Professional Documents
Culture Documents
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THE HANDBOOKOF
GLAZE RECIPES
THE HANDBOOKOF
GLAZE RECIPES
Linda Bloomfield
HERBERT PRESS
Bloomsbury Publishing Plc
www.bloomsbury.com
BLOOMSBURY, HERBERT PRESS and the Herbert Press logo are trademarks of
Bloomsbury Publishing Plc
Linda Bloomfield has asserted her right under the Copyright, Designs
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Contents
Acknowledgements
Introduction
100
3: Earthenware glazes (cone 06-03)
101
Cone 04 matt glazes 1060-1100°C (1940-2012°F)
104
Cone 06-03 shiny glazes 990-1100°C (1814=2012°F)
Glossary Lay
Bibliography 141
Index 142
Glaze is made from three essential components: silica, the glass former; fluxes,
which melt the silica at a temperature attainable in a kiln; and alumina, a stabiliser
or stiffener, which prevents the molten glaze from running off the pot. There
are many kinds of flux for use at various temperatures. Low-temperature fluxes
include lead, sodium and boron frits. Higher-temperature fluxes include feldspar,
containing sodium, potassium and sometimes calcium, which strengthens and
stabilizes the glaze. Secondary fluxes such as magnesium (present in talc and
dolomite) or barium carbonate can be added to produce matt surfaces. Alumina
is usually added to glazes in the form of clay. It helps stiffen the glaze and makes it
more viscous when melted.
Mirka Golden-Hann, interactive colour play, porcelain bowls installation, Salisbury Arts Centre,
2012. Photo: by the artist.
SECTION 1: GLAZING — AN OVERVIEW
Silica is available in the form of powdered quartz or flint, ground to 300s mesh size.
It is also present in other materials including feldspar, clay, talc and wollastonite.
Clay can be added in the form of china clay, ball clay, red earthenware clay or
bentonite, and is useful for suspending the glaze particles in water and adding
strength to the raw glaze.
Secondary fluxes can be added to a glaze to increase the gloss (zinc oxide, borax
frit) or make the glaze matt (whiting, talc, dolomite, barium carbonate). Calcium
is an important ingredient of glazes, a flux which also strengthens and stabilizes
the glaze. Calcium is found in whiting, limestone, wollastonite and dolomite.
Magnesium, present in magnesium carbonate, talc and dolomite, is used to make
satin matt glazes. While calcium and magnesium tend to mute glaze colours,
barium carbonate can be used to make bright turquoise and blue matt glazes.
Barium is toxic and can be replaced by strontium carbonate, which will give
similar effects in glazes.
Wood and grass ash can be used in glazes as these contain silica and fluxes as
well as other minerals including phosphorus and iron. Wood ash can be washed
to remove soluble alkalis and sieved through a 60s mesh sieve before use. Some
potters use locally found clays or rocks in their glazes. These must be crushed and
ground in a mortar and pestle or milled in a ball mill before use in a glaze.
11
12 THE HANDBOOK OF GLAZE RECIPES
Joanna Howells, Pillow Box, Chun glaze on porcelain, ht: 14cm (5%in), 2013. Photo Anthony Cutler.
Bone ash or calcium phosphate, which is made from calcined cattle bones, adds
streaking and opalescence to glazes. Large amounts of bone ash (more than 10%)
can cause blistering of the glaze. Bone ash is a major constituent of bone china.
Zinc oxide is used in crystalline glazes but has an adverse effect on some colouring
oxides, turning chromium oxide brow a.
12
The science of glazes
In the past, glazes were concocted by trial and error, by mixing various materials and
firing to see what happened. In the last century, the chemistry and structure ofglazes
has become more understood.
Most ceramic materials in the glaze melt are oxides (carbonates change to oxides
during firing and give off carbon dioxide). The most important ingredient is the
glass former, silicon dioxide, also known as silica or SiO,. In crystals such as quartz,
silica molecules take the form of tetrahedra lined up in rows. Each tetrahedron
has a silicon atom in the centre surrounded by four oxygen atoms, one at each
corner. Each oxygen atom is shared by two silicon atoms from adjacent tetrahdra,
hence the formula SiO,. When a glass or glaze melts, the silica molecules become
disordered, although they are still linked together in a three-dimensional network
of chains.
The behavior of glaze materials on melting depends on their chemistry and whether
they are acidic or alkaline. Non-metal oxides such as silica are acidic and have
the general chemical formula RO, (where R is the element). Most fluxes are alkali
metals, having the formula R,O (sodium, potassium) or RO (calcium, magnesium).
Alumina is amphoteric, neither acid nor alkaline, and has the formula ALOr Ihe
number of oxygen atoms bonded to each metal atom affects the way the metal oxide
reacts with the silica chains in the glaze.
