Cálculos para diagramas T vs X-Y y X vs Y ideales para Metano

Pman (Hg) 0 Patm (Hg) 585 PTOT (Hg) 585

(g/mol) (cal/g°C) (cal/mol°C) Van Laar (cal/mol) A

Compuesto PM Cp Cp A12_21 l Ctes. de Antoine (mm Hg y
Metanol (A) 32.04 0.605 19.3842 0.9014 8415 8.0724
Agua (B) 18.015 0.999 17.9970 0.5559 9718 7.96681

Ec. (10) Ec. (9) Ec. (9) Ec. (7) Ec. (8) Ec. (21) Ec. (22)
(°C) (mm Hg) Frac. Mol líq. Frac. Mol vap. (Cal/mol) mm Hg (-)
T PA 0
PB 0
XA YA hl Hv P total y1
58.074 584.9957 135.4943 1.0000 1.0000 1125.72 9540.72 585.00 1.0000
60.000 632.9205 148.2320 0.9011 0.9749 1154.82 9608.61 585.00 0.9749
62.000 686.1136 162.5225 0.8069 0.9463 1185.21 9682.11 585.00 0.9463
64.000 742.9848 177.9661 0.7204 0.9149 1215.76 9758.87 585.00 0.9149
66.000 803.7296 194.6368 0.6409 0.8805 1246.48 9839.10 585.00 0.8805
68.000 868.5504 212.6116 0.5677 0.8429 1277.35 9923.02 585.00 0.8429
70.000 937.6565 231.9712 0.5003 0.8018 1308.37 10010.86 585.00 0.8018
72.000 1011.2641 252.7998 0.4380 0.7571 1339.53 10102.86 585.00 0.7571
74.000 1089.5966 275.1849 0.3804 0.7085 1370.83 10199.28 585.00 0.7085
76.000 1172.8842 299.2179 0.3271 0.6558 1402.26 10300.37 585.00 0.6558
78.000 1261.3647 324.9940 0.2777 0.5987 1433.81 10406.42 585.00 0.5987
80.000 1355.2826 352.6119 0.2318 0.5369 1465.48 10517.71 585.00 0.5369
82.000 1454.8901 382.1744 0.1891 0.4702 1497.26 10634.53 585.00 0.4702
84.000 1560.4463 413.7881 0.1493 0.3983 1529.15 10757.19 585.00 0.3983
86.000 1672.2179 447.5634 0.1122 0.3208 1561.13 10886.02 585.00 0.3208
88.000 1790.4787 483.6151 0.0776 0.2374 1593.21 11021.33 585.00 0.2374
90.000 1915.5100 522.0618 0.0452 0.1479 1625.37 11163.49 585.00 0.1479
93.023 2117.9891 584.9940 0.0000 0.0000 1674.13 11392.12 585.00 0.0000
Tabla No. 1.- Datos de Equilibrio L-V para sistema Metanol-Agua Ideal a 585 mm de Hg.
ales para Metanol (A)-Agua (B) @ 585 mm de Hg 585.0 mmHg = 0.8 atm =

NOMENCLATURA DE COLOR

B C (°C) (cal /mol) Celdas dato (llenar)

Ctes. de Antoine (mm Hg y °C) Temp. Eb. hlA HvA y Constantes de los componentes d
1574.99 238.8 58.074 1125.72 9540.72 y Titulos generales del proceso de c
1669.21 228 93.023 1674.14 11392.138 y Variables calculadas

(cal °C/mol) volatilidad Referencia

hl Hv K1 K2 a f (x) = 1/(y-x) p/gráficar
1126 9541 #REF! #REF! 0.00384 -135290.3 1.0000
1155 9609 #REF! #REF! 0.00360 13.5 0.9011 Diagrama 1 - T vs x-y (mezcla met
1185 9682 #REF! #REF! 0.00337 0.8069
IDEAL
7.2
95
1216 9759 #REF! #REF! 0.00314 5.1 0.7204
1246 9839 #REF! #REF! 0.00292 4.2 0.6409
1277 9923 #REF! #REF! 0.00270 3.6 0.5677 90
1308 10011 #REF! #REF! 0.0024772 3.3 0.5003
1340 10103 #REF! #REF! 0.00226 3.1 0.4380
85
1371 10199 #REF! #REF! 0.00205 3.0 0.3804
1402 10300 #REF! #REF! 0.00183 3.0 0.3271
1434 10406 #REF! #REF! 0.00162 3.1 0.2777 80
Temperatura, T (°C)
1465 10518 #REF! #REF! 0.00141 3.3 0.2318 Líquido + Vapor
1497 10635 #REF! #REF! 0.00120 3.6 0.1891 75
1529 10757 #REF! #REF! 0.00098 4.0 0.1493
1561 10886 #REF! #REF! 0.00077 4.8 0.1122
1593 11021 #REF! #REF! 0.00055 6.3 0.0776 70 Líquido
1625 11163 #REF! #REF! 0.00033 9.7 0.0452
1674 11392 #REF! #REF! 0.00000 97430.4 0.0000 65

