CHEMISTRY PAPER -1 (THEORY) (Maximum marks: 70) (Time allowed: Three hours) {Candidates are allowed additional 15 minutes for anty reading the paper. They must NOT start writing during this time.) All questions are compulsory Question 1 is of 20 marks having four sub parts, all of which are compulsory. Question numbers 2 t0 8 carry 2 marks each, with two questions having internal choice. Question numbers 9 10 15 carry 3 marks each, with two questians having an internal choice. Question numbers 16 to 18 carry 5 marks each, with an internal choice. All working, including rough work, should be done on the same sheet as, and adjacent to the rest of the answer. The intended marks for questions or parts of questions are given in brackets [ ]. Balanced equations must be given wherever possible and diagrams where they are helpful. When solving numericat problems, all essential working must be shown. Jn working aut problems, use the following data: Gas constant R = 4987 cal deg! mot! = 8314 FE! mot! = 0.0821 din’ atm Knot! 11 atm = 1 das aim = 101-34, 1 Faraday = 96500 coufombs. Avogadro's mumber = 6023 «10. ‘Question 1 (a) Fill inthe blanks by choosing the appropriate word/words from those given inthe [4x1] brackets: (iodoform, volume, mass, haloform, gram equivalent, chloroform, carbylamine, sp'd’, high, coke, d’sp*, low, gram mole, carbon monoxide) (@ Equivalent conductivity is the conducting power of all the ions furnished by one of an electrolyte present in a definite of the solution. (ii) Bleaching powder, on treatment with ethanol or acetone gives This is an example of Gii) Outer orbital complexes involve hybridization and are spin complexes. (iv) Zine oxide is reduced by at 1673K to form zine and This Paper consists of 7 printed pages and t blank page. © Copyright reserved.(b) Select the correct alternative from the choices given: [4x1] @ Gi) Gi) tiv) ‘The packing efficiency of simple cubic structure, body centered cubic structure and face centered cubic structure respectively is: (1) 52-4%, 74%, 68% (2) 74%, 68%, 52-4% (GB) 52-4%, 68%, 74% (A) 68%, 749, 52-4% ‘When acetone is treated with Grignard’s reagent, followed by hydrolysis, ‘the product formed is: U) Secondary alcoho! (2) Tertiary alcohol G)_ Primary alcohol @) Aldehyde ‘Which of the following electrolytes is least effective in causing flocculation ‘of positively charged ferric hydroxide sol? (D KalFe(CN)o] Q) K:CrOy (GB) KafFe(CN)o) 4) KBr ‘On beating an aliphatic primary amine with chloroform and alcoholic potassium hydroxide, the organic compound formed is an: (I) Alkyl isoeyanide 2) Alkanol 3) Alkanal (4) Alkyl cyanide (©) Match the following: [4x] @ a Gi) (iv) 1220-8624. Silicon and phosphorous (a) Acetaldehyde lodoform test. (b) Xenon hexafluoride Arhenius equation (©) _naype of semiconductors Distorted octahedral structure (@)_Frequency factor(d). Answer the following questions: [42] (i) What is the common name of the polymer obtained by the polymerization of caprolactam? Is it addition polymer or condensation polymer? (ii) Why Zn* ions are colourless while Ni? ions are green and Cu** ions are blue in colour? (iii) ‘The molar conductivity of NaCl, CHyCOONa and HC! at infinite dilution is 126-45, 91-0 and 426-16 ohm cm* mot! respectively, Calculate the molar conductivity (Az) for CHsCOOH at infinite dilution, (iv) Identify the compounds A, B, C and D. C,H,COOH 4A“, BBB SNH, ‘Question 2 (2) (a) Anelement has atomic weight 93 g mo" and density 11-5 gem If the edge length of its unit cell is 300 pm, identify the type of unit cell. (Na = 6:023%10 mo) (b) Calculate the radius of copper atom, The atomic weight of copper is 63-55 g mot. It crystallises in face centered cubic lattice and has density af 8-93 g cm’ at 298K, (Na = 6-023%10" mot) Question 3 2) Complete and balance the following chemical equations: © Pes NaOH + Ho —_heat + Inert atm. @— Cus HNO; —> + + ail. Question 4 p21 (i) Write the chemical equation for the reaction of glucose with bromine water, Gi) Write the zwitter ion structure of glycine. ‘Question § (2) @ How do antiseptics differ from disinfectants? (ii) Name a substance that can be used as an antiseptic as welll as a disinfectant. 1220-8624 ‘Turn over— ws mie < Lured shi come erserk w/ me ~~Why he kinda ...@oo ASA Sarre, OFFERING FOR The INVOCATION OF boy, NOT JUST ANY Luyp OF FLESH AND BLOOD WILL Do,a = —...— ae ai ee a wl NVWAnything's a dildo if ur Le). THE GOLDEN AGE (D: END forties) ey tap that too