9th Class Chemistry Chapter No. 1
a FUNDAMENTALS OF CHEMISTRY
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. Difference between organic and inorganic chemistry:
. Biochemistry covers all chemical processes taking place in living organisms such
._ In biochemistry we study how living things obtain energy from food and how the
. Examples of applications of biochemistry are in the field of medicine, food
Short Questions and Answers
Define Chemistry.
The branch of science which deals with the compositions, structure, properties
and reactions of matter is called Chemistry.
Define physical chemistry.
Physical chemistry is defined as the branch of chemistry that deals with the
relationship between the composition and physical properties of matter along
with the changes in them.
Differentiate between organic and inorganic chemistry.
Organic Chemistry Inorganic Chemistry
Organic chemistry is the study of Inorganic chemistry deals with the
covalent compounds of carbon and study of all elements and their
hydrogen (hydrocarbons) and their compounds except those _ of
derivatives. compounds of carbon and hydrogen
(hydrocarbons) and their derivates.
Define biochemistry and write its scope.
Biochemistry is the branch of chemistry in which we study the structure,
composition and chemical reactions of substances found in living organisms.
Scope of Biochemistry:
as synthesis and metabolism of biomolecules.
fundamental biological changes occur during a disease.
science and agriculture.
Define industrial and analytical chemistry.
Industrial Chemistry: The branch of chemistry that deals with the
manufacturing of chemical compounds on commercial scale is called industrial
chemistry.
Analytical Chemistry: It is the branch of chemistry that deals with separation
and analysis of a sample to identify its composition
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Chapter No. 1
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What is nuclear chemistry?
Nuclear chemistry is the branch off chemistry that deals with the radioactivity,
nuclear process and properties. The main concern of this branch is with the
atomic energy and its uses in daily life.
What is environmental chemistry?
It is the branch of chemistry in which we study about compounds of the
environment and the effects of human activities on the environment. The
knowledge of environmental chemistry is necessary for the improvement of
environment and its protection against pollution.
Write the difference between physical and chemical properties.
Difference between Physical and Chemical Properties:
Physical Properties
Properties that are associated with
the physical state of a matter are
called physical properties like
colour, smell, taste, hardness,
solubility, melting and boiling
points.
Chemical Properties
Chemical properties depend upon
the composition of the substances
e.g., ionization energy, electron
affinity, electronegativity etc. are
the chemical properties.
When a substance undergoes a
chemical change its composition
changes and new substances are
found
Define element.
Element is a substance made up of same type of elements having same atomic
number and cannot decomposed into simple substances by ordinary chemical
means e.g., oxygen (0), hydrogen (H), sodium (Na) etc.
What is the significant (ei) of the symbol of an element?
In chemistry an element is represented by a symbol because it is easy to write
symbol in chemical formulas and chemical reactions instead of complete name
of the element.
Define valency. On what factors does it depend?
It is the combining capacity of an element with other elements e.g., the valencies
of sodium, oxygen and nitrogen are 1, 2 and 3 respectively. Valency depends
upon the number of electrons in the outermost shell
What is meant by radical?
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A radical is a group of atoms that have some charge e.g., ammonium (NHZ),
carbonate (CO3~), sulphate (SO~) etc.
Q. _ Howdoes homogeneous mixture differ from heterogeneous mixture?
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Difference between homogeneous and heterogeneous mixture:
Homogeneous Mixture Heterogeneous Mixture
Those mixtures that have uniform Those mixture in which composition
composition throughout are called is not uniform throughout e.g., soil,
homogeneous mixtures e.g., rock, wood etc.
gasoline, ice cream etc.
Q. Write the difference between compound and mixture.
Ans. Difference between compound and mixture:
Compound Mixture
Compound is a substance made up When two or more elements or
of two or more elements chemically compounds mix up physically
combined together in a fixed ratio
by mass e.g., water (H20), sodium
chloride (NaCl). The components of
compound cannot be separated by
without any fixed ratio, they form a
mixture e.g., the components of
mixture can be separated by simple
physical means.
simple physical means.
