You are on page 1of 46
ow Eg) 604.2 at 6114 nd ag te 4-10 ans) eens tn ne acer vot ana em te ithcomesen dole ela eaege eng nh searing dein otro tn thera pe pete i npn orate epee ern mime be OA ‘certian “Te spi te pat ete rece sept We Se Spee BI) and a See So ‘ashe Te pres of is mage waste tems af Sere hee ae ee ‘Sopeig, eeh Weay © ay Se ea ua 11.2 The Energy Balance Fain a a Secs vin oe erin ae Pere ae ea ete Se jeu ‘fue the har lo oc sem 8 ins the wrt ne by Se een on he (Siting Sor sin nt eegy ae ai = 59-5" au en) cao inattns aoe nce setae ate ee Si eae cerca nace a oe agin rion eta oa eR tear sou the om oF DS Ete eee SE op “ten : i a at | feat) fag) [StS] [tg eel 7 MS. ns _ypealus rach emin eon 1-2) ole Jol hye Sanpete ‘eam tat ecome be em we a ss suepin pent wil ape soap fe a elena rt ia ‘Sy hla roe oma yen te > ‘segs eng tem a reece ol fo FF ots rcs ennthopcn cg Ese fare »- Ef a be 4% Reve nh 1 Newnan no Ma :Po tou we sean une Bow We Sethe the aff wrk we cna wth he th yuton 13 Le hase a emt nn th em cane em ‘heey bac tt pre ecg ngs te gc ‘pace Romie Succes -t t al fe guw Sram ri Seamer 9 “The ene Eth mm ol ral ene hte ine ne (0/2). THe penal eng ea any the ne mck deco mage ety orig nau tee tater as) tn i at hen cr i a nd he Sar clietaatcoietnsanes ane Bau, a _e rea hep ned eine nsf the nena exergy ade oc PY and ~ ae Hari ars, aot a setae pe ene ct — Peete cs pore Pea) (pt ot, aDb ESR MEAN NOW Wiehe gp Somiticiee egw Sel - Sen reper tans Pc great mee ede fe term wr tr kc Soreciatatecmecsat qooelscns one Pac te mbt A repent he net condiions. The si he ue fhe cent seu wl be repre! Sy bcd Zz | 2 COTA ange U8) aa sit er rare ono — = = I ois Shale B= a9 Save ‘In Seton 11, we dscused that inorder to solve reaction engneting rst ht las eae toe enprse, srs ‘ot fava acon Teeny Ec eg ia Euston (1) hema ‘Srv sarin potas ne prssd Wo deep ts aon. 11.28 Oven of Enogy Baarcos NEES spe te lloing pees we manipulate Equation i sea petit er) O-2 » ca a or yes we hve been desig FF 14. Rin ert ecm ofthe energy balan abet in Step 5. 7. The equations ip Table 1-1 ls: zante) ga | ie” (eec-0¢a) “FOG, -368) eset oly Ge Sra eam) ee i vc ~oa e ae Foveaumple lhe elon finder etn. Eqs 11.9 in Eee mee y) ee a ib cd wth he mit fi he anc Tinos nd cops pts inf ro eee Soe icine stains ea Seat ph coor crt al pee ea Fee capo a (Case 1 Ada ie eatin aid out fiat. we Ea on (LB ford aston 8 = 8 ntxample Tt w obtain mm, Consent wean ow ba fncon of X ane fast choosing tes cling fom Eaton 11-18 hen lang om (E1113) thn inal ealating (1) om Equation 1113. (Chose X cate Taek caleaate- cake anne thiequns opp of ia faction of X, ‘We cat then posed tau FNS sd CSTRS he sbohne wot abe Tere ces mcr? Level pthc ace ie frmaas Appene Au However of wang Levenspie Se uy am Pm oe ou coupled rea Ee and mat lnc equate —— Ee " Te User erty ney arcs ematong ws ez nmzncumpegcgmmain tir 113 Ta Users eat an oe crane en ries! We wil now a Hatin Soccernet Lourie eam cad ind ae tee a