Brock University Visual Arts Department Darkroom Safety and Orientation Guide Amy Friend Photograhy Instructor rnold Visual Arts Department Facilities Technician Visual Arts Department Marilyn |. Walker School of the Fine & Performing Arts Brock UniversityCONTACTS: Visual Arts Staff Arnold McBay Visual Arts Department Facilities Technician Extension 5046 amcbay@brocku.ca Amy Friend Photography Instructor Extension 5305 afriond@brocku.ca Environmental Health & Safety Dan Pozzobon Environment Health & Safety Officer Extension 5994 dpozzobon@brocku.ca CONTENTS 1) Introduction 2) General Safety Rules 3) Safety Equipment 4) MSDS Sheets & Chemical Storage 5) Chemical Disposal 6) Emergency Chemical Spill Procedures 7) Darkroom Closing Procedures 8) Additional Tips For Handling Chemicals Appendix MSDS sheets for darkroom chemicals1) Introduction: This guide is designed to assist you in working safely and efficiently in the darkroom. All aspects of expected safe conduct, how to store and handle chemicals, and what to do in the event of a chemical spill are outlined here. All instructors and students working in the Brock University Visual Arts Department Darkroom are required to read this document in its entirety, and take part in a training/orientation session lead by the instructor. The conclusion of your training/orientation will be filling out an on-line quiz that ‘covers the information herein, failure to pass this quiz with a mark of 80% or higher will result in your having to do a second safety session. Please visit the Visa website Darkroom page to complete the quiz. In order to prevent students from sharing quiz answers student quiz results will only be reported to student as to whether a student passed or not. Upon completion of the safety training/orientation session and quiz students must sign a training completion form indicating that they have completed the safety session. If you have any questions regarding any of the information covered in this guide, please contact the Visual Arts Department Facility Technician, or the Photography Instructor. Brock University Health & Safety regulations require that anyone who comes into contact with potentially hazardous substances must receive specific training. This training will cover the following: + How to mix all darkroom chemicals from concentrates. + Howto label all containers, and how to pour waste chemicals into the waste chemical containers. + Basic familiarity with the WHMIS system, and the dangers of the chemistry in use in the darkroom. + What to do in the event of a spill 2) General Safety Rules: + Only 12 students are allowed to work in the darkroom at any given time. + Only students who have completed darkroom training are permitted to work in the darkroom. + Only students who have completed the safety training session and on-line quiz are allowed to work in the darkroom, + Students are required to familiarize themselves with the MSDS sheets of any chemical they work with for the first time. These sheets are available in a binder on the darkroom walll. + Keep the work area clean and uncluttered to prevent tripping hazards. + Wet and dry areas should be clearly separated + Only store chemicals in their appropriate storage cupboard or shelf. + Never eat, drink or smoke in the darkroom. + Appropriate safety equipment is provided and must be worn at alll times: gloves, goggles and aprons. + Always wash hands with soap and warm water after working with chemicals. + Know how to use the spill kit and eye wash station (and where they are stored) prior to an actual ‘emergency. + Pregnant women should not be exposed to any powdered photographic chemicals. + Store all chemicals in locations that will minimize the chance of breakage and splashing + Allchemicals must be labeled with the proper MSDS label. + Keep all containers & trays closed or covered if not in use to prevent the release of toxic gases. + Do not wash any chemicals down the sink. + All spent chemicals should be placed into an appropriate waste container, then labeled with the appropriate WHMIS label3) Safety Equipment The following items are available for use in the darkroom: + Fire extinguisher: currently located outside of the darkroom in the hallway beside the GL162 studio door + Eyewash (in each room where smaller amounts of chemicals are used) + Waste containers for each chemical + Safety glasses/goggles for each person in the darkroom + Gloves + Tongs + Darkroom safety guide Eye Protection Alll persons in the darkroom (including visitors) must wear safety glasses/goggles at all times, even when not performing a chemical operation (this is only when others are working with chemistry at the same time). Contact lenses should not be worn in the darkroom because of the possibility of trapping foreign materials against the comea and their difficulty to remove in the case of a splash. Safety goggles, not safety glasses shall be worn whenever chemicals are being poured. Gloves Gloves should be worn at all times when working with chemicals. Confirm there are no cracks or perforations in the gloves before use. Prior to leaving the work area, gloves should be removed to prevent the spread of chemicals and stored in the glove storage receptacle. Clothing Clothing should offer protection from splashes and spills, and should be easily removable in case of accident. Aprons or lab coats are highly recommended. High-heeled, sandals, open-toed shoes or shoes made of woven material should not be worn. Shorts and miniskirts are also not advised. 