Moin Gjemp “clonnts concelis of polymerisation - 9a Polyrnesti action Z Aniving forces ane G) Complettons of its octet M0 smicimam rotor e- sheis/ inten elehooie epulsion 26H, — Boy _ es ‘ Brddge bonding ee Wo Yaa ay nd Spe ney 0 BH, molectes we Na ; yao 4 ei be formeel the Bole in the ~_ W Bridge bonding ton ob bridge beoz i a (aes CD Pre P i °) Ci) diamagnetic Coupliog 97 Lewis Concept _— L exe 7 F dehecient Hene the cliuing forces jo ocho fompehon. oT Eze] ore ? & precine ~> > Valent 29 hypere vatont- So teemove She Jeb Genay: & Aehiceat conju : | ee ee Opyb ' } By in By nature By both 4. Buy (To a babil G4 /e Lit fem igh Yai ce ee , F : badge bonding sore Backbonding ot = PES/P chy € io more Ave [der Brabitived) t So, H wil algo aeeeprBoraxine- py- PT Sulpharine = pr- PT bax bon cling Fe | 0 T-baen bonding & EN te Ahenakice af F io oh ene the cto f ype. fase cana @9t donate & to B. and F han Lorepaie Le (8) gids by tide & terry 4 fom B. Cord? Kons 2 @) Compounds mut be polan inmahtre. CB) Faken elechovic reekt” Zhould prevent Back Bonding ; (Inka molenstox Juin auid-bare toleractin) Note Becut hendling +au2e» place ©” that compound which ane Odetfrcient by porn on by natin. Ex- BE. ty ar Bo Mw tl es IG J FPR — votont Ovbital. LD one atom shoutd have Done Patee Ane Other atom Vacant. (9 Bom Shout have 4 vatont orbital, one belong be Dad peniod % thy aqjet shout Cp-ordinalr bonds be thing « T= Co-ovdli natr bond (Dative bond) Ue co-ordinate bond (N- bate bondigy ene Hene pata} bonding ai plow. C HNO BY, BFy + f° ° 1 aon — Bry fast Sp e sp? after boncling M44 FO x ox theoe in Sp2. Co from Md vacant Obital . . baidge) & cotm. Sxtenlie Teboodings pre ef 3 po ~ © basic conape © Pr-Par poncting 4 eye = © GB Pad bonding® 6 We KNW, Clocon the go chistenee tofuo -p100 Moleutey ap Aexe Ancreany ood on wellan the Tnken Joni also tncwand. $50 the een oh Overlapping A tom. © Te Didante in more, O T ig When, the atom and the meluké ane mean fo Lath o4 : eo a oventappeng, tntreang. Noles Pon p group clement ‘he (bax bonding 10 sigaibeant ubh ond peniod . a bone) StRength “a t _ Size C4) 20 Cane of ab block elements : hen then the @ othent OH we go dai00 the greoups the die the ectom Shout be dr HP Ad Hey shoutd be filed 4D Pingt. be Chad) a Zeldaahive Increard 4 She Should be decrearce| L 1 Ad-ad orbitals sho utd be Conhrauted ay, to cath othen . OMe MOE 1640 dt “PT bam bonding.bn ovedlabbing + Ap hone Pair ©) | Andbloc, Ind 1 Lante? in P_orhilay ap oP BPN = PITT Bondiog > Mane” erent of Oveclab big, o G28 4 I Dod blew and blocw i 4 ap 3p [2P4-3Pi bonding Jdows bau bonding Nats Pn Cope of Bd gaup | Q T ‘ elements & 3 GU? 3p obi tals wil donan 3) ih 