roe e gv pew MF 11.9.4 Disactng na soa ta ar Seana - » inal be ‘10 Obtain the Hoat of Reaction = a 7 thence tty res epee pe ae A saa ei btn 008 hI aero. aa sete econ it Stieber rh fives uti nd, eee ee patient men, ‘nated ind vit mera rn oa ews ogee Mn sh Saint oh ny Cho ea a ae ee ise meant wh fe ea het es enue Ce We ees Serena : itn yee mn ot ‘ Able i Vue hs tes No al toes - « Ek (hpi deneny eonea % i ‘Sor eon ope aly The ool dese» sendy oy tle ean by stig Un ea oe Faun nner ye tale pasion qn wh erage sn pa fnAM) ONT + Te aii oy ati PR and TR FR nd PE wt SiR whe cts ope can se ope ae Principle, one could sme eb Stlctang he Sain ef ce sso ‘open and eatin of vrs ey me ow che een Ge Sha avg pcan he ma ei 0 ml ea Aste —. testo an “The ne an ott seman ters Eaten (110) re expanded ren to 2 Hafn= Haft Han Hat Hoof Haka any ad EH R= NR Hehe Hato ania wre th abst represen ert species “We gre he mo fam tos nsf cones ta gna, Ane mbar te of pear he ae fo anal abd ocho etc coeficen Re Band A= Oh ‘We con mtn hes gb fr the mali ow rt et Ear We twatnti ender Eguton 112 fom 1-1 gue Sra Sea Fatt +H Hg HIP Hy) (Hy 48) 7 Teen peas aed Pate he tet ee ana eetT AOA EAH | 038 Alleshalpies eg, Hy Hy) ae evaluated at a in the reactor and. Seep iiake act ele ene hese ie. species A Joues per mole of A reacted). sen en 2 = 0 ae Entre a Ha hae hae pce sae 6s nh cr mac eter ee Se eer coe tae en fn a heen arp nich () gen aly 25°C oe any substance hat hy hed E00 ae pee a Ga aus ‘pla uns ofthe et capt ae e ol mmm alot legs punt of cent racine card coin ine 30 ot Inve pecans Cnsequcty l uber in oa en Dele (Capri e sgeyhe sien races, Under thee endo, the tuo oes facies Tt do be ey formation at thereto temperate FY cn =H) any Af pe changes Jo uke pen ging on the temperate fr which be Uy orators aen ante veacon temper Egon {Att na be el nted of Egon 0119 Teena opcay a exapenture Ts equ expres squat fancton oferta a Gnas ar eat =e sremararre pe calculate the change i js. uct se oy Pemmamenne Morir Oro, senefirw eh oe: fro* =fleareeit a is == * 1133 fing tT. SMT ar AC ue of ence mPa TWH EY ea uy Be a res attempt Tinton 1-10 sy Demeter BM) ine eit any of ch pci i en by es fee owing hey oh specs, we Be neff ser -bGr-H ‘thectea}mo abn bd in cacy pr mae ofA ae, SC " i en spc cane und in Chr the ton of byoyre cad sarogen st See te nna aoe nage 12 Ha of esi Se et TS Sesh Sie Se ea eae eho et Tce 34,7, ee in 129 ak eb ee fe noni he goss ES ped ye spore st ERT SS ESS ean em aa a mete Pore NE C5) fe) I-MEY——_N na =-2apeane! Soe FRC W Gua Pace Ra Do eta ie A Ana e183 25 Reeyeceaes ona r argimey= nian Ny eo een ahem he eminem 1 ering a ee cio He Seca ‘soln Gorse a a oe nai a12)425-28) ‘ 2531 allow a OSEK) = ~239Kjmal AIBC ‘eh bon nro rece angen Fim) sucen=—n91 HE wa Ana Tis esshoved mocks the ext of atin wi {sz crs pa he es loan fhe tans 4 Ro oid ea exo wh epoch lion ah pes tae sesh extn Fl = Nowhere empese sr Nahant can cals the ea of scion tan eo se TOUTE tm antec PitacFh