3824, 9:34 AM, (CHEM 102 - PRACTICE Lab Exam (page 1 of 22) ueston 1 Not complete Marked ext of 100 A student was studying the decomposition of reactant A to form product B by measuring the concentration of A every five seconds for thirty seconds. The raw data is tabulated below. The student then prepared plots of [A] versus time, In[A] versus time, and 1/[A] versus time. Only one of these plots revealed a linear relationship; this plot is also shown below. Spreadsheet software was used to generate an equation for the best- fit line for the plot: y = -0.0257 x - 7.54 Time | (a () (mol/L) Z antes Si of he Comerson ofA 8 0 [537x107 ” 1 feet) an) 10 |aosxio*| z= * 1s 3.61 x 104 ~ ass * 20 | 3.2010] | i 28 2.80 x 104 ° * * “ ° ‘ Time) 30 |2.47x 104 Spreadsheet software, although powerful, will not include units when generating the equation for a best-fit line. What should be the units of slope for the best-fit line described above? Select one , U Nd untt Os lope = Rie ay v mol/L in 3K © none N¢ © L/mol fos) © mol hips simeskanas:macewan.calmodiquizlatempt php attempt=10401168cmide833705 12se24, 0:34AM (CHEM 102 -PRACTICE Lab Exam (page 1 of 32) uestion 2 Not complete Markee out of 100 Based on the information provided above, what is the order of reaction for the decomposition of A? Select one (0 first order_| UnfAl vs. € © zeroth order © pseudo-zeroth order © pseudo-second order © third order © second order Check vestion 3 Not complete Warked out of 109 Based on the information provided above, at what point in time will only 10% of the original amount of A remain unreacted? Select one: Y= —0.0254 4 —. > © 109.48 | Ik= ons O 49.48 \ntal= —kt + WC Ao J [oasas | 0O29.4s of) a 5 o 12848 Un (0.10 oS = —00254t + In {Alo © 69.4 oho CASs a iar) Wn Tay) = “Rost u - Vn 0 4 Announcements > aoe a HFS] - Jump to CHEM 102 - Lab Exam > hips /imeskanes macewan.ca/modiquzlaiemppp?attempt=10401168cmis+@33795se24, 6:34 AM CHEM 102 - PRACTICE Lab Exam (page 2 of 32) ueston 4 Marked ot of 100 A student wanted to gain insight into the effect of temperature on the rate of decomposition of A. As such, the student repeated the decomposition experiment at several different temperatures and, for each temperature, determined the value of the rate constant, k. The student then prepared a plot of In(k) vs 1/T, shown below, which exhibited a best-fit line as follows: y = -788x+6.5 Wak SB ck) + in Temperature Study for the Conversion of A to B 672 6.64 6.58 648 a4 0.0023 0.003 0.0031 0.0032 0.0083, AUT (11K) What is the activation energy (E,) for the decomposition of A? Report your answer to three significant digits and include units. Ea= RX 4B Answer: (cece = Bi ly /mel 18 K hitps:meskanas macewan.cajmodiquziatempphp?attept= 10401 16Bcmid=6337958page=1 18824, 9:34 AM. CHEM 102 - PRACTICE Lab Exam (page 2 of32) uestion 5 Not compete Marked out of 100 A student wanted to gain insight into the effect of temperature on the rate of decomposition of A. As such, the student repeated the decomposition experiment at several different temperatures and, for each temperature, determined the value of the rate constant, k. The student then prepared a plot of In(k) vs 1/T, shown below, which exhibited a best-fit line as follows: y =-788x+6.5 =-Eay a Unk= ~ ER ttn A Temperature Study for the Conversion of A to B 672 * 664 658 648 64 0.0023 0.003 0.0031 0.0032 0.0033, 4IT (IK) What is the value of the pre-exponential factor (also known as the Arrhenius A-factor) for this reaction? Note that the pre-exponential factor is often referred to as A, not to be confused with the starting material A. You may disregard units for this question. Input your answer to at least three significant digits, in 4 A= 4.5 Answer: “Announcements htpsimeskanas macewan.ca/modiquzittempt php?attempt=10401168cmid=€357958page=1 29318724, 934 AM (CHEM 102 - PRACTICE Lab Exam (page 3 of 22) verton 6 Not complete Markee ot of 100 A student performed a titration in which aqueous NaOH Concentration = 0.1000 mol/L) was added via burette to a 20.00 mL aliquot of aqueous HCI in an Erlenmeyer flask. Endpoint was reached