GAUT UTENG PROVINCE EPORUC OF SOUTH AFRICA GAUTENG DEPARTMENT OF EDUCATION PREPARATORY EXAMINATION 2017 10842 PHYSICAL SCIENCES: CHEMISTRY SECOND PAPER TIME: = 3 hours MARKS: 150 15 pages + 4 information sheets + 1 answer sheet PHYSICAL SCIENCES: Papr 2 1M (AO A 10842E X10 EN P10.PHYSICAL SCIENCES: Ca (Second Paper) 1084217 GAUTENG DEPARTMENT OF EDUCATION PREPARATORY EXAMINATION PHYSICAL SCIENCES (Second Paper) TIME: 3 hours: MARKS: 150 INSTRUCTIONS AND INFORMATION 1. This question paper consists of 9 questions. Answer ALL the questions in the ANSWER BOOK. Start the answer to each question on a NEW page. Number the answers correctly according to the numbering system used in this question paper. Leave ONE line open between sub-questions, for example, between QUESTION 2.1 and QUESTION 2.2. You may use a non-programmable calculator. You may use appropriate mathematical instruments. ‘You are advised to use the attached DATA SHEETS, Show ALL formulae and substitutions in ALL calculations. Round-off your final numerical answers to a minimum of TWO decimal places. Give brief discussions, et cetera where required. Write neatly and legibly. Detach the answer sheet for Question 4.3.1 and hand it in with your ANSWER BOOK. PTO.PHYSICAL SCIENCES: CHEMISTRY (Second Paper) 10 QUESTION 1: MULTIPLE-CHOICE QUESTIONS Four options are given as possible answers to the following questions. Each question has only ONE correct answer. Write only the letter (A-D) next to the question number (1.1~1.10) in the ANSWER BOOK, e.g. 1.11 D. 1.1. Which ONE of the following Is the correct IUPAC name for the structure low? Hy a CH; A 2-ethyl-2-methylpropane B 3,3-dimethylbutane C — 2,2-dimethylbutane D — 2-methylpentane @) 1.2 Which ONE of the following compounds is a possible product after the addition of Clz to but-1-ene? A CH;CH-CH,CHCIa Bo CH3CHZCHCICH,Ct C CICH,CH»CH2CH,CE DD CHsCHZCCLCH3 (2) 1.3. The rate of a chemical reaction is increased when the surface area of the reactant is increased. This change in the rate is due to the ... ‘A increase in the density of the reactant particles. B increase in the concentration of the reactant. C __ increase in exposure of more reactant particles to a possible collision D alteration of the electrical conductivity of the reactant particles. 2) 1.4 Which of the following is the strongest oxidizing agent? A Agtte = Ag Et= 40,80 B Pb*+2e = Pb B= 0,13 C NM +26 # Ni Et -0,27V BD sn*+#2e @ Sn E’= 012V (2) PTO.PHYSICAL SCIENCES: CHEMISTRY. (Second Paper) 84217 4.5 Consider the following results of experiments. Experiment 4 Reactants Powdered Cu and HCI ‘Temperature 20°C. Concentration of 0,6 mokdm® HCI Acid Rate Which one of the following factors would account for the lower rate in Experiment 1? A Temperature B Concentration of acid C Surface area of Cu D Nature of reactants (2) ‘The four graphs shown below were obtained from experiments involving nickel carbonate and hydrochloric acid of different concentrations. The rate of the carbon dioxide produced was measured. Which ONE of the graphs shows the reaction that had the most concentrated hydrochloric acid? Volume of COz (cm*) Time (8) (2) PTO.WW 18 1.9 1.40 PHYSICAL SCIENCES: CHEMISTRY’ (Second Paper) 10842117 ‘The quantity / quantities that remain constant in all oxidation-reduction reactions is/are ... A charge only. B mass only. C both charge and mass. D concentration of reactants. @) A student wishes to prepare approximately 100 cm’ of an aqueous solution of 6 mol-dm”® HCt using 12 moldm* HC#. The correct procedure to follow is to add 50 cm’ of... A 12 mol-dm’S HCt to 100 cm? of water. B 12 mol-dm® HCe to 50 cm* of water. © water to 50 cm* of 12 moldm® HCt. D_ water to 100 cm’ of 12 mol-dm* HCt, @) In the Haber process, a catalyst is used. The catalyst ... A increases the kinetic energy of the reactants. B changes the AH of a reaction. © provides @ reaction path with a lower activation energy. D decreases the potential energy of the products. 