Professional Documents
Culture Documents
SILICA SAND
PROMOTION
DOCUMENT
July,2012
Table of Contents
1 INTRODUCTION...................................................................................................................................2
1.1 Physical and Chemical Properties................................................................................................2
1.2 Processing Technologies..............................................................................................................3
1.3 Geology and Occurrences............................................................................................................4
2 APPLICATIONS.....................................................................................................................................5
3 SILICA SAND POTENTIAL OF ETHIOPIA.................................................................................................7
3.1 Fetera Silica sand/Sandstone.......................................................................................................8
3.2 Mugher Silica sand/Sandstone..................................................................................................10
3.3 Enticho Silica Sand /Sandstone..................................................................................................12
4 MARKET AND TRADE.........................................................................................................................13
4.1 Opportunities.............................................................................................................................14
5 ABOUT THE MINISTRY OF MINES.......................................................................................................14
5.1 Mining Legislation......................................................................................................................14
5.2 Investment Climate of Ethiopia.................................................................................................15
5.3 Mineral Investment...................................................................................................................15
6 REFERENCES......................................................................................................................................17
Table ofFigures
1 INTRODUCTION
Industrial sand is a term normally applied to
high purity silica sand products with
closelycontrolled sizing. It is a more precise
product than common concrete and asphalt
gravels.Silica is the name given to a group
of minerals composed solely of silicon and
oxygen, thetwo most abundant elements in
the earth’s crust. In spite of its simple
chemical formula,SiO2, silica exists in many Figure 1 Silica sand deposits at Fetra(Photo.by Michael N.)
different shapes and crystalline structures. Some silica sand deposits may cater for the
Found mostcommonly in the crystalline used primarily as metallurgical sand.
state, it also occurs in an amorphous form Thecopper and zinc at some smelter uses the
resulting fromweathering or plankton sand as a fluxing agent which, in the
fossilization. moltenstate, reacts with various impurities in
For industrial and manufacturing the ore and produces a slag. The slag is
applications, deposits of silica yielding drawn offwith the impurities, leaving a more
products of at least95% SiO2 are preferred. refined metal behind.Silica sands have a
Silica is hard, chemically inert and has a large number of other industrial uses
high melting point,attributable to the depending on their characteristics.
strength of the bonds between the atoms.
These are prized qualities inapplications like 1.1 Physical and Chemical Properties
foundries and filtration systems. Quartz may The three major forms of crystalline silica -
vitreous lustre, hence its use in glassmaking at different temperatures and have
silicon dioxide contribution and non-reactive distinguish between alpha and beta quartz.
Figure 2Silica sand deposit seen from top view and Wenchitriver
physical and chemical processing. This
from distant view (Photo.by Michael N.)
involves crushing, screening and further
Quartz is usually colourless or white but is
adjusting the grain-size distribution, together
frequently coloured by impurities, such as
with removing contaminating impurities in
iron, and may then be any colour. Quartz
the sand and from the surface of the
may be transparent to translucent, hence its
individual quartz grains. The presence of
use in glassmaking, and have a vitreous
metallic oxides in glassmaking sands usually
lustre. Quartz is a hard mineral owing to the
results in colored glass. If iron is present, the
strength of the bonds between the atoms and
resulting glass is coloured green or brown.
it will scratch glass. It is also relatively inert
The iron level is consequently the most
and does not react with dilute acid. These
critical parameter in determining whether
are prized qualities in various industrial
particular sand can be used to make clear
uses. Depending on how the silica deposit
glass. Sands used to manufacture colourless
was formed, quartz grains may be sharp and
glass are therefore likely to be processed
angular, sub-angular, sub-rounded or
further by methods such as acid leaching,
rounded. Foundry and filtration applications
froth flotation or gravity separation.
require subrounded or rounded grains for
best performance.
1.3 Geology and Occurrences
Silica sand is an industrial term used for
1.2 Processing Technologies
sand or easily disaggregated sandstone with
Silica deposits are normally exploited by
a veryhigh percentage of quartz (silica)
quarrying and the material extracted may
grains. Quartz is the most common silica
and it is rare for it to be extracted by purity also helps prevent interaction with
underground mining. catalysts or curing rate ofchemical binders.