after the student added 20.02 mL of sodium hydroxide. Based on the amount of titrant added, what concentration of hydrochloric acid was present in the flask at the start of the titration? Report your answer to four significant figures, and include units. Answer Naot +d > Natl +0 creck Nao = o.ro00 mel (LX Goe. K10?)L* 0.202 msl 4 Announcements At equi. point Wnt = Wwe = 0.002002 vol Jump to. CHEM 102 - Lab Exam » (aw ror) 1-100 mel | Chaps 20282 mel Intpsimeskanes, macewsn ca/modiquzittempt php?attempt= 1040 16&omid=8337958page=2 nm3/8/24, 9:35 AM (CHEM 102 - PRACTICE Lab Exam (page 4 of 32) ‘veston 7 arkes out of 100 A student performed a titration in which aqueous NaOH (concentration = 0.1000 mol/L) was added via burette to a 20.00 mL aliquot of aqueous HCI in an Erlenmeyer flask. Endpoint was reached after the student added 26.93 mL of sodium hydroxide. What concentration of chloride ion is present in the flask once endpoint was reached? Report your answer to four significant figures, and include units. Answer:| check “4 Announcements Jump to. (CHEM 102 - Lab Exam WA-+ Nook > Nac + 0 At equivalence point? Naat = MHA = Nina = Nar Y D000 mel [LX (Zb9%Xw™) L = 0,002b4% mmol . Nar - 2A wn ol tu = —* 5 ay (E0798 mL Vaid> Vom (20.09 +24.93) Xo". hitpsimeskanas.macewan,calmod/quizlttempt. php ?attonpt= 1040 168cmid=9337958page=3 1p1824, 9:35 AM (CHEM 102 - PRACTICE Lab Exam (page 5 of 32) veston 8. ares out of 100 Student X performed a titration of 20.00 mL of an unknown monoprotic weak acid (HA) with 0.4217 mol/L NaOH(aq). As shown in Figure 1a (below), student X observed that straight lines drawn through the data points in regions before and after the equivalence point intersected the straight line drawn through the data points in the equivalence point region at (28.99 mL, 5.23) and (29.25 mL, 11.84). Student X also found that the initial point of the titration curve was at (0.00 mL, 2.21) and th ial acid was half neutralized at (14.56 mL, 4.21). Figure 1a Titration of20.00 mi-of Unkown Weak Acid Using 04217 mol/L NaOW(aa) on 4SsCiSs«CRagS ODD] YotumeofNa04(oq) (mt) Based on Student X's results, calculate the initial concentration of the unknown acid HA. Input your answer to four significant digits, and include units. — = 25 : srw Ve= G25 t2¢0H 2 ME opal Cheek Nawns 420 mol/L x (29(2K107 I 0.1224 mel <4 Announcements Nha = Vinwo = 0. 01229 mo | Jump. cs = oe _—___— } Crip); = 2 Dtzzeumol " Ga.00 yo) O- GRO ral FY hitps:meskanas.macewan,ca/modiqulaattempt php atompt=1040'168omid-9357958pago=4 12i824, 8:95AM ‘CHEM 102 - PRACTICE Lab Exam (page 6 of $2) ueston 9 A student was interested in accurately determining the concentration of a weak acid in an aqueous solution. In a quick titration, the student pipetted a 10.00 mL portion of the weak acid solution into an Erlenmeyer flask, added some indicator, and added 0.1000 mol/L NaOH solution via burette until endpoint was reached. In this quick titration, the student had to refill the burette during the titration: endpoint was reached once a total SST my tent was added. ara ngals 0 be dilutac\ To achieve a more accurate result, the student decided to perform a dilution before completing several more careful titrations, each using 10.00 mL portions of analyte. The student wanted to achieve endpoint upon addition of ~35 mL of titrant. Which of the following dilutions would the student perform before completing the careful (accurate) titrations in order to achieve an endpoint closest to 35 mL of added titrant? “ tat volun is ~ halted , conc os Su hauls ve walked ap [O The student should dilute 25.00 mL of the analyte (the acid) to a diluted volume of 50.00 mL. _ - — \ © The student should dilute 10.00 mL of the titrant (the base) to a diluted volume of — 50.00 mL. © The student should dilute 25.00 mL of the titrant (the base) to a diluted volume of 50.00 mL. © The student should dilute 10.00 mL of the analyte (the acid) to a diluted volume of 50.00 mL. © The student should dilute 40.00 mL of the analyte (the acid) to a diluted volume of 50.00 mL. © The student should dilute 40.00 mL of the