Ay Chapbor 3: Chonieat cqultbsivry _ for peaction: oA + bb ec tal, at “seals one vans = ECD > A | — Tp 2 tactions are adoled © P [Hd i oS CHT ke HArc 2 A +c fs Solubility Fodct] ub Higa.Chs (s) = Ha, : = Ksp = [Hy J Lad 2 The snabler Kp], the harder to dissouak » bigger ee | phsp = - dog Ksp Sheng of Ag af Weak atid «HA ( Kad small) A HA + Ho = Hyot + A fH ‘ jas tho, HNN Yale CL the solid is stable IEE BOSSE I CHAS rns Weak base: B (Kb t& small Bt Ho SS BHT ror | +p 7 TF ko= feH'S gor" Uo hcuys° {83 alwovys fa. Kb = kw sag Scanned with CamScannerawe VN pH + pOH = ff af 6° eee -tHy)»Ww! pit = — og HF gary gt pet -6 — oF THIS 410: Ha H' + : fy 5407 551 6.40 Ho = Ht + OH {3 2 > ty:tass Lot J + a Kw > fH}. 50 F Fay => pHs Wit base sobuhon. 7 4 Kw 5 = 40 a Se = Lou's Case) * Far = for] + poH = pH = 44 - pott By Chapter 4: Monoprotic A-B8 Equilibria Fc 9 Tia do 2 Gna Fo FU Sut pho = ~ fog Ka, ka = 4g” ot Scanned with CamScanner\t Bufprs (Din) | A Haden = Maslin Cr 4) for aud; HA = = (ie a ple yo | “a 2 Ps +o for base: a a . ‘o 4 He ‘4 | aaa =» - f C; Chior 8 fbb ie tic, Systens fi be Morore ‘ts ; , tng + ho Wh (HDF tf ‘ein + ie > 4 tors, ~ Dione MES _— Hy wed ete dius tly told = ad i ee * LA” = ine + hot! + kaBe Kiko Ree We oe RGR — Triprohic Systems. : - - cHal ob LHAd CHAI @ When pH T ao a Scanned with CamScannery Y SA | Ved SB & Sh | AL Sb ( before. £9. 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HA ey ural” ott of {at Fe H 2 50 wie ate Ky and ins: castors 8 UT Bar Ee - kw 4h foated o» monobasic, wi Fah fy Ky Ka, Ke HAY” [ HA | HAT I Pp T* Llphy +t) ee p= Lint) Scanned with CamScanner( Tiraion ww Dy, Sy Systons of Beda oe Gt) Mr Z 0 ot i 9 wr bli Vez At of? aye 20807 Hh exes i OD fey Ha: on wt + ne + Heo Hf. waar OS ae je Ne: © ae mare plas toa ate i ow cK Cae ee ph > phos * “con's - Ab EQ r Vo: 0) is (aE 4 (par the) wt yiore : Fo: . 7b) ot Ve. i £Q put ie: G) p au ~ tne Pe PD te tg—Ie ao «ae. z Scanned with CamScanner| WNC oxcons (6) ye apd i sf comenianion HCP pxcors Chapter Ts EDIA Traction {Edi DA BOTA Cig ¥2") 1, 20 (0B) | is = a5 (alt) 7 wdoslt ae phy 2 2 (calt) Hecehy nce, oa @ Nunca oft = 208 ce : pts = 6% cnet" od” = curs pe 2 Apart N cnet’) Ceoras af : Eka ks Poke ke - Oe TH fi + WS ah tet ey k3 Rhee 7 EDTA couplexte fonmalton anata : ; were Yo MERE Mtoe EDTA => my) p's cnlakonal formation cnsfot a 7 VEorA ~ Region 1: before EP ro" is excas - % te EMMS = Im") excess 4 Region 0: At EP 4 a a oe My" yes Met BOTA kf hf {My Few L x 3 “ 2 LM"S g Scanned with CamScanner209999900 900009999929999990 B= 9649 aot C fone _____— (BP = Srandartpcbonted (Ans 4 = 4) $65 je-—— = ——— z = Gt ps fatale yy A Cw. L pe Fare, geuisn Scanned with CamScannerle: - G0 + be tate = 200" ito. eg OTHE pp CORB. piy't Pee aes a rE og ie ©) Phat ann Rigg Bee fa a ot fig TE as ——— G Example — - 4 fe Cwtia) cst + be Ps Cqaa)- on » be 0706946 tp > Be fy ~ 2 ty Tiere 6 S Oe fog fr, . =i eles eg oC re a 9 = at eae) : Y $by055 COS _ FF (oo Spr 5 ae ~ PGs O -E>B _ ‘es = ara — OQ . Mog st Se BHT > Mn HPD, B+ 2° 4. 008 & Log we UTE g ) a0. Scanned with CamScanner= Ondation-[Roduction E — Chi $l an $4. Mose Conopis = eee fee takes 0 (be eluerd | Redluctous — ies ©. belied) — eR vO a 3.4. Sfardard er ) The ate Rom) Fhe chondasel cicinle phoist (ED + Loy le __ Stondouel_ conditions: of*°C, Cus 10; OP shar © 2099 Sab7458 as Eun, 20-4 : =o 93S a Fx,” | & ly 9 ea ae 10 K = 0,083 joo GOS = sone io. SS. Ct “att 2 5,083 Lie af aoe 0 U Bom Bt GQ", % of E poi Vo (ttt) Scanned with CamScanner| F: EDTA Thotws | $4 Metal - Chelate (orplexos $2 ETA ( Hy) He) | egy = BERR cut} + {ASE t + ERABE ty" 3 pepTAl FA.2 EDTA Complnes . nv ae aw + yt os nytt ag &: hag oe bat : pay? J (@ wee OT yt = vo > ky s Fy. olyie, TAT Precptedion Tihtation , 2 Ambn = — eee ee, , kes ek c * = nba Fhe, te water . + ut be byt + Hd & fa F | + = Hy?* + HG (@) Common Un effect , Cig (on), (0% 4G 4 Con a F Fes = ay lo | Fes = (427 x wi 62> 23.0” ~~) Scanned with CamScanner| 2 + Strongths of olds 2 Bases © Weak ootds x bases _ CHtCAT ka - “ee ua THA] aod dlissoovadion const CBHtTEOH de ce] base hydrolya's const = > 8 + HO Bt ae k= 2 i s @ Conjugate actols & bases Ha Sat wig-. put, = Hoy _ ai AT + HO <= HA_+ 0H > ty L Ha LAW cmjugate pr has [Fab > Lov =A] ee —————— + er 4% MONOPROTIC- ACID-BASE. \ i 4-4 Shong acids £ bases n HBr Ht Br NU pOSDSSESS HECKEKEKMK MKC COMO Me Scanned with CamScanner