4) Material Safety Data Sheets (MSDS) & Chemical Storage The Visual Arts Department is required to have Material Safety Data Sheets (MSDS) available to any individual working with hazardous chemicals. Faculty, staff and students have both a need and a right to know the hazards and identities of the chemicals they are exposed to when working. They Everyone using the darkroom must alsoalso need to know what protective measures are available to prevent adverse effects from occurring. Information that can be found in an MSDS sheet includes: ~ The identity of the chemical substance ~ Physical and chemical characteristics ~ Physical and health hazards ~ Primary routes of entry ~ OSHA Permissible Exposure Limits (PEL’s) ~ Carcinogenic status ~ Precautions for safe handling and use (including personal protective equipment) ~ Spill response ~ Emergency and first aid procedures ~ Date of the MSDS. MSDS sites/resources on the Internet There are many sites on the internet that list darkroom related MSDS. Below is the manufacturers web site supplying the Brock darkroom:Please visit the Visa Darkroom FAQ page on the Visual Arts Department website to consult directly with the MSDS sheets with each chemical you will be working with. Also, all MSDS sheets for chemistry used in the darkroom are available for reference in the MSDS binder on the darkroom wall. http //www.brocku.ca/humanities/departments-and-centres/visual-arts/future-students/film- ‘photography-darkroom. Students may also add a Brock H&S MSDS resource page to their Brock Portal page by clicking on the “Add More” option in the upper right of the main page and selecting MSDS online database: The Health & Safety Department page of Brock University: http://brocku.ca/hr-ehs/environment-health-safety/health-safety The Province of Ontario WHMIS resource page: http www. labour.gov.on.ca/english/hs/pubs/whmis/index.php. You are responsible for reviewing and being familiar with the MSDS information for the following chemistry: Film Developer Print Developer Fixer Fixer Remover Stop Bath Wetting Agent The full MSDS information sheet for each of these chemicals is listed in the Appendix. Itany new chemistry is added to the darkroom processes in any Visual Arts Department photography course you are required to familiarize yourself with the MSDS sheets of each item. These new sheets will be appended to the MSDS binder in the darkroom and the Visa Darkroom information page on the departmental website, Chemical Storage All chemicals must be stored properly, including proper labeling, proper placement (off the floor) and compatible storage containers. Improperly stored and labeled chemicals can result in the following dangerous conditions: ~ Release of potentially toxic vapors. ~ Degraded containers that allow chemicals to become contaminated. ~ Degraded containers releasing vapors that can affect the integrity of nearby containers. ~ Degraded labels that result in generation of unknowns. All chemicals MUST be correctly labeled. Proper chemical storage includes the following practices:~ Containers must be dated when they arrive ~ Older chemicals are to be used first. 8) Chemical Disposal ‘Asa chemical user, YOU have a legal and moral responsibilty to ensure the proper disposal of any hazardous waste you generate. In addition to potential citations, institutional fines for improper waste disposal can also result in negative media attention and damage to the University’s reputation. When chemicals have been exhausted, the following steps should be followed to dispose of them: ~Place spent chemical into appropriate container. DO NOT MIX CHEMICALS. Seal container. ~ Using a WHMIS hazardous waste label, label the container including the chemical name and the date on the container. ~As soon as the container is full, e-mail or inform the photography instructor. ~The Facilities Technician will be informed that pickup of wasted chemicals is required, and is responsible for affixing a numbered waste tag to the container and forwarding a list of the chemicals to Science Stores when scheduled for pick up. ~ The chemical will be picked up at the darkroom on a scheduled pickup day by a hazardous waste contractor contracted by Science Stores. 6) Emergency Chemical Spill Procedures For MINOR spills that are known to be of limited danger: In the event of a spill involving the release of a type or quantity of chemical that does not pose an immediate risk to health, and does not have the potential to become a major emergency within a short time period: 1. Notify the Visual Arts Dept. Facilities Technician and the photography instructor. x Isolate the area. Close darkroom doors and evacuate the immediate area if necessary. 3. Remove all ignition sources and establish exhaust ventilation if possible, a large box fan is available for this purpose (stored in the anteroom of the darkroom) and should be placed at the entry of the darkroom positioned to vent air out of the darkroom. 4. Choose appropriate personal protective equipment such as gloves, goggles, lab coat etc. Utilizing your spill kit and spill guide confine and contain the spill with absorbent material. Collect the solid material into the dustpan and place into the 5 gallon bucket or other appropriate container. Call the Instructor who will arrange for pick up. In the event of a serious injury in the darkroom the following procedures are to be followed: Clear anyone not assisting the injured person from the room. Report the injury to the instructor, if the instructor is not present contact security at extension 3200. There is a telephone beside the sink in the GL162 studio across from the darkroom access to the area. Remain with the injured individual until help arrives, no seWhen reporting an injury you will be asked for the following information: ~ Where the injury occurred (building and room number) ~ Nature of the injury (SPELL CLEARLY and SLOWLY) ~ Any immediate actions you took ~ A call back number (if available) Spill Kit: This is a yellow bucket which located just inside of the front door of the darkroom ante-room that contains all of the spill cleanup materials. The kit consists of a spill guide, a range of absorbent materials, sealable bags. gloves, gogglesand goggles. This kit is only to be used in the event of a spill. 