2) The dehydration of butan-2-0l is represented below. Compound ¥ is one of the products. HW ES ees ott Y # Which ONE of the following is the correct condensed structural formula for compound ¥? A HyxC—CH==CH—CH, Bo HyxC——~CH,—CH, CH, © HyC—CH,—CH,—CH,-OH ii Dye —C-—cH,—cHy (2) {20} PTO.PHYSICAL SCIENCES: CHEMISTRY {Second Paper) 10842/17 QUESTION 2 24 22 2.3 24 25 26 The boiling points of organic compounds A, B, C and D, are shown in the table below. Organic compound | Boiling point | Condensed formula ec) A [119.3 CHsCH2CH2CH(OH)CHs B i 99 ‘CHsCH,00CCH;CH3 c | 103 (CH3CH,CH:CH;CHO D | 187 CHsCH2CH2CH,COOH Define the term homologous series. Name the homologous series to which each of the following compounds belong. 224 B 222 C Organic compound A is dehydrated during an acid catalysed reaction to form pent-1-ene. Write down the general formula of the homologous series of this product. Write down the IUPAC name for organic compound D. 2.5.4 Willthe boiling point of the next member in the homologues series of compound D be HIGHER THAN, LOWER THAN or EQUAL TO that of compound D? 2.5.2 Fully explain the answer to Question 2.5.1. Organic compounds consist of different types of isomers. 2.6.1 Define a positional isomer. 2.6.2 Draw ONE positional isomer for organic compound A. 2.6.3 Write down the IUPAC name for the isomer drawn as the answer to Question 2.6.2. (2) (1) a (1) (2) 4) (3) (2) (2) (2) 17] PTO.PHYSICAL SCIENCES: CHEMISTRY (Second Paper) 10842/17 QUESTION 3 3.1 Leamers prepare an organic compound (used as banana flavour in milkshakes and ice creams), by mixing 3-methytbutan-1-ol and ethanoic acid in a test tube. 3.1.4 Draw the structural formula of the product of this reaction. 8) 3.1.2. After the reaction in Question 3.1.1 is complete, the leamers pour the contents of the test tube into some water in a beaker. What is. the reason for pouring the mixture into water? (ty 3.1.3 Name any TWO safety precautions that should be taken during the preparation of the ester. (2) 3.2 3.2.1 Hex-t-ene is mixed with water during a chemical reaction under specific reaction conditions and an alcohol Is formed. Write down the IUPAC name of the major product that is formed during this, reaction. (2) 3.2.2 Name the type of reaction described in Question 3.2.1 a) 3.2.3 Name TWO reaction conditions for the reaction in Question 3.2.1. (2) 3.3 The compound C(CHs);OH and hydrogen chloride react. 3.3.1. Draw the structural formula of the organic product formed, @) 3.3.2 Name the products of the reaction. @) PTO.3.4 PHYSICAL SCIENCE: CHEMISTRY (Second Paper) 10842/17 Octane and propane are produced in industry by the thermal cracking of fonger chains of alkane molecules, as shown in the equation below. CrsHa2>X+CaHo+ Cote 0 No catalyst was used in this reaction. 3.4.1. Name TWO reaction conditions needed for thermal cracking in REACTION I. ‘Compound X can also be produced in reaction I! as shown below: —-- (i) C2HsOH(g) S815 X+H,0 AH = #45 kno!” 3.4.2 Identify X. 3.43 Name the type of elimination reaction that occurs in REACTION Il. 3.4.4 Define addition polymerization. 