60

55
0.0 0.1 0.2 0.3 0.4 0.5

Fracción mol

Diagrama 2 - x vs y (Metano
IDEA
1.0000

0.9000

0.8000

0.7000
el vapor, y

0.6000
 0.9000

0.8000

0.7000

Fracción molar del vapor, y

0.6000

0.5000

0.4000

0.3000

0.2000

0.1000

0.0000
0.0000 0.1000 0.2000 0.3000 0.4000 0

Fracción molar
 0.7799337 bar = 0.795 Kg/cm2

URA DE COLOR

stantes de los componentes de la mezcla

os generales del proceso de cálculo
ables calculadas

- T vs x-y (mezcla metanol-agua) @ 585 mm de Hg

IDEAL

l i qui do Vapor

Vapor

Líquido + Vapor

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

Fracción molar x, y

ma 2 - x vs y (Metanol-agua) @ 585 mm Hg
IDEAL
0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000

Fracción molar del líquido, x

 Calculos para diagramas T vs X-Y y X vs Y no ideales para Metanol
P man (Hg) 367.78 P atm (Hg) 585 P TOT (Hg) 952.78 P man + P atm = P total

(g/mol) (cal/g°C) (cal/mol°C) VanLaar (cal/mol) A B

Compuesto PM Cp A12_21 l Ctes. de Antoine (mm Hg y °C)
Metanol (A) 32.04 0.605 19.3842 0.9014 8415 8.0724 1574.99
Agua (B) 18.015 0.999 17.9970 0.5559 9718 7.96681 1669.21

Ec. (10) Ec. (9) Iteración Ec. (13) Ec. (14) Ec. (16) Ec. (17) Ec. (18) Ec. (21)
(°C) (mm Hg) Frac. Mol Ec. Van Laar (mm Hg) Frac. Mol Frac. Mol (cal/mol)
T P A0 P B0 X A supuesta gA gB P TOT X A calculada YA hl A
58.074 584.9957 135.4943 1.0000 1.0000 1.7435 584.9999 2.0546 1.2615 1125.72
60.000 632.9205 148.2320 0.8703 1.0064 1.5940 585.0057 1.7881 1.1955 1152.26
62.000 686.1136 162.5225 0.7427 1.0283 1.4585 585.0020 1.5277 1.1313 1179.69
64.000 742.9848 177.9661 0.6234 1.0687 1.3432 585.0073 1.2861 1.0718 1207.15
66.000 803.7296 194.6368 0.5141 1.1300 1.2484 584.9862 1.0670 1.0171 1234.87
68.000 868.5504 212.6116 0.4172 1.2130 1.1740 584.9990 0.8747 0.9672 1263.15
70.000 937.6565 231.9712 0.3344 1.3149 1.1186 584.9838 0.7122 0.9216 1292.26
72.000 1011.2641 252.7998 0.2661 1.4297 1.0792 584.9556 0.5797 0.8796 1322.36
74.000 1089.5966 275.1849 0.2111 1.5502 1.0522 585.0070 0.4739 0.8401 1353.45
76.000 1172.8842 299.2179 0.1670 1.6709 1.0340 585.0141 0.3898 0.8019 1385.38
78.000 1261.3647 324.9940 0.1315 1.7879 1.0218 584.9834 0.3227 0.7639 1417.99
80.000 1355.2826 352.6119 0.1027 1.8989 1.0137 585.0431 0.2686 0.7256 1451.16
82.000 1454.8901 382.1744 0.0789 2.0036 1.0083 584.9378 0.2243 0.6863 1484.73
84.000 1560.4463 413.7881 0.0591 2.1011 1.0048 584.9547 0.1876 0.6455 1518.63
86.000 1672.2179 447.5634 0.0424 2.1917 1.0025 585.0537 0.1567 0.6029 1552.80
88.000 1790.4787 483.6151 0.0281 2.2761 1.0011 585.0672 0.1305 0.5582 1587.16
90.000 1915.5100 522.0618 0.0157 2.3550 1.0004 584.8688 0.1079 0.5110 1621.69
92.000 2047.6005 563.0264 0.0050 2.4276 1.0000 585.0850 0.0884 0.4613 1656.36
93.023 2117.9891 584.9940 0.2399 1.4835 1.0658 ### 0.1308 0.4312 1705.09
Tabla No. 3.- Datos de Equilibrio L-V para el sistema Metanol-Agua a 585 mm de Hg, con soluciones no ideales
eales para Metanol (A)-Agua(B) @ 585 mm de Hg 952.8 mmHg = 1.3 atm =