7) Darkroom Closing Procedures ~ Proper disposal of hazardous materials is required whenever a student leaves the Darkroom ~ You are responsible for leaving the Darkroom clean and ready for use by the next group/student. 8) Additional Tips For Handling Chemicals. ~ ALWAYS discard stop bath solutions contaminated with developer ~ ALWAYS cover all baths when not in use (to prevent release of toxic vapors).r STANDARD FILM DEVELOPER SYSTEMS OF PHOTOGRAPHY MATERIAL SAFETY DATA SHEET L ‘PRODUCT AND COMPANY IDENTIFICATION Prahet Nae ‘Standard BAW Fite Developer Syeinn Sytem of Phatgzapy Ine Ciaalog Number Na 1057 Chaps Koad Chena! Nase Mixture ‘Sette 10285 een Nowe NA soa. n078 Cente 800.288.0800) z ‘COMPOSITION/INFORMATION OW INGREDIENTS umber Dior ‘pom opm lplene sed NE 100 ge? (vara Hyeuinone iwiate amen! Sidhu metab 191 NE = [HAZARDS IDENTIFICATION 'ENERGENCT OVERVIEW Waring! Mains skin aenitistien. Maca mid invitation, eee, ad the verity tac, Harm itewallomed May be sot gh skin. May emu {Wil net hm. nec es snag meds suitable the material that ie baring POTENTIAL HEALTH EFFECTS Pray ROUTES) OF ENTRY gontion: Can emis Bd damage and may be tat the Inhalation eating, ve an ein conta. SYMPTOMS OF EXPOSURE Skin Contact: Alay suse mili station. Maybe aber {traiah incon oo ngetion membranes othe nes Uo respon tat anmay Bye Contac: May case mild istuton ‘dese Pesan aenitizel 0 arm metabimulfte ave at risk REPORTED AS CARCINOGEN ORFOTENTIALCARCINOGEN Cove Applicable Tinternatinal Aga fr Recah an Caner CARO) Appendix: MSDS Sheetsa FIRST AID MEASURES ‘kin contact: Wach afte arene with pene of water and tp if evlabe, i ever itn, Sek medal ltt It inritation develope and pei Inhalation: Remove fam arent fea ai. Seek medial attention irespratoryiritation develops ae Chretbing havin trouble breathing, traaport tomato are ond if cvalale, give supplemental Bye contact: Rinse ee wth water. Remove any cantact lenses, ondcontnne ashing wath plenty of wate a evel rminitee Seek metal attention ifrritation develope and pelt Ingestion: (ive 34 plants of wate, bt BO NOT ndoce vomiting [fuming ocurs give Bul again. Get mica ‘tention to determine whether vomiting o vacation of NOTE TOPHYSICAN ‘ane own, 5 FIRE FIGHTING MEASURES loch Paine nt Meth a0"F em.CO) Fie orexrensve heat may produ hazards decomposition product ‘xrINGUISHING MEDIA ‘maverial that ebanine. SPECIAL FIREFIGHTING INSTRUCTIONS. None known, FRgFIGHTING EQUIPMENT “ [ACCIDENTAL RELEASE MEASURES, Wear appeopriatopeotertive equipment (Sco Section 8) Avi contact with ee, hin and this, orth an package na mits container fr disposal HANDLING AND STORAGE Wear appropriate protective equipment (See Section 8 Ava onact with ees, skin, an lating. Wash thwaghly fer hanins ‘Keepin ail lve container eer in ea, hy veilated aren 2 ‘EXPOSURE CONTROLS/PERSONAL PROTECTION, ENGINEERING CONTROLS {Use epneeringcontrola toed ni ontario ermine exposure lve. Respirator: Incomes wlre high cuxenratios af ‘epee or mist are present or exposure ite are exceeded, ‘rae eespraor that has been lected techrcally quale person fr the spec work eandtione. ye Protection: Wear approved saety glasee owes: Butyl rubber. fd aca ey te inspect tears, pike loves bere ech woe eso sige of wer. (Clothing: Wee angler clothing, Uae ruber one, Other: Rye wash; safety shower, PHYSICAL AND CHEMICAL PROPERTIES Store Liquid Specite Gravis 835 °F is alee ight yellow to rown Vapor Dent (Air) Odor Suis side ‘Vapor Presents) Nelle Melting Pint"? Na pH a7 Bali FoF 2 Water Sebaliy Saute PagetSaliiy in ether Hide NE 30, STABILITY AND REACTIVITY aenernvry Stable under normal use ceuitions Wil dacernpove i aid selutions, berating toe and litting euler dni pe, InconPaTIBLTIES Acc unit tng adios tale rd gabe (60,,CO, and oxides ot lr ConDImoNs To AVOID aviv host, side anata, nL TOXICOLOGICAL FORMATION “The proc is mat on eitant The primaty dem station For Bthstene glyeot score wat 0.08 flowing a chour exuded dra exposure in timated PF 1¢ Design, 1GCFR 1500 For DimethsHformamie: Inhalation Ly m8) 9400 rn? ie Oral LD at) 2800 mp Oral Dy nb) 42 mat Dermal LD, (abbid 4720 me ke Lente breathing of wapors by workers hae ‘used liver damage dept. For Diethslene glycol: (ral LD (nt) 12.665 rhs (ral LD us) 29,70 mph Dermal Dy rabbit) 1,800 me ks or Sodium metaborate: ‘ral LD (at) 2:90 mh Auman tly of an ocupetienaly exported baste ‘worker paplation showed no adveresreprodhetve ‘asa. Animal atic of sla inorganic borate lmonotrted epreductive effete in male Inhalation LC ab 103576 mi (ral LD ab 4.700 mars (ral Ls owe 5,500 mk Dera EDs bb): 3,680 al he ain and weaken, wll ar drunken, ‘kanes, stor, convulsions on coma, Death ould lle Kidney femegu sony ree Animal ute iene that repeated ingestion can mire formation of ler and kid stones, well kidney dae. For Hydroquinone Oral LD. at 820 mh (ral EDs nome) 205 gh 2 ECOLOGICAL INFORMATION ECOTORICOLOGICALINFORMATION For Diethylone glo! 95 heLC., dathund minnow): “100 mul, Cand Stati hr LCy( water fea; 03-10 me, Cond: eae Sou EC, Photobucerian phwporcum) 228 amg L Micros tet BW Fim Developer For Hydroquinone: 9 Lo nib rot) 0097 mg 6 fr Li. Ueda 1.0.18 mg 1 he Ey ere) Og 20 min HC, Photobotarium phoophaceu): O82 rig Mitotox tet Page sotFor Etislene geo: 26h LC (ainbow tout 41,00 mg, Cand 29°C 6 br LC el 27500-41000 m/l. 98 HF LC le: 27300-1000 96 LC ter es): 46,800 mg. [ENV RONMENTAL MOVEMENT AND PARTITIONING Not known. Onin EC, (Photoacteium phosphor} 620.0 a ‘mal Mizotox tet Be ‘DISPOSAL CONSIDERATIONS RCRA Waste Code: Not regulate. = TRANSPORT INFORMATION ‘Not rgulated by DOT, ICAO, oe EMD. rt REGULATORY INFORMATION (OSHAHAZARD COMMUNICATION STANDARD (28 CFR TSCACHEMICAL SPECIFIC RULES 810.200) itea Ciimardous —Now-Hazaridoue lnvenTorysrarus SS ee All ingresiont thi prot are on the TSCA inventory yrouinene: RQ 100 Ie ‘SARA EXTREMELY HAZARDOUS SUBSTANCES (0CFR.385) yoquinons: TPQ - 00 Ibe. ‘SARA HAZARD CATEGORIES 40 CFR 370) ‘rcate Lomaic Fire = Peemune — _Meactive Nene SARA TOXIC CHEMICALS 40¢FR272) Hodroquinone-<% Dimitytormamie= 58 Bihylene gyal 5 STATE REGULATIONS Florida Hazardous Substance Lie... Dimethytormamide, tetiylene een. ytroquinone, an eum metabieufite Maveacnugta ight To Know List... Dimethformamide, tyene glen hydroquinone, and eed metabiculte Minnesta Hazandowe Substance Litt. 