titrant (the base) to a diluted volume of 50.00 mL. Cheek Announcements Jump to. 1318/24, 8:35 AM (CHEM 102 - PRACTICE Lab Exam (page 7 of 32) uestion 10) Net complete Marked out of 100 A student constructed a titration curve for a weak acid (HA) upon titration with 0.1250 M NaOH. The student began by pipetting 20.00 mL of the weak acid solution into a clean and dry Erlenmeyer flask. The student noted that the original pH of the weak acid solution was 2.760. The student completed the titration and determined that the [HA] of the original 20.00 mL of weak acid solution was 0.1794 M. What was the percent dissociation of the weak acid, HA, in the ini solution? Calculate your answer as a percentage, but DO NO’ your answer. weak acid Report your answer to 3 significant figures. Answer HA +Hho 2 thot + Ar (aaa) ow YL Mmodtatim = eo Kio “4 Announcements CHAS incr ume to. CHEM 102 - Lab Exam o 2Aho = —_— yl 0.1944 hnttsimeskanas macewan.calmodiquiialtomplpp2attempt= 10401 16&cmid=203796&page=6 128024, 9:36 AM. ‘CHEM 102 - PRACTICE Lab Exam (page 8 of 32) ‘uestion 11 Not compete Marked cut of 100 A student performed a careful titration to determine the concentration of acetic acid in vinegar. In order to achieve an optimal result, the student needed to dilute the original vinegar sample before titration: the student carefully pipetted 25.00 mL of the original vinegar sample into a 100.00 mL volumetric flask and then filled the flask to the mark with deionized water. After thoroughly mixing the diluted sample solution, 10.00 mL of this diluted sample was subjected to titration with 0.1000 M NaOH. 20.28 mL of NaOH was required to reach endpoint. What is the concentration of acetic acid in the original (undiluted) vinegar sample? Include units and report your answer to 4 significant digits. Answer 4 Amouncements Jump to. (CHEM 102 - Lab Exam Tr ditwtod vintgo’ > HA t Wao 7 Wan tHd Vngo = ove mol {LX (20,2%X157) L= 0.002028 mol Wa Moun, =0,002008 iol cvooneog rel Cle, ork JL 2026 mA/ L 29K moh ( LX (a. comnl 35.00 mL 02 mol (L | hitps/imeskanas macewan.calmod/quiz/atempt php?attempt=10401168cmid=03379S8page=7 1318/24, 9:96 AM ‘uestion 12, A student completed a careful titration to determine the concentration of a solu weak acid in water. (CHEM 102-PRACTICE Lab Exam (page 9 of 32) Before performing the titration, the student accidentally rinsed the burette with deionized water (instead of the titrant) before filling it with the titrant. The burette was not rinsed with titrant, and the student continued with the titration. How wi Select one: F —___ - \© The [HA] calculated by the student will be higher than it should be. © The titration will never be able to reach an endpoint. — he student's titration be affected by this error? © The [HA] calculated by the student will be incorrect but it is not possible to predict whether it will be too high or too low. © The [HA] calculated by the student will be /ower than it should be. © The [HA] calculated by the student will be correct, as long as no other errors were made. y Jump to. ntosimeskanas:macewan.ca/modiquiiattempt pip atternpt=10401 68cm Angone CNavli) x Vino Mutn= raat cna) = aa 1=0837958page=8 A sora Naw i ditwiod , Ate yotds move Nao to yeavh e4wivalone pivt ‘CHEM 102 - Lab Exam >3/8724, 8:36 AM (CHEM 102- PRACTICE Lab Exam (page 10 of 32) Information A student prepares two titration curves: 1) A strong acid titration curve is prepared by titrating 10.00 mL of 0.100 M HCI with 0.100 M NaOH 2) A weak acid titration curve is prepared by titrating 10.00 mL of 0.100 M acetic acid with 0.100 M NaOH Answer each of the four following questions on the based on these titration curves: ovestion 13 Markee out of 0:25 Which of the acid titration curves will ex! the highest initial pH? select one \U Ine strong acid titration curves \oo isc octentiyy) wilh moe Libel and [0 The weax acia titrawor ‘ower YH © Neither: they will each have the same initial PH check } ution 14 Worked ot of 0.25, Which of the acid titration curves will exhibit the highest pH at the endpoint of the titration? select one © The strong