6 the & J 4 ang G34 oxbHals Shoutd Accept nel gr the & box ad oab 3d amp agp alonate hou be veto “ god gr [saa ma Orden cakat of Onetatting» apn — apm 7 2 apm part-aderEdn Condifone of aun bending ¢ One atomic Onbitals /rhoute be fiwin the and Onbifalo and ad jeent © adic Onbilala should be Yin in QP | 3p, ad. wohen we tole about xq Peniod ow DH BP—donate ov ater both ap. Buk Co 3p > clonate aeeept ad., it clonate 3 Panel aauph aol. Example - © Bry E9- Cn0 Done Pale: hasvacany orbitals) é > Shell ® Pe ~ den- an bb coun B have Subshel VaLaot onbliat ita o} Shell = 921/2)3 Be,- Lary. Spy Aaa Abel - rae . Orvbitedh = Pa Pay Pe @ BBY, x © aw x FQ) ney © Ah (peroa both bane ad periods) - — o. en &- ® wey x a © Ni fo mone © than ef. © meg, x (no Lip? X no bb deox » borp ane mot dud feral @ cy x polan . ‘% Ga, Once), x -@& etly > on & Nh ‘ - ® 2X (Nd vacant Orbital) (® Ot X (na vecant ora CPE x eno vacant wital4) : s ®) N (gi 5), (apm sai bs&ae oS Ro Po oO {a Ww & es v © 20,59 80 bd w\> I 2 Se e ey ; 8 Cig “CH “F 0 &-s -at- 2 Ne CR -uy-F 9 12 Cy tHe Applications by Back § Back B, © Bond Owdere: nag Peek toreling. Generates: pan bal louble ey poco f ee by v an” | 2, a Ga Cracant onbitay?CW Bond Length : ; Bond oven a! Bond Lanyth . lb.0 « Bog | B BE Ys BR 4 4 BB No. B.8 postal = bond — Plu Single bond Co) Gheone tical 6.1 = Obsereed BL =>, NO bat bending Sheorebcal BL Obscene BL =e, Bawx boncing - On nohich of tbe following Caney obs. BL of theo BL. DNR X (no vatoat) ti) Nel, x ii) Of, x ; pet eM) Othe Poth WY OCEHS), x S. Bond Length and Bo Sh BOT -OxYgen bond in Compare , e Hy B05 418 CoW,] move 8:0 (% 9 % Bd) Wop, Tacony)Shape Hy bitin Se Boo tg: a8 Side atom L ~ contrat ato Conkralato ole) y ; Side atom. = x Yk | 9 PQ Ni “yn 2Pa- 34, Fe F ae _ otk | Sis Sp? able . PSS sp SiMy No change op ie ope bs ‘hs Che ash r) n Ceiny) oa open bb ysn indebs | war) a 2k Othe yd beg the 2870 ap? ater 6B gee Chen ‘e!) Boe oO tk Cts, Nas : i x" ere ray Peay No BB. Sop O ia AP? alwoup- o“compare hape » hybad, bond angle it) os) > © Caits)y, eC NeC aS. & gis— NOC: °P Os wer Oty A OOS, 2p3_— p 5¢3 > ep2 ve) moh ten morte 8 Ch Cineveenet to oe) Hear ¢ chav diunos ai) Hy 2s rc x. c (wg SNE Sp? Cno-b-b) bent- w He se Co _- = NH] ? ap —Lineaa RIX, . NE), So NphsCompanion A Lewis ihe Sheng: of Br [vars | T 7g ae ne br ep BB No.BB Aas deficient ano oleffuint vill attawt bewinhone more eedaly , 0,94 ina quod Lavin aridre on baut beading Ducts aud ch cleereour, BB eel Leusin ausdily @. _ ' BE < 8th ¢ apy, BBR ow Le No Crore audit) 2Rap apap B& BCU ), 5 Blom), > Blow 7 Bp xX i - - “pe 2p-ap pop | Ot “& denuily moxe in Elly) So m0% donald o- yf S. Lewis Basic Ahenath © >) dort @ | at oa cu) Son uy,\ \ PB Teois anidity Uawk baathy 6. Addust foremakion + Adcleet Poremation, > Belloc L-+ Belen La. & © Oley, +05 OF denay, 5 BF, (Peox they both deo B-8) GD) OC, re Coto “tay lowe form 8°), (wy 0 (sims), 4 Bel, Shobslty af Coegene Inleneciy ie q Wo. bb: € 9, Compare the lability ef ‘ an apap ‘i : Ca oe c ° WO cB > & oy uy ana z wie @ of Lede PO) me x ® ® \ @F c Ww tbr S ah oH Bor > Ch wr oP (os So S v) Oy, - ¢ we ce Crh) @ 2 | 5 Z 4 ~ 8 -oy"F Gy He OO > ae . ? Teh eb. Se @ aye ec (ert chigt ay -F ei Ub w So ? wsitl dicpetrroe) & g ow v a (mone Eve destebitie + Pa Pp RD chan) c 8 eto Atahiline tore (-v2 choy Cao officicoh Ba) A ehoye)”@ ff Uy Re Q @ & . @ 6 F a os BB ve os Ap-ap ap- ap re @ @ 0 8. Acidity of halons Compare the auidic Steneyf ofp CHE, cH Cher, % cf COR or Va * e a ‘Har Cor S Gay eed on Bronstes) Coneepl ie Aid ut Fu BaF tau, OV c—U \ o =Spm enaultiplicly stl. ee canna + Es. © Hero Cqaipler gutted rene ee gical Ate) a | (singlet gourd eso at ps Mote) asite | (Mingld exalted 23 MV Gs ye, ‘fats) UF the entesgit) to egual fo Thaanheld energy tren the Spin aill be Aarne in fr ercrited Atos -1f the eneegy ythen +h T& then it will Charge # Apia - Hear thene 3 fete ane paxtible bak Tplar gourd] Mats io nor pagible beox Hevolebs He paculi”s entelenion pondpee . Tesplet Singer QP ® O Grenerialty Triplet Stab in ¢ enw Babe theo Ringler Mot: : ZN . LY \ with paining He Enten elahanic aepl? it destabiler He Sytem, go, Praplar cond (4 moe lable. Hene fone parr bate donate by a ‘ne varant Orbital and partial inerack Inereaun the AMobstity inca. 1B bb in fostible then Singlet fo Mable- 1B a Compound kp wonder Ge bob then HA Mayud Mats 10 Mable. 2 # lap Ts AMI eh CU, . a. ; B) FO —> PCy 8 BA apap 2p- ad. a>T Cau te bb) ed, more stab @ F) Pel) Choth hose vacant onh'sa) Bo but cinne ¢ 19 alteads ¢? Bape 4h eo tll fame, as pap oe 3) ap-ae (Ch jo more Hable) ; Ev) InOrganic Bensere a Bor axéne ( Patah) fomba® of Benzene ard Bosaxine . & Both haw same physical pooperbo and aluy! danivatus but beth bp Hey hase Aifferent Chernicerd Prborbo. Hore 2 cE les ce" MP 271 & Ss wo NWen Gera Benz) a \ a ene N haue 3p? hy, Bb 4 .07 ~y | Heece the lire’ 10 Brom A N & B mot Pom pte n Clocalirabien 4 &). H (Bortaxine) In BeN if fo the pase ging bond to Point ob Aiilaity Coens (Both ome sp : / Plano C ®D (8) Beth ane I4o- saetehweal > Wbo-eletomrc . B=N - C-€ wy) Poth ane Coloaslen hig. at RT (Roorn Tel) Potot of dlippsimi lavdy « “ge BO Casctic detoculs” a tp. C Benzens) ( bad NWR Fuk In cow af Boreaine Seg Olea laren) Locatizabion & Nédabiltel , a . w Cars @ | Benzene Ahete io pane qbod CEE Cmax avomabe #9 nodunes bed _i9 