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PRODUCT AND COMPANY IDENTIFICATION Prot Name ‘Quiksilver Print Developer Sprit Sytem of Phaoaropby ne (Catalog Number NA 1057 Chopmiat Hl Raul (Chnial Name Mixture Suse, BL 02857 Cammen Naame NA S00 a7 Prahit Use Photeasle wn develope [EMERGENCY TELEPHONE NUMBER ChemiTt (-80n28-2009) ‘COMPOSITION/INFORMATION ON INGREDIENTS sack = cocemcwae TADS DSTREATON ra ho atin sino eS ee SYMPTOMS OF EXPOSURE hens. Pre-esitng sin disorders, ye problems, or impaired iver and Inhalation: Bevathing vapre or mist may iitatethemuceue Key. Persons sented tain ule ae ate, membrane of the nove hut, eriratory tract, and may couse heedache,ligheeedness, diziness, nd mien REPORTED AS CARCINOGEN OR POTENTIAL CARCINOGEN Loser Applicable BHA Suspect Carcinogen Natinal Tsicoesy Program (NTP) international Agen ir Research on Cancer QARC) Bye Contact: Causes ey ‘uleksiver Pit Developer Page oti FIRST AID MEASURES running er, and soep if vaable, 1 tes Remove ‘contaminated eluding and show, Get immediate medial fatten. Wah elothing nd deccntaninate show btire Tihalation: Remove an ate to tel ae Inet beating, slow airway an stat mouth io mou artical vespisation ce ‘seatbag- mask eopirater Ge immediate medial attention If td, alae sive eugplerestal ype, Ahushing eyes with large amines of running water or at onst Sminute. Mf paeiian ie not available Mua or an ational 1S minuter. Get iamedinte meical attention ngostion: Give 2-1 laees of wate, but DO NOT induce ‘Vaulting vomiting ccs, give Guide agin. Get medial “tention to determine whee ving or weeuation of tamaeh ie ecweary-Do not give anya by mouth to an ‘unconsciou a convuing pean NoTETO PHYSICIAN Rye contact: Immulistely rinte wy with walar Remove ay None own contact lencee. Hold epi pant to ensure nang othe FIRE FIGHTING MEASURES, Flash Pint ond Method > 00°F Moc) Fire excessive heat may palue hazardous decomposition radu Incase offre ube etinguiching media cuitalie fr the satel thai bring Noni known, FrerichiNG coveMeNT ‘As inany fe, wear NIOSH approved, postive preaeure aE ‘ontained breathing apparate ad fal ectective ear [ACCIDENTAL RELEASE MEASURES Went appropriate osetiveeainment re Section 8). Donat set ineve, on ein, eon cothing. Ventlate ara lea or sil, Aber with ity te, ean or earth and package ina ‘tablecontainee er depo WaNDLING Wear appropriate protective eguinment (See Section 8. Do fines, on chin, cen clathing. Wach thorough after handing HANDLING AND STORAGE stoRact Keep in aly ceed cantar, red in aco, dy veniated ore, EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS Use engincering cont to veces contamination 0 permiasbe expomire lve. PERSONAL PROTECTION. Respirator: Incondtions where high onceneatians of spit that haa been selected by technically quiet (ulesiver Pint Developer esto fhe speeitework contin {Glowos bor uty, Neoprene) Clothing: Wee lng-lovelelothing. Uso rubber pean. Uae rubber toot (Other: Bye wash: eafetyebower Page ztPHYSICAL AND CHEMICAL PROPERTIES Stote gid apes Density (Air=1) a6 alee ight brown ‘apo Presure cnn Hi) NA one Mid, eweet, vs sos Mating Point Na Water Soltis Soluble Bailing Paine “P >ai2 Sela the iid NE Specie Gravity © 68°F 1.815 io. ‘STABILITY AND REACTIVITY sencriviy IncompariaNsTiEs Stable under normal use cenutions Will deernposein aid Acidic material, tte osidiner, male and organic CONDITIONS ToAVOID. HAZARDOUS DECOMPOSITION PRODUCTS Eoeuinberiaiie (60.60, and ides of war u. ‘TOXICOLOGICAL INFORMATION ‘Theproduct i corronve to abraded ein in a modi Fortiydroqulnone [BHSACPSC Design, 18 CFR 1500 tet provoke It not (Ora 1D (rat 320 meh corrorivs ta iat in (Oral LD (muro: 25 mh For Sodium slits For ethylene glyco (Ona Ly Mone: 520 make (Ora LD at) 12565 mets (ral LD, (mee 24700 meth ForPotassumcatbonate: Deel LD ebb) 1,800 make (Oral Dat) 1870 mas (Oral LD moure 2/570 mes 2 ECOLOGICAL INFORMATION For Diethylome glyeok ae npsinatinen 96 LC tend inno): =100 my. Con ‘9 LC (iow to) 087 mL ‘9S LO water Mea 0.8.0 mel. Cat State A he BC ser De) 0.09 eh Ife B04 Phtabteris phorphorean 2 0 in EC Phetobteian poephare: 00882 rl Micros tet sme Mito eet RV ROREHENTAL MOVEMENT AND PARTITIONING [ENVIRONMENTAL FATE Net know, Net kno. Be DISPOSAL CONSIDERATIONS RCRA Waste Code: Not regulate. ‘uleksiver Pit Developer Page sotu "TRANSPORT INFORMATION. 5 REGULATORY INFORMATION ‘OSHAMAZARD COMMUNICATION STANDARD (28 CFR 910.200) Litoearioue ——_NontNararde ccenctassurenruno4ocrn 17,303), yruinae; RQ 100 be. SARA EXTREMELY HAZARDOUS SUBSTANCES (40CFR.355) roinane TPG 20 Ibe invenrony staTUS All ingriens of thir oct aren the TSCA inventor ‘SARA HAZARD CATEGORIES 40 CFR 370) Crowe Lonronic Fire “Pressure Reactive Nene ‘SARA TONIC CHEMICALS (49 FR 272) Hipdeoquinane ‘TSCACHEMICALSEECIFIC RULES Nae now, STATEREGULATIONS Florida Hazardous Sutstonce List... Hykoquinone arsorhsetts Right To Krow List Hyonsinane Minnesota Harari Shbstaee List Diethylene yet oad Rhode Island Hazards Substance List ydroqvinene, Diethslene glyco ie “OTHER INFORMATION Heath Prepared by... Sprint Sytems of Photography, Le. Fire 1 Date Prepared: | Mayo, 2000 ABBREVIATIONS (Coli iit ERG - Eergeney Reepunze Guidebook N/A-Notappiable ND -Not determined NE-Not etait NIK- Not known HQ Reporte Quantity TPQ Thresold Panning Quanity ‘uleksiver Pit Developer Replaces