acid titration curve [© The weak acid titration curve | | fom weal nd io weak ise © Neither: they will each have the same endpoint pH Check} A” +Heo 2 HA tH hitpsimeskanas macewen.ca/modiquilatempt php?attempt=10401168cmid=@337958page"9 12378/24, 9:96AM (CHEM 102- PRACTICE Lab Exam (page 10 of 32) uestion 15 Which of the acid titration curves will exhibit the highest endpoint volume? Select one: © HAT Nath? Nad t Ho © The strong acid titration curve M6 Cwi/Alene pointy Nao = Nid = Oloomxixio7L. © The weak acid titration curve = 0.90l00 mel LO Neither: they will each reach endpoint at the same volume of added base. Check cmt CPA Naot 2h Coe t Hav rercorste AE @yavsalen® Fine: YN Naor =Murjvant = Ol00 WX L000 Ki07L Ve = monte tel — Der = 10,00 mp Which of the acid titration curves will reveal the highest percent dissociation of the acid at the start of titration? Select one: [© The strong acid titration curve _|\00'| © The weak acid titration curve © Neither: they will each have the same initial percentage dissociation Check 4 Amouncements Jump to. (CHEM 102 Lab Exam > hitpsi?meskanas macewan,ca/mod/qui/attempt php Yatorpt= 10401 168cmid=9337958peqe=9‘1824, 9:37 AM. (CHEM 102 PRACTICE Lab Exam (page 11 of 32) uestion 17 Marked out of 1.00 A student studied an equilibrium by determining the value of Keg at different temperatures using a method similar to the one used in Experiment R. The student began by adding 12.00 mL of 0.100 mol/L Fe?* solution to 8.00 mL of 0.200 mol/L SCN’ solution. The student then placed some of the resulting mixture into a cuvette (b = 1.00 cm) and warmed the mixture to a temperature of 67.5 °C. The absorbance of the solution was measured at 447 nm, and a value of 0.403 was recorded. @ = 2.20-108 L/(mol cm) for Fe(SCN)?* at 447 nm. What was the [Fe**]; in this experiment (after mixing the stock solutions)? Report your answer to three significant digits and include units. oom, cr = OV. s.too mel (LX 1 cov Answer CRP vice Va cae +600) mL Cheek Announcements Jump to. (CHEM 102- Lab Exam > hntps:/meskanas.macewan.calmodiquziatiomptpp?attempt=1040116Bemis=9337958page=10 42.784, 9:37 AM ‘CHEM 102 PRACTICE Lab Exam (page 12 of 32) ueston 18, Marked ot of 100 A student studied an equilibrium by determining the value of Keg at different temperatures using a method similar to the one used in Experiment R. The student began by adding 12.00 mL of 0.100 mol/L Fe** solution to 8.00 mL of 0.200 mol/L SCN" solution. The student then placed some of the resulting mixture into a cuvette (b = 1.00 cm) and warmed the mixture to a temperature of 67.5 °C. The absorbance of the solution was measured at 447 nm, and a value of 0.403 was recorded. # = 2.20-108 L/(mol cm) for Fe(SCN)** at 447 nm. What was the [Fe(SCN)?*Jeq in this experiment at 67.5 °C? Report your answer to three significant digits and include units. AL ek A _ Ay (,00 Gry, (2..20Kyo” L/mol- mm) \ Yio” mol /L | < Announcements Jump to. CHEM 102 - Lab Exam bntps:fmeskanas macewan.calmod/guzittempt. php attempt 1040"16&emidxG337958page=11 1218724, 937 AM ‘CHEM 102 PRACTICE Lab Exam (page 13 of 32) ueeton 19) A student studied an equilibrium by determining the value of Keg at different temperatures using a method similar to the one used in Experiment R. The student began by mixing known volumes and concentrations of Fe** solution with SCN‘ solution. The student waited for equilibrium to establish, and then determined the [Fe(SCN)?*]eq at various known temperatures. At 47.8 °C, the student found that [Fe(SCN)**Jeq = 0.000176 mol/L. The student also knew that that [Fe?