In order to melt silica in a kiln, a reactive flux such as sodium oxide (Na,O) must
be added. When sodium is heated with silica, it reacts with the oxygen, breaks the
silica chains and causes the glaze to melt. However, sodium and silica alone make
sodium silicate, which is soluble in water and therefore not suitable as a glaze.
1/53
14 THE HANDBOOK OF GLAZE RECIPES
©. @. @.. e... ©,
This shows the structure of a glass or glaze. The silica tetrahedra are joined in a three-dimensional
network. The sodium (purple) atoms break up the chains, the calcium (green) atoms act as a
bridge between two chains and the aluminium (brown) cross-links the chains.
A third ingredient, calcium oxide (CaO) must be added to make a durable glass.
Calcium forms a bridge between two oxygen atoms in the silica chain, making the
glass stronger and resistant to attack by acids. However, most glasses are too runny
when melted to use as a glaze, and some alumina (Al,O,) must also be added.
The alumina cross-links the silica chains and stiffens the glaze. Alumina is added
in the form of powdered clay, which also helps to suspend the glaze ingredients
in water.
The transition metal atoms absorb particular wavelengths oflight. The colour we
see is the remaining light, which has not been absorbed by the metal atom. All
atoms have electrons spinning around the nucleus in orbitals. Each orbital can
only contain a sj ‘number of electrons and the lowest-energy orbitals are
THE SCIENCE OF GLAZES 15
&
e¢
ee ee
This is an image of asodium (Na)
atom. It has 12 neutrons, 11 protons «
and 11 electrons spinning in three Ae
orbitals around the nucleus. Only the & e
electron in the outer orbital takes
part in chemical bonding with other
atoms such as oxygen.
When metal atoms bond with oxygen, the electron orbitals change from spherical to
hybrid shapes and the molecule starts to look more like a blackberry on an atomic
level. The electric field around the metal atom is distorted and this alters the colour
of light absorbed. The colour will vary, depending on the number of oxygen atoms
and the shape of the electron cloud around the metal atom. Metal atoms can be in
fourfold tetrahedral coordination or sixfold octahedral coordination in a glaze.
In glazes, the colouring oxides can bond with the oxygen in the silica chains and
are also affected by the surrounding atoms such as sodium and aluminium. For
example, the colour of copper oxide in a sodium-rich glass is turquoise. In a glaze
however, the addition of alumina can cause copper oxide to show a green colour
instead. Another example is in pink glazes, or more specifically chrome-tin pinks.
Chromium oxide is usually green, but when combined with tin in the right glaze
base, the colour changes to pink. The colour will only be pink if the glaze is high
in calcium and contains no zinc or magnesium. The chromium bonds with the tin,
calcium and silica in the glaze to give a pink compound.
When transition metal oxides dissolve in the melted glaze, the resulting coloured
glaze is transparent. However, most commercial stains are prepared so that they
remain unchanged in colour when melted in a glaze. They are highly refractory and
remain suspended as small particles in the glaze, causing it to become opaque.
Colouring oxides
include cobalt,
Colouring oxides can be added to make coloured glazes. These oxides
change colour during
copper, chromium, manganese, nickel and iron oxides. They
whether the
firing according to the level of oxygen available in the kiln, depending on
ies (usually
kiln is electric or fuel-burning. They are added to glazes in small quantit
thoroug hly to avoid speckli ng.
less than 5%), though the glaze must be sieved
Cobalt
Cobalt oxide and carbonate produce a bright blue in glazes. Only a small amount
(0.1-2%) is required to give a strong blue. Cobalt can produce grey in combination
with nickel and purple with manganese.
Copper
Copper oxide and carbonate produce green or turquoise in oxidation or red in
reduction (0.5-3%).
Chromium
Chromium oxide produces green in oxidation and reduction (0.2-1%). It will
produce pink or maroon in combination with tin oxide (0.1-0.5% to 5% tin). If used
in glazes containing zinc oxide, it turns brown. Chromium oxide is toxic.
16
COLOURING OXIDES 17
Iron
Iron oxide is used to make tan yellow or rust brown in oxidation and celadon blue
or tenmoku black in reduction. It can be used in quantities from 0.5 to 15%. Yellow
ochre is a form of iron oxide. Iron oxide is present in many locally sourced ceramic
materials such as red earthenware clay.
Manganese
Manganese dioxide and carbonate produce pink-brown or dark brown in glazes
(1-15%). Manganese and a small amount ofcobalt give purple. Manganese is toxic,
particularly its firing fumes.
Nickel
Nickel oxide is used to moderate other colours but will also produce bright pink
and purple in barium-zinc glazes. Only a small amount (0.1-2%) is required. Nickel
oxide is toxic.