Sure 21, 000 Section 1 was updated to rflect results of ivitation say ‘Section 14 was oveed Wo tak scent akin corona tet PagesotsBLOCK STOP BATH SYSTEMS OF PHOTOGRAPHY MATERIAL SAFETY DATA SHEET x Fan STA aa onic earn voce oe passe oe EMERGENCY TELEPHONE NUMBER Chanel (1-800-256-9084) ‘COMPOSITION/INFORMATION ON INGREDIENTS ‘CHEMICAL NAME EXPOSURE CONTROLS Acetic acid 10pm 10 ppm (FLY) - 15 ppm STL Sodium acetate NE NE Water NA wa ‘Seo Section 18 for OSHA Regulatory Status zx HAZARDS IDENTIFICATION EMERGENCY OVERVIEW loo yellow liq with a aniline oor. Incateof fle us fan, ent diide (00), dey nial Warning! Causee eye initation. Beeathing vapors mist nay cote antmtke symp, May be half allowed POTENTIAL HEALTH EFFECTS PRIMARY ROUTES) OF ENTRY Ingestion: Mas’be harm swale Inhalation eating) ye and sin contac. [MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE rmtpToMs oF Ex80SURE Persona ewusitze 10 oeti acid are at ik, Skin Contact: May ease mild akin ritation REPORTEOAS CARCINOGEN OR POTENTIAL CARCINOGEN Bye Contnet: Causes eye itvitation, Lice Applicable TOsHA Su TNavional Txedecy Preeram NTP) Inhalation: May enue epitatry tact insttin, cen ae renee in threat, noe ad repiratary tract. Breathing acetic. ree eos ees eee international Agen or Research on Cancer (ARC) a FIRST AID MEASURES Skin contact Wart afcte areas with plenty of wate, andy contact: Inmet rie vee with water. Remove an soopif avaiable, fir aver minutes Seek metal attention sf contact lenses an enn Hushins eye with runing water feritation develops and perso fora eat minutes, Hold evel past to ensue rinsing of ‘he entire ousfae ofthe eye andi wh water Get Block stop Bathimmediate meta tention, Inhalation: ems fom veto sh at. tne beeatng five artificial wepiraion or ee a basmaek einai. Imediate medical atteaticn. vet isang wouble teeathing transport to meiial care and, avaliable, give nemetl ene Ingestion: Give 04 gasses of wate, but DO NOT inice vaniting Ifvonitingcecure give Bui again. Get mek tention to dctemine whether viting or evacuation of Inhalation - Delays putmanary edema may oer, and patient shoal be maintained under beervtion fr hi empleation, TIRE FIGHTING MEASURES, Flach Pain and Masha 200 7 fll eur) GENERAL HAZARD None know, Inca offre use on, cab did (C03), dry chee SPECIAL FIREFIGHTING INSTRUCTIONS one own, FReFIGHTING EQUIPMENT 4 in ang So, wear NIOSH approved postive smeceure cll ontaine breathing appara ai fl raecive gear "ACCIDENTAL RELEASE MEASURES: Wear appropriate protetive equipment (See Section. Avid contact with we, kin oe clothing. Aberin ity ite, dey ad earth and place intoconainics fe dnp Sal ‘ils maybe fused in amore ith plenty of water z HANDLING AND STORAGE HANDLING Wear appropriate protective equipment xe Section 6. Avot sronace ‘cep ina ight lowed cantine, stared in con é ‘EXPOSURE CONTROLS/PERSONAL PROTECTION ‘ENGINEERING CONTROLS ee egincering contro to rede contamination to permizabe exposure lve. person ir the specific work coins ye Protection: Wear arprovedsakety glasses or soe, Gloves: Neoprene PERSONAL PROTECTION lothing: Wear logleevd thing, Use robber open. Reopirster:Inconthlonerievehigh nventratons of (Oner:Hye way anya pire are pos or expeure Liiteaeeacerded, wea 3 espiatoe that hae been ected by echically quiet PHYSICAL AND CHEMICAL PROPERTIES State gid Vapor Density (A= 1) 08 ater (Geer yellow ‘Vapor Prestoe fn i) ND or Vanilltcetic acid (inegae) pit 40(19cittion) Baling Pant “P 218 ible in ater Bgside Specie Gravity © 25°F u lockStop sath Paget30. ‘STABILITY AND REACTIVITY seacrivry INcOMPATIOLTIES Alkaline materiale and trong ines HAZARDOUS DECOMPOSITION PRODUCTS ne known ane known. n. TOXICOLOGICAL INFORMATION ‘The producti ot wea tant. The primary dasa lnsitaton score wae 0.17 illowing a Hour eluded dra ‘ayorure in amodided FHSA\CPSC Design, 16 CFE 1500. For Acato acta Inblaton LC (nove) 200 pp. Oral LD (ab. $510 ahs Deval LD. bl: 1000 as 2 ECOLOGICAL INFORMATION Fr Aeotie nei Net tow, 96 LC (ahd minnow AS mg Cexitine Stati, BEC ? Sr LCuegl ash) 75 mp HE TCOMAHIAL ATE ‘2th LC (gale): 428 me Nat own, BC, 15, 5 min) Phalobcterium phosphor) AGLI met. Mietox test. Conditions 18°C DEB of water ly 2-47 me = ‘DISPOSAL CONSIDERATIONS TROPA Waste Code: Net regulated a "TRANSPORT INFORMATION DOT Hassed Cle Net regulated ‘This proiut wed not cororve to ste! o urna when texted eeurding to 19 OF 178457 % REGULATORY INFORMATION ‘OSHAHHAZARD COMMUNICATION STANDARD 29 CFR tero200) CHlozanious N (CERCLA/SUPERFUND 40 R 117,302, Acetic ai: repertable quantity - 5000 Te. ‘SARA EXTREMELY HAZARDOUS SUBSTANCES (40FR385) NA ‘SARA WAZARD CATEGORIES (40 CFR 370) Greate Cehronie Fire —Prewure — _Remive None lockStop sath 'SRRA TONIC CHEMICALS (0372) NA wa wenroRy status All ingredients ofthis prac are an the TSCA inventory. Page sotFlavia Hazandone Substance Lit... Aesic aid Maveachuete Right To Know Liet Aes aid Minnnecta HizardoinSubetance Let Aerie acid NNewdeesey Right To Know List... Aedtie acid 16, COTHERINFORMATION NFPARATING PREPARATION INFORMATION Heath Prepare by: Spent Syeteme of Photography, Inc Fire Date Prepared: Js 10,2000 1 AnoRcvATIONS ‘A-Not applicable ND - Nat determined [NIE Not estas Not ko NAERG - Nerth American Emergency Response Guidebook [RQ Reportable Quanity TPQ -Threhld Planning Quantity lockStop sath Replecee: Jie #1, 2000 REVISION INFORMATION Pagesots‘SYSTEMS OF PHOTOGRAPHY RECORD SPEED FIXER MATERIAL SAFETY DATA SHEET 1 PRODUCT AND COMPANY IDENTIFICATION Praket Nee cord Spel Fier (Catalag Nome Na Chea! Nas Mixture (Oanien Sanae Na Sri Syetee of Petagrapey, ee: 1050 Chapmis Hil Roa Seat, RLC2RS? [EMERGENCY TELEPHONE NUMBER hemiel (1-800 985- 200) ‘COMPOSITION/INFORMATION ON INGREDIENTS ‘CHEMICAL NAME cas EXPOSURE CONTROLS ume Osha PL AcsHHTW Ammonium thioeltate aS N read soe NE NE howtioncsd 10 ppm 10 ppm CWA) 15 ppm TEL) Sodium sulte NE Solium