gpen eb smectite [e=Fat6G Ty -an AGT] 012m {eal fhe stems we wl uy heen le ing the he sue eer re ne ae a we Ean 1-2 reper od nd then prosed to crate the ren ecb eae Hone thc oer to ea te atm dre same Te Meme in bene sec en aha {bom the sytem can vary along the lng ofthe reactor or Q ea yyw me, Tis robe des nt oan aha maces wach ne eget found i indy Tee he aac tab ear ml fe oboe 1144 Adiabatic Operation eto ney a gc ot lal wh aio Sndstingalubac aca eonimpono i Oe In the previo secon, ede ution (1-28 hi ete omesion {6 tempera snd theese Soar Q Lets nope aay Se tah be me a clef gd nlc one psi f conan ooo wok W, = 0, abate open QO Ts T andthe eurangg tao inh fam xp the omveron Xs Tuc enya Teqq=to Tiamat 1860=T 129 te ay na 3677 tom ne emi fon tte habe comrade Pee daa gue! tneny base ater nthe aie eh sas Ebel mae 2 i pgs CTE PR oP and alo 4B wl etait Fr a teal Tale a common wh Fees ees soke ge vane of chem eacion apnesting problems ss dacs in Sein 1.1 ce Basan eanyle aah today sto use ste sucha alah a er ttn 1 nT i ain [STE dnp om Sec bmw 6206-79 semana Aar:CSN ry, teers he Ge 10 mat isin CE both “hele Mma we CRE age ANT dS ae gh peace ER ‘to Xnd~ note wpa (afer (4 Ue ea red a pt) eet FR cha Adin nati 0} tame, Anne = 657m ese Gee" jim Go [ete ail bre 07 ng wilde ech nd re ‘Sleesur mie ocean Slt cquren coe 009 Pa a Poin sa Be tata ‘s enn alive Juana aa win rte ce8205 = fie k= bey! on ws caer) epic sem en cnr eer tone a ait =o ing rent ins tine 127 erm = (seam Elan Penoer ers filmer ewe cath soar (oot it amc.= 0,245) cen repost, seein degen (&-2)« ‘Surg recon ey, Tank 4, 0° R ing eS, 7 nd gaan ale s commen (al ms tee oo] eum ma actealt-fr+g a] aon gv Come 4 {bie cn ae un 5.7m cme woe ens ae) PR compte ano lot conerson nd temperate pole Bee Ran phe peeing to equi fi he cer wa pet deg eat ee Seer mic iaphe nace: bot na terion and actor Pea Tipeee freee smd EEF ste oa ng tae SN, GUINEA. EH A TAN, Osborn ET ag Feceoen us 374 = ‘ ‘Teoeietinligetrmrrwis e Seeiyricencareeettiar wg vette," ‘anu hs men oh orion wan cmp eA nme [oleae ZEEER £ & thet eTAE1e abe ger? I Teri: he 708 tren ltd ee ‘Sree ley me spp ae ‘Sst concn 07 mew ne nla per mug Ung Egon A 26351228 pe Ane bin sere axasoesatin! +}sMaat 659923290! Rermatemet Rea Ovni, on ts ern eT ae r 11.8 Adiabatic Equitrium Conversion Zee ces tt echelon the hm seein, fr cnr cose squibum comerion ‘crac wih intaog capers op os cman 1 for eee ‘eos eeu cone Seeae wi cee npeanae Fam 404) = 303K See AIM TE AT : et een corer fe hcmei [Exothermic Reactions ig 1-1 shms the aiton of he content tin guru cnr ars onc of wnpent a an terme eution see Append igue i-th a tum eer as» aco of empresa fora int rer maton th cults owes nb dae gusion E11 1) aiid ena oosequey cat te alae a anon of: acy sing eer utons-51and 13.4 rm aga FM sda ont 312 "he moh hsp of he Xena Tce Fgue1-3) wl be sii forecaster inode "prema the mama coven that can be aed na Sere fulbmu converioa rence ef tenpertae igure 13) th am jr