Vanadium
Vanadium pentoxide can be used in dry matt glazes (2-8%) to give a mottled
yellow colour. In transparent glazes it is yellow, green or muddy brown. Vanadium
pentoxide is highly toxic.
Opacifiers
Opaque white glazes can be made using tin oxide or zirconium silicate. These opacify
the glaze when used in quantities of between 5 and 15%.
Stains
Commercial stains are made using colouring oxides which have been stabilized by
being heated together with silica and opacifiers. They do not change on firing but
often lack depth of colour. They are used to make bright red or yellow glazes, which
cannot be made using colouring oxides.
Mixing glazes: weighing, sieving
half full of water.
Glaze materials should be weighed carefully and added to a bucket
will prevent the feldspar
If the less dense ingredients such as clay are added first, they
atic in this
from settling in a hard layer on the bottom; materials which are problem
be avoided by
respect include soda feldspar and nepheline syenite. The problem can
ion can
using a recipe with sufficient clay. If the recipe is low in clay, glaze suspens
be improved by adding a few percent bentonite, or floccula ting with a small amount
te should be
of Epsom salts (magnesium sulphate) dissolved in warm water. Bentoni
mixed into the other dry ingredients before being added to water, otherwise it may
form lumps.
After all the ingredients have been added, they should be left to soak for a few hours
before being sieved three times through an 80s mesh sieve. A rubber spatula or brush
can be used to push the slurry through the sieve. Coloured glazes may need sieving
again through a 100s or 120s mesh sieve to disperse any specks of colour.
tier e
Weighing glaze materia!s on a triple-beam balance.
18
MIXING GLAZES: WEIGHING, SIEVING 19
The glaze may then need to be left to settle overnight so that excess water can be
removed from the top. Glaze thickness can be assessed by dipping a test piece
and measuring the thickness with a pin. Most glazes are applied to the thickness
of about a millimeter (1/2 inch) or slightly thicker. Once the consistency of the
glaze is correct, it can be kept constant by weighing a fixed volume of glaze (such
as a pint/500ml) and recording the weight. When a new batch of glaze is made,
the thickness can be corrected easily by weighing and removing or adding water.
Some glazes may seem thick at first, but after a few days left standing may
become thin with the result that water may need to be removed. This occurs
when soluble substances in the glaze materials dissolve in water and cause the
glaze to deflocculate.
Sieving a glaze.
Applying glazes: pouring, dipping, brushing
coating
Many studio potters apply glazes by dipping, the easiest way to apply an even
and
of glaze. The pot is held between finger and thumb, or with glazing tongs,
dipped quickly into the bucket of glaze before being set down on a clean surface.
Any fingermarks can be quickly touched up before the glaze dries. When using matt
flat
glazes, which are viscous when melted, make sure to level drips or runs of glaze
with a knife. The glaze must be scraped and sponged from the base, or footring,
before the pot can be placed in the kiln. When using runny glazes, a 5-10mm
(4-%in) margin at the bottom of the pot should be cleaned of glaze to avoid drips
sticking the pot to the kiln shelf. Earthenware pots are sometimes glazed all over
and supported on stilts during firing. The stilts leave small scars, which need to be
ground down after firing. The kiln shelf should be coated with batt wash to soak up
glaze drips and prevent them sticking to the batt.
Glazes can also be poured or brushed on. Large pots can be held upside down over
a bucket, or placed on a wheel and have glaze poured over them. Very thin pots can
be glazed by pouring the inside and leaving it to dry overnight, then dipping the
outside. Potters often use Chinese brushes or wide Japanese hake brushes to apply
glazes. CMC or gum arabic added to the glaze helps it to flow off the brush and
adhere to the pot. Several coats of glaze are brushed on to build up an even coating.
Pots can be re-glazed after firing, but should be heated up first and the glaze brushed
or sprayed on.
20
APPLYING GLAZES: POURING, DIPPING, BRUSHING 21
Spraying enables very precise control of glaze application, but a compressor, spray
gun and spray booth with extractor fan are required with this method. The pot is
placed on a banding wheel and sprayed evenly all over in several thin coats.
Health and safety
when
Silica dust is a health hazard so a respirator mask should always be worn
containi ng silica include quartz, flint, clay, frit,
weighing glaze ingredients. Materials
should be kept in lidded container s.
feldspar, talc and wollastonite. Glaze materials
Work surfaces and floors should be sponged or mopped frequentl y, and aprons,
overalls and towels washed to avoid build-up of clay dust. Food and drink should
not be consumed in the studio.
