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I pre ces z I t I z 1 s 1 fr FZ z 1 z 1 z 1 € 1 Olt s I £ I 00S 1-867 O0SI-867 O0SI-867 00S1-867 00ST-867 00SI-867 O0SI-867 00S1-867 O0LE-£17 00sI-862 000-0051 O0SI-SI'867 ST867-0S OOLE-€L7 000-0051 OOS I-SI'867 S1'867-0S 0061-867 00S 1-867 OOLE-€Lz 00S 1-867 s0ze's 969 v9soe 167 LLz9'T OPEL'O- Ol X SZUIL 99°0- 9981 I— Ol X 8'80I- 9z'I- 0z0'0 soy vLr ol Ol X SPNz— 400°0— vElO- 7856 wo £1980°1— bk nas 1z¥6 12— 89- 60Ls'01— TH 876S'S— 0%80'0 Lrg 91'0- Cevl'e 1270 vl 1e€ sez'0- £161— 689SE 16L1'0- or £00°0- 09s"0- 867 Le0- esse €8b'0— eoe ¥6b0'67 ove 6rE0'ST ysl 9LIS'9 1966'L lse0 78 6Lt'I— BBP g0- te1- 1801 oct61 uss— sosT a 0990 2087 BETO 1L7 6100 pore w0- geor's 968 v9les, ses 9879 soo Teou'L 409 LL90'L ots'9 6669 LOL ves ZI Lo6'> ws wel ESOL LL Neo ssoo wo 909L'L 0169 ore ‘os ‘os ‘HN, ‘oO ‘0 OH apixoun anyding 2pixop snyding (rmorerp) anyding ecw uasomy, 2u0zO, u28ix9 IDEAL168 Stoichiometry ve 196" wv wosty ve 196% oN uoaN, ve 196" oH GINHeH oO oT 00S1-862 S¥ES'PI 90sb'Is— 820'79 196L°8 SON aprxoiad us8onruq oO of 0051-862 L608" €LI€'61- 6b6'1Z 65568 ‘oN aprxorn tafonrag oOo of 0051-862 €1z6"L— 2008°21 Ize9's € 1 00S 1-867 96'L- vel es's "ON aprxorp wa8ontN 00¢ 1-867 sous8 Tego'ee— SB8c'sp rOL'L "ON sprxonay usdong oO of 00s 1-262 Ist t— 080L'2 z06r'0— 8740'L € I 00s 1-862 860- 7 $90°0— 69 ON 9PIKO OLIN oOo of 00s 1-862 ssevz SITOI- zL00'S1 zers's € I 00s 1-862, £€7 29°6— sol 9's ON 2prxo snostN £ 1 00S 1-867, Ive wsi- sil 34H aprmosq uaSoupiH £ 1 00S 1-867 187 9L'0- $69 1h 2prpor uafoupsyy £ 1 001-867 x0 vel 10'1- ork dH apliony ua8orpAH e 1 00s 1-862 01 Loe 9 I- wt OH apLio[yo wa8ospAH ow 00s 1-867 wil ay's— 69 68s tq suLon[y £ 1 00s 1-867 zw 7 wz 13 ng surwosg, £ I 005 1-867 Oe 6p sos 00° 19 su0TyD uonenba jo ‘pu wor y ‘oduey Ol XP gol x2 Olx9 ” punodwo>, Cpiuod) Ps 148.Energy Balances 169 i OAT MAT MON AT ATMA AA MA HN an aa ae aaa - =a OOSI-ST°ELE 00S1-867 OOI-ST°ELZ 0001-867 00S 1-S1'867 00S I-S1"867 00S 1-S1°867 00S 1-867 O0SI-G1'86 006 1-S1"867 00S 1-S1°86Z 00S 1-867 00S 1-$1°867 00SI-S1'86e 0051-867 00ST-S1'867 (0001-862 8866 a8 ese'0 oP 060'9 ool’ zs8'6 86 (Ol x C901 wort OX ¥e- £46 9€6'91 sel BEL Ol X 9'SSE6— 9S6°81 ost Ol Xx S'SEIS 19" L0e sis 1t— £'62— T8L'1t= 9'6t— ‘Tae bE ‘TSb'Or— 9EL'St— ssh ol- ‘TO8'ss— otI— £89°8P— SOELS— ses— 990°St— ¥'0s— 79L°9L— ro- oor— €'sI- ooI- vies Tee 80°98 116 L6S'TL 81808 Cle es res LV69 ‘07001 ove 98S'6 PSE PB TI8 7s0'S9 6101 SeVLil oot ole ISIE ver 61 971 Los € 1st Te €L8'I- 69S'0- sis0- 6E 6217 6£05°8 s8s'0- vot I 950- seve tet'S— £40°6— 6L'8— 66pL'E sees "109 HOW'D "HD ‘HOD ‘H'D oR oD *H'O "HO *H?D "HKD 11°8- *HN‘H?O (euewourosopysenst) apuoyyoenay uoqseD (jouerng: [oyooye Aing-u auaing-7-supat auang-¢-57 auaang-1 (euedosdyéyyour-z) oueing-) ouwing-u austpemngre'T aualpeing-¢'1 ouezueg (oudmpa) su2Si20y (euyurm suayd) ouyrery spunodwo 210819 '@170 Stoichiometry rue < = Ol X 125601 €s"OI- 9L0E 9L10'1 ee et 0001-s1'ELz 8LL'0I- £00°r1 IstZI 6S (ouemay) € I 0001-867 = soL- 6M @€ = HOTHO Toyooye [kway Teabre| oost-€1z £9°7- £08 ozI sly fis 2% oa Ol X 9°8rp— ose 69- Loze's oT O0s1-S1'867 £0L'7— 987 Leet 865'r £ 1 00sI-862 Ls— ag te'6 v's "HO suEMOW, Fi --% — Ol X 0'€69b2— V0s— so'ser REPS" coef 00¢1-sI'67 908°ST 989'L— 66°81 *01- "HYD auexay-u (oueypatxods) Cee o0sI-86¢ ee Ve- vrs 907- O'HID Sprxo ouayAyag ¥ eu z = Ol X 92608 oz 99 zav'9 c i 00S 1-S1"867 ss0'b LLy'61- 9z0L€ 9860 (2uaqi9) £ I 00sI-867 lov €6I- 698 760 "HO sushi, cL 00s1-s1"86z sree 86L'001— sox'09t 1LL'8— Eo | o0sI-267 “et $'66- 06s! t8- — SHIO-SHD suazuaq (Am, t I 00S1-ST'ELz a ) T0L'61— cp0'0s 68h7 (lourmna) a 00sI-86¢ “v6 90°8¢- £7 6t7'0 = HOFH'D Toyoore (kmag Veen? = Ol X Vest Ly 7 oles z I 00s 1-51"86 7207 ous'91— sesty £62" a 00s 1-867 9b'0- ou 19¢ we HD suena z I O0SI-SI'ELz zen ove 8z— ¥80'9¢ OL (sueyremosoqyouy) t