rns the seg) tae gee 11-2 nd joni (U-LA satan nee 20Gq—T9 ae my — a Aldi fens = sa id Yaak G,= allen K = ff) =m") wa = nosh oan i i Setting ee -..., (0 Combine rate an ich to ity afc af reset) ee Sikes 1 Malet : ea oi ad may cael a 4. Stohiomery io =) is eae rt i ery tae a 6-8) aay : aay eee Ghani pia anni a is asic pre eat eatin ee ae Ths onrecon of he ee tlc ie, Xa, with the them sa salen 3 cane gabe ancl cer “Smperer a eising epee, hein eed rom Ty 10 Ty. the ne ans) ‘ac tine wl be Sie th ght {0 the orga! le {ils wl Stel ph ad be pr ote or im sti ntterperatte nas Shug Kin ems fn aon 1-49 sd inghng team omen eee Po Es man Shing Egon 1-4 es aes} Eo (0) naib gion tempera conversion 1 egitim Contant Cae 3. ton as con of epee am 1-4 ating he Aha rion emptor Pera the dene x ans) 36 264-6, BB selina Fiano ef hme Dt XO, 28 74 Jeo) BIA, wen cs ay, peer F ean ep DHT 298) 1) seem Tmt. ee Sa. eee ea een salph “tana borne EI. — Fre E1141 fhe ats rm pete a ‘sr No Ces pn epae [Feat al hp Oa {cae the CSTR romeo i 9% he ac ii com ‘eptncomspning an eey era 40K Freee el ED b= (sxe J) - 1510 enftcafE24] rom Fp 1-41 we ht fr semper of 80 te aac Fer cerca 67 Kad the conependng sb ean {Syecn sO Team x= 09009) = 044 rom in atin ns tempt comepenng X= 04, reny(eite)saoe ony -sae sta t= sek X.-0Stanle= COM nag The a sete saul deen te a Serrano th a ample o eodce the conc Suter The abate cingout an ass ett genrennone anh ee aint inns on 89), ullrium conversion FS ng ae ein decease with easing ering ce at endemic iaseanpenn cress iinet "7a, Tondo rgae Eta wan Pema th se eee ere inti. stl sor sa508 | +16 Racor Staging wih Interstage Cooling or Heating 1161 Bxdherme Reactors omens the shonin figure 1-41 can be achieve as ‘Src peor cmecing recor srs Wirt ey = beh Se iee{ fem Fore 115. Rowers i merge col, JnFigue 115, we show the cae ofan exathermie abate reat ae hecinaiRreacerais Theat epee to Reactor es i ad conven, X ow 8s the reactor conver Ss Xa Nex we pass the ext steam from adabate | eto ring he emperte ack down to 50 Kv To nea the conversion, the seam the Increases 0X, which s fallow tor ‘ thisscheme is shown in Fig 14 BX conversion canbe achieve" 11.62 Enacheric Reactions "upg the octane nue a da eins en henna tune The mere com higher the octane ring Son 105 pts dcme ahr he ae to 1035) Coneaueny tis dene to eh chin hdrocarbons to branched hemes, nahn an roma The extn quence www oO = Om oe ae mason ow cope he nd a sup tiene he wl ete ng a tion sion gus ure Art SPC me ad ck ernie oF extn ay ose SBctcou agp! oolsox npc ugha ah vl ea Coane re oy a ae ets nora keen orden ated ale Weuercitbove Soap sisies milano pc ele a Meese mht 2m yong al spe eae podic com nr sve 17 ima pars ee a Aheequilbriv cove sorte nner tr Go 1 ye _ ee =~ Seeteeeeeea cose “the fist reacor i 480K — Peer eae rn Se Be cage fre cert The ce Solcmesnns ToBI an e001 ee in eg the ior T= 568 Kb downs che eH) einen 0-3 tale Brn on 8-26 -Tt= Et) usa) F013 = 52 Ny HET) BHA nse is rt