Lead and barium carbonate are toxic and should be handled carefully. Toxic
materials should be disposed of in landfill, not washed down the drain. By law, glazes
on domestic ware should not leach lead or cadmium (the latter is an ingredient of
some bright yellow and red glazes). Laboratories where leach testing of glazes is
carried out are listed in Appendix 4.
Many of the colouring oxides are toxic, particularly chromium and nickel oxides.
Manganese dioxide and vanadium pentoxide are very toxic if dust or firing fumes are
inhaled. Kiln rooms should be well ventilated and equipped with a fire extinguisher.
Water-soluble colourants such as nitrates, chlorides or sulphates are not usually used
by potters as they are more toxic than the insoluble oxides and can be absorbed
through cuts or abrasions in the skin. Rubber or latex gloves can be worn when
mixing and using glazes, particularly ash glazes which contain soluble alkalis.
22
Testing glazes: test tiles, line blends
Glaze recipes should always be tested on a tile before being used on a batch of pots.
Test tiles can be made from slabs, extrusions or a thrown pot cut into sections. The
shape ofthe test piece should be similar to the shape ofthe pots being made, whether
flat plates or tall vessels. Test tiles can be numbered on the back, either stamped with
a number or painted with a mixture of iron oxide and manganese dioxide.
In a plastic pot, make up a small amount of glaze (100g/3%oz) and dip a tile into
it. The thickness can be varied across the tile by dipping two thirds of the tile twice
and a third of the tile three times. The glaze batch can then be scaled up to a larger
amount — for example, 7.5kg (16%lb) will fill a 10-litre (2% gal.) bucket.
When adding colouring oxides to a glaze, make a series of tests as you gradually
increase the amount of oxide. A series of glaze tests with, for example, 0.5, 1.0, 1.5
and 2g of colouring oxide is called a line blend (see celadon line blends on p.43). The
quickest way to do a line blend is to add a small amount of oxide to 100g (dry weight)
base glaze, mix with water, sieve the glaze and dip a test tile, then add more colouring
oxide and repeat. The precise tone of colour required can be found by selecting the
most suitable test in the line blend, or interpolating between the closest two.
A cross blend is carried out using two different colouring oxides in varying
proportions. A quantity of base glaze (200g) is mixed with water, then split into
two equal-sized containers. A small amount of colouring oxide is added to each
batch — for example, copper carbonate to one batch, cobalt carbonate to the other.
Once each batch is mixed and sieved, they can be measured out in small amounts by
wet volume, using a syringe or measuring cylinder. The two different colour glazes
can then be blended in various ratios: 90:10, 80:20, 70:30, 60:40, 50:50 40:60, 30:70,
20:80, 10:90.
A triaxial blend can be made in a similar way but using three variable additions, for
example red stain, yellow stain and vanadium blue stain.
Records of glaze tests should be kept in a notebook, with numbered recipes and a
correspondingly numbered tub ofglaze and test tile.
23
Adjusting glazes
amount of clay in
To make glazes more shiny, or to lower the firing temperature, the
line glazes are made
the recipe can be decreased or more flux can be added. Crystal
m dioxide
by reducing the clay content to below 5% and adding zinc oxide and titaniu
ge the
in order to seed crystals. This type of glaze is cooled very slowly to encoura
clay content may not be as durable as those
growth of crystals. Glazes with very low
with more than 5% clay. Crystallization can also be encour aged by adding calcium
or magnesium to a glaze and cooling slowly.
If the glaze is too runny, it can be applied more thinly or fired to a lower temperature,
or it can be adjusted to fire higher by adding silica and clay. Glazes can be made
matt by adding excess clay, whiting, dolomite, talc, barium or strontium carbonate.
In general, colours will be muted in matt glazes, with the exception of barium and
strontium matts.
Streaking and opalescence can be encouraged using rutile, titanium, calcium borate
frit or bone ash.
Linda Bloomfield, porcelain bowls, 2012. Runny, transparent, coloured glazes, satin matt
translucent on the outside, dia: 14cm (5in)
24
Firing: oxidation, reduction
Glazes are usually applied to pots which have been biscuit-fired to around 1000°C
(1832°F). This makes the pots easier to handle during glazing. It is possible to apply
glazes to leatherhard or bone-dry pots. This is called raw glazing.
Glazes fired with sufficient air present, such as in an electric kiln, are fired in
‘oxidation. If the air intake is limited in a fuel-burning kiln, oxygen for combustion
is taken from the glaze and clay body. This is termed ‘reduction’ and can bring
enriching effects to glazes. In raku firing, the pots are removed from the kiln while
hot and covered in sawdust in order to reduce the glaze. Crackle glazes are often
used, with the smoke from the sawdust emphasising the craze lines.