3.4.5 Compound X reacts to form a polymer. Write down the name of this polymer. @) (4) (1) (2) (4) [23]PHYSICAL SCIENCES: CHEMISTRY (Second Paper) 1084217 QUESTION 4 4.1 Consider the following potential energy diagram for a reversible reaction. Progress of the reaction For the reverse reaction, write down the value of the ... 4.1.1 activation energy. ay 4.1.2 heat of reaction. a 4.2 Below is the Maxwell-Boltzman distribution curve of the distribution of the kinetic energy of molecules at two different temperatures. Number of molecules Energy E, 4.2.1 What does the area under both graphs, A and B, to the right of the line labelled Ea represent? (1) 4.2.2 One of the reactions takes place at a high temperature. Which ONE of the graphs, A or B, represents the high temperature? (1) 4.2.3 Explain the answer to Question 4.2.2 in terms of the collision theory. (4) PTO.PHYSICAL St (Second Paper) NCES: CHEMISTRY 10842/17 4.3 The data in the table below indicates the changes in volume of N.Os recorded at different time intervals. | oH T ae | 0 100 200 300 | 400 500 600 700 800 | Volume | / N:Os | 0,100 0,081 | 0.068 | 0,054 | 0,044 | 0,035 | 0.029 | 0,023 | 0.019 fem’) | L l | 4.3.1 Use the table above to draw a graph of the results, Use the attached graph on the ANSWER SHEET at the end of the question paper. (5) 4.3.2 Define the term reaction rate. (2) 4.3.3 Calculate the rate of the reaction at t = 240 s. (3) (18) QUESTION 5 An equilibrium reaction for the decomposition of a reddish-brown ‘substance, AOz, is given below. Bath products are colourless. 4AQzq) = 2AzOxq) + Ox Brown Colourless Initially 2,0 mol of AjO and 1,0 mol of O2 are present in 1,0 dm? container. Only 10,0 % of the AOz decomposes at equilibrium. 5.1 Define the term dynamic equilibrium. (2) 5.2. Use the information above to calculate the equilibrium concentration of each species. CS) 5.3 The volume of the container in Question 5.2 is now reduced to 0,5 dm’, while the temperature remains constant. 6.3.1 What colour change is observed? Write only BROWN or COLOURLESS. ay 5.3.2 Use Le Chatelier's Principle to explain the observation made in Question 5.3.1 (3) 112} PTO.PHYSICAL SCIENCI CHEMISTRY (Second Paper) 10842/17 QUESTION 6 6.1 Define an acid according to the Bransted-Lowry theory. (2) 6.2 Anacid-base reaction is shown below. H,PO; + HAsO} — HPO? + HAsO; Write down the name of the conjugate base of H.PO;. a) 6.3 In attitration, a 20 om? potassium hydroxide solution was neutralized by 15 cm’ dilute sulfuric acid with a concentration of 0,1 moldm’. H2SOx + 2KOH > KSO, + 2H20 6.3.1 Which indicator will be most suitable for this titration? Choose from: phenolphthalain methyl orange bromothymol blue (1) 6.3.2 Give a reason for your choice of indicator in Question 6.3.1. 2) 6.3.3 Calculate the concentration of the potassium hydroxide solution. 6) 6.3.4 Calculate the pH of the potassium hydroxide solution in Question 6.3.3. (6) 6.4 The salt ammonium chloride (NH,C1) reacts with water. NH; + HzO > NHy + H;O* 6.4.1 What do we caill this type of reaction? (A) 6.4.2 Whatwill the approximate pH of the salt solution be? Choose from EQUAL TO, SMALLER THAN 7 or GREATER THAN 7. (1) 6.4.3 Give a reason for the answer to Question 6.4.2. (1) [49] PTO.PHYSICAL SCIENCES: CHEMISTRY (Second Paper) 10842/17 QUESTION 7 A metallic object, to be plated with copper, is placed in a copper(!!)sulphate