I 00s 1-862 oe v9— ve It = OHO wHOjOI0T4 ge Ert 00s 1-862 1% 6'38- ofzI i6'S— SHO 2uzzueqos01y uonenba ge ‘py wioy y ‘oduey Ol XP ol Xo olxg D punoduto> (PID) T's sige,Energy Balances 171 uodsup1y ‘X101s0qv7 po11uaD (41) ‘aouv4y *: mbrT AV. (2H) ¥SA “0D Surysuand JN9 (8) “VSN “0D YOOS INH CHA “uy [IPH -2a1TUE4g (A) pun opp ‘raganG ‘éurspuyy wean ayy (1) fo uowsnaiad ays ysm paonposday) ON ATM MAT MN MAT MNT MA aA an ma AN = ee Re ne nee 00S I-S1'86z 0051-867 00SI-ST'867 00S 1-867 O0SI-ST'86z 00S 1-867 O0ST-S1'86z 00s 1-867 O0SI-ST'867 0051-867 0001-C1"€Lz 0001-867 00S I-$1 867 00S 1-867 0001-862 00¢1-S1'867 O0SI-SI"ELz 00S 1-867 OOS I-ST-EL7 00ST-862, €s7'81 981 €S9°61 $961 £66741 ZBI Ol X O'26163— LO 90% OLX ET 16r's os SI¢r" Isl Ol X L'190€ 819" +59 soz Ol X 6°68Sb L971 7389'S rs BL8'1 sez lev'e8— vy8— Les’ 18— og 80618 ze vss— Lys t8— w18- oe 8601Z— 9'8¢— $88°0¢— OLe- se 608°LE— 6ze- 9LY'SPL O'9FT Ep8'8hT O'6bI 865" IPI OI 8v'8IT fIS vel Sel T6E £68°Ss 89S 59°99 989 £0'0r STL 669 Oot LT 6 vero Lyset Lee 60'S TH orl £9- 819°9— L9°9— 119'— 89°e— ltrr— 90b'8— tee soEe's 568'0 390 sore Ue ont ong one 'HOSHD °HD HOH HED HOSHD YS toHO (auazuag [Aqnaunp-p'T) ausihy-d (euazueq [Aqpounp-¢'1) 2uaihx-ur (auazuag [Ayjeunp-7‘]) aua|sx-o uonyoy, (euedorg) auayédorg, (touedoxd-1) joyoote thdorg-w auedoig louaud auequag-u (ueysawoxo[ystp) apuoryo auarkmayy (eueyrawos01y5) Sployys Amo06 |- =e ai er | — ie | 0s 0 fen] 0 a a a aD Remperature, C Fig. 5.3 Heat capacity of gases Substituting c,° in Eq. (5.10), for equation form | (Table 5.1), o=f[ at bT + cT? + dT’) dT = AT, ~ Ti) + (0/2) (TP — TH) + C/3) (T? -— Ti) + (d/4) (Ti — T,') (5.16) and for equation form 2 (Table 5.1), o=f @tortertaryarEnergy Balances 173 f | Temperature, C Fig. 54 Heat capacity of gases = aT, — T) + (b/2) (TP — T?) + (6/3) (TP — T) = dll/T, - 1/T)) ; = aT: — Ti) + (b/2) (TP — 7) + (c/3) (T? — TY) + dT — T)/TiT, (5.17)174 Stoichiometry SE88 10) eo “200 0 200 00 60 80 00 Koo Temperature °C Fig. 55 Heat capacity of gases Solution Basis: | kg mol methane T, = 30 + 273.15 = 303.15 K T, = 250 + 273.15 = 523.15 K (A) Reference 2: Q = 4,598 (523.15 = 303.15) + 12.447 x 10°((523.15)?176 Stoichiometry soc'L L1zs01 S8o'L 1908 r0Rst Sue (o0zz) F021 ead £96001 6C9L we08 £96011 069°8 (0012) 6'8b11 lore ¥'PL96 OLS L 66'L O'S1901 £998 (0002) €"£601 Oris 95676 Zs'L £96. O'sElOl 9198 (0061) ¥L£01 ozre ¥Or88 Sse Leek 81596 vlS'8 (oog!) 7'286 ore r9ocrs 668L 888. 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(ooo) sees TELOL 6€7R98— HVZ 6rd Ors IZ— ars (006) czar 6ss°01 VO8YL8— ove" ISL cuseee— OspL (008) L 9¢% PLEO Coriss= 09s'I1 ore 6'399%2— TEL (002) rtze 84101 EeLLe8— e671 €LOL b'Plogc— 9st" (009) 9's1¢ 1966 e8geos— 168°01 roe o'serez— ore (00s) 0097 0ri'6 8'78668— 66601 TOL ViLgec— 160% (OOF) F'r0z 3676 6 £SS06— 85001 1669 ee9ebe— ZeOL (008) 6'8r1 9E0°6 ¥66016— $9S°6 re) RZS9b7— 0669 (002) ¢"¢6 996'8 r91916— 0106 1869 s'0v0sz— 3969 (ool) 8:Le = FOELI6— 0L8'8 = vocisc— $969 (LL) o's@ = 6£1816— 8908 = O's61s7— 7969 (09) 9's1 = ¥ 64616- 965°8 = €e0ES7— 6569 (a) 0 wt,y “HY + OH — oH 2 dg %HV + SH — oH 2 2 (lo) Do 70D ‘PIXoIp Uoqi> 09 “eprxouow uoqied aunaesodinay (puop) Ts aig,Energy Balances 179 (piw0D) * 88° Loizsz fe€l oss'zI esol lest (o0zz) F071 LISI SLLboz asvel 86671 19802 os'st (o01z) 6811 Ove'tt G8ELET wel wee! czee9 lest (0002) €"¢601 09911 gs00ce srel 84071 oeRes +0'SI (0061) 8'L€01 9s 1 RLL2E 80'E1 z16 11 6Essy 6Lb1 (oost) 77786 6gr TI gsssiz 6671 11 ororee es'bt (onc) £976 68E IT EEE80T 6s'zI es Il PEROT Str (0091) TIL 06711 Te10e 6L7I L6E 1 L191z 96'E1 (ost) 9°18 esr £9161 8971 SIZI1 oseel Sorel (OOPI) 0-092. 890°1T LOIL8T PSZl L201 Cert feel (O0EI) rrOL Oroor TezO8I et! 