Q. State three reasons why do you think air is a mixture and water a compound?
Air is a mixture becaus
1. Airis a simple mixing up of Nz, O2, CO2, noble gases and moisture.
2. Air shows the properties of constituents.
3. The compounds of air can be separated by physical means.
Water is a compound because:
1. Water is formed by chemical combination of oxygen and hydrogen
2. The constituents of water lose their identity.
3. Hydrogen and oxygen present in water cannot be separated by physical means.
Q. State the reasons: soft drink is a mixture and water is a compound.
Soft drink isa
1. Soft drink is a simple mixing up of water, sugar and CO
2. Sot drink shows the properties of constituents.
3. The compounds of soft drink can be separated by simple physical means.
Water is a compound because:
ture because:
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4. Water is formed by chemical combination of oxygen and hydrogen.
5. The constituents of water lose their identity.
6. Hydrogen and oxygen present in water cannot be separated by physical means.
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Differentiate between atomic number and mass number.
Difference between atomic number and mass number:
Atomic Number Mass Number
1. The atomic number of an element 1. The mass number is the sum of
is equal to the number of protons number of protons and neutrons
present in the nucleus of its atom. __present in the nucleus of an atom.
2. It is represented by symbol “2”. 2. It is represented by the symbol
3. Formula: Z= A-n, where nis the “A”.
number of neutrons. 3. Formula: A= Z+n, where n is the
number of neutrons.
What is meant by relative atomic mass?
The relative atomic mass of an element is the average mass of an atom of that
element as compared to 1/12th the mass of an atom of carbon-12 isotope. The
unit of relative atomic mass is amu.
Lamu = 1.66 x 10% g
Define atomic mass unit. Why is it needed?
One atomic unit is 1/12" the mass of one carbon atom of carbon-12 whose
symbol is amu. It is the unit of relative atomic mass. Atomic mass unit is
expressed as follows:
Lamu = 1.66 x 10% g
Atomic mass unit is needed because the mass of an atom is extremely small and
cannot be determined experimentally.
How many amu 1 of a substance has?
We know that
amu = 1.66 x 10% g
1.66 x 1074 g = 1 amu
1g=—— = 6.024 x 10-?3amu
66x10
Hence 1g of a substance has 6.024 x 107 amu
Differentiate between molecular and empirical formula.
Difference between molecular and empirical formula:
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Molecular Formula Empirical Formula
Molecular formula shows the actual Empirical formula is the simplest
number of atoms of each element whole number ratio of atoms
present in a molecule of that present in compound e.g., empirical
compound e.g., molecular formula formula o glucose is CHO
of glucose is CcH120s
Q. — Whatis the relationship between molecular and empirical formula?
Ans. Molecular formula is derived from empirical formula by the following
relationship:
Molecular formula =n (Empirical formula)
Where nis 1,2,3 and so on.
Q. _ Differentiate between molecular mass and formula mass?
Ans. Difference between molecular and formula mass:
Molecular Mass Formula Mass
The sum of atomic masses of all the The sum of atomic masses of all the
atoms present in one molecule of 2 atoms present in one formula unit of
molecular substance is called a substance is called formula mass.
molecular mass.
Example: Molecular mass of water Example: Formula mass of sodium
(H20) is 18 amu chloride (NaCl) is 58.5 mu
Q. What is the empirical formula of acetic acid (CHsCOOH)? Find its molecular
mass.
Ans. Molecular formula of acetic acid = CH3COOH = CzHsO2 = (CH20)2
So, empirical formula of acetic acid is CH,O.
Molecular mass of acetic acid = 2(mass of C) + 4(mass of H) + 2(mass of 0)
= 2(12) + 4(1) + 2(16)
60 amu
Q. Calculate the molar mass of nitric acid (HNOs) and sulphuric acid (H2SO.).
Ans. Molecular mass of nitric acid (HNOs) = (mass of H) + (mass of N) + 3(mass of O)
=1+14+3(16)
=14+14+48
= 63g molt
Molecular mass of H2SO«= 2(mass of H) + (mass of S) + 4(mass of 0)
= 2(1) +32 + 4(16)
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=2+32+64
= 98g mol
Differentiate between atom and ion.
Difference between atom and ion:
Atom lon
‘Atom is the smallest particle of an lon is an atom or group of atoms
element that can part in chemical having a charge on it e.g., CI, K* etc.
reaction e.g., sodium (Na), hydrogen There are two types of ions:
(H) etc. Atom can or cannot exist 1. Cation 2. Anion
independently. It is electrically lon can exist independently.
neutral.