solution (CuSO,). ‘copper metallic object CuSO, solution 7.4 Identify which electrode will be the anode. (1) 7.2. \dentify the terminal to which the object must be connected. ay 7.3 State whether the copper ions are oxidized or reduced. (1) 7.4 Write down the half-reaction that occurs at the cathode. ( 7.5 _ Explain why the power supply must be a DC and not an AC power source. (3)QUESTION 8 84 82 PHYSICAL SCIENCES: CHEMISTRY ¢ The standard cell potential produced by a voltaic cell consisting of a platinum electrode in contact with a solution of Co* ions and a silver electrode in contact with a solution of Ag’ ions, is 1,01 V. 8.44 8.12 8.13 Write down the cell notation of the reaction. Identify the oxidising agent. Write down the reducing half-reaction. An unknown metal, M, is connected to a hydrogen halt-cell as indicated below. He (g)—> Metal X. H’ (aq) 8.2.4 8.2.2 8.23 8.2.4 8.25 The metal, M, is placed in a solution of its salt, M°*(aq). M® (aq) What is the purpose of a standard hydrogen half-cell? Name the metal labelled X in the hydrogen half-cell. State ONE function of the component labelled A. The reading on the voltmeter is 0,74 V. Identify the unknown, metal, M. Use information from the Table of Standard Reduction Potentials to obtain the overall balanced redox reaction for this cell, cond Paper) 10842117 3) (1) (4) (1) Q) a) 2) @) PTO.PHYSICAL SCIENCES: CHEMISTRY (Second Paper) 10842/17 8.2.6 How will the reading on the voltmeter change with an increase in the concentration of the M™* ions? Write only INCREASE, DECREASE or HAVE NO EFFECT. Give a reason for your answer. 2) 8.2.7 Write down the reading on the voltmeter when the reaction has reached equilibrium. (1) 8.2.8 Name TWO potential hazards associated with the use of a hydrogen half-cell. (2) [18] QUESTION 9 The flow diagram below shows the main steps in the industrial preparation of two important solid fertilisers. From Air SASOL | i [ Nitrogen Hydrogen Haber process HpSO, £. Fertiliser A }-————- Ammonia (NHs) p Emenee YT NO [+] Brown gas le —] Liquid c | + Fertliser B 9.1. Write down the: 9.1.1 Balanced chemical equation for the formation of the brown gas @) 9.1.2 NAME of process Y (1) 9.1.3. Chemical FORMULA of liquid C a)9.2 O38 a4 PHYSICAL SCIENCES: CHEMISTRY (Second Paper) 1084217 Give the chemical FORMULAE or NAMES of fertilisers 921 A. ) 9.2.2 8. (1) Mention TWO ways in which the use of fertilisers cause damage to rivers and dams. (2) A farmer stores fertilizers with NPK ratios 4:5:8 and 13:5:9, ‘The farmer wants to grow tomatoes and other fruit. 9.4.1 Explain the meaning of NPK ratio. ty 9.4.2 Which ONE of these fertilizers is more suitable to grow fruit? (1) 9.4.3 Give a reason for the answer to Question 9.4.2. @) 9.4.4 After a soil analysis, it is found that the soil has a shortage of potassium. The following two fertilizers are at your disposal. Fertilizer D: 4:8:8 (25) Fertiliser E: 13:5:0 (20) ‘One of these fertilizers must be used to increase the potassium content of this soil. By means of a calculation determine which of these two fertilizers, D or E, will be the most suitable. (3) 116) TOTAL: 150 £NDPHYSICAL SCIENCES: CHEMISTRY {Second Paper) 10842/17 | * | DATA FOR PHYSICAL SCIENCES GRADE 12 PAPER 2 (CHEMISTRY) GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 42 VRAESTEL 2 (CHEMIE) TABLE 1: PHYSICAL CONSTANTS | TABEL 1: FISIESE KONSTANTES NAMEINAAM SYMBOL/SIMBOOL | VALUE/WAARDE ‘Standard pressure : : 4,013 x 10° Pe Standaarddruk e dete