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De OEN ‘2pixo snomIN, ON ‘aprxo Sun ainyeiodwsay (piucg) 7s 48Energy Balances 181 (pep) 6vU 6 8ZL39- Ivel Sec0l f'e00s— ott weet 8 L9P69— Le'el zl o0L9s— 6611 zrzt TTIZOL— feel girl Loeeo— Bs sired L-9960L— evel szoo1 1 7669- Sut 9p0'zI 9S691L— veel 8266 Te9L- wt Sus" 6 8Ub7L— srel 1€86 Vgzs— owl z06'11 “ostcl— el RUL'6 pr los— OF veel 6 8L8EL— roel $796 L9ES6— s'il Sell T109%L— 9671 1056 8'Lp101— seor ova" SL1ESL— 9871 8076 eESL01— wot azs"11 E09L— ott £606 SLE i— 85°01 viv it orLoe— wesrzl Z81'6 TLE6UI— Leo” SB’ o-orrLL— 621 990'6 L'96rzi— vol oot 6 €T18L— ea 0568 eesoel— 166 zo £€088/— eral E88 TLosel— 196+ one'01 -8'ZLb6L— O61 61L8 SLZIbl— wo 699°01 L9c108— writ 00'S v'ppapl— a6 zay01 ¢£9208— Ten loss SLpIst— 68 94z'01 s'zsels— L601 66e'8 e'BE9St— 8 gs0°01 90861 8— Ls:01 Soe8 LOLI9T— 0s'8 706'6 s'197z8— zror ore oessol— 1€8 £08°6 orsssz8— 26 Lt TIVOLI srs = L9CER— 6 = O'SpILI- we = rorees— £76 a weeeLt— 60:8 = TTOVER— 166 = BL vELI— 908 “ao HU + SH — off ? 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Lovet OCF LOLI Vtsee— 00'1z (o06t) B'L€0; P6C'ET LOP9IT tel Loe LI ¥69988— 08'0c (0081) 7786 zez'el Tzs801 Leet 829'L 9'07368— 65-02 (OOLT) £926 69r'er £'€9001 Ice aor LI 6°£5606— RE07 (0091) F118 960°E1 ¥ ble suet Seo L L18026— svo7 (oost) 9518 0z0'e1 Vrs Lor LEO'LT 8 T61E6— 06°61 (oort) 01092 06°21 celle € 11891 8'267b6— 9°61 (OOE1) v'0L 9re'ZI ors 06'€1 USO T9Leso— 9f61 (0071) 6 +9 esett 69919 08°€1 Soc‘ol E'8hr96— 0°61 (oor) €'€65 e971 czors 89'EI S091 8 U6rL6— 6981 (oor) 8LEs €2s°1 Loper ese SEL'SI 907586— 6c'8I (006) 7zsr al L106€ Lee ters 9'0z566— SELI (008) L:9zb Rsz7I eeore gel 90'S 1105001— SELL (00) rue 96 S189 96°21 599'bI 6 esrlo1— Ler (009) o'si¢ 66°11 vel out ssc'p o's9ezor— 60°91 (00s) o'097 Lee TLZ01 rz! ves'el vveceol— I¢sl (oor) v'r0z Sestl 6'8be+ O71 SIC el 0'S90b0I— rel (O0€) 6'8tI £6011 zL0E— 6ST 99'Z1 p'resbot— srer (002) €'¢6 £8011 TLE6— wort 9ee'et T'ssso1— Lear (ool) Sze = 6'8L01- 1601 = O's1Ls01— wat (0) ost oa 6 RL11- 08°01 r9zgsol— wl (09) 9's = 8 crel— 19°01 — ¥°600901— ol ee) 0 “i “HY + OH — of 2 uo CHV + GH — 4 (do) De gD ‘aprydinsip uoqrey, £Qs “eprxoun snyding aanyusadwa |, (p09) 7's 1481Energy Balances 183 (piued) eo19z TL6ILI OzL'be sov'st o'sRop 65°07 (00z2) 't0z1 OL'St o'sezst o9t'Pe esz's1 wisse 90€"02 (0012) 6h TT Lest V9ReE! 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Or018b— 000°LT (oo!) *t02 Ist Iz 9°soh— 890'82 e8s'ZI vreels— Beh'91 (00z1) 6'8¢9 soe 0'S661— £6047 ETT cLE99— 0s8's1 (oor) E"t6s 69861 RTLpt— £7097 Sig t 9*00SL— Lest (0001) BLES P8161 oss 81662 80S TT eazea— 696°F1 (006) 7'zae PLy'8! s0rz9— sicez ecrtt BT Lege (008) Loz Weel BLzsL— op te 1SL'01 6'3986- ovr (o0u) rice £6691 V1bL8— S017 S9EOI €8LS01— 68e°71 (009) 9s1E Izr9i RZLR6~ L35°61 6166 O'svzlI— 09°11 (00s) '097 doe'st 9°S1601- 10°81 265°6 8 LO8TI— 118701 (oor) +07 lyr! £'89811— oreo 8£7'6 o'spreI— £001 (ooe) 6'8¢1 PEE! voulzl— 89P1 BLB8 ©'€8671- 9086 (007) £"£6 €RLZI 8'L6bEI— L671 609°8 o'08rE1— $99°8 (001) SUE oS T199¢1— oRs'z1 = o'06s¢1— LES'g (Ld) o'sz Fr 6'RLLEI- ez eS '699E1— Orr's (Coors. = TL96EI- Poet = L96Le1— 96'8 (co 0 %GHV + SH — oH e ue CHV + %H — off 2 (40) De PHD “URWOW ainyesadwiap "HED ‘oueuIy184 Stoichiometry Sera pense gIz'e9 ZHE'LE 8°ZL08Z 120°6r (0zz) ¥'p0z1 isily 90z0SE zorz9 LOL9€ cisesz £or'sr (ooiz) e'ghtt 990° osesie L919 loe'9¢ ybolez Teele (0002) €'€601 867'97 TUOz8 LIL 09 €LS'SE TLs00e SEOLP (061) 8Z£01 SLy'sy TUHBHT 98L'6S Bh6VE CEBPLI Iye'9b (081) 7786 Tz9' Lovsiz OFL'9s blZve 6 FEST con's (ooL1) £926 feL'ey orsiest 9Ls'Ls ous'e€ Seer 0zS'by (0091) 1148 los'zy vOrist eve'9s 8UBTE T7866 sos'ey (ost) 9518 918"Iy TLpOeT sto’ss 190°2E 08S Gorey (oort) 01094 £18'0h 8'ZH06 o19'es sec'le 68675 19¢'Ih (oe!) p'r0L SSL'6E gsI19 6907S 66€'0E 9'S66z SzI'Ob (ooz!) 6'899 699° 8E ERLE oor'0s 91562 o"s08+ L6L'8E (oor) e'e6s 88r'Le osest £09'8P £8587 fetel— Tee LE (0001) BLES 697 9E vP01z— 819 9F 20947 orosee— Sz6'se (006) 7z8b TLO VE voto 