Differentiate between cation and anion.
Difference between cation and anion:
Cation Anion
An atom or group or atoms having An atom or group or atoms having
positive charge on itis called cation. negative charge on itis called anion.
e.g., Na’, K’ etc. e.g., Cl”, O- ete.
What is meant by free radical?
Free radicals are atoms or group of atoms possessing odd number of (unpaired)
electrons. It is represented by putting a dot («) over the symbol of an element.
For example, H’, Cl’, H3C* are the free radicals.
How free radicals are generated?
Free radicals are generated by the homolytic (equal) breakage of the bond
between two atoms when they absorb heat of light energy such as the
generation of Cl* in the presence of light is expressed in the equation.
Sunligh
cl, —S 2cr
Differentiate between molecule and molecular ion.
Difference between molecule and molecular ion:
Molecule Molecular lon
Molecule is the smallest particle of When a molecule loses or gains an
an element or compound which can electron, it forms a molecular ion
exist independently and shows all e.g., CH, He*, Ndetc.
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the properties of that compound It can have negative or positive
e.g., CHs, He, Nz etc. charge.
It is always neutral. It is reactive specie.
It is stable unit.
Define monoatomic, diatomic, triatomic and polyatomic molecules and give
their examples.
Monoatomic Molecule: A molecule consisting of only one atom is called
monoatomic molecule e.g., He, Ne, Ar etc.
Diatomic Molecule: A molecule consisting of two atoms is called diatomic
molecule e.g., Hz, 02, Clz ete.
Triatomic Molecule: A molecule consisting of three atoms is called triatomic
molecule e.g., COx, HO etc.
Polyatomic Molecule: A molecule consisting of many atoms is called polyatomic
molecule e.g., H2SQs, CHe etc.
Differentiate between homoatomic and heteroatomic molecule.
Difference between homoatomic and heteroatomic molecule:
Homoatomic Heteroatomic
A molecule containing same type of A molecule containing different
atoms is called homoatomic types of atomsis called homoatomic
molecule e.g., Hz, Ps, Ss etc. molecule e.g., HOz, H2SOz, CHs.etc.
What is gram atom?
The atomic mass of n element expressed in grams is called gram atomic mass or
gram atom. For example, gram atomic mass of hydrogen is 1.008 g.
What is gram molecule?
The molecular mass of an element or a compound expressed in grams is called
gram molecular mass or gram molecule. For example, gram molecular mass of
water is 18.0 g
What is gram formula?
The formula mass of an ionic compound expressed inn grams is called gram
formula mass or gram formula. For example, formula mass of sodium chloride is
58.58.
Define Avogadro’s number (Na).
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Ans. The 6.02 x 10” number of particles i.e., atoms, molecules or formula units is
called Avogadro's number that is equal to one mole of respective substance. It
is represented by the symbol Na.
Na = 6.02 x 107 particles
Q. Define mole.
Ans. A mole is defined as, “the amount (mass) of a substance that contains 6.02 x
1023 number of particles i.e, atoms, molecules or formula units”. It is
abbreviated as mol.
Example: One mole of carbon is obtained by expressing the atomic mass of
carbon (12 amu) in grami.e.,
One mole of carbon = 12 g of carbon
Q. Write the relationship between mole and mass?
Ans. The relationship between mole and mass can be expressed as:
Known mass of substance
No. of moles = Molar mass of substance
or Mass of substance (g) = number of moles x molar mass
Q. Calculate the number of moles in 40 g of HsPOs.
Ans, Given mass of H3PO4 =40g
Molar mass of HsPOs = 98 gmole?
We know that
Known mass of substance
No. of moles = ————————_—_
Molar mass of substance
No. of moles = > = 0.408 mol
Q. Calculate the number of moles in 9 grams of coal (carbon)
Ans. Given mass of carbon =9¢
Molar massof carbon = 12 gmol?
We know that
Known mass of substance
No. of moles = —————————_—_
Molar mass of substance
* = 0.75 mol
re
No. of moles
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Multiple Choice Questions
10.
11.