n + P atm = P total NOMENCLATURA DE COLOR

C (°C) (cal /mol) Celdas dato (llenar)

de Antoine (mm Hg y °C) Temp. Eb. hli Hvi y Constantes de los componentes de la me
238.8 70.421 1365.06 9780.06 y Titulos generales del proceso de cálculo
228 106.657 1919.51 11637.51 y Variables calculadas

Ec. (22) Ec. (17) Ec. (17) Ec. (17)

(cal/mol) Rel. Equil. Rel. Equil. volatilidad Referencia
Hv A KA KB a f (x)=1/(y-x) p/graficar
9221.08 1.0000 0.4038 2.4763 1.0000
-1.3 Diagrama 3: T vs x-y (mezcla metanol-agu
9339.64 1.0888 0.4039 2.6958 -1.7 0.8703 NO IDEAL
9457.05 1.2061 0.4052 2.9765 -2.5 0.7427 95
9568.43 1.3573 0.4086 3.3215 -4.7 0.6234
9673.67 1.5526 0.4154 3.7378 -20.0 0.5141 90
9772.80 1.8009 0.4267 4.2207 10.8 0.4172
9866.40 2.1076 0.4436 4.7515 4.8 0.3344
85
9955.46 2.4717 0.4664 5.2996 3.3 0.2661
10041.36 2.8874 0.4950 5.8336 2.7 0.2111
Vapor
10125.49 3.3500 0.5289 6.3342 2.4 0.1670 80
Temperatura, T (°C)

10209.01 3.8552 0.5677 6.7910 2.3 0.1315

10292.80 4.3989 0.6110 7.1998 2.2 0.1027 75
10377.60 4.9835 0.6588 7.5646 2.2 0.0789 Líquido + Vapor
10463.89 5.6050 0.7108 7.8859 2.2 0.0591
6.2644 70
10552.10 0.7669 8.1684 2.2 0.0424
Líquido
10642.59 6.9656 0.8275 8.4175 2.3 0.0281
10735.65 7.7127 0.8929 8.6376 2.5 0.0157 65
10831.52 8.4957 0.9623 8.8282 2.7 0.0050
10885.94 2.5592 0.5078 5.0394 3.3 0.0000 60
iones no ideales

55
0.0 0.1 0.2 0.3 0.4 0.5 0.