109° 19°97 6'8675— S61'be (008) L'9¢r woo ee eLsoL— set S8P'st vr oPlL— 80r'2E (oo) rice eS1'ZE O'sres— 806'6€ creve 7 L688— SLY OE #29°0E 9 06r1I- weLE BS1'EZ 8 LZS01— 08¢'8¢ ¥€0°67 TLLvel- LOE bE 626'17 o'seozt— 180°9¢ (oor) b'r07 Sele eeezsI— oor'le 109°0z SLIbEI— sus'ez (o0€) eget stLst “ott Ieslz 9761 9'ssort— 2€6'02 (o0z) €"€6 £00 oosesi— oH ve E16'LI Vivesi- $0c'8t (oor) size = ZL8981- ZI9'€z a '0L651— OLS LI (LL) ose es 1'90681— S60'E7 = or0ei91— 860°L1 (09) 9's = 9ssz6l— SLUT ame T9geo1— Izeor (ee) 0 “to CHT + WH — of ce) ia Ly +O — oH % (40) De *YD ‘ouedorg aumerodwioy ont ‘aueing-u (pro) Z's 198LEnergy Balances 185 (piuod) Zens os9tp LOL £¢9'8h 9'SPOLE weee9 (0022) b'POzT $89°85 Vise 96°94 €r6'Le Vassee 99°29 (ooiz) 68r1t @L'Ls V9ctoy Tos'sL o0c'Ly 6 8600E PLD (000z) € E601 9E8'9S SLS6SE Tip pL 6th or L90L9T 168° (0061) 8'LE0T eps'ss vorsie eve'EL R59°Sh 6 RLEEZ £0665 (oogt) 7'796 L08'rs eersiz ELOTL SI8'by 78007 P1685 (oot) L:9%6 qees T1psee, 70902 c06' ty ¥6189T 89L'LS (0091) 1128 E98 TS v6r66l U1 69 Over 9 0C9EL ESS9S o0ST) 9'S18 wes GESI9I 67s'L9 Is6"1y 681801 8Ez'S5 (ort) 01092 Izros OosezI L6L'S9 Is6'0r #L6bL ger'es (ooet) poe sos'gr ree 176'€9 vL8'6e V'issb 06z"25 (ooz1) 6869 Sstv'ly oBrEs 99619 vOL'8E O'SOLI+ 8€9°05 (oo11) €'€6s vL6'Sr O0L61+ 80L'6S OLS LE eLS01— 658'87 (ooo) sizes SEboy TLZI— OrE'LS Oze'9¢ 9'0zLE— E699 (006) 7zar 61st 9'S0r>— B8L'Ps 966°rE ¥6979— Obey (008) 2:97 wir orocec— 0075 zi9‘e€ 8'2698— Lusty (002) r'tce 996 '6E £89101- $9687 evi ce £°98601- r60'0r (009) 9'st¢ los'Le L16L21— 199'Sp Tus '0€ LUwiel- L9ELE (00s) 01092 GEs'se CLeesi- 60% 016'8z eREISI— LLE VE (oop) »'v0z isv'ee v6SbLI— ZzI'8€ 9zt'Lz 6£9691- 9zI'Ie (00€) 6'gbt SLT IE TL9v6I— ROFL we'st T10981- (002) €'€6 wOE6e 90EzIZ— ZOL'6z PLE? °0€002— (ool) BLE = yyosiz— PIL'8z > r9ze0c— (LL) o'sz = 6 eL8IZ— v10'8z a 6-8soz— 8Lb'7Z (09) 9'¢1 a €C0E¢— 688°97 io ££ 80— 80817 Ge) 0 “e HY + OH — of @ uo “HY + UT — off 2 (do) De USD “oueWag-u oy ?D “aueing-ost aumeraduiay,186 Stoichiometry STEOIy VIpise LEE07 LEC 9T (o0z2) r'voct CR16SP 1s0'07 TEE Et6'Se (0012) 68r1 oocer Isc6l SLplse €8S°ST (0002) £°€601 SL9SI> 6rr'6l 6 CPL9E 9iz'sz (0061) 8°Z¢01 Peeve 8161 vosese Lise (ogi) 2296 SEEELE $8L'81 6 C86EE L8E'7e (0021) £976 o'seese feP's1 BUPITE OE6 8 (os) F148 GO EITEE 1081 STeCle 9EP'EZ (00st) 9°S18 £°80EIE PLOLI L906 906'7z (oort) '092 SURC6Z O7LI E'BLL97 zee'tz (ooe1) +'b02 rorsez Lys Tassie BILIz (o0z1) 6'8r9 E0LST 9791 FOLEIT SSO (OID £°€65 . 6 ES6ET SPO'ST STCTST SE'0Z (0001) sLEs SELLE vsp'ST RTL z9¢'61 (006) z'zab 179907 961 T9v0cz 9SL'8I (008) L9ee ¥SZI6I 6E'b1 Ss Le0Te L9B'LI (oow) Vice SULT oes! T9017 68°91 (009) 9°st¢ Ceol ical EES 107 LE8"ST (o0s) 0'097 [90ST 5 sacz1 o'sor6! 81991 (oop) F097 S288e1 61611 ees Lire (oe) 6'8r1 FLESH aT E18L1 £60771 (002) £°€6 TUO6IT cs ol I8IZT £201 (OO) SLE 5 9°s04 = L9POLI 80°01 (Lo) ost ae 9ST ag or0c691 6101 (09) 9's zs V9eett Ti ZL6L91 BLL'6 ce) 0 “9 “HV + GH — of “40. HY + GH — off 2 (do) Do HID ‘auayhdoig "HED “ua}cug aunyeradway, (pluod) 7S age LEnergy Balances 187 (piuoa) PSL9E Voutee eror (0022) pp0z! ZOE'9E V9rore vo'sr (001z) 6'8¢11 BCB'SE CE0ITL z'st (0002) €'€601 9EE'SE 's1969 9S" (0061) 8:ce01 Orbe 6estL9 seer (008!) 77786 SLEPE “1ele9 ceer (00.1) £976 coL'ee STvETO ose (0091) rizs sores £86665 SIP ece'ze OIL erty (o0s1) 9'518 SLrze £86915 lotr eR071€ L9€169 $S°Or (oor) o1092 vIste SZrpss €r'0r 666°0€ £11699 09'6e (OED) FOL Here wees 8168 9C'0E C8ELr9 LS (0021) 6'869 6LE0E 8 CO0IS 91'8e 91S'6z 2929 Sree (oi) €¢6s L656 6 £0067 80LE RIL 9"SL509 *T'9E (ooo1) sees asL'az 19169 race LES Lz 'S6s8S Ove (006) czar Logie s0z0sr ssve £669 16995 Ise (008) L9zb 81697 Strley sore £90°97 O'OL8bS OO'E (002) rice SRST Early + Bre p80'S7 SLerEs SeOE (009) o's1¢ ILe'€e £8H96E 69°67 zso'ez ciosis €5°82 (00s) o'092 ELSET TLSOE £97 £96 O'0L66r « ssor (o0v) # P0z