25
Correcting glaze faults: crazing, shivering,
crawling, pinholes, blisters
Hannah McAndrew, bubbles and crazing on earthenware glaze tests. (Left) White slip-trailed on
black slip; (right) black slip-trailed on white slip. The bubbles are caused by gases emitted during
firing from the oxides colouring the slip. Photo: courtesy ofartist.
Crazing
Crazing occurs when the glaze is too small for the clay body. The glaze contracts at a
higher rate than the clay body on cooling, and a network of fine cracks forms. When
used as a decorative effect this is called crackle, but it is undesirable on earthenware
as it allows water to seep through the porous clay body. To correct crazing, silica can
be added to the glaze in 5% increments. If this causes the glaze to become underfired,
try adding low-expansion glaze fluxes such as talc or calcium borate frit instead.
Shivering
Shivering is the opposite ofcrazing and occurs when the glaze is too big for the clay
body. Stresses build up at the edges of pots, and shards of glaze flake off at the rims.
If the stress is too high it can cause the pot to crack in two. To correct shivering,
the
silica in the glaze can be reduced or a high-expansion flux such as feldspar
or high-
alkaline frit can be added to the glaze.
26
CORRECTING GLAZE FAULTS 27
Crawling
Crawling is often caused by high surface tension in the molten glaze, which rolls
into beads with bare patches in between. Certain glaze materials can cause this,
including alumina, zirconium and tin oxide. Crawling is also caused by shrinkage of
the raw glaze on drying. This happens when the glaze is applied too thickly, or if it
contains a large amount of clay, zinc oxide or magnesium carbonate. Calcined china
clay (molochite) can be used instead of china clay to reduce shrinkage. Biscuit ware
should be free of dust; it may need to be sponged before glazing. If pots are not left
to dry thoroughly after glazing and before firing, the steam produced on firing may
cause areas of glaze to lift off.
Pinholes
Pinholes sometimes occur on glazing turned, grogged clay. Particles of grog
dislodged by the turning tool leave small pits which the glaze does not fill. The
turned areas can be smoothed with a sponge after turning to avoid pinholes.
Certain glaze materials including zinc oxide can cause pinholes, particularly in
viscous matt glazes.
Blisters
Blisters occur if a glaze is overfired. Some fluxes, such as sodium borate (in borax frit),
start to bubble and give off gas above 1200°C (2192°F). Bone ash can cause blistering
of glazes unless it is calcined before being added to the glaze. Another cause of blisters
is overlapping two glazes, where the top glaze matures earlier than the underlying one
and traps any gas bubbles given off. Blisters can be ground down and re-fired.
Bloating ofthe clay body can occur if there are air bubbles in the clay or if the biscuit
has been underfired.
Test tiles showing crazing in a transparent glaze (left) and blistering in a matt glaze containing
bone ash (right).
SECTION 2: GLAZE RECIPES
The following recipes were tested on white stoneware and porcelain. Test tiles were
dipped once, then half the tile dipped again to show variation in thickness. Most
tests were fired quite slowly in an electric kiln, with a stoneware firing taking about
14 hours. Where reduction is stated, tests were fired in a gas kiln with reduction
from cone 06, with heavy reduction in the first 45 minutes and moderate reduction
to neutral atmosphere for the rest of the firing to cone 9. Orton cones were used
throughout (see Orton cone table in Appendix 3).
Linda Bloomfield, thrown porcelain, 2003. Satin matt glazes, fired in an electric kiln to cone 8.
pposite Linda Bloomfield, porcelain test tiles showing a broad range of colours. Most (except for
yellow and coral red) were achieved using transition metal oxides rather than ready made stains.
29
1: Stoneware/porcelain high-fire glazes (cone 9-10)
CONE 9 MATT GLAZES 1280°C (2336°F)
White stoneware fired in oxidation (unless stated otherwise)
30
~ CONE
9MATT GLAZES 1280°C (2336°F) 31
Andrew Priestman, wood-fired porcelain beaker, 2012. Bernard Leach transparent glaze,
wash of local iron-rich earth, reduction-fired from 850°C to 1300°C (1562 to 2372°F), 7.5 x 8.5cm
(3 x 3M%in). Photo: Shannon Tofts.
34 STONEWARE/PORCELAIN HIGH FIRE GLAZES (CONE 9-10,
Andrew Priestman, three porcelain beakers, 2012. Ash and hazel wood-ash glaze, sieved through
a 60s mesh sieve, reduction-fired from 850 to 1300°C (1562 to 2372°F), 7.5 x 9cm (3 x 3%in).
Photo: Shannon Tofts.