Following the casting process, core sand can
chemicalssuch as sodium silicate, silicon mildew, cracking and weathering. Low oil
tetrachloride and silicon gels. These absorption allowsincreased pigment loading
chemicals are used inproducts like for improved finish color.
household and industrial cleaners, to Ceramics & Refractories: Ground silica is
manufacture fiber optics and to an essential component of the glaze and
removeimpurities from cooking oil and bodyformulations of all types of ceramic
brewed beverages. products, including tableware, sanitary ware
Building Products: Industrial sand is the and floorand wall tile. In the ceramic body,
primary structural component in a wide silica is the skeletal structure upon which
variety ofbuilding and construction clays and fluxcomponents attach. The SiO2
products. Whole grain silica is put to use in contribution is used to modify thermal
flooring compounds,mortars, specialty expansion, regulatedrying and shrinkage,
cements, stucco, roofing shingles, skid and improve structural integrity and
resistant surfaces and asphaltmixtures to appearance. Silica products arealso used as
provide packing density and flexural the primary aggregate in both shape and
strength without adversely affecting monolithic type refractories toprovide high
thechemical properties of the binding temperature resistance to acidic attack in
system. Ground silica performs as a industrial furnaces.
functional extenderto add durability and Filtration and Water Production:
anti-corrosion and weathering properties in Industrial sand is used in the filtration of
epoxy based compounds,sealants and caulks. drinking water,the processing of wastewater
Paint and Coatings: Paint formulators and the production of water from wells.
select micron-sized industrial sands to Uniform grain shapesand grain size
improve theappearance and durability of distributions produce efficient filtration bed
architectural and industrial paint and operation in removal ofcontaminants in both
coatings. High puritysilica contributes potable water and wastewater. Chemically
critical performance properties such as inert, silica will not degradeor react when it
brightness and reflectance, colorconsistency, comes in contact with acids, contaminants,
and oil absorption. In architectural paints, volatile organics or solvents.Silica gravel is
silica fillers improve tint used as packing material in deep-water wells
retention,durability, and resistance to dirt, to increase yield from theaquifer by
expanding the permeable zone around the fertilization. The natural grain shapeand
well screen and preventing theinfiltration of controlled particle size distribution of silica
fine particles from the formation. provides the required permeability
Oil and Gas Recovery: Known commonly andcompaction properties for drainage,
as proppant, or “fracsand,” industrial sand healthy plant growth and stability.
ispumped down holes in deep well
applications to prop open rock fissures and 3 SILICA SAND POTENTIAL OF
increase theflow rate of natural gas or oil. In ETHIOPIA
this specialized application round, whole Consolidated sandstone may be crushed for
permeability and prevent formation cuttings attractive, cut and shaped into blocks or
from entering the well bore.Silica’s hardness slabs for building (dimension stone). When
and its overall structural integrity combine sandstone, silica sand and quartzite are
to deliver the required crushresistance of the crushed or ground are a source of SiO2
high pressures present in wells up to 2,450 (glass, ceramics, chemical) and fluxingagent
meters deep. Its chemicalpurity is required (iron and steel). Silica is a principal glass-
Recreational: Industrial sand even finds its Cretaceous sandstones are the main sources
way into sports and recreation. Silica sand of silica sand in Ethiopia. Silica sand occurs
isused for golf course bunkers and greens as in the Mugher Valley, in the Jemma-
well as the construction of natural or Wonchit River basin, and in the Enticho
syntheticathletic fields. In golf and sports units of Adigrat Group of Tigray region.
Table 1 Estimated reserves of Silica sand
turf applications silica sand is the structural
ID Location X Y Reserve
component ofan inert, uncontaminated,
(M tons)
growing media. Silica sand is also used to 1 Fetra 485908 1107781 212.5
2 Mugher 454244 1031638 3. 413
repair greens and tofacilitate everyday 3 Enticho 571865 1593770
maintenance like root aeration and
The sandstone deposit of fetra is light gray oxide and 0.4% titanium oxide. This result
to white some pink layers few centimeters to indicated that washing increases percent of
one meter thick. These layers interlayer with silica and decreases percent of alumina
the light grey sand layers. The pink layers while unchanging the value of iron and
commonly are coarser in grain size and titanium oxide in the silt to sand size grains.
contain relatively lower clay content than The result verifies that silica content is
the gray to white varieties. related to the silt to sand sized quartz grains.
The chemical analysis of 58 unwashed Whereas, the iron and titanium would be
samples showed about 91.29% silica, 5.29% associated to either silt to sand sized quartz
aluminum xide and 0.75% iron oxide (table as coating, intergrowth or as a free iron and
2). While 8 washed samples showed about titanium bearing mineral grain.
97.9% silica, 0.8% alumina, 0.65% iron
The average chemical composition of the The estimated reserve of the area is found to
Koffe-Mute sandstone is shown in table 2. be 3.414 million tons (table1). Generally,
The analyses were carried out on the 0.1- the chemical, mineralogical and
0.25mm sand fractions. In SiO2 indices the granulometric assessment of channel and
averageSiO2contents in excess of 95% after core samples from Koffe-mute area
simple washing, theFe2O3contents in 95% of (mugher) proves that it could be used for
the channel and core samples ranges bottle and sheet glass factories.
between 0.01-0.38% (table 2).