ore ossoe 6v'sz SeBIT eesser wee (O0€) 6861 ozg'0r PESTSE soe 929°07 CRS7Lb rz (002) €'€6 16e°61 OSLOPE 1261 8Er'61 L609 16! (oor) see = TLeREe lo6t = reresh +16 (20) o'sz + gosoee seal = TeLOSb o's (09) 951 = yoleee ssut = eBsesy 66'L1 (ze) 0 “> CHV + OH — off cc) ue “GHY + GH — off 2 (Ge) Do °H'D ‘auatpeing ¢-1 HYD ‘uoIpeIng 7-1 aimiesadura |188 Stoichio oso'st VILpeL EHO LI (0022) p'P0z1 9z6'b1 oS6rEL paP'L1 (001Z) 6811 ‘ Lott ERTSTL SIELI (0002) €'E601 599°P1 SZLSIL sere (0061) 8:Z£01 8ZO pI L9T9OL Sr69 (0081) 7786 oRe"PL 193969 wL'91 (00L1) £976 tert Tz9L89 les'91 (091) 1148 6L0°61 F'0s8L9 loro! (Oost) 9°S18 616 El 905699 L091 (oorr) o'092 1es91 prisit— wee Iseel 379099 618'SI (OOE1) PPOL €cror goze— 01-02 9us'€I 0'06169 9ss's (o0z1) 6'8t9 Ils ry1see— 0°02 96c"€1 eecers 82'S (ooit) e'e6s soc's €€06rE— £61 Love TtorE9 l66'rl (0001) sees LSB el eesose— 8o°81 LOOT T9979 689'FI (006) czar R061 6'8569¢— L'il loL'zt 009819 EP! (008) L9zb Tree Vizeee— 6°91 lesz riL019 zoel (oo) Vee esv'el TLesse— v0'91 see 110609 ovo (009) 9'st¢ SS6T1 L10l6f— Ors C9071 PPssos Ope el (00s) 009 Bor 71 901S0r— atl BOLT LLES8S 1e7I (00¢) b'PO7 SI6tt oouzit— ser LOETES #2771 (o0€) eset R6E'11 z'L9614— oz 180°1T TLels ws" (002) €'€6 L801 T LO 1011 zs9'01 T'9s89s RILOL (oor) Sze = 1V9bLZp— wl PS Orgs 66r'01 (LL) 0'S@ =a Lopszh— 88°01 on £17995 e€C'01 (09) 9°S1 i 6'800¢r— or aT T19p9s Oro'or (ze) 0 “io HU + OH — oH ws Hy + Ww — oH > | (do) Do HOTHD ‘Touran, HED “auayiiaoy eats dua (piweD) Ts aIgeLEnergy Balances’ 189 (‘pauog) Iss‘ 6826- rors cov'le TL8bLI— 166€ (o0zz) F021 000'zr Zz16E— eres 160'1€ TLR99€1— over (0012) 68h11 wry w'7989- Les $99°0€ 9oLest— Lose (o00z) €'€601 sis'or 6BLLE— qe recor 9'0z081— sy'se (0061) 8Z£01 LVF L9sozt— ovis L9L'67 TLE10Z— BOLE (0081) 7786 o1s'6e 0106s 1— 19'0s vaC'67 ‘9eeez— RULE (O0LI) L976 08°86 68iz8I— Ler LLL L1gzp2— z9'0¢ (0091) 1128 84086 TTIOIZ— suey 967" 8'26297— 16's€ (o0s1) 9°S18 €1ELE 0-069¢7— vely LoL ez 9 OL782— vise (oor) 0°092 sos'9¢ TzE92— 59°9b 8zI'LZ £°8610¢- Tete (O0E1) b'b0L os9'se e'€L887— op'ce s7s'9z igoze— wee (00z1) 6849 seve TzsEle— ocr £68'SZ orstece— orrze (OLD €°¢65 LOL'EE ¥pBLee— v8 cP wre'st TiLgose— ove (ooo) sats 6aL'zE fezioe— selp crs ve ¥ 60PLE— 96'0E (006) czar zeLIe eecese— ZL6E 678'EZ ¥'6606f— 81°67 (008) Ltr 0LS°0E vresor— rere £90°E7 e'sb90r— 06'1z (002) FILE 096 67 vrEscr— 66'st wet v6sizr— ws9e (099) ste 90°87 68esr— Eg'ee vrblt V16ser— £0°S7 (00s) 0°09 19°97 ooreay— Lele 61502 8 LE6rr— eb'ez (00p) #F0T $80°S2 ZLOOK>— 19°87 730°61 TT619~— wz (00£) 681 aSV'EC TTIS6r— ws'st $9081 eabeL— 16°61 (002) ¢°¢6 969°1Z sLER0S— ore BLT 8'2Or8Y— o's (oon) 8'4e = Ositis— £17 = 9 0E98P— 6st (LO) o's = 6ElEgls— sLoz = 9°S6L8P— wut (09) 9°S1 = 6'87915— al = ¥°6S06>— zo (7 0 uo “HY + BH — of 2 “2 WV + GH — oH 4 sdb D> HOPHED ‘loueyrg auneaadus HO‘H'D “loyooye [Adorg-u (pwOD) 7s 719FL190 Stoichiometry R6r'E1 + 69r8— £1691 865°tP oeLzs— 8I'bs (o0zz) 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¥2L'8 CE6LEC- L106 LeRez LORRES— lesz (002) €-¢6 ws" C1szyz— spss 16€"2z v'6zzss— we (001) 8:€ = 9'06€r2— Ivy's a osIsss— 061% (40) 0'sz = 6 89%rc— 88 = eBress— RE 17 (09) 9's = 6 86S%7— 1878 = T'9¢09s— $02 (0 “oo “HY + oH — off 2 “ SHV + GH — off 2 a (Ao) Do OHOH ‘p{yapjewi04 HO‘H SD “loyosye [Adosg-osy aanqesadway (Pwd) Ts aIgEnergy Balances 191 (pruop) (0022) P'P0z1 (0012) 6'gb11 (0002) €'€601 (0061) 8z£01 (ost) 7786 (oz!) 1926 (0091) T1z8 (ost) 9518 (oor!) 01092 voL'oc BT9PL 16407 ¥'65661— (OOET) p'POL 19-0¢ GELS 00E'0z 9'0zbIz- (o0z1) 6'8¢9 18661 6EzSy ZaL°61 s'zveez— (oi) e'¢6s west eezie SE2"6r 9 0¢ehe— (0001) s'zes ee'81 OLLI zL9°8T e8rssc— (006) 778 POLI 9°06r+ €L0°81 rg9cavz— (008) L9z% 98691 SUL al €'8r08Z— ~ (004) Ize error 6EI6I- 62°91 zL0%6z— (009) 9'st¢ Tee's L100¢— 60r'9T 0-000 (00s) 01092 ley 8'L00P— €0r'ST Licele- (00r) b'v0z vLs'el 