Wood ash 60
Bentonite
Copper oxide 05
Cobalt carbonate 0.1
llmenite 5
CONE 9-10 SHINY GLAZES 1280°C (2336°F) 39
Oxidised stoneware
Reduced stoneware
Reduced stoneware
{
7
f
Mirka Golden-Hann, porcelain bowls fired to cone 9, 1280°C (2336°F). (Top row) oxidised
(bottom row) reduced; (left) celadon (iron oxide), (right) copper oxide.
COPPER TURQUOISE/RED GLAZE TESTS — CONE 9, 1280°C (2336°F) 47
Copper oxide is turquoise or green in oxidised firings but can turn red in reduction.
To obtain red, the glaze needs to be quite fluid and should contain around 0.5%
copper carbonate and 5% tin oxide. The formation of copper red relies on the friction
between the molecules of tin and copper in the moving molten glaze and requires
a thick glaze application. Increasing the copper to more than 3% results in a green
glaze. Colemanite can cause the glaze to splutter owing to the high water content, so
borax frit is a preferable flux often used in copper reds.
Key
(left) porcelain (Audrey Blackman)
(right) stoneware (Valentines HT Special)
(top row) oxidised firing in an electric kiln
(bottom row) reduction firing in a gas kiln.
Mottled grey-green
Nepheline syenite 1]
China clay 34
Flint D3,
Soda ash i
Whiting 5
Lithium carbonate 11
Tin oxide 5
Copper carbonate 3
COPPER TURQUOISE/RED GLAZE TESTS — CONE 9, 1280°C (2336°F) 53
Mottled blue/purple/grey
Nepheline syenite 1]
China clay 34
Flint D3,
Soda ash ia
Whiting 5
Lithium carbonate 11
Tin oxide 5
Cobalt carbonate 0.4
Copper oxide 1S
1280-1300°C (2336-2372°F)
Slip 1 for soda firing (Lisa Hammond)
tion
Soft cream/orange depending on thickness and reduc
HVAR ball clay 50
China clay 50
Photo
Lisa Hammond, tall jug, 2012. Soda-fired stoneware with shino glaze, ht: 27cm (1034in).
Andy Stewart.
56 STONEWARE/PORCELAIN HIGH-FIRE GLAZES (CONE 9-10)
Lisa Hammond, tall bottle, 2012. Black clay, white shino with finger wipes, 28 x 9cm (11 »
Photo: Jay Goldmark
2: Stoneware/porcelain mid-temperature-range
glazes (cone 6—8
Linda Bloomfield, nesting porcelain bowls, 2011. Satin matt translucent on outside, grey runny
transparent inside, dia: 20cm (8in).
58
_ CONE 6-8 MAGNESIUM MATT GLAZES 1200-1260°C (2192-2300°F) 59
Emily Myers, Faceted bottles, blue crystalline glaze, 2009, ht: 28cm (11in). Photo: courtesy of the artist.
64 STONEWARE/PORCELAIN MID-TEMPERATURE-RANGE GLAZES (CONE 6-8)
Oxidised stoneware
Oxidised stoneware
Oxidised stoneware
Emily Myers, Blue Rocking Pot, barium blue glaze, red stoneware, ht: 25cm (934in).
Photo: courtesy of the artist.
6-8) aa
68 STONEWARE/PORCELAIN MID-TEMPERATURE-RANGE GLAZES (CONE
é Saari ‘5 eS a ae a
Reduced stoneware
Reduced stoneware
ee
—
Oxidised stoneware
Oxidised stoneware
nena . ——
Reduced stoneware
C5 Semi-matt off-white
Recipe C (see p.79)
+ rutile 2
+ tin oxide 5
Linda Bloomfield, thrown porcelain cups on a tray, 2012. Runny transparent glazes with
praseodymium and copper, satin matt translucent on the outside, dia: 40cm (1534in).
st ee
Runny transparent pale pink cone 8
A shiny transparent pale pink
Soda feldspar 45
Quartz 17
Calcium borate frit 15
Whiting 14
China clay 5
Erbium oxide 4
ne
2 i ee base 3s fe ae iy Se oe S Sieacte f ‘iae Gi z aes pee nite soy Mina .
Linda Bloomfield,
nfield, cakecake stands
stands with1 graduated
graduated turquoise
turquoi glazes, dia: 31cm (12%in).