Fracción molar x, y

Diagrama 4: x vs y (metanol -
NO IDEAL
1.0000

0.9000

0.8000

0.7000
r del vapor, y

0.6000

0.5000
 0.9000

0.8000

0.7000

Fracción molar del vapor, y

0.6000

0.5000

0.4000

0.3000

0.2000

0.1000

0.0000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000

Fracción molar del líqui

 1.27026535 bar = 1.295 Kg/cm2

URA DE COLOR

stantes de los componentes de la mezcla

os generales del proceso de cálculo
ables calculadas

T vs x-y (mezcla metanol-agua) @ 585 mm de Hg

NO IDEAL

l i qui do Vapor

Vapor

Líquido + Vapor

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

Fracción molar x, y

ma 4: x vs y (metanol - agua) @ 585 mm Hg

NO IDEAL
0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000

Fracción molar del líquido, x

xa xb pa pb ga gb p ya
1 0 952.779977 236.233664 1 1.74350944 952.779977 1
0.9 0.1 1009.28998 252.238471 1.00370262 1.62724402 952.76965 0.95691996
0.8 0.2 1071.18644 269.90425 1.01616885 1.51786303 952.740574 0.91400016
0.7 0.3 1139.60019 289.586016 1.04007436 1.41590896 952.696485 0.87088414
0.6 0.4 1216.38325 311.859592 1.07933032 1.32202256 952.641763 0.82688753
0.5 0.5 1304.8741 337.756632 1.13985466 1.23699311 952.584725 0.78070054
0.4 0.6 1411.67118 369.314327 1.23096248 1.16184083 952.536381 0.7297209
0.3 0.7 1551.21935 411.013377 1.36800471 1.09795559 952.514718 0.66835987
0.2 0.8 1759.6526 474.187694 1.57768377 1.04733844 952.543071 0.5828976
0.1 0.9 2149.15853 594.751347 1.90954789 1.01304013 952.648397 0.43079075
0 1 3260.24934 952.766868 2.46304897 1 952.766868 0
yb t
0 70.42129
0.04308004 71.94796 X vs Y
0.08599984 73.54092 1
0.12911586 75.21529
0.9
0.17311247 76.99826
0.21929946 78.94129 0.8
0.2702791 81.14652 0.7
0.33164013 83.82969 0.6
0.4171024 87.48937
0.5
0.56920925 93.46715
1 106.657 0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
.8 0.9 1
 Calculos para diagramas T vs X-Y y X vs Y ideales para Metanol (1)-Agua(2) @
Pman (Hg) 175 Patm (Hg) 585 PTOT (Hg) 760

(g/mol) (cal/g°C) (cal/mol°C) (cal/g) VanLaar (cal/mol) A B C (°C)

Compuesto PM Cp Az A12_21 l Ctes. de Antoine (mm Hg y °C) p.e.
Metanol (1) 32.04 0.605 19.3842 0.9014 8415 8.0724 1574.99 238.8 64.574
Agua (2) 18.015 0.999 17.9970 0.5559 9718 7.96681 1669.21 228 100.197