8'Z6r— LL9"gL TL9eee— (o0e) 6861 65971 v'6ELs— b6'EI ezelee— (o0z) ¢'¢6 611 vpsro— Live egtece— (001) size = ¥'7099— = 9°S80rE— (40) o'sz. cz cutlg— = SB LOzrE— (09) 9ST = £1889 = 6'€0rrE— () 0 oa HY + GH — of ay “HY + GH — off 2 (do) D6 OPH®D ‘2pixo auatéyig OHD‘HD ‘apAyaprray aunjeioduayStoichiometry 192 yH0'bb TLs008+ Lev Ls Leese Tete vesr (ooze) v'v0z1 60" SLR8OL+ 628°9¢ 668'PE TU9LP— 99'br (0012) 68¥IT reece VI9Lel+ ELI'9S sse've 687ZL— LOvY (oo0z) €"€601 OL ty zLs90L+ zov'ss ove'ee £9596— bree (0061) g'e€01 066'Ib S6SLO+ 969'ts cores V1soct— Ley (oost) 7786 Ofz'Iy SLLSPO+ zsB'es SEL TE TClvrl— over (oozt) L926 Liv'0r 8°L0919+ Sv6'2S Loree 6 87L91- 9E1F (0091) 1148 91S 6€ org98s+ bb6 1S ses Ie £90061— 1L0y (oost) 9'¢18 989°8E L9E8SS+ 898°05 LLs0E veeciz— Loe (ort) 07092 TLL O'spOEs+ 819 OF 961° 0F TTlvtc— OLE (00€1) y'POL LEE TUEOS+ O8E' sy SLY'6e oorss7— OLE (0021) 6849 899°S€ E'CLOLY+ 856°9% OzL'8z £909127— ov'9e (oor) e'€65 BCS'PE TLoIsrH L8E'SY 026Le Tz196e— se (ooo1) sees ogee ccever+ 099'tr cL0'Le Vissi¢— ze (006) zzsr S1OTE L19t0r+ SPL IY £8197 TUlpee— Osze (008) L°9¢r 919'0€ 6866164 119°6E sor'sz vpsise— TIE (00L) ILE 61162 S'799SE+ SEC LE €80'bZ © €199¢— €s'67 (009) 9's1¢ POS Le 9'S98EE+ vss've 290" ez Tzopse— 89'L7 (00s) 0092 £81'S2 6'8z0ct+ LES'I€ lice EEPO6E— ost (oor) ¥v0z weEL €'R0C06+ 91°82 pel lz FOIEIb— 8SeC (00¢) SFI 94612 6 0687+ Tye 180°02 Lossee— welt (007) €'£6 01861 T9s9de+ OLb'0z 609°81 T169¢h— 8e'8I (oor) sue = TUOvLt+ vis 61 —~ 6 806tb— R81 (4) o'sz = LUT 68L'81 = s.001rr— 68 LI (09) 9's 7a ose6oc+ E0L'LT as eel ery— ort (ze) 0 “9 CHV + GH — oH to “2 “HY + SH — oH 2 (0) De 2}°D ‘suazusg, aimeadwey SHOODHD “suoI20y (pio) z's ageEnergy Balances 193 PIu0D) 182'99 9°S1086 o8'ss SoE'SS LpLLe obIL (00zz) F021 I98'¢9 TUG aa'b8 PI9'Ps Lostes LOL (ootz) osrit 868°F9 +8588 88'e8 ales 9 0LT6L 18°69 (0007) £'€601 168"¢9 685688 0878 9r6%s 68crSL : 96°39 (0061) s:ze0r S829 6 88E6L 7918 0907s 6'8E91L 86°19 (oo!) 7°86 969°19 TTR8bL veos 60°15 6919 06°99 (o0z1) L926 £2509 T19b0L 968L soos Leis £L's9 (0091) 1128 787'6S TL1199 SH LL reO'6P 90509 oF'r9 (O0S1) 9°S18 LOLS 779819 zest BIG Lb T9045 80°¢9 (oop1) o'092 65°95 L1OLes £0'bL OrL'9b erroses isto (oor) "+02 lerss Tisoes 60% Zor'sp €'88105 z6'6s (021) 6'8r9 ws'es 87696r 9669 zee O's0697 ass COOL) E°€65 6161S PPLEsy £919 voLtp yreley v1'9s (0001) s:zes €LT0S L161ee 80°9 £97'Ib T7290" 96'¢S (006) czar L6z'8y TIS98e 1779 199°6€ LOELLE 9s'is (008) L'sep $629 osizse 916s £96LE o'svore o8r (00) Fue sey Trs0VE or'ss 1919 SCIEeE S6'sb (009) 9's1¢ Sos ly 006062 98'IS olz've 684367 Lt (00s) 07092 Lev'6c eseegz ssue Lure orossiz 10%6e (oor) ¥'+0z o€8'9¢ place Lee 16°62 Lest sore (008) 6'8P1 680°VE VISsiz 8S'LE £8907 BLO9ET Ls 0 (002) £°€6 “ele 908961 zoze 192'sz 682127 06°52 (ood) gue = L1ST6L 69°0€ = T9081z 08'sz (Lo) o'sz a 689681 069'62 ee TLLsiz 96° (09) 9°s1 al GEIS8t £6182 = Viz Ot © 0 “oO HY + UH — off ” “i GHY + SH ~ off cd (do) Do ony ‘ouszuag [Aug YL ‘ouanfoy aunynsadwi3]194 Stoichiometry 5799 yr9ee9 sor'ss 97609 C0stLII wee (022) p'voe1 6s1'S9 OSSPLS 98118 ve 09 VIL6TH vol (0012) 68PII 20°99 EE99ES 70698 056s ££98011 6S°SL (o00z) €'€601 81679 V9p6Ly £1698 fop'as L9ISpOr 89°bL (0061) 8'z¢01 99919 Lister L98"¢8 6zsLs ¥'6£001 69'EL eos 81986 9EL't8 f95'95 SLTE96 19L F685 826005 102"08 ossss SLUEC6 wll ogy Ls 9°59967 yS8°8L BLr'bs $'P6E8R 910L Tp6'ss o'0vEST LL6°9L teres Cecsrs 189 R0€'rs CET 068'rL vel'zs ¥'S5208 svg sos ts 109 PLB'0S £990LL 65°59 (o0z1) 6869 Los @'Esost $80°0L tes'6y TULPEL Leo (oor) e'¢6s easy 68E76 O0E"L9 S80'8 £°£8669 BL19 (ooo1) gzec vel TL8ss 6179 tss'or 111999 65°65 (006) czar 8esy eelie+ 0z8'09 El6'ry L99EE9 ores (008) c:9zr azz 6EoTI— 850s 6rl'ty 119709 PPS (00L) V1Le oz6'6E TLLIP— L16¢s S8C'ly Tees wis (009) 9's1¢ ere T'9€0L— see BrC'6E orossrs oer (o0s) 01097 S6v've 1'9856— 99E'ey 960°LE eesels