*], was 0.001462 mol/L. What value of [Fe**Jeq should the student use when calculating Keq at 47.8 °C? Report your answer to three significant digits and include units. Feit 50N = Fe Coen) (ox) 1 0. ° cx ty Announcements E (ooo) Xx (CHEM 102 - Lab Exam X= Checsanye) = oom th Ml/L Ce y= aeplrba. - 0, 0046 |= d.opfq mas L | bitpsifmeskanas macextencalmod/quzlttompt php ttemot=1040168cmid=9397958pege=12 1(CHEM 102- PRACTICE Lab Exam (page 14 of 2) ‘vestion 20 A student studied an equilibrium by determining the value of Keg at different temperatures using a method similar to the one used in Experiment R. The student then prepared a plot of In(Keq) vs 1/T for the equilibrium, and obtained a best-fit line with the following linear equation: y = 746.31x + 3.6082 Determination of Thermodynamic Parameters for formation of [FeSCN}* 1 6 —|___ y = 746.31x + 3.6082 Ink ‘0.00295 003 00205 nos 00315 0082 ons A/T (Kk?) What units should be reported for the y-intercept of the best-fit line in this plot? Select one: oKt tercept is unitless | ost © Jmol © The units of y-intercept for this line depend on the overall order of reaction {creck} 4 Announcements hntpevimeskanas.macewan calmod/quz/atierphpattempl=1040 168.cmid=93837958page=13,CHEM 102- PRACTICE Lab Exam (page 15 of 2) uestion 21 Marked out af 100, A student studied an equilibrium by determining the value of Keg at different ‘temperatures using a method similar to the one used in Experiment R. The student then prepared a plot of In(Keq) vs 1/T for the equilibrium, which appears below. Determination of Thermodynamic Parameters for formation of [FeSCN]* 602 598 596 Ink 2.0031 cass 00032 nase at (Kk) Based on the plot, which of the following statements is most correct? Ink= Fe \+ + "7 © The positive y-intercept of the best-fit line from the plot indicates that the librium is endothermic as written Select one her temperatures but endothermic at lower © The react exothermic at temperatures dqe70 2) 2° <0 lonthevinty) © The reaction is endothermic at higher temperatures but exothermic at lower temperatures © The positive y-intercept of the best-fit line from the plot indicates that the equilibrium is exothermic as written ol possible to determine whether the reaction is exothermic or endothermic from the information given — - = / © The positive slope of the best-fit line from the plot indicates that the equi exothermic as written — © The positive slope of the best-fit line from the plot indicates that the equilibrium is endothermic as written ntpssmeskanas. macewan calmodiqu2zattempt php?attemp=1040116Somid=888795&page=14 20CHEM 102- PRACTICE Lab Exam (page 16 of 32) ‘Question 22 In general, as the temperature increases, the equilibrium constant, Keg Select one: © Is constant regardless of whether it is an endothermic or exothermic reaction © Increases regardless of whether it is an endothermic or exothermic reaction © Increases only for an exothermic reaction \ses only for an endothermic © Is constant only for nonspontaneous reactions Check Announcements Jump to. . . CHEWIG2 Lab Bom > = (4) 4, 26 O oxcrnenmic: Ink & 7 ++ Cai? <0) Ik Vy Pky] @ endevnormic » (oH? 7 0) nk KY hitpsmeskanas.macewan,ca/mod!quiz/atterpt ph atlempt=104016&emid=9337958page=15(CHEM 102 PRACTICE Lab Exam (page 17 of 22) ‘veion 23 A student studied an equilibrium by determining the value of Keg at different temperatures using a method similar to the one used in Experiment R. The student then prepared a plot of In(Keq) Vs 1/T for the equilibrium, and obtained a best-fit line with the following linear equation: y = 525x +5.19 Determine the value of the standard enthalpy change, AH’, for the equilibrium based on the student's data. Report your answer to 3 significant digits, and in units of KJ/mol. Answer } ‘vestion 24 Not compte Marked ot of 100 A student studied an equilibrium by determining the value of Kg at different temperatures using a method similar to the one used in Experiment R. The student then prepared a plot of In(Keq) vs 1/T for the equilibrium, and obtained a best-fit line with the following linear equation: y = 525x + 5.19 Determine the value of the standard entropy change, AS*, for the equilibrium based on the student's data. Report your answer to 3 significant digits. Calculate your answer in units of J/K-mol, but you do not need to enter units when inputting your response. 