CONE 6-8 SHINY GLAZES 1200-1260°C (2192-2300°F) 91
i
cone 8-9
Lasse Ostman semi-glossy blue and yellow crystal glaze
A very runny crystal glaze
Potash feldspar 63
Dolomite 16
Zinc oxide 17
Rutile 3
Cobalt carbonate 1.6
Oxidised stoneware
alkaline glaze cone 7-8
Base Glaze Recipe A - Runny transparent
s copper red. This glaze has a wide
A runny alkaline glaze adapted from Derek Emms
at high temperatures.
firing range and can fire to cone 9, but is runny
Soda feldspar 45
Quartz i
Calcium borate frit {5
Whiting (ls
China clay 5
‘Sole Ke 4
A8 transparent pale straw yellow ; oi
> it, aa,
Recipe A (see above)
is
+ Cerium oxide 5
Reduced stoneware
7
CONE 6-8 SHINY GLAZES 1200-1260°C (2192-2300°F) 99
Reduced stoneware
Emma Williams, Medium form with neck, 2012. Press-moulded and assembled black stoneware
with copper turquoise barium glaze and smooth white crawl glaze, fired to 1050°C (1922°F), ht:
11cm (4V4in). Photo: courtesy of the artist.
100
CONE 04 MATT GLAZES 1060-1100°C (1940-2012°F) 101
Talc 8
Whiting 8
China clay 12
Quartz ys)
Cobalt oxide
Manganese dioxide
lron oxide )
Chromium oxide |
CONE 06-03 SHINY GLAZES 990-1100°C (1814-2012°F) 105
aeeeeeeeeeeeeeee
Cloudy yellow-brown 1060°C (1940°F)
Calcium borate frit 39
Soda feldspar Dy
Whiting 5
China clay 6
Quartz 23
Rutile p)
Cloudy grey-brown 1060°C (1940°F)
Calcium borate frit 39
Soda feldspar Di
Whiting 5
China clay 6
Quartz 23
llmenite 5
yy 2
Raku glaze tests were made by Gill Tennant-Eyles from Earthstone white stoneware
clay with copper slip in the upper left corner (ball clay 85, flint 15, copper oxide 3)
and porcelain slip in the lower right corner. Test pieces were fired to 900°C (1652°F),
removed from the kiln while hot, and one left in the air to smoke on top of sawdust,
the other covered in sawdust so that post-firing reduction of the glaze could take
place. Spraying with water encouraged fine crazing.
Gill Tennant-Eyles, Sea shard, 2012. High-alkaline frit-based glaze, raku-fired to 900°C (1652°F).
Photo: courtesy of the artist.
111
112 RAKU LOW-TEMPERATURE GLAZES (CONE 09)
Egyptian paste is a self-glazing body in which soluble salts migrate to areas of the
surface exposed to the air during drying to form a glaze when fired to around
1000°C (1832°F). The layer of salts acts as a flux, glazing the surface and helping to
vitrify the clay body at low firing temperatures. The paste is difficult to work with
but can be used to make beads and jewellery. Slow and even drying ensures good
sodium coverage and glaze effect. Kiln shelves should be coated liberally with batt
wash before firing. The following Egyptian paste tests were made by Mirka Golden-
Hann and students at Salisbury Arts Centre.
122
1. Nigel Wood Egyptian paste 1 2. Nigel Wood Egyptian paste 1
1000°C (1832°F) 1000°C (1832°F)
Turquoise blue, reliable body Bright cobalt blue, reliable body
Potash feldspar 42 + Copper carbonate 2
Quartz 42 + Cobalt carbonate 0.5
China clay 6
Sodium bicarbonate DS
Sodium carbonate 25
Bentonite 5
+ Copper carbonate 3
3. Egyptian paste 3
1040°C (1904°F) 4. Egyptian paste 4
1040°C (1904°F)
Turquoise blue, mottled surface
Nepheline syenite 39
Light turquoise, mottled surface
Sodium carbonate (soda ash) 6 Flint 25
Sodium bicarbonate 6 Quartz 25
Ball clay 6 Bentonite 33
Flint ay Sodium carbonate (soda ash) 17
Bentonite 2 + Turquoise stain 7
+ Copper carbonate 2
124 CLAY BODY RECIPES
132
GLOSSARY 133
|
Material Formula
Alumina ae
Alumina hydrate Al(OH),
Barium carbonate BaCO,
Calcium borate
Cerium oxide
Dolomite |CaCO,.MgCO,
Erbium oxide a
llmenite Ieee
lron (ferric) oxide (red) FeO.
134
CERAMIC MATERIALS AND CHEMICAL FORMULAE 135
Material Formula
| agnesia Th gO
=
ie etires carbonate oe
anganese dioxide nO,
Petalite Li,O.AI,O,.8SiO,
=
Praseodymium oxide Heel
o)
Quartz _[s0,
Rutile |TIO,
Silicon carbide |SiC
jee SiO,z a
| Spinel MgALO,
Zinc oxide
[ | ZnO
UK |
USA
Flint Silica
Fremington red clay Redart clay, Alberta slip “|
High-alkaline frit Ferro 3110, Pemco P-25
Low-expansion frit Ferro 3249
Quartz Silica
136
Appendix 3: Orton pyrometric cone temperatures
Pyrometric cones measure heat work, and so depend on the heating rate. A slower
temperature rise will cause the cone to bend at a lower temperature.