Industrial chemistry deals with the manufacture of compounds:
(a) in the lab (b) on micro scale
(c) on commercial scale (d) on economic scale
The branch of chemistry which deals with the manufacturing of chemical
compounds on commercial scale is called:
(a) biochemistry (b) organic chemistry
(c) industrial chemistry (d) physical chemistry
The number of naturally occurring elements are:
(a) 80 (b) 86
(c) 92 (d) 109
Which one of the following elements is found in most abundance in the
Earth’s crust?
(a) oxygen (b) aluminum
(q)silicon (d) iron
The most abundant element occurring in the ocean is:
(a) oxygen (b) hydrogen
(c) nitrogen (d) silicon
Percentage by weight of hydrogen in ocean is:
(a)11 (b) 12
(13 (d)14
Percentage by weight of chlorine in ocean is:
(a)1.8 (b) 2.8
(93.8 (48
Which element is found in most abundance in atmosphere?
(a) oxygen (b) nitrogen
(c) argon (d) chlorine
Percentage by weight of nitrogen in atmosphere is:
(a) 78 (b) 76
(77 (d)79
Percentage of oxygen in the atmosphere
(a) 21 (b) 22
(23 (d) 24
The third abundant gas found in the Earth’s atmosphere is:
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Chapter No. 19th Class Chemistry
Chapter No. 1
12.
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15.
16.
17.
18.
19.
20.
21.
22.
(a) carbon monoxide (b) oxygen
(c) nitrogen (d) argon
Major part of a living body with respect to mass is made up of:
(a) benzene (b) ammonia
(c) urea (d) water
The percentage of oxygen in human body is:
(a) 66 (b) 65
(63 (d) 64
Potassium, Sulphur, magnesium and sodium constitute ---
mass.
(a) 0.6% (b) 0.7%
(c) 0.8% (d) 0.9%
Majority of the element exist in the form of:
(a) gasses (b) liquids
(c) solids (d) metalloids
The element present in liquid state is:
(a) bromine (b) fluorine
(c) chlorine (d) iodine
Mercury is the metal which exists in
(a) Solid (b) Liquid
(c) Gaseous (d) Plasma
The symbol of boron is:
(a) Be (b) Br
(8 (d) Ba
The symbol of silver is:
(a) Si (b)s
(c) Ag (d) Hg
The valency of chromium is:
(a)2 (b)3
(94 (a5
The valency of boron is:
(a)1 (b) 4
(c)3 (d)2
The valency of phosphate radical is:
(a) 1- (b) 2-
~- of our body
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109th Class Chemistry Chapter No. 1
()3- (a) 4-
23. The valency of Fe in FeSOs is:
(a) 2+ (b) 3+
(c) 4+ (d) 5+
24. The chemical formula of washing soda is:
(a) Na2CO3 (b) Na2CO3.6H20
(c) Na2CO3.7H20 (d) NazCO3.10H:0
25. Which one of the following can be separated by physical means?
(a) mixture (b) element
(c) compound (d) radical
26. Example of homogeneous mixture
(a) soil (b) rock
(c) wood (d) ice cream
27. Atomic number of an element is represented by a symbol:
(a)k (b)L
(c)A (d)Z
28. The atomic number of fluorine is:
(a)3 (b) 4
(5 (a)9
29. Mass number of an element is represented by:
(a) K (b) N
(A (a) Z
30. Which one of the following is mass number of potassium (Kk)?
(a) 12 (b) 14
(c) 40 (d) 39
31. One amu (atomic mass unit) is equivalent to:
(a) 1.66 x 107 mg (b) 1.66 x 107" g
(c) 1.66 x 107 kg (d) 1.66 x 107? g
32. Mass of proton is:
(a) 1.0073 amu (b) 1.0087 amu
(c) 5.486 x 10% amu (d) 6.486 amu
33. Mass of neutron is:
(a) 1.0073 amu (b) 1.0080 amu
(c) 1.0087 amu (d) 1.0097 amu
34. The mass of electron is:
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(a) 1.674x 10% g (b) 9.106 x 1078 g
(c) 1.672 x 10% g (d) 1.66 x 10% g
35. The empirical formula of hydrogen peroxide is:
(a) CH (b) HO
(c) CH20 (d) SiO.