epee 0 Fale, 6O9K-T) =a ans Tuts 244 teem cl ema mite om 56 1 ‘okie idiea owe SST ey mie cr the a cer Raging maf a Sponing fsbiceulbrum comers w 07 Ney pce ef he ee ea ca mse 92 Thee bg a Same aslo aes | Semen” : perenne (SE) fetes aac ie yore seca Smeg ce me sus cog 2Ghace ee Sey erate cme tern Sa Stereos toumgrsm ce et, Eetaaimeedapem een sal 0h reread ate the ex ladon ech exchanger se ee 2 ee Sa = 117 Optimum Fed Temperature Wey nr dbr of ide or xa wi ai {osc lagpe te el epee aed Th eon or ‘Shenton Alor enn gsr ph ed temper ‘itacin a ibaa acon wil paced rp oc ‘aur omen wl bce osm Conse, vy i pe ‘life Arde ober extene ow dtp es ‘Sitesi Soh guesson “Why oc col the ed othe wes ScStovenyomaety Tey kn to cnt psi the reac wld prose! ‘Rison ing in realy oo ile cones, 80" etremes, low coeversion, temperatures duc to equildri™ “ cause os smal a sr Searing 0 nen er Se Ee aaa oun = le he ote (1-1-¥ ten mse ot grein mle Chana te Aubin TempertrandComenson ‘pun cs ancien fF ee EA dh ney ae bs sooty 43) Figure E61 shes pl Xd Xo tes pt ri ening ere HLA Ahlan eget cect te gunmen foe ae ech mc has cop ereet eens tac Se eset copa BE Conversion Pies or 0X, sorbent e Teun eae empowers em ree et ces ces tn 3) ncn Toners gc eaipendl ae em ttt 42 canon ple. hose eer emptiness we mere ng he ar Salles soe ene cri pte dove hee ook ats ow aa et ates te Sieg aaia ed ry etree Soon noo eee serpy a oe op So cope eae ‘BE eae al yd crc Se he ean pals “Sree ar fos cer cat epee weal has ihe ‘eee pts in oe meg empe e iJ eee tL44 come teatticnt Sone Bl stain ee ear 12 ll fous on rotor was itn th al coded on the CHE Fag er reteset SS eta eg Wwe ona) tang Eatin Sl nal aa ple pre at ORE Wee SITE waTERIALS iia ecyieaies pos TSermary Notes hy wide yy ie ese oe 2 ae ee cr a ieee eas eat a oer tee aarp ere nen EN describe, en 20 ot 21 Stead Ste Tar Reacot wih Heal Exchange De... ni econ, we coma fthe reactor (Figure 12-1), ries es Smee sicko ‘Boonie 2 er er 21 ute wt gamers 121 Doing te Ena Basce for 3 PFA Dewy om the lame AV There wok tas O comes oery ee rr) ofthe over ea 2 ld the diference bee pando tack Stay Sat rR wer he eae TERE he he exhnge prt ome of ec Fr 3 a where the actor they inh rac debe 89 gion 2 ible 30" ar, AEE g aa aan oon Psy teense 6-year % oe Seng i129 2-4 in in 23 win vat 1 Boh 19M era wean ws oma cay q.= vat—1) cas in ehprne tt te en aaa ress Hu Eatrye eesti me, creme es er ee SEE So Sea San Spe Sees tren athe of oe “Sika Scene be onc por arate a ec na, son Ne sn deh elma gictencfiey incre See ireemine me ingen nt Si eon yn reagan nap St rani won [Fame ee] ees pel aor = AN HOE elk Senses rp nde. here fu ed ilaneoaa Te sf! ea mee sare) w ta ber hs ‘ seo sn eh he rose op gation $avexn © and sdk he temper oe etn iT rr me ma Be cio ane Hoe nes ten we wl ere he ong etn fr sce dtr) o sh wth he ston crc erie: i fr felis gmc ie ch ea ‘ms (A), (B.C), and (D). i 5 Lind Phase For par eso, der not net fl prema 9 mek - Comeqeny we ed ey she us (A Da enc: 