ceyy (oor) voz wOL It eBrBlI— 966'LE OL'VE TLE96Y oor (O0€) 6'8r1 12887 £-908¢1- oor'ze Ose'ze TLESLY wrse oe'sz 9'SbosI— 929°97 81°62 TZ LOLs ge°08 - r9eest— T8€'sz = Lovesey 81'6z = 8'L009I- sov've a o'ssosy £87 = €89691— 90877 = 8 LC9KF w9t @e) 0 “a HY + tH — 2 “ CHV + SH — off 2 (do) Do TIS ‘auexayopaia, THOHO'H®D ‘auatis aunesodwia | (piwo9) 7's a1q6Energy Balances 195 R0rTT Prseoy (0022) ¥'r0z1 6ze'IT zzezor (oo1z) e'grit te ororsse (0002) €'€601 svt 6'86LrF (0061) 8'z¢01 290°IT E'e60rr (0081) 7786 £4601 eeocey (OL) £'9%6 61801 yroitr (0091) T'IL8 €ZL'01 o'st0ze (00s) 9°s18 zu9°01 c'evely (oor) o'09e 6882/8 srst sss‘ol V'iL90r (OE) F'b0L 688798 S6LI prv'0l 9° 100% (0021) 6'879 POTS eLel Sze'O TL9t6E (oor) €"¢6s CE8IS Bet 20201 SOELsE (ooo1) sees orssees Iwer z0°01 vvO18E (006) zz8p 9's0vz8 1691 v6.6 YO8PLE (008) L'9¢p SLLvI8 6S 91 €8L6 9'sB89¢ (oo) Vie 879508 9 £796 9°S6z9€ (009) 9's1¢ 969961 88's £966 eEZLsE (00s) o'097 6 B6LEL ysl v6t'6 Tugise (OOP) F707 L1S6LL 00s! Z6 E'879E (00€) 6'8¥1 ECeTlL spel S68 OOlIvE (oz) €"€6 v6rEoL wel z50°8 ororsee (oon) gue = O'SLIOL oorer = ¥ 66bEE (Lo) ose a TLvO9L aver ie O8IPEE (09) 9°S1 = 6 BERSL wel oa SL87EE 0 “oo “HV + 3H — of cd “ “HV + tH — ff (4) D0 ®(NO) ‘waBouvk5 NOH ‘opmedo usfospay sinyerodura198 Stoichiometry 00s or 9'ETT sLo0 lero ¥'s01— “e's 39290 0— 4 Surpoy Stor po- £90 S197 8eL'7— 6611 bbb'0 7O°H —-apixouod uodospéy OPI 01 g'9s— = sor ss'oz— ELL 8199'0— 1H apipor us8opéy, SLIO C'eg— ee s'e8 1c69— Iroc vipI- dH pony uadospsp 02% ZFII— _ 1799 lese— 8PO'L 1711 0— 10H @plio[yo uasoipAH 08 01 6'93— = sors Ly Ip ZOO se 48H apr uatopéy SPT— 01 '6ST— = 8 er7— eOLIZT e67e— ole HH usdoipAH 002 017 suo “e9st rosi— oer ver THEN aurzepsy Opl— 91 61z— a Oren orlee— BUT 887'0— gy auts0n1 4 081 1 SZII— = v0'0e 9911 Lez 66870 = OPHD apixo auartyg Or— 01 691- = e921 “0s- aIz9 Zove'o— PHD ousting, OzE 01 S6— sir0 669'L oe t— ML7 Ip6r0'0 SHEOSH*O auszuaq Kya, 081 1 T'1I— 80 6s"¥s on ee— 6856 66re'0- HOTH'D jourya, 0zo1 z'e8I— a 97 ¥S'95— 18P°8 83El'0 HD sueyty 097 91 $5°9 tro we “se- Catal *87I- THD sureK aq OTK 052.01 7'¢9— sto v7 ¥9'0l- ore ¥S1600— ISH UNIOFO.10THD Ore 01 7'sp— 1€0 Ivor 99°01- ozs’ Lorl'0- IHD auezuaqoz0[y5 08 01 101— a 6°82 Le-or- ory ugo- 4D SuHs0TuD, 097 01 6 zz— a) 019°8 0 L— 8507 8Z7100— "19D aptuoyysenay uoqae) 0s1— 01 so¢— : = S616 Lei- 86L'P sr9s'0 02 aptxouow woqie> 0291 s'9¢~ a eLst $°S601— obsz osl- 09 2PIXoIp uogsey 00z 01 E'6R— 9c'0 65°85 zr'9r— L6z1 L8SL'0- HO*H joueing-u 021.01 6°801— = o'er 19L's— P01 s8Le0 HD aueIpeIng-£ “T 08709 TL 600 wel 9e'EI- tbr oser0- auTwosg 052 9} €5°S Ivo 60° 0L'&>— OP's IgrI- HD. auazusg 0€I-01 ¢68I- = LU6é sosz— Lvez SLLFO- v wosay S9€ 01 C1°9— 6r'0 1265 $80°9— Love “ovi'0 | “HNSH®D aumrey OOF oy ¥*LL— LET soli- re {6l- HN vuowWy Do ‘suey Dose wo OLxP gl xo Olxg o ‘BINULIOL Punodwo> “y aimendua = L ©© 8p 84)/Teox “yeoy oupoods = 2 a104M IP + 19 +19 +2 = 7 uonenbg SAINDI] NOs sNortvAdY AIH O1sIOAEg f's IGE,Energy Balances 199 C¥SA “0D YOR INH-MDUDIW 241 fo uoWsmuciad ay1 YsIo poonposday) 10 1968 67p8'0- HD) HD auaix-d v0 6rs'e £6180°0— “HO) *H°D au ayhx-ue stro 7689 86rh0- 45HO) "HD aualix-o “Ol Stsz 14290 OH Ja1eN = s6e'0 sy 19p0- “HO*H?D. auanfoL 6L0 oor 8L6'¢- 0S aprxout snyding = Peo! Leus0-—-*OS aprxorp anyding Ivo sors psIc0— "HEOSH9O auaikig = £891 90Lr'0 HD. austkdorg uso £Ls8 19t0- HO‘H'D jouedorg-u = weez gree'0 "HD auedold i giz8 9699°0- HOH. louaud a pete Lasro— ‘0 ua8KxO, 2 very s167- ON aprxo snosin a 66°81 sto I— ‘ON aprxorp usBo.11N, = eusee Ly6s $90"1— 'N wadonN a o-lizrt vers 90'6I- ON aprxo 9UnIIN = £9°61 zIvI- HD susqeyryden, sao Lol LIN1O0 = HOH ePHOTYD aualkyreyy oe €L'67 88h EZ1H0'0 I‘HD aptroryo [AMIN 309°0 6891 "0— leze- zaex0 = HOH journo = EL0I- e€'0l— il "HO aueMaW, Do$Z we F Ol XP lx? DP. — BINUIOY punodwo Cpiuod) €'s 1481200 Stoichiometry 1-04. 