5 a = Sq Answer: chew} [creck] 25° = GAVK YAMS fool -K < Ammouncements { sump to |htpsvimeskanas.macewan calmodiquz/attempt php ?attempt=10401168cmid=9337958p=g0=16 12(CHEM 102- PRACTICE Lab Exam (page 18 of 2) vestion 25 A student studied an equilibrium by determining the value of Keg at different temperatures using a method similar to the one used in Experiment R. The student then prepared a plot of In(Keq) Vs 1/T for the equilibrium, and obtained a best-fit line with the following linear equation: y= 518x+4,01 Based on the student's data, at what temperature will Ke, = 207? Report your answer to 3 significant digits. Report your answer in K (Kelvin), and include units when inputting your answer. Yee x + 4 ol Answer: [ / 5 - a big a8) + 40 — n2st = ABC) + Hol usion 26 Not omits {T= BK \ Worked ot of 100 A student studied an equilibrium by determining the value of Keg at different temperatures using a method similar to the one used in Experiment R. The student then prepared a plot of In(Keq) vs 1/T for the equilibrium, and obtained a best-fit line with the following linear equation: y = 518 x + 4.01 Based on the student's data, what is the expected value for Keg at 261K? Report your answer to 3 significant di Y= se x + Fol Unky= sec) +4i0\ Answer: Un Key = sex (ty + 4,0\ < Announcements Jump to, hitps:/meskanas macewan.calmodiquzlttempt pnp ?attempt=1040116&cmid=B337958pago=17 12CHEM 102-PRACTICE Lab Exam (page 19 of 32) vestion 27 Not complete Makes ot of 100 (Cells) and was in the process of cleaning up when he spilled water over his observation illegible: the surviving legible data is tabulated below. Student X completed Experiment § (Vol eet. Sadly, much of his data was render Fortunately, Student X had enough surviving Iegible data and didnot need to re-do the experiment, Use the tabulated data to answer the following question. Based on Student X's tabulated You may assume thatthe Beg for C&* + 2e°—+ C4 is known tobe 0.403 ¥. cut +26 Cu Bey E40? mB Input your answer Co three decimal places Include mit when patting your antwer calculate an experimental value for E*: for the following half reaction. B 0 co Y2d wivhode- B'yed anode ~ Bred y - Bad ed onBV + Bred of SOA + (- 0,403V) [= o mag. hntpsimeskanas macewan,ca/modlquixetompt php ?attempt=10401168cmid+8337958page=18 18 Yd Ou(CHEM 102 - PRACTICE Lab Exam (page 19 of 32) Question 28 {Not compte ‘Marked ut ot 109 Based on Student X’s tabulated data, and your previous calculation(s), celculate an experimental value for E®,, forthe following becton - neo Act te oe OAV = Ered (= Cred Rg Rg? 2 input you saver tore devil pcesandinchseanis, 70) Ag = Credo, + 9. a4av answer ) =0PEV 0.49 ic 2A) ee Question 29 ‘Based on Student X's tabulated data, and your previous caleulation(s), calculate an experimental value for E°,., for the following bal eatin : IAW = Cred ag ~ Chey an Za" #267 Bey =? . Input your answer to thee decimal paces and include wits. -¥04 Zn = EXyed, fig — aa answer ( J 20 78 - 4494 check Caza (Eaqv | | Quvetion 30 arkes out of 100 Based on Student X's tabulated date, and your previous calculation(s), calculate an experimental value for E®,, forthe following half eaton —o0.601V = Bed an - Eve Yb bP 4 De" Pb Ego? Input your answer to tree decimal places andinchude wits. = ved Y= Eve Zn + 0. bol anor) = (~072AV) +0.001V (am (oa) . =~0,\20/ ‘httpsi/meskanas.macewan.caimod/quiz/attempt php attempt=1040116&cmid=933795&page=18 23CHEM 102- PRACTICE Lab Exam (page 19 of 32) ouestion 31 Markee out of 100 | Based on Student X's tabulate data and your previous cleltions),cleulte an experimental vale for yg forthe following half rection _ oo. . Reese O MAY = Oie4 oh - Cred Ly Been? 4 Pry = 2 Taput your answer to three decimal places and include units L= Pred oh + 0. tv — = (-0\\99V) T 0.g4v (3) AAV ‘ouestion 32 Net complete Marked outot 100 (Create « Displacement Series (i.e, Substitution Series), and rank the series such thatthe strongest reducing agent (Za) is last (atthe bottom) adhe weakest eucing agent (Stonges oxidizing agen) st (atthe top) | [eat +26 ea | ft +07 7 Aig oney | fears ] baw a2 ory | [arrtesm | OF Ee G4 oF | fararce pf +20 7% 02. V | [bere Gh +20 > Cd —0409V mies Bat sa 72n | OAV cheek “4 Announcements [sump to. CHEM 102- Lab Exam > hitps:meskanas, macewan.cafmodiquzlatemptphp?attempt=1040116&cmid=8337958page=18 33CHEM 102 - PRACTICE Lab Exam (page 20 of 32) unction 33, Consider the following redox reaction: Zn (8) + Cd?