metabivulce Sagi Stim metaborate NE iota NE See Section 15 for OSHA Regulatory Stas E HAZARDS IDENTIFICATION Lhe yellowish aid with aight bane ede scelcocl pore sry coves ata, My corel tsi eta, My one eaters ois ges, PRIMARY ROUTES) OF ENTRY ‘Skin Contact: Prfenged or repented contact may caine initation,rednese,crocng, ond dermatitis, Cater may Inhalation: Vapors ma itt the repiratony tac. Breathing acetic aid may eae asthe ecord Speed Fer Rye Contact Conta 5 ih ye may vitae ad [MEDICRLCONOITIONS AGGRAVATED BY EXPOSURE Persone seit to acti acd, od metabaulfte scdiumn elle ae at ik, Page otLet Anmticabie OSTA Suepet Careinogen National Tosa Program (TP) Tioternaticnn Agee fr Reveasch an Cancer GARC) 4 FIRST AID MEASURES ‘op if aaa, several miniter Sele maa aentin Feitaton develops and persists Inhalation: Remove frm atest sh a. Seek medial tention i respratrytetation develope ot ifhecathine ecm dfiult.-Ivietin ie having rele teething transport to atic care and if valabe eve upplemetl ive contact Rinks eves with water Remove an contact Tene, andeontinne faking wath plenty of water br evel Ingestion: Give 3 glsees of wate, but DO NOTindace ‘vemiing vomiting car, give Ouids agin. Get masa fvtention to detemine whether vamiing or evacuatn of taac ie neeecary_ Dono ese anti by mouth to an unconeioue arccvuling pero NOTE TO PHYSICIAN Noinftemation ail, & FIRE FIGHTING MEASURES. lash Point ond Mea 200°F @m4ce) Fire or exresive eat may produce hazard decomposition pralucte [SxINGUISHING MEDIA Inca offre ute etinguishing mala cuitalie or the rateril that i bing Nave cen, Asin any re, sear NIOSH approved positive-preseure ll contained breathing appara and fl potctive goa [ACCIDENTAL RELEASE MEASURES Wear appropriate protictive eapment re Section 8. Avid sein loti o inc er Aor in yi dey sand oath ana place ino containers diapoea HANDLING AND STORAGE Wear appropriate protective equipment See Section 8) Avid etn on lthing or ain we in es Wash throughly afer Panaing stoRact Keepin hil clove container, stared in col dey, veiled ren 2 EXPOSURE CONTROLS/PERSONAL PROTECTION, {ENGINEERING CONTROLS se eaginceringcontale to ree ai ontainats to permissible expomue lve PERSONAL PROTECTION Respirator: Incondtions wher high soneentrating of superar present or expocare limit ae eaceeded, Wear & eepiata that hae been ederted by technically quai ecard Speed Fer, Bye Protection: Wour approved safety glasses or goals. Gloves But rubber Clothing: Wear long-stowat clothing. Use rubber ape. Other: Hye wash vatity showee. PagetPHYSICAL AND CHEMICAL PROPERTIES Stote gid Vane Density (Aie= 1) NA alee ight yellowich ‘Vapoe Freer nm Hi) Neglisible one Sake Yanan Ba eo Mating Point NA Water Solutiiey Soluble Baling Paine >ai2 Solubility in ahr igi NE Specie Gravity © 25°F 15 e ‘STABILITY AND REACTIVITY eacrviy HAZARDOUS DECOMPOSITION PRODUCTS Stable under normal use emntions Wil dacempesein seid Ammonia, CO, C0, oxides of itrogen and aul, hyogen solutions, hberatingtoxic and eitating wlferdioidegae. ade Acide mated, strong oxide, alkali mata coetvs bon sla alien ne ‘TOXICOLOGICAL INFORMATION ‘The producti not aca nitant The primers dermal isttien For Sodium sulfice: score wat 0.11 flowing a hour acted dermal expsurein Oral Dy (meee) $20 meth famotiled FESACPSC Design, 16 CFR 1200 For Soatium metaborate Foe Acetic acid Inhalation ce) 8280 ppm Drak Ua age a0 elle Ora LD aby 3.810 mee For Borie cot Dera LD ait): 1.060 ae (ral LD (at 00 rhs Oral LDy eae) 110 mh For Ammontam thiosulfate: Ora LD (rat: 2800 as Alnuman sui ofan cecupationally espooed brat worker Oral LD nous 100 mh Population showed no adverse reproductive elle. Animal ‘Ludioe af eile noeganie bates demanetated eprodutive ‘fictein male. 2 ECOLOGICAL INFORMATION SCOTORICOLOGICALINFORMATION ENVIRONMENTAL MOVEMENT AND PARTITIONING Por Acute ack Nit own, 96 tr thea inp: 88 ng/L Cont Static, aes ENVIRONMENTALEATE 6 br LC git wont 5 mL Pah Lc (aleish:-429 me Nat own 248 be BC ter ea): 12-17 met. {886-11 mgt Mert tet. Cond 15°C For Bort act the LC (vater Sea) 115041580 mail. Cea: Stati. i ‘DISPOSAL CONSIDERATIONS RCRA Wate Cate Not regulated ecard Speed Fer, Page sotu TRANSPORT INFORMATION 5 REGULATORY INFORMATION ‘OSHAMAZARD COMMUNICATION STANDARD (28 CFR 910.200) SC itazardoue _ Non Harardoue ccenctassurenruno4ocrn 17,303), Acca RQ: 5,000 he. SARA TOXIC CHEMICALS (40FR372) wa TSCACHEMICAL SPECIFIC RULES ‘SARA EXTREMELY HAZARDOUS SUBSTANCES (CFR 355) NA 'SRRA HAZARD CATEGORIES (40 CFR 370) Loewe Cewenie Fue Freeswe ——_Reaetive ne Flora Hazardous Stetonce List Massachusetts Right To Know List ‘qmsnun sorta aodoctdven stint Minnesota Hazanious Subetane List.» Asti ac and satin metabolite Asti ocean ‘Now Joeeey Right To Know Lit Acti ocd nd Rhee [ld HlzarlousSbetance Lit. Acti, Sedum All ingrodicns ofthis product aro tho SCA invent olatielte 16, ‘OTHER INFORMATION NFPARATING PREPARATION INFORMATION Heath Prepared ty: Sint Sytem of Photography, Ine Fire 1 Date Prepared: Jane, 5000 Renctivity 0 Replacers November 10,1998 AsaRevATIONS REVISION INFORMATION Colin iit NIA--Not applicable ND -Nat deters NIE Not etal NABRG -Nerth American Rmergeney Reepense Cuidbook RQ Reportable Quanity ‘THQ Thebold Pani Quantity ecard Speed Fer, Sestons 11 and 16 were updated to reflect welt of der sentation st PagesotsARCHIVE FIXER REMOVER SYSTEMS OF PHOTOGRAPHY MATERIAL SAFETY DATA SHEET 1 PRODUCT AND COMPANY IDENTIFICATION Praket Nee Archive Finer Remover Sprit Sytem of Phtosrupy, le (Catalog Number NA 1067 Chopmis i Road Oheieal Nase Misture State, LORS Cominen Narne NA 00 be-sona Product Use emove photographie xr [EMERGENCY TELEPHONE NUMBER Chemie (1-80.98. 