no. of fully filed orbitals is nine. 1no.of unpaired electrons = 3. no. of electrons in 3s & 2p are eight. no. of electrons with m = 0 may be 11. (D) _ Ni: 1822s? 2p 35? 3p8 3a* no. of fully filed orbitals is twelve. no. of unpaired electrons = 2. no. of electrons in 38 & 2p is no. of electrons with m = 0 ‘Scanned with CamScannera. (en i taba icas 10.36 (A) >Q (8)>P (+s ()>R (r= 0.521 x A (i) V=2.18x 10% zim (uy Tox KE® = (ke ee 1037 (Ars) (B>p.8)i (C >a,n8); (D>p.as) (A6>3 An=3 no, oftines = 23+ Alllines are in infrared region (733 0 ans +4 no. oftines = “4*9 249 2 Aillines are in infrared region (C)592 an=3 Lines are in visible region and also in infrared region (0)51 Number of ines = £%4 = 49 Lines are in visible region, in infrared region and also in U.V. region. 1038 4 Here n,=5&n,=2 So longest wavelength means least energy difference transition i.e. n= Stony =4 (antes (| eae lar oF Sox. =4*10%m 10.39 For the positive particle, applying energy conservation initially and at a point A KE, + PE, = KE, + PE, = eV'+ (+40) (OV) = 0 + (+46) (x vott) {x = potential at point A} = x=1Vvolt Now applying energy conservation for the negative particle at point ‘A’ and initially => KE, +(-2e) (4V) =0 + (-2e) (1 volt) KE,-8 eV=-2eV > 10.40 x=8 We have ae= 2 x 08sev as energy = 0.6375 the photon will belong to an (+) =136 (% on (od) [8] Hence x= 8. 1041 4 @ xiao Let no. of moles of X be a ‘Scanned with CamScannerAnswers & Solutions (Section-1) JEE (Advanced) - RRB ca D 10.42 9 > = n » ’ (41) 14 , 102+17=136z [57-zy] and 425¢595= 1362 (3-5) ' ‘Solving the avove two equation we get, Z= 3,n=6 10.43 12 ‘Since electron goes the state where the path length is 5 times de-broglie wavelength. > ar = 5% 2nr also — FA => n=5 n Hence electron goes to the Sth state. — 5 4 3 2 2nd highest energy line will be 4 -> 1 tbo, If this photon is used for Li*? then (. 1) 1 = x22 136 [ #) 13.6Z ny my > 3412 Hence final excited state = 12. 10.44 325. x xt 1 — > +e 5 Le. nail 2 2 2 ’ ers FE Acar) Ci 2 2 2 (+) 1 1 4 XK K+ 5X (LE. -EA)=410 kd LE. - EA = 820kJ (i) AH Now 3x — prez Now equation (i) can be achieved by (i) + reverse (i) and we will get 1 1 > > EA =735 giE+ 7 EA LE. +EA = 1470 soe (W) 2E.A = 650 EA. = 325 kJ/mol. ‘Scanned with CamScannerAnswers & Solutions (Section [) gs SEE (Advanced) - RRB CR 10.45 16 (PE),., =-192 eV -. -27.2Z2=- 192 or 27.2 Z?= 192 ». 13.6 Z?= 19/2 = 96 eV 12400 X= 1550A ». E= Gae5 = 8 eV Electrons from ground state cannot gain this energy as the I* excitation energy (10.2 Z? = 72eV) is greater than supplied energy. Electrons from (n = x) state jump to (n= x + 3) state absorbing 8eV energy. HLLLLLS, so, electron jumps from 3 —— > 6 Upon back transition, max 10 lines are produced To produce max 10 lines, minimum 4 atoms present in (n = x) state. So, maximum number of ‘Scanned with CamScanner