Chapter 14 AMINES Lt, L » INTRODUCTION 2 | ___ and ______. both containing « secondary amine group, are used to increase Heed pressure. 2 _______. a aynthele amino compound is used as an anaesthetic in dentistry 8. Draw allomine ‘6 Common name of NHa-(CHale- HH - 5. -Toluidine structure - NCH), 6 IUPAC name of e PREPARATION OF AMINES T Nitro compeunde are reduced fo amines by pasting hydragen gas in the presence of Finely duided nickel palladiurs or platinum T/F No, NH, ‘o 6 je ? SnsHCl ne or Fev (0. Reduction of nitro compounds with iron scrap and hydrochloric acid is preferred T/F A. The renin of elbore ahehement ix = [2 Electrolytic reduction of ndrebenzene im strongly acitic solution yield ~ (NEET) 18 Electrolytic reduction of ritrobenzere in weakly acide soluhon yall - (NEET) |b, Ammanalysis is carried out in a sealed fube af 313K. T/F UEE 2021) |S, The order of reactivity of halides with amines i RCI > RBr > RI. T/F 16, RN —» R-CHp-NHp. Reagents used in ths eeaction are - (NEET) IT R-CONHp —> R-CHp-NHp Reagents used in this reaction are - 18 Phibalimide structure - 19 Aromatic amines can be synthesised by a apie TE NEED aE en, oC P= os ae = OF; op Naot, 5AMINES 193 2 /2°/3° amines ore prepored by Gabriel phtholmide synthesis, 22. I°/2°/3° amines are prepared by Hoffmann bromamide degradation 23 Reagent in Hoffmann bromamide degredaton are - (NEET) UEE) 2h, Write Hoffmann bromamide degradation reaction 25. The product and reactant contains equal no, of carbons in Hoffmann bromamide degradation (NEEN) 26. Retention/inversion occur in Hoffmann bromamide degradation, © PHYSICAL PROPERTIES 211 Primary amines with. umber of carbon or less are gaseous, 28 Lower alphatic amines are soluble in water because - 24. The order of beding point in I, 2°, 3° isomeric amines is - 30, Amines have higher baling point than alcohol uith almost the same molecular mass. 1/F © CHEMICAL REACTIONS 31 Amine selfs are soluble in weter but insoluble in organic solvents, T/E 32. pkb of Ethanamine is larger than that of Benzenamine. T/F (NEET) 33. The basic strength on any aky/ amine depends upon - (3) 3b, Basic strength order of °, 2°, 3° amine in gaseous phave is - 35. Basic strength order of °. 2°, 3° ethyl amine in aqueous solution ~ 36. Basie strength order of (223? methyl amine in aqueous solution - (NEET) (JEE) H | 3) Gn: + cH—c—c1 BE ' I CH, ° 38. The above reaction occur in the presence of base like _. 34 CH,—-N—H + a a u ° ° 40. CH3NHy + CgttsCOC] > whose function is ~ 4 RON, + cHeI,+ 3KoH He (NEET) UEE) 42 The above reaction is called _____ and used as a test for ______ (NEED) 43. Corbylamine test can only be given by |° amines. T/F (NET) 4& RON, + HNO, NSNQ+HCL 4 H®, g Tell 2B (NEET 2022) 4S. The above reaction ie uted for the qualitatve/ quantitative estimation of amino acids and prateins 46, Structure and name of Hinsber's reagent is - 41 Hinsberg's reagent cannot react with I°/2°/3° amine. (NEET)194 CHEMHACK q us Cs =Cl + H-N-C,H,—> rey 464. The above pode i soluble/insolsbe in aal: (NEET) oO} -cl + H- NOCH —> SI The above ee is sohbet in alkali ae was earlier used to differentiate between |°. 2°. 3° amine. (NEET) 53, Nowadays, benzenesulfeny! chloride is replaced by ~~ for differentiating between |®, 2°, 3° amine. NH, SY) spe, Basin, 55. The colour of precipitate Formed in above reaction is - 56. To obtain mono-substituled aniline, activating effect of -NHz group is controled by - ° i 51 Yt H=N=C—CH, NK, yeep A Be é oH,COOR 8 = B 5B. What is the funclon of pyre and CH3COOH inthe above reachon ? " 54. Arnon on is ortho/meta directing (NEED NH, 60, O ino, 1180,, 28a {he major products formed are ~ NEE) NH, NH, a ¢ (RCO, HNO HS, 288K NO, 62. Suharto acid structure - 83 O > #88N73K ty weeks, Gl Aniline doesn't undergo friedel-crafts alkylation and acylation T/F 65. The reason of above statement is -AMINES 195 © DIAZONIUM SALT 66. Write the reaction of preparation of benzenediazonium salt with all the reagent used and temp specified (NEET 2022) (JEE) 61 In situ preparation of ______ occur in above reaction 68. Benzenedlazanium chloride is readily soluble in water. T/F 64. Benzenediazonium fluoroborate ic water insoluble and unstable af room temperature T/F TO. In sondmeyer reochon reagents weed ore - (JE) Tl Write the Gatterman reactions - TA. The yield in Gatterman reactions ie more than Sandmeyer reactions. T/F 7B Arg ‘CF + Ard, using ~ Te, Artz *CP > AF, wsing - (NEED CJEE) 15. Arta ‘Gl — benzene. using - (2) (NEET) 6. Ari "Ch > ArOH, using - (NEET 2022) No, Na . n 5 + HBF, ——» 7? ——+» + N, + NaBF, 8 Cpa ¥ we pron im, (NEED 14 Colour of praduct in above reaction - aa (prin + {en (NEED UEE) 8 Colour of preduct in above reaction -