36. The empirical formula of benzene is:
(a) HO (b) CHO
(c) CH (d) CeHe
37. The empirical formula of glucose is:
(a) CH (b) CH20
(c) OH (d) H202
38. Molecular formula of benzen:
(a) H.02 (b) CHO
(c) CeH1206 (d) CcHe
39. Molecular formula of glucose is:
(a) CsH1206 (b) CHO
(c) CHO (d) CoHeO2
40. The molecular mass of O2 is:
(a) 44 amu (b) 40 amu
(c) 32 amu (d) 50 amu
41. The molar of H20 is:
(a) 18 amu (b) 18 g
(c) 18 mg (d) 18 kg
42. Formula mass of sodium chloride is:
(a) 57.5 amu (b) 58.5 amu
(c) 35.5 amu (d) 38.5 amu
43. Formula mass of potassium sulphate (K2SOx) is:
(a) 174 amu (b) 164 amu
(c) 154 amu (d) 144 amu
44. The molecular mass of nitric acid (HNOs) is:
(a) 65 amu (b) 63 amu
(c) 62 amu (d) 60 amu
45. The removal of an electron from an atom give rise to:
(a) cation (b) anion
(c) molecule (d) molecular ion
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46. After gaining one electron chlorine atom becomes:
(a) cation (b) anion
(c) molecular cation (d) molecular anion
47. Charge on an atomis:
(a) positive (b) negative
(c) neutral (d) none of these
48. Point out mono atomic molecule:
(a) He (b) Ne
(c) On (d) Os
49. _Allof the following are tri-atomic molecules except:
(a) Os (b) H20
(c) CO (d) CO2
50. Which one of the following is a diatomic molecule:
(a) COz (b) HCI
(c) H20 (d) CHa
51. Example of diatomic molecule is:
(a) Os (b) H20
(c) He (d) COz
52. Which one of the following molecules is not triatomic?
(a) CO2 (b) He
(c) O2 (d) H20
53. Which one of the following is polyatomic molecule?
(a) H280+ (b) CO2
(c) H20 (d) CO
54. Gram atomic mass of hydrogen is:
(a) 1.008 g (b) 2.016 g
(c) 1.008 amu (d) 2.016 amu
55. One gram molecule of sulphuric acid (HzSO.) is equivalent to:
(a) 98 kg (b) 89 amu
(c) 98. amu (d) 98g
56. The molar mass of KzSOs is:
(a) 174g (b) 98 amu
()9.8¢ (4) 9.8 amu
57. The molar mass of nitric acid (HNOs) is:
(a) 63g (b) 63 mg
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(c) 63 amu (d) 63 kg
58. Molar mass of HsPOs is:
(a) 98 gmol* (b) 100 gmol*
(c) 63 gmol* (d) 174 gmol*
59. The symbol of Avogadro’s number is:
(aA (b)Z
(Na (d) Ay
60. How many numbers of moles are equivalent to 8 grams of CO2?
(a)0.15 (b) 0.18
(c) 0.21 (d) 0.24
61. - -- number of moles are equivalent to 11 grams of COz.
(a) 0.15 (b) 0.2
(c)0.25 (a) 0.3
62. The number of moles in 29.25 g of NaCl is equivalent to:
(a) 0.25 (b) 0.21
(c)0.50 (d) 0.75
63. The number of moles of carbon in 4 grams of coal is:
(a) 0.25 (b) 0.33,
(c)0.50 (d) 0.75,
64. The mass of one mole of water is:
(a) 18. amu (b) 18g
(c) 18 mg (d) 18 kg
65. Which one of the following pairs has the same mass?
(a) 1 mole of CO and 1 mole of Nz
(b) 1 mole of CO and 1 mole of CO2
(c) 1 mole of 02 and 1 mole of Nz
(d) 1 mole of O2 and 1 mole of COz
66. 12g of carbon contain atoms:
(a) 6.02 x 107 (b) 12.04 x 1078
(c) 1.672 x 1074 (d) 18.06 x 1073
67. Which one of the following pair has the same number of ions?
(a) 1 mole of NaCl and 1 mole of MgCl,
(b) % mole NaCl and % mole of MgClz
(c) 4 mole NaCl and 1/3 mole MgCls
(d) 1/3 mole NaCl and % mole MgClr
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