Ec. Antoine Ec. Van Laar Raoult m

(°C) (mm Hg) (-) (-) (-) (mm Hg) (-) (-) (cal °C/mol)
Ti P1 i
0
P2 i
0
X1 g1 g2 P X1_calculada y1 hl Hv K1
64.574 760.0135 182.6218 0.999977 1.00000 1.74348 760.00317 0.999970 0.999994 1252 9667 #REF!
65.000 772.8605 186.1434 0.978081 1.00017 1.71746 763.05399 0.971343 0.994631 1258 9681 #REF!
66.000 803.7296 194.6368 0.928205 1.00187 1.65936 770.60911 0.906207 0.981613 1273 9717 #REF!
67.000 835.6176 203.4562 0.880382 1.00540 1.60523 778.70387 0.843961 0.967978 1288 9752 #REF!
68.000 868.5504 212.6116 0.834511 1.01076 1.55480 787.32044 0.784595 0.953704 1303 9789 #REF!
69.000 902.5545 222.1132 0.790497 1.01795 1.50785 796.43759 0.728087 0.938772 1317 9826 #REF!
70.000 937.6565 231.9712 0.748250 1.02697 1.46414 806.03008 0.674402 0.923159 1332 9865 #REF!
71.000 973.8839 242.1965 0.707684 1.03785 1.42347 816.06819 0.623496 0.906845 1347 9903 #REF!
72.000 1011.264 252.7998 0.668720 1.05060 1.38564 826.51704 0.575316 0.889806 1363 9943 #REF!
73.000 1049.826 263.7921 0.631281 1.06525 1.35048 837.33595 0.529802 0.872019 1378 9984 #REF!
74.000 1089.597 275.1849 0.595295 1.08184 1.31782 848.47770 0.486883 0.853462 1393 10025 #REF!
75.000 1130.606 286.9896 0.560694 1.10039 1.28749 859.88772 0.446486 0.834110 1408 10068 #REF!
76.000 1172.884 299.2179 0.527412 1.12096 1.25937 871.50324 0.408530 0.813938 1423 10111 #REF!
77.000 1216.46 311.8820 0.495389 1.14360 1.23330 883.25233 0.372932 0.792922 1439 10155 #REF!
78.000 1261.365 324.9940 0.464566 1.16836 1.20917 895.05288 0.339604 0.771036 1454 10201 #REF!
79.000 1307.628 338.5664 0.434888 1.19530 1.18686 906.81147 0.308454 0.748253 1469 10247 #REF!
80.000 1355.283 352.6119 0.406303 1.22449 1.16626 918.42213 0.279392 0.724546 1485 10294 #REF!
81.000 1404.359 367.1435 0.378761 1.25601 1.14727 929.76508 0.252322 0.699889 1500 10342 #REF!
82.000 1454.89 382.1744 0.352214 1.28993 1.12980 940.70521 0.227152 0.674254 1516 10392 #REF!
83.000 1506.908 397.7180 0.326618 1.32635 1.11376 951.09059 0.203788 0.647611 1531 10442 #REF!
84.000 1560.446 413.7881 0.301931 1.36535 1.09907 960.75073 0.182135 0.619931 1547 10494 #REF!
85.000 1615.538 430.3985 0.278112 1.40704 1.08566 969.49480 0.162103 0.591185 1563 10547 #REF!
86.000 1672.218 447.5634 0.255122 1.45151 1.07345 977.10961 0.143601 0.561342 1578 10601 #REF!
87.000 1730.52 465.2974 0.232926 1.49889 1.06238 983.35754 0.126541 0.530371 1594 10657 #REF!
88.000 1790.479 483.6151 0.211487 1.54929 1.05239 987.97415 0.110837 0.498241 1610 10713 #REF!
89.000 1852.13 502.5315 0.190774 1.60283 1.04343 990.66577 0.096405 0.464919 1625 10771 #REF!
90.000 1915.51 522.0618 0.170755 1.65966 1.03545 991.10679 0.083165 0.430372 1641 10831 #REF!
91.000 1980.655 542.2215 0.151400 1.71990 1.02838 988.93677 0.071040 0.394567 1657 10891 #REF!
92.000 2047.6 563.0264 0.132680 1.78371 1.02220 983.75734 0.059956 0.357469 1673 10954 #REF!
93.000 2116.385 584.4924 0.114569 1.85124 1.01686 975.12886 0.049841 0.319043 1689 11017 #REF!
94.000 2187.046 606.6358 0.097041 1.92266 1.01232 962.56681 0.040629 0.279253 1704 11082 #REF!
95.000 2259.622 629.4731 0.080071 1.99814 1.00854 945.53794 0.032254 0.238065 1720 11149 #REF!
96.000 2334.15 653.0212 0.063635 2.07785 1.00549 923.45609 0.024656 0.195439 1736 11217 #REF!
97.000 2410.671 677.2971 0.047712 2.16199 1.00314 895.67774 0.017777 0.151340 1752 11287 #REF!
 98.000 2489.224 702.3182 0.032280 2.25075 1.00146 861.49721 0.011564 0.105727 1768 11358 #REF!
99.000 2569.848 728.1021 0.017319 2.34434 1.00043 820.14150 0.005964 0.058563 1784 11431 #REF!
100.000 2652.584 754.6666 0.002810 2.44298 1.00001 770.76481 0.000930 0.009808 1800 11506 #REF!
100.197 2669.136 759.9934 0.000003 2.46302 1.00000 760.01349 0.000001 0.000012 1803 11521 #REF!

Tabla de Xw y 1/(Y-X) para 2 etapas, Yd=0.84, Rcte

refujo 2 et yd xw 1/y-x Aparcial
2.25 0.2584615 0.84 0.8131 37.238547 0.54630
2.25 0.2553846 0.83 0.7970 30.267117 3.33403
2.25 0.2307692 0.75 0.6218 7.8000035 2.12052
2.25 0.2215385 0.72 0.54 5.5555556 1.72009
2.25 0.2092308 0.68 0.4 3.5714286 0.98687
2.25 0.2 0.65 0.1983 2.21372 0.24463
2.25 0.1846154 0.6 0.08 1.9230769 0.0696
2.25 0.1692308 0.55 0.0443 1.977457 0.0491
2.25 0.1384615 0.45 0.0215 2.3337223 0.0217
2.25 0.1076923 0.35 0.0133111 2.9701012 0.0180
2.25 0.0769231 0.25 0.0082586 4.1366513 0.0449
2.25 0.0307692 0.1 0.002 10.204082 0.0153
2.25 0.0153846 0.05 0.001 20.408163 #REF!
2.25 0 0 0 #DIV/0! #REF!
etanol (1)-Agua(2) @ 760 mm de Hg 760.0 mmHg = 1.0 atm = 1.0132472 bar = 1.033