* (aq) — Cd (s) + Zn?* (aq) Calculate the standard potential for the reaction (E*ceu) as written. ide units. Input your answer to three decimal places and i 2) 7. 29 $267 CEO) CAR 0X) Aree Answee: | check A 456° 5 cd CGER) (Red Ue) Geode =o Ee Etch Cres an wot = (-n40) = (otev) (oosav | Consider the following redox reaction: 2 Ag (s) + Iz (aq) — 2 Agl (s) Calculate the standard potential for the reaction (E*cqi) as written. Input your answer to three decimal places and include u Ag? 2Agt +az Ande Answer ) (ome) Lire yz Othe = os oveton 35 ©. Credis— Ered i) Netegere =O6V — 0.500 orkee oto 100 AE = 0.205071 =o, LEV | | Consider the following redox reaction: Pb?" (aq) + 2 I” (aq) > Pb (s) + la(s) Calculate the standard potential for the reaction (E*cqi!) as written. Input your answer to three decimal places and include units. ( WT 2e tb — Ciehode. (ou) 2V te anode. Answer: oy = 2 . spunetosameonncimotyninanp ns doetnlbilontetedhde I =(—0:\2gV)- (0.95V)a wiv)‘CHEM 102 - PRACTICE Lab Exam (page 20 of 32) ueston 36 Net complete Consider the following redox reaction: Cu?* (aq) + Cd (s) — Cu (s) + Cd?* (s) Calculate the standard potential for the reaction (E°,<) as written. Input your answer to three decimal places an units, on - Cat 4207 Cy cAVhod@ tex) - CA O* 4207 role ‘ueston 37 P= ted G- Credcd Hot complete = 0742 —( -0.409V) Which of the following redox reactions is/are spontaneous as written? Select all correct answers. Select one or more: an @ + ca @q) > Cd + Zn* [ D2ne9 + ca® aq —ca ey + Zn aay _| © 2 Ag (s) + 12 @q) > 2 Agl (s) © Pb? (aq) + 21 (aq) > Pb 6S) +1268) (0 CuP* (aq) + Cd (5) > Cu) + Cd?" (5) check ) Announcements Jum to, CHEM 102 - Lab Exam itpstimeskanas macewen calmod/quizlttempphp?attempt=10401168emid=8997968page=19 22.(CHEM 102 PRACTICE Lab Exam (page 21 of 32) uestion 38. Which of the following is the strongest reducing agent? oO Cu ocd O Pb OAg [oma \nwor E%ed Check < Announcements Jump to CHEM 102 - Lab Exarn > hnpss/meskanas macowan.cafmodiquzlttempt php ?attempt=1040116&cmid+8337958page=20 a.CHEM 102- PRACTICE Lab Exam (page 22 of $2) ‘uestion 39 What colour is a Clz solution in CHzClz (dichloromethane)? Select one © Red © Purple © Blue © Pink [© Faintly yellow (nearly colourless) check | uestion 40 Not complete Marked ut of 100 What colour is a Br2 solution in CH2Cl2 (dichloromethane)? select one © Colourless (© Orange/Brown | © Green © Blue © Pink | Check hitps/meskanas macewan.calmodlquiettempt php ?attempt=1040116&cmid=9237958page=21(CHEM 102- PRACTICE Lab Exam (page 22 of 32) uestion 41 Marked out of 1.00 What colour is an Iz solution in CH2Cl2 (dichloromethane)? Select one: © Yellow \ © Colourless © Green check < Announcements (CHEM 102 - Lab Exam » hitps:meskanas.macewan.calmadiguilatempt php ?attempt=10401168omid=9337958page=21 2pCHEM 102- PRACTICE Lab Exam (page 23 of 32) vestion 42 Marked out of 100 A voltaic cell is constructed to study the following reaction: 2 Ag*(aq) + Mg(s) — 2 Agis) + Mg?*(aq) Which of the following statements is true for the reaction as written? Select one: ZAgT +207 > 2Ag Girhode, © E* ce is 3.156 V with Mg at the cathod _ i s wit ig ai e Ci le Mg—> My 42¢ anode. © Eau is -1.556 V with Mg at the anode | foeo 1 7 a) |© Econ is 3.156 V with Ag at the cathode | Bau = Bye fg — Cred bag © E%cou is -1.556 V with Ag at the anode - Pod — (-2 266V) {check } 4 Amouncements Jump to. (CHEM 102 Lab Exam » hntps:meskanas macewan,calmod{qui/atompt php?attempt=10401168cmid-8337958page=22 1.‘CHEM 102 PRACTICE Lab Exam (page 24 of 32) ovestion 43, Marked ou 0100 Several cell voltages are given in the following table: Black Ne paypa MyM La/la* cathode A] 2A = Bed WE, Pa/Pa* &3331V\ lt as ste Fret tall = Bel a/ePlazai Mywe non-spontaneous = ogs\V—3,731V la/la* —_|non-spontaneous | 0.460, = 2a ] The standard reduction potential for the Pd/Pd?* pair is: Pd? + 2e° > Pdi) =+0.951V 0 / Identify the unknown metal M by calculating the standard reduction potential for the M/M?