Table 3 Standards for chemical composition of Silica sand for different countries
3.3 EntichoSilica Sand /Sandstone 0.1mm and the coarser fraction (>0.63mm)
The silica sand deposits of Enticho area are
ranges from 11% to 30%. Chemical
grouped within the Upper Paleozoic-
analyses of Senkata silica sand shows 98.4-
Mesozoic sediments of lower part of Adigrat
99.6% SiO2, 0.1-0.33% Fe2O3 and 0.1-0.6%
group. The rocks of Adigrat group
Al2O3 (Table 2). It is possible to obtain high
comprises of three formations (Garland,
quality material by washing, sieving and
1980), namely Enticho sandstone,
attrition so that the raw material can have
EdgaArbiglacials and Adigrat sandstones,
acceptable grade for the sheet glass
which overlay unconformably on the
manufacturing (Tibebu M.et al.,2002).
Precambrian rocks of Upper Complex and
overlain by the JurrasicAntalo limestone,
AmbaAradom formation and Tertiary
volcanics.
The silica sand deposits of Enticho
Sandstone at the localities of EdagaHamus
and Senkata are generally white to grey,
medium to coarse grained and at places
kaolinized. The thickness of the sandstone
ranges from 15-30m. According to Tadelle Figure 7Fetra Silica sand deposit (Photo.by Michael N.)
4 MARKET AND TRADE low priced silica while higher priced silica
World production of industrial sand, based came from Belgium, Canada, Germany,
on information usually provided by foreign Japan, Sweden, and the United Kingdom.
Governments, was estimated to be 120
Table 4 Industrial (Silica) Sand: World Production by
million metric tons, about the same as 1994. Country
The United States was the leading producer Country 1996 1997 1998 1999 2000
United 27,800 28,500 28,200 28,900 28,400
followed by, in descending order, Germany, States
Germany 5,503 6,000 6,000 7,000 7,000
Austria, Spain and France. Most countries Austria 6,012 6,000 6,329 6,857 6,800
in the world had some production and Spain 5,300 5,800 6,200 6,550 6,600
France 6,550 6,560 6,500 6,500 6,500
consumption of industrial sand because it is United 4,816 4,800 4,800 4,000 4,000
Kingdom
essential to the glass and foundry industries. Italy 2,950 3,000 3,000 3,000 3,000
Japan 3,557 3,306 3,049 2,764 2,800
Beyond those countries listed, several other
Brazil 2,700 2,700 2,700 2,700 2,700
countries were believed to have had some Australia 2,500 2,500 2,500 2,500 2,500
Belgium 2,300 2,300 2,400 2,400 2,400
type of silica production and consumption.
South 2,168 2,439 2,273 2,163 2,100
Africa
(table4) Czech 2,486 1,800 2,000 2,000 2,000
Republic
Sources: Data for 2004-04: Yager TR (2004) US Geol.Surv. Accordingly the Federal Government’s
Minerals Yearbook 2004, 17.1-17.5.
4.1 Opportunities
Ministry of Mines is responsible to
The accessibility of the deposit area to the administer and supervise all large scale
capital city, a large potential mining operations including:issuing
resource/reserve and the increasing demand prospecting, exploration and mining licenses
of the booming construction industry will for foreign investors and to these in joint
create a huge market in the country. The venture with Ethiopians as per the reform
chemical, mineralogical and granulometric issued in 1998 on the Mining proclamation
assessment of channel and core samples following the realization of previous
from Koffe-mute area (Mugher) proves that shortcomings of earlier laws and policies.
it could be used for bottle and sheet glass
The reform clearly stipulated the
factories.By using simple beneficiation
responsibility of National Regional
process such as washing, screening, attrition
Governments to issue licenses and
scrubbing, acid leaching, the Fetra and
administer all small scale mining operations
Entichosandstones can easily be improvedto
owned by Ethiopians and collecting all fees
the required quality for production of
in addition to issue prospecting and
various glasses.
exploration licenses for national investors.
6 REFERENCES
BGS, (2007): Demand/ Supply Survey of the
Ethipian Industrial minerals Sub-sector,GSE,
Addis Ababa.
Garland, G. R. (1980): Geology of the Adigrat
area, Ministry of Mines, Energy and Water
Resources, EIGS Memoir No.1.
KamarA., (2004): What is silica, EBS 425 – Mineral
Perindustrian.
Lavrinenco L., Tibebu M., Tesfaye E., HagosT.and
Wondafrash M. (1989) evaluation of sheet glass
row material(silcasand,,Dolomite and Calcite
marble, Feldspar at North Shoa,West
Hararghe,Sidamo),GSE Addis
Melkamu M.,Michael N.,Genenew B. and Nigussie
D. (2010): Report onDetail Exploration and
Evaluation ofIndustrial Resources ofParts of
Wenchit and Jema river valleys,GSE Addis
Ababa, Ethiopia
Mengistu, T. and Fentaw, H.M. (2002): Industrial
Minerals And Rocks ResourcePotential Of
Ethiopia,GSE
Tadele, H., (1996): Assessment of Sheet Glass
and Ceramics Raw Materials in Tigray Region.