422 Balance onthe Heat Tanstr Fd “The heats dw be cv exter ractons a inert hn perso or ey igh spo th ext od rset he acing ee a a ee bel nye ilo eraly ea sg en woul halen be lope anc uo ora com {Store he for exter ios homer sesame sons 8) SS cabuhema nares ne len ero a ta ay teren Vand WA shown igre 22 Fre ne acelthche eng aegcoke Weel eo eae the ety coed and the outer rl fhe oan SHE OC altel i by coenton @ te Beat aed the eceit? (oon daeppeb ecinge user Po reesen Wm eH Eh a nee fe as a a. ae “4 WS an decoinin sre ween Vand +4, ‘eee eon Bs pts teal ' nde) [elves rian ic... a seems tte te artical 0 hee 2 nh suat—1) ws “posses uo (124 th cane ely of he cx can Mgt 5 Mag on ‘erin ssn empress eee | eo cr ar chert as conan o sie opera pris or bth ete sca fal onos To ho? sn 1222 Cartaciet Pow Md ecole fiw At the et of he rece erwin earn yh tbe oa oe ec q- eD aay ‘Aube ensnce V0 :X=0md Ta ‘We ote at ibe ore bres Equation (121 and 12-1) mins see oh “einen sume ow poten fin eae sndunpentire qa sou pce shows eT aie iad « = » pee it5 tare maa came gs vember tons cone el ah 7 Mapai or PROPOR Oey wh Yat Chace Crete it re den 7H. aan tte gre ene eatpenin eis ae a cau cea rue aS deiner tee 3 OE, “emai agama Ape ne Tener aE Gt, Getta ee {Sa matpama mayan ee Tetemerc ee shown Fie E21 Ott as ok ROPE lds nin ce Re cee Weise ee Soon ee SE oer egh Xs mrhbcow bee eben PE S SS cena el iinet al ISIN ae een ig a aces aS om tah mi heh cpu oon Cn inn or rnin as Rens eo ere a eC a Boat ind dele rant pe Pt Tan oe hol (0 Abt poten et Compr gl sb ad re papa ee Atel etme ma ith yd =a Ae ange the pmeh pegs aepare aphid ema The melo oA exh fhe nrc pel ar wossimgh 3 -rerboala pee ae aa tee os teen navtonatsentioneny [nae ER] men psieiele] ae Eno ena fart ge cn mien Sema cyedte xT toon nd wh vm Tree rae neti Fae tae ha Afri ean. [afental ond apt itvand 131i orca iw he aac hn of sary Sand T= 15 Kat 2 The Rath prog ol ‘Soevinetioa ES} ‘Aarne PFE Ce won, ne iy feet 11 rds manera re 21 sot ra eprecg wr hlte erro cera ce per Haan ‘tiempo ecg mi ee oa hea {icles td Tessa tn When ond oe mh i tn Pl QR od ont het ster ese remem “nsils Far ) C-cren achenge We oe rete neste aa a he nt ce tet eta Sse none bihfe rc 1 an ys Com Sue Meteo apenas Soon Kon ema ihe ler Sap sete emer el 8 he on seq ert Tt he hc en eng ae tess Xe ox temp eee a hee 0 ‘oer set ce throes Cogn, he ec a sg ae dba ee WAR Titan emer aha ee he wo cages ine poem Fi nan 1212 mm eee lla wrt) a bate = — manent naysamsrcliascs secgenty sree cnnis rargConmtan ar Es i aon ~ a |, Atif comer cn tt the ne he lhe erate Aig ‘seed atm omer ened SRE aT open np mt erga Hoty 24 ae a “he an nash nthe path pr adhe ae po He urtnen show etm Sheets ae ee , tetera cry te ante ech Siiceepirteenanor sas acts Fad ee sil eeieaiis onc Pa te tema feof oma Wistalenipgeides te pgs oo cpm ah ip bot pe pr math report we he tin Adicio eae cng es tauirum bring X°X.