bowaaing thent iy parWal te bona (aromatahy $9 letraBl naation Rearhon Benzene do not gire 044” peathon « But boraxin fren add red, (Jie No wea? Boraaie acl rea? M t Lees B Ny Hos hon Nw | 6 | eI V0 oN in aio" ay OP nae ywo & ae U 4 FT cwean or TT inttrashon) " 4 Herte, N will not be Peletfierent So, @ packal +ve Chore develope on P and a parbatevt Chorje davelepe On Ny Soy In ved EL wlll combine wlth B and a wr 1? wil combine with N. wy Q) Aubshhaion Reckion : Sd bowréne Aubs tau in & Meps © pBmany step Cadd) ® Llimincdson dlep Sn benzene. Labs" tau plaw indy ep H ve ny PNA ny NN a —— NF . \ | . . WB aH my FMD Nwill Combine 7 Nee with H Cox both cantain® 3: Bx) ew w fone pase a and N etiminakr 8Y and Palit uth H and B th laban ab Wreienk fo i wid our bond with H. Sine Horo at“nA ake - ‘. Cn Peene clonatfon : } NS pace © bord, Bek In cone eh bewenice theat inne AW ; paste interaetion go in That come H will haus pasdal 67 2 Char, and B calll hou Cea )enorye Freepaation 4 y Beh, + Ni ——> Ch BGNg Se J Na Buy Rar, . ee) ; aso- Y ee Bot, +Nth mace Banat, “ Py i 2% -(RKner 4 Ch —9 Els Banh Fy, > Pa Byhaly aluy) diaivabte,, A. CipHy + Nigel —> Bg NsNe +Lic, Q. Between benzene and Bowading Which io mone a) Kinebrcatly more ag » ‘Therroerecdyna oui cally foe OOK Romaine in winekeally wane mone reactive — Sfable- us fo polarity a] bourne. Cex benzene har zero cLipole moment. CN”) b) Borwrire tn alo thermodynamic lyramically move Mahle thay p enAEL dur by polar. Fant, defied’ on — Kinebe dem (KXT.) oe et “ea 2 most orlen depends on —9 thermedynantc Padew non ghepennen AG OH an ede. cow Gheamodynamie om LN Ausave Cenc) Bat one’ = fog WAH te) dog ey = 78 Bae. _ eh er Ope beg T (ave * ; OPT. oni de® ® ep = or an be 8 Cans ciyt) | ef, Ans ve _ Th oe deg bt ve) Cel only Ror 144 over. WY hes = Cel Coz depend on hog kslopy - E, a Pr ago, whey! Ea = _Kinadc Atabilily, Js Ohenedyoamic Ability 7 & , ONT ineneur Ths Prarkon daunere Go, KO incre [ret] Shere Ay sane (£4) fey hyp hog a ay 303 FT T thom Jee BnBerzene > Boaxine > Bovaxine (is 950; ‘oan Sy) Ce Bs 4 ‘ faxbad \ y ewes) hord (bs) Jat i, . ¢| oct Cplaner) ! j Planar) doluatta® yO Ne “ a Beatin GE 2 ayper Q i i OP > Aacatiad © P P (laren gu have equal : Ee more Mindy. bob frond Length: efassest- Apn~apn [ie Fa Q- Comblet: the Frtlowang reeastido ZLipity 2 NHy et —> Uick + Hy + NHg—> Ally. + J Addu ute ang — tly ef Napiay 1 NHyer —>Nactt ty eK nog ar OE ae 7 i u7 Jo y “ i - Bry +H Bridge - Bonding : a \S Bet + ng Sng Roding tee bad: Adcuut - J, Boro Contral . S “9 ce “oom SP? 68 ONC at BP auts/| oeGar Bh —— BME : RJ Arce 15D UT /m9) Imes? 7 : to highly census trwords alt Zoteot of dimes? 