Wolar gas volume at STP a Seat Molére gasvolume by STD ‘Standard temperature 73 Standaardtemperatuur a fee i ject Chalye oer e A,6x 10°C Lading op elektron A i if ncondry ¢ conten Na 6,02 x 10” mol" Avogadro se konstante TABLE 2: FORMULAE / TABEL 2: FORMULES m m net M nN n= Vu H = =k OV, Me Ph alto} Ka = [Hg0" OH) = 1 x 10 atiby 208 K’ E8, = Esnode ~ Etnoco (Ete * Efsate ~ Etnose Orlof Ek, = 6 ® pauctin ~ E" oxidetion JES, = Ease ~ Ete Orlof | Ee = ESasnnnerne~ Etancrg ane Eka = Eheceumset ~ Entre otges Beh lse Lae les cl se lone? D8e (kas B-8 Sz ese igs g sa or oe az st Sz Fee es EF es joo2 fos SH Bes ise ges |ez 2 se | sz | vz | ve | oz aes 5 2s met Mon ge ah isas | gas ee é oe x4 oz eh eb feel g | cs ros ras Bae aa ER | p28 les ae st ah eh sth ca 38 2 lems fezn [age sf iers | gag igs 3 oz | sh | oF | ce | ot a e 2 BSS ISSES28 ees iss & | et pect is Rdg S28 Res sb sit a sz ez8iecd il i 5 ey | ze a és Reseese=8 les ge | fi i i ey | ze J ane | s 35 \e | apa 8 bg gees ee RSE as 52 en S g\| ov | zz foe 7 Epeesee eee a . 2 é rae igs g> 8 e ES{ ss jer) i Fi tes veske3 | [pes se z (os | ov a oa | aos eee ces g a 3 est ses = ag oth eae 1 a | ce lake ena ieee sh vt oF i RSS 8>SiBSB Be ish | ae ees née isasleas s2§ zh or | oF so dR @<8 bee 888 fet eo | eo | eo | vo zo} P10. TABLE 3: THE PERIODIC TABLE OF ELEMENTS / TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTEIncreasing oxidising ability! Toenemende oksiderende vermoé PHYSICAL SCIENCES: CHEMISTRY (Second Paper) 10842/17 TABLE 4A: STANDARD REDUCTION POTENTIALS TABEL 4A: STANDAARD REDUKSIEPOTENSIALE Half-reactions/Haifreaksies Lee Fig)s2e = 2 +287 Co*+e & Co” | +1,81 HO: 42H" 420° = 2H,0 +47 MnO; +8H"+5e = Mn +4H.o | +1,51 Chig)+2e = 2Ct $1.36 nO} +14H" +60" 2Cr+7H0 | +133 Og) + 4H" +40 = 2H $4.23 MnO;+4H"+2e = Mn +2H,0 | 41.23 PE +20 = Pt +1:20 Bret) +20 = 28 +407 NO3 +4H"+3e 2 NO(g)+2H.0 | +096 Hg® +20" = Halt) +0,85 Agta = Ag +0,80 NO; +2H"+e = NOg)+H:0 | +0,80 Foto" » Fe” +077 Oxg)+2H" +26" = HO. +088 i420 # ar +054 Cute = Cu +052 80,4 4H"44e" = S+2H,0 +045 2H,0+0,+4e° + 40H | +040 Cu +26 = Cu | +036 S02 + 4H" +26° 2 S0{9)+ 2440 | +017 CM+e = Gu +016 Sn + 26° = Sat £016 S+2H'+26 = H,Sig) +014 2H +20 @ Hig) Fe" +3e" = Fe Por 420 = Pb Sni"+2e" = Sn Ne +26" & Ni Go" +20 = Co Cd" +20 = Cd Cte 2 ot Fe +20 = Fe Cr +30 = Cr Zn +26 & Zn 2H.O +260 = Helo) 20H | Ce +28 = Cr | Mnit +26" 2 Mn Att+3e = AL | Mg? #26" = Mg Nate = Na Ca¥ +2e° = Ca SP +20 = Sr Ba" +20" = Be Gs'+e 2 Cs Kite = K urs ui Increasing reducing ability/Toenemende reduserende vermos PTO.Increasing oxidising abitity/Toenemende oksiderende vermos PHYSICAL SCIENCES: CHEMISTRY (Second Paper) 10842/17 TABLE 4B: STANDARD REDUCTION POTENTIALS TABEL 4B: STANDAARD REDUKSIEPOTENSIALE Sot + aH +20 uF # 26° 2H,0 + 0, + 46 50, + 4H" + 46" Cu +e 1+ 26" Ox(g) 2H" + 2¢" Fo" +e" NOs + 2H +e agi +e Hae NOS + 4H" + 36° Br{O) + 26 Ptr +2e MoOz+ 4H" + 26" Ox(g) + 4H" + ae" cuOF + 14H + 66° Ctdg) + 26 MnO; + BH + Se Hy02+.2H" 426 coe eeeieelatnene le? wy] HUE URTENA DODD TAH HTDE AR ADAH HH HAHAH Eh Ne Mn cr Hi(g) + 20H" Zn cr Fe. cr ca Co Ni Sn Pb Fe a o) ere cu SOx) + 2,0 | cu 40H NO(g) + 2H,0 28r Pt | #1,20 Mn? +2H,0 | 2H,0 201 + 7H,0 2cr Mt + 44:0 21:0 oe 2F Increasing reducing ability/Toenemende reduserende vermos Pro.CHEMISTRY . 10842/17 ANSWER SHEET NAME: GRADE 12: QUESTION 4.3.1 Hand in this ANSWER SHEET with your ANSWER BOOK. | Tr | | im } I i ; 1 + T t Trt I T T [ fig tf pit i td 4 Lit T 1 T — t Tro I 1 Tet | 4 { { EEE EEE