- 000TH oa brane oe (pet The rier Xe Km horn oe 13 ao ‘Soe es ba eer a thet lng penne Te se spots eon ‘Ti ttonoy ew nda boning ice oneseresno pe Ny eet crn eR ordinals an carry inporant copl te a uORE Petts ino samen Sena tena ebb semen oi a ope 122.2 Appyng he Agertn tan Endoberme Rectan led the fur dire pes of heat exchanger onan tn Example 121 we is sean ne cy oa te same stay tater ecto. he ac val 12-2 sof a Ane a tr marten 7 elt coe 400 CH, seer tb ran fet a HP Hg, ara en . vane Ba tarp cana T i Kab. Ws ee ft 9, TRE fer baw atu eae The eco conse of 9 oy Sepiules be We al comer our eases ths cunt Eee ene sn ae Bee a (ce tales wm acai ea wie hs = a nk of 100 conch dh bes 179 nn length crepe, Seema ceewes slp cnesce cn Aaeas ott bh good eon to ep the conversion on Spectators eter ware ee es See Seen st rea ct Seance |e Aid fens 4004, (21667 /mo.c, =163a CO 4(r,>-6tay/mac, = K NN Honk aay 0s 2. hata earmeey tina “Me anny, bso) » Soldotna dg. fondeiterner mas eet wan) auton F127 an E228. ce we ie ene ecina reer etre comb ‘heen pected gaay 1 tether Now turbo Wel enh weeny el lot en hrc re hy eee — emp (6 Cetin tl Be Paramterson Pe Tbe ac a Ei cel ~ = 0076 ml ews 2. Caen nr Blane Puram: ‘hemadmc Bh A DE wing estar es amt anata = HTD “ETOH TD “eh +7481) C2 ot 507 Mia acing te meant 3 2616-24 WDTH Oe io [ect mm anya re oles gt echelon f Eisele dpc senl shoring cess sn Scien fy at we ty mas i a hry orm New pe est fre she bien betwee sha res hs ee ome Mucaorsn enlace ests cocssh mod esgic f S Aut | As: Opin: teen and ne mers etal che gel ces os oe wiboes realtone O ‘teed esha Sc ald te pe al yl ‘ap ect mach i oa ee EST act peee ue une dn crow eo Seg Hoses bens mann na ogi Sha eso meaey wa bcp be (a2 Comat er chang Sid epee, SERA Santor pop ote ofthese a) Wirt) g 140i ee 2) ie ope bomen aoe (Stetson 9s vr fn face Once ths mas aes Sioresabiatacon pnts ews ntact ore, re me a “sony sie Nac Mp . oo ee peek ee aa at 12.4 CSTR with Heat Effects: F Frgwe 126 sm, ad Lo ae sneer ng ope cy sce temo eh 2 ac, Th sn ea sca ene hl St yon leu pebrS ste ; to heating ens nic: nat Re Tes pane ee a ma See my ta es he nero Te Siac =... Segre 9 he le ee eee... a Steers vs... an es Sa aa |e | Gm) ~ atin (Recall hat AN, mean tha the add heat of rato rl Ta) ’A ery high empertres the xtra ee he Aeon dense! Exton 123 20 at hee eee ts Smominatr cacel nd redid 6) =~, Gt shown sa fancion fT fr ent aon eee nie 1291 he fw te Secreasel erhe rece ume aad 02 Ince he tener om). changes sh ng 1210 Ze gee t29 vam cmine ge 218 Yt ae a on, ps9 Wy «Mone, ices ond 128 conn ow SET. gesor wen a 253 ee eam armen 0 ese © i hn ech PMR Einanmeaes lated by cue yc Sein esi pret urine soc eect ct oe Soret amen eee eee

