smhis& ~ ett eee (202 ) When oxidation is complete, the solution is acigited ce eS and the liberated iodine is titrated with standa: 4 lay A * NaOlI + Nal +2HCI-2NaCl+ 1,+H, 1 lit of 0-1(N) Iodine =1 lit. of 0-1(N) Na,S,O, soln. =HCHO/2 x 10 = 1-5013 gm HCHO ic il lution of HCHO is procedure is applicable only to dilute so} oe mm. ether aldenrde= ‘and most ketones must be absent. PROCEDURE : Preparation of Formalin soln. ° Weigh out accurately about 4.0 sm of Formalin sotn, (5x) iato a 250 ml volumetric flask and dilute with distilled water to mark, Mix well. Preparation of standard K,C#,O, soln. : / Weigh out accurately 1.225 gm of K,Cr,O, in a 250 m) volumetric flask and make up the volume with distilled water upto the mark, Preparation of lodine 10! O.1N) Dissolve 12.7 gm of AK. sodine in 20 gms of iodate-free potassium iodide to 1000 m! Preparation of Sodium Thisrdphate soln O.1N approx.) : Dissolve 12.5 gm of sodiem thiownlphate in $00 ml of distilled water, Preparation of Starch sola Make a paste of | gm of soluble stare and pour it into 100 ml of boilieg w add 2-3 gm of KI (2-3 drops of © solution more stable) Estimation of Formaldebide. Transfer 25 ml of the Formalin sol > _ flask by a pipette and add $0 zal ‘fa lanee toa 250 ml conical introduce ca. (N) NaOH solution dropwise! solution, Immediately pale yellow in colour. Fopwise until the liquid becomes After !0 minutes, acidify with ca. 2(N) HCI and tiernic the ora odie with standard 0.1 (N) Na,S:0, solution using starch Carry outa blank titration to 1,-solution and also to deduce the set wok soln, equivalent to the sample. Tablel: Weight of K,Cr,0, : Tablo Il Titration of excess lodine b fable Ill : Blank titration : Tablo IV: Standardisation of Ky Or. S witha Jittle cold water boil for 1-2 minutes and mm added will render the ‘mine the normality of the lume of stantdard Na,S,O, y standard Na,S.0, soln: 10+ selution =(203 ) ] Caleulations : 1 ml of 0.1 (N) I, =1 ml of 0,1 (N) Na,S,0, 0001501 gm of HCHO % of HCHO =(¥1— V2) x Nx Mx 100 | W «2x 1000 where, V,= Vol. of Na,S..0, solution used for blank V,=Vol, of Na,S,0, solution used after reaction of sample with iodine solution. | N=Normality of Na,S,O, solution | M-=Mol. wt. of formaldehyde (30.026) | We Wt. of the sample in gm. | N.B. The normality. of Na,S,0, solution can be determined by any of | the following methods : {] (a) by standard K,Cr,0, soluiion : Dissolve about 4.904 gm (weighed accurately) of K,Cr,0, in a 1 litre volumetric flask and make up the volume upto 1000 ml. ‘Take 100 ml distilled water in a $00 ml conical flask and dissolve in it 3 sm of iodate free KI and 2 gm of pure NaHCO,. Add 6 mi conc. HCI slowly. Then run 25 mi of standard K,Cr,0, solution, Mix well and allow to stand for § minutes, Dilute the solution upto 300 ml. Titrate the liberated iodine with, Na,S,0, using starch as indicator. Calculate the normality of Na,S,0, by using the relation : 1 ml (N) Na,S,0,= 0.04904 gm of K,Cr,0;- | (b) by standard KIO, solution 3.567 gm (weighed accurately) of KIO, in a Dissolve about 1 Titre volumetric flask and make up the volume. "Take 25 ml of the iodate solution in a 500 ml conical fiask and add 2em | | of iodate free KI and 5 mi 2 (N) H,SOq allow to stand for 5 minutes, Dilute | the solution upto 300 ml by water. Titrate the liberated Ty with Na,$,0, solution using starch as indicator. Calculate the normality of Na,S,0; 1 ml (N) Na,S,0, = 9.03567 sm of (c). by standard KBrO, solution : * em of KBrO, in a 1 litre volumetric flask and make Up led water. using the relation : 10;. Dissolve 2.784 the volume upto the mark by distill ‘2 500 ml conical flask, add 1.5 2m tand for 5 minutes. Dilute , using starch Take 25 ml of the iodate solution in 2 of KI followed by 4-5 m the solution upto 300 m as indicator. Calculate the normality of Na,S,0; 1 mi (N) Na§,0, = 1 of 4 (N) HCI and allow to s! 1 Titrate the Tiberated iodine with Na, by the following relation = 02784 gm KBrO,,