79 hishs Ryo, to hs! Ny pore She corrpound which donot uncer ga bacu bonotirg they only forum brutdge boncling IP the side acto contain Lone pala it witl forum he 30-48” and IF the Side atom ctonot Contain Lp ik eit! form Sc-@” Bue Me Big can coun oped its Byte with Rg. SUE aN) Undker Go Aieanh® bub not 4 sp form acdaedt- | Oo Ot can't Fane a Ram H- 60/14 ewill oli meving nw ; woth anotiw Bits \AROQ nA ON, aa Hers the H Mane bad with borh B. tn angtiy AlCl, to tate part in badge bora]. OnAichs, The et peomeutConcliBons fon _bnidge bonding - © Ghene will be md bast boncting: WD Abscente of Steaic cnouting form bob has dee tte kph a if ch ibs orehP incveuner us Gi) pak fo senic ¢mutn. 2 PK AM the Allumintum Halide denivahe alo not form b arte bonding four fm bridge bond and altho Bromine halids denivete form bob but not bridge bondg On cone ef BCL Vt can BO EES Sing Badge bontin + Bes e ' * X BH, — 30-22 a BF: © cy ea ar x 3. Bh a ae x 4. BBG x bey « . ° 5. atts x JAAtHG oe Be-ge Alot, eee _ e 6. As x > AVC ve 8C-4e Plot 4. Mer, x x Ve 3e-g8 AY Om @® g. ba Bry x . Vy Beye’ 498% oe, 9. AL Cow), x x ~~ 3¢-8€°' Ply) Jus. Us), x oa vac aeBa He (Berane) 2 pana bond BO! Ny aS DES. ap? PS Pe ~> 3e-a& C bridging bend) . 3 Momonfanily Compl 4 octal: 3 No- of 3-98 = g 4. Ctsminal bond) —no< af ac-gee Erdent ob over laping io Api g-cp? Overlappirg - (WD form nanone bond GAN Ga) tno. 90 a aoens 19 plane=¢. ortrall ib te non-flanan nolente. B.Bafam 3~Nuskes- 92-5 g-wutun hodd Ahongly 2 - 98 held tun aee3 a rude rors ly TA him 3 Aro ae Boy B® han mone strength 78 -[Gp minimize tue rting Asad Tt beorn, [oor re] Tonger_and Sreongee |Methylation h 1 Pytt, WG5—3_— Ng "NA 47 neh a. Ratt, +E) —sy ON ng 78 (eR _. NW’ aint uy” Na Meo} ent 3 Bate 4+ fae Ba HC), : 4uge — 4s Batt, + gel Pg gC), oar) Satgee —5] Patty Ho), SD 6 Cry By Hy HED, G Limiting rteorgent note Ci Can Atplour Upto 4 H cuforo hich epee, prcorent Co tenminet Gana) ut i cant creflaue & bridging H Pah Coe X as{us), Xx Bx, PE By Xe S92, pla), will aot Atmenin O-Dothe Sin. of dit ee ° oh diwerr of meth) derivative Of reespuehue B Compoud q MPF Bottytyy and Caleutetr tte No. + ac 2¢ " Orel +, Brg Ory), ut a eNN / a “16 a 79 Pn en, =I ac-2e 7 4 Ye Borde oo NaN ZNreoof for, de ficies fin gin: Hy ane of & pew Ay tonts'Cof W@W) Onugyonchy' to. he etearage % As at! anniek Nie A gree al ( : Vartgmmnabsced poo? ®& Syrmetnicod @) Un Symmmmedeu cay Ba Hg2384 Tome tle 5 Pg tg Pty) 4 (Bry) i Q Liganal alo HY | oF Hene one Hts will mate _ By 'y) ; ery) looad) ysith One L- Bage— Lb BHA—t Note @ Ligonds Buy Syne C02 Shong tr-anaphr: + Car Ran, C7 CLO, MES) THE wear dlenorc i fe @ Ligando—> snast—9 Unigmnte + ex: Ni on a: e- Shorg donee 708, ENMy | R-Nty,. 