2009) 2. ‘COMPOSITIOW/INFORMATION ON INGREDIENTS CHEMICAL NAME. os EXPOSURE CONTROLS umeen Bibolene geod wrsa NE 100 mn? (aeons Potasium colt of ehylenetriamine Misne NE NE pentanetie acid Situ metab Ne ad sulfite Ne Se Scion 15 fae OSHA Regulatory Sta. z HAZARDS IDENTIFICATION blue tomo yee solution with aight ule dose ler Warning! May cate skin seoitzation, Mayenne il kin, eyes, and the respiratory rt May be snot soo ain. May canes heentaniog inn Tiel ere ecagciig ann site fo he material that bring POTENTIAL HEALTH EFFECTS PRIMARY ROUTES) OF ENTRY Inhalation eating) ve and akin contact STMPTOMS OF EXPOSURE Skin Contact: May cove mild imitation. Maybe absorbed enh se ad ence stone sve. May emise skin sitvation, te Hit thoes Bingen ot Inhalation: rething vapors may itt theme membranes ofthe nove, throat, eriratory tact, and may Hye Contac: May cause mild eitation Ingestion: Can emse Kidney damage, and maybe tsi tothe Archive Fier Remover Uhretening acta, Fiestiin skin dasre aye vecleias oe ubaivd red eve, Persone entine to sacim metas soon cult are trie, REPORTED AS CARCINOGEN OR POTENTIALCARCINOGEN Love Appieabie “OSHA Suzpect Carnage siaal Tosealgy Progam NTP) international Agency fr Rear a Cancer AARC Page ota FIRST AID MEASURES Skin contact: Wach ato areas with plney of water and peat oup fala, everalitr. Sk medal atten if Inritaton develope and peiete Ingestion: Git panes of wate, bu, DO NOT indie ‘vomiting 1vomitingacurs give Huis gain. Get meen lear airway sv start raticoomonth artifical repnation oe stomach isnceeary’ Dont pve anything by mouth oan ‘ue bags ak eopiratee Gt imedite medical attention, Lf uncon or corulsing perso, fan tava, ive snplemental oxygen, NoTETO PHYSICIAN contact new ayes with wate, Remove ey ce LETS: sminulee Seek media ltention Eisation develope ae 5 FIRE FIGHTING MEASURES loch Paine ond Methot > m0 ‘material that ie baring. ssenscraanas SPECIAL FIRGHGHTING INSTRUCTIONS. Fire oexrersive beat may produce hazardour decomposition None know. rls FIREFIGHTING EQUIPMENT eiNauising MEDIA Astin any ire, near NIOSH approve, postivepressue self cantina bret appara al fl peaecive gee Inca offre wee extinguishing alia suite fo the & [ACCIDENTAL RELEASE MEASURES ‘Wear appropriate peotctiveenunment xe Section) Avokd pill, Abo with Kt iter, and east al ck in 8 contact with es, kn, oe clething. Venta aren of eal or tahlecontane for deport HANDLING AND STORAGE Wear arproprine postive exipment (See Section 6 Av Reap ina ight dosed contsine, sr in con dy contact wh ees, akin, ee ting Waeh Uhaoushly afer ventilated area hanatine 2 ‘EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS Eye Protection Wear approval sty sass, ‘Use eginering entre o reduc ir contamination to Gloves: Buty rues peaieiiemaeetio, (Clothing: Wer longsleeve clathing, Use rubber a PERSONAL PROTECTION. Other: ye wash: sty shower. Respleatar:Incontions wher high concentrations af ‘apart or mist ate present cr exponir imite ace exceedal weae aespeatr that hasbeen selected by tecically ‘qual pesen far the specie work candition. PHYSICAL AND CHEMICAL PROPERTIES Liguid Making Point NA luo tomate green Baling Pot aie Sulfur dioide Specie Gravity © 25°F 1 Archive Fier Remover Pagetoper Density (Air= 1) wa Woter Sais Solute Vapar Precere am Hg) NA Selby in eee iid NA BH 10. STABILITY AND REACTIVITY aencrtviy IncomPaTiBN Es Stable under nal use cenitens Wl daempewe fn aid Ae materiale, etrne oizere selutions, berating toi and itating sul dixide ga. azanDoUs DécoMPosiTION PRODUCTS Sends en cli (604, C0, snd oxide lr un TOXICOLOGICALINFORMATION OSS ‘The pect io not on eitant The primary deem itation For Bthylene elyoat score wor 03 flowing hour ace dermal expose. ‘odifed FISAICPSC Design, 16CFIL 1500. Tndulation LC at: 10878 mig (ral Da rt 4.700 mas . (rac. now 5,500 mh a aa ae Desens, abhi) 9.580 le (rl DC ra 690 soploapa te mall ox anor ists sar ‘onvatsons ancora, Death could result om rexpeaory Anima state icate that rept ingestion can cae feematen of badder ond kidney stones, ax wel oe Kx” 2 aor apes era neo swore = ST a TaneeTRERTON Not regulated by DOT, ICAO, 6 BAD. Archive Fier Remover Page sot1s REGULATORY INFORMATION ‘OSHAHAZARD COMMUNICATION STANDARD 29 CFR ‘sra200) Ciimartous _Now-Hlazardons CCERCLA/SUPERFUND (40 CFR 117,302), NA SARA TOXIC CHEMICALS 40CFR372) Bubylene seal 20%) Nave known STATEREGULATIONS Calienia Propoition 65 ..... Warning! Tie product, conta ermal @ ‘chemical mw tothe State of Califenia tocmse cancer, Florida Hiearlow Substance List Sodium metab, sta elie ea ‘SARA EXTREMELY HAZARDOUS SUBSTANCES (40FR 355) NA ‘SARA HAZARD CATEGORIES 40 CFR 370) Lrewe Lonwonic SPs _Retive IvenroRy starus Allingetiente of thie produc re on the TSCA inventory Maesactiets ie ‘To Kiow List... Formaldehyde, seri etal, andethylene yal Sodium metabilte, audetighese deol Soxhurs meals, audetishee lead ‘de dean Haare Subetnce List: Sodium metabilte, sndethiylene yeol Minnesota Hazards Substance Lie New Jersey ight To Know Lit i OTHER INFORMATION Heath Prepared by: Seine Syetems of Photorraphy, Ie ire 1 Date Prepares Ape 19, 3000, Reatvity 0 Replat November 19, 1990 © -Ceiing init Sections 3 6, 7,8, 11, 14nd 10 woew pdated toot N/A-Not applicable ND Not determined NIE-Not establish NK Nat nen NAHRG- North American Emergency Reepance Guidebook HQ. Reportable Quanity ‘TPQ Threshold Planning Quantity Archive Fier Remover rule of «dermal irritation etuty Pagesots‘SYSTEMS OF PHOTOGRAPHY END RUN WETTING AGENT MATERIAL SAFETY DATA SHEET ‘PRODUCT AND COMPANY IDENTIFICATION Praket Nee ad Rua Wetting Agent & Saber Sri Syetee of Petagrapey, ee: (Catalag Nome Na 1050 Chops i Cherie Ni Mixture Seat, RLC2RS? (Oanien Sanae Na son s8-Sora charge [EMERGENCY TELEPHONE NUMBER hemiel (1-800 985- 200) CHEMICAL NAME as numer Paleter Propeietry nope aeahol eran Water ei ‘Seo ction 18 for OSHA Regulatory Statue ‘COMPOSITION/INFORMATION ON INGREDIENTS EXPOSURE CONTROLS Osha PEL, AcoiHTLY NE NE 400 ppm TWA 200 ppm TWA; 400 ppm STE, NE NE 2. [HAZARDS IDENTIFICATION For product a sold Char igi with a rubbing slob ox ‘Warning Flammable