6-6 sth hee emprt wil dcrene a eterno 7 On pA teas opnteperatr blo Ts nd! > ‘eGo ptichtgencd cue ig than the beste ne ‘[fRsnilrocar pearlescent ope Tntasileseay ae chips when he lmer sendy te tener othetenpersture shown ane 3" remo Reger than hc es! arp and nen bathe temperature dst than thet removed (6B. sn eins to come ule card ou foe find that rector ope Bas wien syed «0 > eter bl ron ay bes” trl rhe per enya creping ih on et ga 126 Nonisothrmal Mute Chemical Reactions ‘hema Thi section oat ofthe man portant, no he moat Important ecm ofthe bok. esnips ast {tae mip rence "7 feetag tx wang Conese Sep at aad a a ren byEquaen 2 nee ston ag way Wher we hae multe reactions cc we hae o acon fi arb sum ip.altbe hes recten nthe rast or cach en ery seo, Fe puis any pce ns FR what tne ae pec a ‘Shum hat Equson han pecalond ee PLS 0239) is, Note thc we om hve ne bar onthe et faction. The hea of ae eater torts rue eerste tee ich ke mpd wc Moe ofan eon) fest” mreacton tense tee nea) -[eopesteemes 0236 where the subscript resto th specs the bs esto he paar ‘acon she sre of ndependene Species ewe ping oe eacioas adm the mabe of | e, . seco hom ect gone cia AA meen EE stoma, rnb mene a SECU nde Sait Quart) ees om wh ay = al fresco mA) ane Bo ieeti 1262 Pat actors 8 PER 2 pm pe ne cumple of maple reacts with ht ca on, Eu 126 dacs ee a min hata eas 50 ada acm tangent 1 Malena non tas ta netsh renner Sach 2, stoma pach P= hs mins) ms) mse wins) ‘npr erm noi 239 MES ACAWN DANN) 5, & Te ee) of ADTs ey 009 #1749180) # arr 0 3 Febiochratantteteare wc omni eee b1251 Tog yt epets2 pte ae se oe eee ecg epee aaa ne Sehr cece g aera es, ee ee 1263 Energy Satna br Mute Rosco na CSTR ell ht he ead ute lance ins CSTR wah 2 ng ection (hyd stand aig Sev GUT 1) 0 ta Ty Te ton 7a beeen QW ry BG, 1) 4LdthgenNiv=0 LIZA) agin. ut scuttle acne in the en SEPT eons lm aptie oe CSTR energy alan comes er ToT Sr atgety=0] 039 pana 230 9 aiecnghe we adam con subaru is | saps sora gun Moe ¥ Sato | 240 Forth wo ple acts eb a Example 15 Gbe STR energy acy Fo SGT TI Mind 8H) =O any psc pny ne emu of hie te he nde ‘Sse igen wi at ce Gk om BSNS Rat SS Ra ch et German ‘Summary 635 SUMMARY Bp FOr slnaerensions the energy blanc on a PFR/Pin ems of mtr te at (rol AH, (0) ace wv LG was In terms of conversion : a-9 ve ) F(teea 12 WW Fa(Z0(,+xAC,) F206, +*8C,) ($12.2) temperature dependence ofthe specific reaction rate i given in the form ker) = ker, onl E (t- | =k) oof =| e124) ; 7 HE The temperature dependence of the equilibrium constant is given by van't Hots equation for AC, =0 r Kq(T) = Ky(T;) on Sa (z- i 124 3 # Neglecting changes in potential energy, kinetic energy, and viscous dissipation, and forthe ease of no done on or by the system, large coolant flow rates (m.), and all species entering at the same tem- ture, the steady-state CSTR energy balance for single reactions is = (TT) ~ X{AHa(Ta) + AC, (T—T,)] = 20 CTT) (812-5) steady states G(r) = (an) & ) = AHR JOO S126 a : ie e én RO) =Gpl+eT-7) gay E aes UA dT= KT, +To 5 ae 1+K sy a(T—T,) (LAH gy (TI-UaT=T,) fs -&-@ < DAH int Day ist peorcan ener ie en term i [apse eam ane ep tenn eben frertaicdenme aon epee eae it Peete rela Seite arate LS Sti greta eta a9 Seite = (Se == {termi a-Si fal eed Seca ae sci catia an ama we hep

You might also like