2 ©. yt, + PN —y (BUINIG),) + BHy a iS, 83 Not, 3mm alpan? > ?%- O. Att ace "> algun, ea) One 0. HH, + 20% ——y Crh Or) + Hy Q. Compoe the enlort of Aémentsation for Ay BH EM), BK), Bits > BH CH), > BCs), l J t Pate ay yl, — Sixe +h Budtys qreubiocruau. As the size of Suhshhunt ator inenuaw, erttent of climeninalion derrsoun. Uh aay Ug Si On 7 Sno S cy e > BH-B= 3e-2€ > spr s—sp? —Pormation } Banana hond, > 16 Qe-ae, Bu Hye corms) . ' >| oo SZ al x, Be ZN fs Wa Sy ——p —W a4 | (v nsymmetni ca) 4dhenw ane 9c. 2¢° —y NO of 3c-90%=4 No of Be ge: F at-2&= 6 CBM) atads 1 C8) i ar efymmebaicad Claawaye ? On Aymmrelaiced Cheauye 2 Vigard with Came Lattadht with BR, and athen adit Asti. Byte Bik + Batty. Uniywoctnical Claawetes B tteng both egg aeth with 4 BHO. and o ‘Ugand upith Bs ¥y5 - Bulls —> BYy tests) : Q By 2 aNNes amnen . (yyg WrtgU) WHI OS: Bythy NM, —3 At B Pind 09 eA Ligand © &. Buty + aNme, —> 3.0 <— Neg] + B Red B © Baldenkty ) Beg A NMe, wed— UDsgmmm But ° - B.Buthe +9e% —> (BLOW) + HF [posiabi ‘ Comple wation U/s Dimenisabion : fe _Complenaton : yey lau eb Butliot &Nme —> dye <—nme,) + (Ast <—novg) ln, ni hone 1 Lip ah eg reepl® clo not foun plow it farouna Com ples. &y imeniAabion ¢ Bub tn cou bh [bgroup CUmnt Siu ors 34 contain & Le eb e @, Baths here | Lip mepel other So reapel® teu plas. go, Bly wit Aimenine fe Foam Byte. Samm 6. Bulho +40 ———> Hy Bys—0 tty t Bolg, “8 Bay Ho #8 mney —> fy By <— $y + Bote, Orden of complex” with Arg. PP, < COX eho 30-ge? = WN 7 > Partral compl? oh oto V we 7 2 3-28 —. 4 2¢-2e%.> Poem af Banana bord. Aver), 0) Dimer fonmation Faun place » oA a \y ae oy a PN Ch Gi) 9-28 . GI pankad Compt of octals © Gy) No-eh 3-327 U) No.of ac-9e=99, ty Eactent af Overlapping = 40% sp? p> W) Nok a banana bond - Note “Suey anana pond hawe ace ae? bab every Sc-a& ase not banana bond. ALY, 4 a ue a, MZ! Pt wos ot oN > 3¢-4e® = > falby compli sh oclats > Sp sp? op? C no- banana hora) & — > gc- ae ( zens)0 Kio. of ac af =% On Alylct), atl bond ane dimilan (te a-9&) Concept of co-ordination m0 in badge bencling ; ; with incaras Lib Mat rma? (MC), @ Y N & cx <> monomen, > Dimer. Polyrnens® NN he > alencnos3 9 Nosh Jw SE solid a | . => OP 5p? Gentes, C) then ang raonomen hate! 2P? hybrsd® i+ fore alimen (PA but any monomen heweing gp hybrid” it Brim Sp? Cpolymeninaton) , + Belly leew}, a!) Be ta)y b s Polymen ynonomen. dimen Rare g.nor a S.Noe 3 Ap cP Ape A M4 x oN es SION I™ Be Pook 2. Be os POT Ie Tendeniy te forum baidgen + 2 FR. do? sf 5 PhoR: 6. AIled,(Pimg) ing et : Nt SiS 30-4 9 O. AL A, J me \ . w Pe Ce ae-ae- 04 BAL Hen), , @- HL CHHE)C PS fe CHa) Ce) ae “ine uw Sas tw NO Ne mi Ss me