NOMENCLATURA DE COLOR

(cal /mol) Celdas dato (llenar)

hli Hvi y Constantes de los componentes de la mz
1251.70661 9666.7066 y Titulos generales del proceso de cálculo
1803.24828 11521.248 y Variables calculadas

volatilidad Referencia
K2 a 1/(y-x) p/graficar
#REF! 2.38699 56429.9 0.999977
#REF! 2.41791 60.4 0.978081
Diagrama T vs x-y (mz metanol-agua) @ 760 mm de Hg
IDEAL
#REF! 2.49319 18.7 0.928205
100
#REF! 2.57241 11.4 0.880382
#REF! 2.65572 8.4 0.834511
#REF! 2.74327 6.7 0.790497 95
#REF! 2.835225 5.7 0.748250 l i qui do Vap
#REF! 2.93175 5.0 0.707684
90
#REF! 3.03303 4.5 0.668720
#REF! 3.13921 4.2 0.631281
#REF! 3.25049 3.9 0.595295 85
Temperatura, T (°C)

#REF! 3.36704 3.7 0.560694

#REF! 3.48904 3.5 0.527412 80
#REF! 3.61670 3.4 0.495389
#REF! 3.75018 3.3 0.464566
#REF! 3.88970 3.2 0.434888 75
#REF! 4.03545 3.1 0.406303
#REF! 4.18762 3.1 0.378761 70
#REF! 4.3464313 3.1 0.352214
#REF! 4.51208 3.1 0.326618
#REF! 4.68478 3.1 0.301931 65
#REF! 4.86473 3.2 0.278112
#REF! 5.05217 3.3 0.255122 60
#REF! 5.24729 3.4 0.232926 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
#REF! 5.45033 3.5 0.211487
Fracción molar x, y
#REF! 5.66150 3.6 0.190774
#REF! 5.88103 3.9 0.170755
#REF! 6.10913 4.1 0.151400
#REF! 6.34606 4.4 0.132680
#REF! 6.59202 0.114569
4.9
Di agrama x vs y (mz M etanol -agua) @ 7 6 0
#REF! 6.84725 5.5 0.097041
IDEA L
#REF! 7.11200 6.3 0.080071
1.000000
#REF! 7.38649 7.6 0.063635
#REF! 7.67097 9.6 0.047712
0.900000

0.800000
 IDEA L
1.000000

#REF! 7.96567 13.6 0.032280 0.900000

#REF! 8.27085 24.2 0.017319
#REF! 8.58675 142.9 0.002810 0.800000
#REF! 8.65027 115228.8 0.000003

0.700000

Fracci ón mol a r del va por, y

0.600000

0.500000

0.400000

0.300000

0.200000

0.100000

0.000000
0.000000 0.100000 0.200000 0.300000 0.400000 0.500000 0.600000

Fracci ón mol ar del l íqui do, x

 Kg/cm2

@ 760 mm de Hg

l i qui do Vapor

0.6 0.7 0.8 0.9 1.0

ol - agua) @ 7 6 0 mm de Hg
AL
AL

000 0.500000 0.600000 0.700000 0.800000 0.900000 1.000000

ol ar del l íqui do, x

 Calculos para diagramas T vs X-Y y X vs Y no ideales para Metanol (1)-
Pman (Hg) 175 Patm (Hg) 585 PTOT (Hg) 760

(g/mol) (cal/g°C) (cal/mol°C) (cal/g) VanLaar (cal/mol) A B C

Compuesto PM Cp Az A12_21 l Ctes. de Antoine (mm Hg y °C)
Metanol (1) 32.04 0.605 19.3842 0.9014 8415 8.0724 1574.99 238.8
Agua (2) 18.015 0.999 17.9970 0.5559 9718 7.96681 1669.21 228