* pair. Jo OAV = Eves Leaflet select on jo Ca Sl © Pb Bras ins = Bred Calidt 0,440 Oo Mg. oO Be = (2.7g0V) — v.Ahov val 0 - Pres msn* (creat) “4 Announcements Jump to, ‘tps meskanas macewan.calmodiquizatempt pp attempt=10401168cmid=0397958page=23(CHEM 102 - PRACTICE Lab Exam (page 25 of 32) uestion 44 A student conducted an experiment in which Eceu values were measured for a series of voltaic cells. In each cell, a strip of Zn(s) immersed in a 1.00 M Zn?*(aq) solution was connected as the anode. In each cell, the cathode was prepared by immersing Au(s) in a solution of Au*(aq). The concentration of Au'(aq) was different in each cel 2 Au*(aq) + Zn(s) = Zn?*(aq) + 2 Au(s) The student prepared a plot of Eceii vs loq(Q) based on the experimental data. Theoretically, what value should the student expect for the slope of the best-fit line for this plot? Report your answer to three significant digits and include units. bog & Answer: 4 check — -0,992V — ~ ~ ZTE ea “Announcements Jamo to ) (CHEM 102 Lav Exam > htps:meskanas macewan.calmod/qullattempt php ?attempt=10401168cmid=8337958page=24 1CCHEM 102 - PRACTICE Lab Exam (page 26 of 2) uestion 45 orkea out of 100 To determine the formation constant, Ky, for [Zn(CN)4]* (aq), 4.00 mL of 1.50 mol/L KCNfaq) and 1.00 mL of 0.0750 mol/L Zn(NO3)2(aq) were combined. The mixture was stirred for 10 minutes to ensure that equilibrium was reached. A voltaic cell was constructed to determine the concentration of uncomplexed Zn?*(aq) ions left in solution at the end of the complexation reaction. The [Zn(CN)4]* (aq), Zn?* (@q), CN"(@q) reaction mixture along with a solid zinc electrode served as the anode while a 1.00 mol/L Zn?*(aq) and Zn(s) was used as the cathode. The measured cell voltage was 0.628 V. Calculate the concentration of Zn?*(aq) in the anode half-cell by using the Nernst equation. ® Nab= ne X GL) = oH IF | XL = oer294 | @ mows yy veacted = Nyy x MW gy, = 0.00284 mo X 203,24 /mne| = 0.4474 9 = jntial may — Gal ma © Val mie ef Yyp= initral may — 0.43399CHEM 102 - PRACTICE Lab Exam (page 30 f 32) vertion 49 Moraes out of 100 A student set up an electrolytic cell similar to the one in the Electrolysis experiment to collect hydrogen gas over water in a burette, using a small strip of copper metal as the anode. Before the electrolysis, the mass of the copper strip was 6.299 g. After the electrolysis, the mass of the copper strip was 6.193 g. The student carefully monitored the applied current and was able to determine that a total charge of 297 C was applied during the electrolysis. Based on these results, what experimental value for the molar mass of copper should the student report? Input your answer to three significant digits, and include units. see aye &- 2 _ BENE F te = = ACE = 0,007, me] check Cu-9 l* 426 Amnouncemenis Nay = fer x 5 = 0.009043 XL mol = 0.015% me) “amp to ‘CHEM 102 - Lab Exam » Mars of Cy veackod = 6.2444 - 6.N29= 0,9 Mb _ 0N069 Ne ~ ans O64 5/mi | hhtps:imeskanas macewan.calmod/aul/atempt php2attempt=10401168cmid=9937958page=29 12CHEM 102 - PRACTICE Lab Exam (page 31 of 32) uestion SO Which of following would provide a low resistance circuit during the electrolysis experiment? Select one: © Hydrogen gas is allowed to escape from the burette. © Alow current is applied. (© Alarge diameter copper wire is used. | © The copper wire is placed on the opposite side of the beaker from the buret. © The nichrome wire is placed far inside the buret. =) Announcements Jump to.. CHEM 102 - Lab Exam » hitps:#meskanas.macewan.calmodiquz/ttempt.php?attempt=10401168cmid=9337958pago=30 inCHEM 102 - PRACTICE Lab Exam (page 32 0f 2) vestion 51 Marked out of 109 The blue colour of the solution after the electrolysis in Experiment U was due to: Select one: _ (© accumulated copper(li) ions. | © oxidation of the nichrome wire. © indicator reacting with the acidic solution. © the decrease in acidity after some acid has been reduced to H2(g). © excess nickel(tl) ions in solution. {cheek } “Announcements Jump to. CHEM 102 - Lab Exam bnps:imeskanas macewan.calmodiqulfatempt php?altempt=1040 68cmid=9337958page=31 1