1-000} 960} 8 R Specific heat, keal/kg-deg C) 3 @ 8 8 600! 0 10 20.30 40 50 60 70 80 90 100 110 120 130 140 150 Temperature, °C Fig. 5.6 Specific heat of caustic soda solution? (Reproduced with the permission of Hooker Chemical Corporation, USA.) EXAMPLE 5.5 How much heat must be added in order to raise the temperature of a 20% (w/w) caustic soda solution from 10 to 90°C? Use Fig. 5.6. Solution Basis: 1 kg 20% NaOH Solution From Fig. 5.6, for 20% caustic soda solution, cy = 0.854 keal/(kg deg C) at 10°C and 2 = 0.888 keal/(kg deg C) at 90°C Mean specific heat, Cm = (0.854 + 0.888)/2 = 0.871 keal/(kg deg C)Energy Balances 203 Sulphur trioxide: 803° CPso3 = 0.0045 (3.96 + 34.6 X 10°T — 26.8 x 10°T? + 6.96 x 10° 7%) = 0.018 + 0.156 X 10°T — 0.121 x 10° 7? + 0.031 x 10°7? Nitrogen: *nz"Cpn2 = 0.8191(7.07 — 1,32 X 10°T + 3.31 X 10°T* — 1.26 x 10°T*) = 5.791 — 1.081 X 10°T + 2.711 x 10°T — 1.032 x 10°7% Summing up, 3x Gh = 6.88 + 4.53 X 10° T + 1.764 X 10° T? — 0.818 X 10° 7? T = 25 + 2735 298.15 K = 500 + 273.15 773.15 K ty Using Eq. (5.16) O = 6.88 (T — T;) + 0.453 X 10° (Ty - T?)/2 + 1.764 x 10% (7) — 7/3 - 0.818 x 10° (13 — T,/4 = 3268 + 115.3 + 256.5 — 71.5 = 3568.3 kcal Ans. (b) Use of c?,, data : From Table 5.2. the following c%,, values are interpolated at 500°C. Table 5.4 cy, VALUES : Component (Gm between 25 and 500°C SO; 11.200 O: 7513 SO; 15.831 Ni 7.148 2Xi * Gmi = 0.0709 X 11.2 + 0.1085 X 7.513 + 0.0045 x 15.831 + 0.8191 X 7.148 0.794 + 0.793 + 0.071 + 5.855 7.513 keal/(kg mol. deg K) Q = 3xi° Com (Tr — T) 7.513 (475) = 3568.7 kcal Ans.Energy Balances 207 OF 1 0¢ siueisuo> auio1uy 0z ss6e $76.62 isto ADHD — (@pHUo}yo ua Ayow) aueyiaWo1o]yr1q oz S+ 1 st— £6re 9°85 SE60L ID'HO (2puo|yo {AyseW) aueyeWIOsOIYD 07 191 01 96 Yoo! 6716 €ss7'9 OHSS JourxayoraX>, Wz Sol VL 92z s10zt E1Ps'9 HD aueKaqo}<> 07 Z€1 01 z9 LIZ Vier 18169 1o*H°D auazuaqos0fy.) 0% L007 6807 usec 31269 "00 apuioqysesioy udque.) 4 Og 1 S'E ove V69IT 8769 oe aptydinsip uoqie) (4 LL 1 611— 7697 s's6zl 36996 09 aptxoip woqre) 0z ZEZ 1 841 ror oebor Lora OD, soydure>) 0 401 1 Ze £891 oustt e1oze OHS ((oueing-z) foyooqe (Aing-~vas 0z 971 01 68 vel csort Lege L o"'HD (joueing-1) loyooqe [sing-u Ic L+. S-98— LWT 996 s0169 HTD (auedosd}91— 097 S6zel TRS L NOH apiueXs uadorpAy 0z 0 SI o'sez oar OUR L "HEN aureeapaH z 76 01 S7— Trew L891 z0L89 "HID auRKay-u > 0 709% 1 €8I 187 1901 ocor9 ‘oH 10129415 oz lor on see £00 76691 g18s'L ‘oD Dror onto 0c 9 S'601- tye 97046 8S6I'L O'HD apdyapy runt 0z T+ 0 S6r— FLET S'sor p8Cr'L ond apixo aua}cyng Z 96 01 6 vez S"P801 12569 S°HD (lompouempa) ueideosowAyng 4 002 91 05 E07 6807 060° O*H!D 109418 auaycung oc €01- 01 0S 1— SST oles 18929 Iz 16- 01 ¢S1— osse orsas 9LPL'9 "HD (auaye) auaysyng oz $71 01 95— o8ez Oy 9869 DH apuorys 1Su2F 1Z S91 01 97 Tet ebel zLS69 OHS auszusqiery “ 1L1 01 $°59 veut “Lest s9sre ON‘HED SUTUE|OUEGTZ (OSe=Y 4 S09 S61 vote 6t6sI crs o"H'D (oweyie) jogo eS 07 €l- 0 LEI 6-957 s'¢99 8789 z SL- © fhI- $967 L'£99 spes'9 *HD oz St 8L— Otz £688 o9L6'9 O*HD v4 L+ 1S 1C— Lit 7096 1780L NH a 07+ 01 19— 8822 19901 £0269 o"'H'D v4 509 9 SIE Vert ress 9108's w [pz 01 ¥61 well 6Lzez RETR D. ‘fuel 5 @ ¥ wne04 pu ainyessditi2], ae Teoms2a) punodwo3 (po) os ametEnergy Balances 209 itd 1% 1 Iz w itd 1 z 1 07 or Iz 0z oz 07 07 Iz oz Iz 1% Oz oz oz oz Iz Ost 9) OOT 66.91.06 68.01 08 6£ 91 0L 69 9109 65 O10 6b 01 0b 6€ OV 0E 6c 10 S£+ 01 0R— SIITOS SE SOCIO Stl 0106 gs1 0129 781 01 LOL Le— 01 LO1- STe— OZ 68 ZS SPOl 09 Zp— 01 LOI SS7- 01 ¢'801— S'LS+ 01 OS— ELI 99 817 SOIZ % PET RZ 01 bbl S78 OS IPT 081 93 08 Ost 91 S98 627 697 Ble Oe vO Lard Tpez E9E7 VRE Slee Loz sole osiz OSIz OsLt TLee Ove S61 S861 Lae Ole weer L997 8107 £061 7861 8'p0e 6107 6o¢or v9sor 65991 68291 7's691 psidt ¥,6EL1 L941 16L1 6556 Orel Svel ¥ Losi SELEL POISE og. 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