Ec. Antoine Ec. Van Laar Raoult m

(°C) (mm Hg) (-) (-) (-) (mm Hg) (-) (-) (cal °C/mol)
Ti P1 i
0
P2 i
0
X1_supuesta g1 g2 P X1_calculada y1 hl Hv
64.574 760.0135 182.6218 1.0000 1.00000 1.74347 760.00022 0.999970 0.999987 1252 9667
65.000 772.8605 186.1434 0.971236 1.00029 1.70939 760.00014 0.971236 0.987957 1257 9690
66.000 803.7296 194.6368 0.905008 1.00334 1.63291 759.99991 0.905008 0.960276 1271 9742
67.000 835.6176 203.4562 0.840529 1.00994 1.56133 760.00006 0.840529 0.933345 1284 9794
68.000 868.5504 212.6116 0.777868 1.02042 1.49464 760.00004 0.777868 0.907120 1297 9845
69.000 902.5545 222.1132 0.717135 1.03511 1.43283 759.99995 0.717135 0.881551 1310 9896
70.000 937.6565 231.9712 0.658485 1.05436 1.37591 760.00013 0.658485 0.856576 1324 9945
71.000 973.8839 242.1965 0.602117 1.07849 1.32392 759.99988 0.602117 0.832130 1337 9993
72.000 1011.264 252.7998 0.548273 1.10774 1.27688 759.99974 0.548273 0.808138 1351 10041
73.000 1049.826 263.7921 0.497220 1.14222 1.23476 760.00002 0.497220 0.784518 1364 10089
74.000 1089.597 275.1849 0.449223 1.18188 1.19752 760.00006 0.449223 0.761180 1378 10136
75.000 1130.606 286.9896 0.404513 1.22643 1.16500 759.99960 0.404513 0.738030 1392 10183
76.000 1172.884 299.2179 0.363253 1.27538 1.13697 760.00000 0.363253 0.714971 1406 10230
77.000 1216.46 311.8820 0.325505 1.32802 1.11308 759.99991 0.325505 0.691906 1421 10276
78.000 1261.365 324.9940 0.291227 1.38356 1.09295 759.99993 0.291227 0.668740 1435 10323
79.000 1307.628 338.5664 0.260278 1.44115 1.07612 759.99966 0.260278 0.645383 1450 10370
80.000 1355.283 352.6119 0.232443 1.49997 1.06215 759.99961 0.232443 0.621750 1466 10417
81.000 1404.359 367.1435 0.207460 1.55931 1.05060 759.99985 0.207460 0.597765 1481 10464
82.000 1454.89 382.1744 0.185047 1.61855 1.04108 760.00006 0.185047 0.573358 1497 10512
83.000 1506.908 397.7180 0.164923 1.67723 1.03325 759.99950 0.164923 0.548463 1513 10560
84.000 1560.446 413.7881 0.146824 1.73497 1.02681 760.00041 0.146824 0.523027 1529 10609
85.000 1615.538 430.3985 0.130505 1.79151 1.02153 759.99932 0.130505 0.496992 1545 10659
86.000 1672.218 447.5634 0.115751 1.84665 1.01719 759.99953 0.115751 0.470315 1562 10709
87.000 1730.52 465.2974 0.102371 1.90028 1.01363 760.00136 0.102371 0.442951 1578 10760
88.000 1790.479 483.6151 0.090197 1.95231 1.01072 760.00144 0.090197 0.414855 1595 10812
89.000 1852.13 502.5315 0.079085 2.00273 1.00834 759.99974 0.079085 0.385989 1611 10864
90.000 1915.51 522.0618 0.068912 2.05151 1.00640 760.00032 0.068912 0.356319 1628 10918
91.000 1980.655 542.2215 0.059569 2.09866 1.00483 759.99935 0.059569 0.325806 1645 10972
92.000 2047.6 563.0264 0.050964 2.14422 1.00357 759.99943 0.050964 0.294418 1662 11028
93.000 2116.385 584.4924 0.043016 2.18822 1.00257 759.99858 0.043016 0.262121 1679 11084
94.000 2187.046 606.6358 0.035656 2.23069 1.00178 759.99922 0.035656 0.228885 1696 11141
95.000 2259.622 629.4731 0.028823 2.27169 1.00117 759.99997 0.028823 0.194675 1714 11200
96.000 2334.15 653.0212 0.022464 2.31127 1.00072 760.00006 0.022464 0.159461 1731 11259
97.000 2410.671 677.2971 0.016533 2.34948 1.00039 760.00032 0.016533 0.123211 1748 11320
 98.000 2489.224 702.3182 0.010989 2.38638 1.00017 759.99853 0.010989 0.085891 1765 11381
99.000 2569.848 728.1021 0.005797 2.42200 1.00005 759.99808 0.005797 0.047476 1782 11444
100.000 2652.584 754.6666 0.000926 2.45640 1.00000 760.00235 0.000926 0.007939 1800 11508
100.197 2669.136 759.9934 0.000001 2.46304 1.00000 759.99922 0.000001 0.000009 1803 11521