qui and vapor. Causes eye intation May cause tation to shin, eyes, ae -epiraory tat. Overexpoeur oioprepanal vapors may ‘ave centrd nervour spot depress. Incaee offre use wate , ach” fon, carbon dose [EMERGENCY OVERVIEW (C0), or ey tania Por diluted products use: (Clear guid with alight aoa odor May caiee eye and ein station, May faa, bu wil nt austen combustion POTENTIAL HEALTH EFFECTS PRIMARY ROUTES) OF ENTRY Inhaation Gratin), ean akin cont SYMPTOMS OF EXPOSURE or product as sold Skin Contact: Repeated or prolonged skin contact may case inition and reneitization Five Comtnct Direct contact eases severe iitatin and ain Inhalation: May state the repiratoe tact and muon rmemirane, Overexpieune to japeonanolvapar may case nd Run Wetting Agent st ‘ental nervous aetem depeeasion:eymptone include hele, ssn, nae, vomiting. Severe overespieine can orn aneonrueroe or death, Ingestion: May cause digcetive teat ieittion and ymptame sinilar tothove ltl for nal, For diluted product as used May cause mild ee and skin iittin. May nue in [MEDICALCONDITIONS AGGRAVATED BY EXPOSURE Fessonesnsitin toinopropyl leo reat sk. Page ot__Natinal Toxo Programa TP) {Cee Arniesbie Tinternational Agee or Research oa Cancee GARC) OSTIA Suepet Careinogen 4 FIRST AID MEASURES ‘op if weiabe, he never miata. Soe miata if ‘eitaton develops and persis Eye contact: Inmedintly rinte eyes wth wate, Remove any theatre surface afte eee a ide wh water Cet tmmediate medica tention, Inhalation: emove fom vet eh a. See mesial ateation ifeepratnyientatin develope or fhecathing ecm dtl. Ingestion: Give 2-4 gases of water tt DO NOT ince _tention to determine whether vomiting or wwacuain ‘aaah a necestary Donat pve artigo toa Nore TO PRYSICIMN ‘Somptumatic and cuppartive treatment ie generally all at ie deeded. Metab oicoprepanel foe acta which may ‘be detected in the serum and urine, Determine the iopeepanal ‘centration in the sms and onitor faaidose and Ispeslyemin. Gaste age mat bo oetive i prem Dallents a thers of eonwaling (0. dey cement 5 FIRE FIGHTING MEASURES Flach Pain nd Meth 80°F low cup) - ms veld Fire rexrozsve eat may produce hazardous decompadition eaticte Inca offre ate water, “lesbo” ham carb dcxide Nowe know, FnerichiNG eQveMeNT ‘As inany fre, ear NIOSH approved, posiivepressure sae contained beating appara and fal secive we [ACCIDENTAL RELEASE MEASURES For produet as sold ‘Weas sopenuitepevttive eqomnt eo Bection etinguish al jenn aamees. Ave apr, lames, oat and stocking, Vota aren of enk o pl Asn with ity ite ‘and earth package ina rable cotainer dior. Use ‘Selatic bce an shovel when cllenting spilled tora. For product us used: May be Bushed ito wom, HANDLING AND STORAGE WANDLING Wear appropriate peoeetiveequnment (See Section 8) Keen ‘vay fm het, pare on on Hee storact Keep aa fem eat parks an pen Ba. Keep ina shy loved container, sored in col dry. venated are, Flammable ged tora. & EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS Use lca andlor senctal exhaust to rede air eontaminaton ‘opormieabieexpacue eel nd Run Wetting Agent & stabilizer PERSONAL PROTECTION Respirator: Inconitione where high coeentrations of ‘pare ate preset or exparure lite are seeded, we Pagetrespirator that has been sete by technically qualified poten fe the epee workeotins otection: Wear approved safety goggles lowes: Neoprene Clothing Wear longeeoved clothing. Use ruber apron, ruber (Other: Rye wash; salty shower 2 PHYSICAL AND CHEMICAL PROPERTIES Stat. gid Vapor Density Air= 1) wa ace Cae ‘Vapor Pressure nm He) Bum (Caeulated) Ode Pusgent ot ar Melting Point Nia Water Sati Salute Specite Graity © 25°F 08s io. STABILITY AND REACTIVITY Stabe ‘carbon dine; sarbon meno string oie Spark, ame, het, alumni contsinees above 190° nn ‘TOXICOLOGICAL INFORMATION. ‘The prot ie not ek vtant. The primary dermal itt care wa 0.82 flowing a chau ocluded dermal expaeue in ‘amodifed PSACPSC Design, 16CFR 1500. For Isopropslaleoho: Oral LD rat): 5.45 mga ‘ral LD, nour) 3600 mks Dees ED bli) 12800 mh 2B ECOLOGICAL INFORMATION ECOTOHICOLOGICALINFORMATION For tsopropy! aloobot 96 LC (theo minnow 29 days cd 9500 NVIRONMENTAL MOVEMENT AND PARTITIONING Ni 10.80 mei. Cond: Fomethrongh, 4424.60, pl iancicteirat rane 7.00, 52.5 mall CaCO, Not known 6 Ui athend mine 2 as ot) 61,300 5.500 mg. Cond: Flow-theough, 216°C, pH, ‘min 0 (Photobacterim haphorn 25:0 me Mie ot 2. DISPOSAL CONSIDERATIONS or product as sold RCRA Waste Code: oot, nd Run Wetting Agent & stabilizer For product us use, RCRA Waste Cade Notepulted Page sot“a "TRANSPORT INFORMATION DOT Proper Shipping Namo: ..., Consumer commodity DOT Hazard Clare orm DOT LD. Nunbe NA Peeking Group NA ‘Marking omep NAEEG Guide No NA 1s. REGULATORY INFORMATION (OSHA HAZARD COMMUNICATION STANDARD (20 CFR 1810.1200) LHleanedous Non Htazantos CCERCLA/SUPERFUMD (40 CFR 117,202), NA SARA EXTREMELY HAZARDOUS SUBSTANCES (0 CFR355) Na SARA HAZARO CATEGORIES (40 CFR 370) Vreate Lotwanie —Pranme Reactive Califia Propovition 05... Waring Mie pradt ‘entains eal tae 9 ical Kawa othe Ste of Cairn to cause cance, 'SRRA TOXIC CHEMICALS (CFR 372) Tope ssn 90 40% propyl ula Section 1) apoet Nici ventory starus AlLingredient thie prs are en the TSCA ingenory. lord Haardoue Substasce List... Inopropylsleabat Marrachusete Right Toiow List. Ieoprpylaleahal Dinette Subvnce List. Leopropyl seca [Now Jersey Right To Know List... eopropylalohal a8. (OTHERINFORMATION Bedth 2 repared by: Sprint Systeme of Photogeaphy, Tne Fie 8 Date Prepared June 2, 2000 Recetvity 1 Replaces November 19, 1600 [ABBREVIATIONS REVISION INFORMATION © Ceiling limit NA-Not applicable ND“ Not determine NE Not etait NIK Not owe ABE - North American Emergency Reaponse Guidebook RQ- Reportable Quantity "TPQ Threshold Planning Quantity End Run Woting Agent stabilizer Seetine 11 and 16 wore updated to reflect results ofa dermal station sti Pagesora