Tabla de Xw y 1/(Y-X) para 2 etapas, Yd=0.84, Rcte

refujo 2 et yd xw 1/y-x Aparcial
2.25 0.2584615 0.84 0.8131 37.238547 0.54630
2.25 0.2553846 0.83 0.7970 30.267117 3.33403
2.25 0.2307692 0.75 0.6218 7.8000035 2.12052
2.25 0.2215385 0.72 0.54 5.5555556 1.72009
2.25 0.2092308 0.68 0.4 3.5714286 0.98687
2.25 0.2 0.65 0.1983 2.21372 0.24463
2.25 0.1846154 0.6 0.08 1.9230769 0.0696
2.25 0.1692308 0.55 0.0443 1.977457 0.0491
2.25 0.1384615 0.45 0.0215 2.3337223 0.0217
2.25 0.1076923 0.35 0.0133111 2.9701012 0.0180
2.25 0.0769231 0.25 0.0082586 4.1366513 0.0449
2.25 0.0307692 0.1 0.002 10.204082 0.0153
2.25 0.0153846 0.05 0.001 20.408163 #REF!
2.25 0 0 0 #DIV/0! #REF!
s para Metanol (1)-Agua(2) @ 760 mm de Hg 760.0 mmHg = 1.0 atm = 1.0132472

NOMENCLATURA DE COLOR

(°C) (cal /mol) Celdas dato (llenar)

p.e. hli Hvi y Constantes de los componentes de la mz
64.574 1251.70661 9666.7066 y Titulos generales del proceso de cálculo
100.197 1803.24828 11521.248 y Variables calculadas

volatilidad Referencia
K1 K2 a 1/(y-x) p/graficar
#REF! #REF! 2.38701 59055.0 0.999970
#REF! #REF! 2.42962 59.8 0.971236
Diagrama T vs x-y (mz metanol-agua) @ 760 mm d
#REF! #REF! 2.53729 18.1 0.905008
100
#REF! #REF! 2.65667 10.8 0.840529
#REF! #REF! 2.78901 7.7 0.777868
#REF! #REF! 2.93557 6.1 0.717135 95
#REF! #REF! 3.0974849 5.0 0.658485 l i qui do
#REF! #REF! 3.27562 4.3 0.602117
90
#REF! #REF! 3.47038 3.8 0.548273
#REF! #REF! 3.68148 3.5 0.497220
#REF! #REF! 3.90779 3.2 0.449223 85
Temperatura, T (°C)

#REF! #REF! 4.14727 3.0 0.404513

#REF! #REF! 4.39701 2.8 0.363253 80
#REF! #REF! 4.65356 2.7 0.325505
#REF! #REF! 4.91320 2.6 0.291227
#REF! #REF! 5.17235 2.6 0.260278 75
#REF! #REF! 5.42789 2.6 0.232443
#REF! #REF! 5.67724 2.6 0.207460 70
#REF! #REF! 5.9185036 2.6 0.185047
#REF! #REF! 6.15035 2.6 0.164923
#REF! #REF! 6.37194 2.7 0.146824 65
#REF! #REF! 6.58287 2.7 0.130505
#REF! #REF! 6.78299 2.8 0.115751 60
#REF! #REF! 6.97240 2.9 0.102371 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
#REF! #REF! 7.15136 3.1 0.090197
Fracción molar x, y
#REF! #REF! 7.32021 3.3 0.079085
#REF! #REF! 7.47935 3.5 0.068912
#REF! #REF! 7.62922 3.8 0.059569
#REF! #REF! 7.77029 4.1 0.050964
#REF! #REF! 7.90300 4.6 0.043016
#REF! #REF! 8.02781 5.2 0.035656
Di agrama x vs y (mz M etanol -agua)
#REF! #REF! 8.14516 6.0 0.028823
1.000000
#REF! #REF! 8.25546 7.3 0.022464
#REF! #REF! 8.35913 9.4 0.016533
0.900000

0.800000
 Di agrama x vs y (mz M etanol -agua)
1.000000

#REF! #REF! 8.45655 13.4 0.010989 0.900000

#REF! #REF! 8.54807 24.0 0.005797
#REF! #REF! 8.63401 142.6 0.000926
0.800000
#REF! #REF! 8.65033 130714.5 0.000001

0.700000

Fracci ón mola r del va por, y

0.600000

0.500000

0.400000

0.300000

0.200000

0.100000

0.000000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000

Fracci ón mol ar del l íqui d

 bar = 1.033 Kg/cm2

OR

mponentes de la mz
proceso de cálculo

etanol-agua) @ 760 mm de Hg

l i qui do Vapor

.4 0.5 0.6 0.7 0.8 0.9 1.0

acción molar x, y

mz M etanol - agua) @ 7 6 0 mm de Hg
mz M etanol - agua) @ 7 6 0 mm de Hg

0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000

Fracci ón mol ar del l íqui do, x