137
Appendix 4: Suppliers
UK Scarva Pottery Supplies
Unit 20,
Bath Potters’ Supplies Scarva Road Industrial Estate,
Unit 18, Fourth Avenue, Banbridge, County Down,
Westfield Trading Estate, Northern Ireland,
Radstock, Nr Bath, BT32 3QD
Somerset, Tel: +44 (0)28 406 69699
BA3 4XE www.scarvapottery.co.uk
Tel: +44 (0)1761 411077
www.bathpotters.co.uk Sneyd Ceramics
Sneyd Mills, Leonora Street,
Ceramatech Burslem,
16-17 Frontier Works, Stoke-on-Trent,
33 Queen Street, Staffordshire,
London N17 8JA ST6 3BZ
Tel: +44 (0)208 885 4492 Tel: +44 (0)1782 814167
www.ceramatech.co.uk www.sneydceramics.co.uk
138
SUPPLIERS 139
Creative Clay
5704E General Washington Drive,
Alexandria, VA 22312
Tel: +1 (703) 750 9480
www.creativeclaypottery.com
140 APPENDIX 4: SUPPLIERS
141
Index
ash glazes 9, 22, 34-37 crystalline 12, 24, 25, 30-31, 34, 35,
37-38, 59-62, 64, 72-74, 76, 85
Bailey, Michael 60, 74, 77, 85
ball clay 11, 111 Davis, Harry 126
barium matt 24, 70-72, 79
Barlow, Joanne earthenware glazes 100-110
Raku house covered with mortar 131 earthenware clay body 26, 125
Blackman, Audrey 43, 125 Egyptian paste 122-124
blistering 12, 27
bloating 27 feldspar 9; 118222) 26,102
Bloomfield, Linda firing 9, 14516, 20,24) 25527,.29,43 757,
nesting pouring bowls 7 Wk, NOs, WA, 2, WP
porcelain bowls 24 flashing slip 54
thrown porcelain 29 Hux 9512524526527 47 122 18130
nesting porcelain bowls 58 Flynn, Sara 53
thrown porcelain cups on a tray 84 Forrester, Bernard 34
cake stands with turquoise glazes 90 frit «951 1122 22, BAG 0739. ei
bone ash 12, 24, 27 115
bone china 12, 125
Brierley, Ben Golden-Hann, Mirka 43, 47, 122
lidded box with crackle shino glaze porcelain bowls fired to cone 9 46
128 interactive colour play 9
porcelain vase 129 grass ash 11
Gestural Vessel 130
Burley, Lucy 102 Hammond, Lisa 54
tall jug 55
celadon 17, 43-45, 99 baking dishes 56
chrome-tin pink 15, 62, 73 tall bottle 57
chromium 14, 15, 16, 22 soda-fired teapot 127
Chun 89 Hansen, Tony 101
cobalt 16, 17, 23, 38-39, 60, 97, 98, 123 Hanssen Pigott, Gwyn
colouring oxides 14, 15, 16-17, 22, 23 Alone 6
cones 25, 29 Howells, Joanna 12
Cooper, Emmanuel 70, 72, 79, 101, 107
copper 14, 15, 16, 23, 47 ilmenite 17
copper red 41, 47, 96, 111 iron oxide 16-17, 23, 43
crackle 25, 36, 91, 94, 112-119
crawling 27 Leach, Bernard 33
crazing 11, 25, 26, 33, 111, 114-115 Leach, David 32, 126
cross blend 23 lead 12, 22
142
INDEX 143
ee
~~ ahi. i
The Handbook of Glaze Recipes is an essential studio companion for any potter. |
Covering a comprehensive range of glazes including porcelain, crystalline and
raku as well as stoneware and earthenware, each recipe is illustrated with a
useful test tile to demonstrate the effects of opaque, matte, and transparent
glazes on different clays and at varying temperatures, and numbered for ease
of reference. The book also features an introduction to the basics of mixing,
applying and adjusting glazes, and correcting typical glaze faults. It also includes
many clay body recipes, including a variety of ones for porcelain, wood firing
and even Egyptian paste. Compiled by studio potter and glaze expert Linda
Bloomfield, and based not only on years of meticulously recorded tests, but
also researched from a large assortment of established ceramic artists, The
Handbook of Glaze Recipes is a must-have resource for any potter wishing to
experiment or expand their glazes and clay bodies.
LINDA BLOOMFIELD has been involved with pottery since 1973, although
her career path led her to train as a materials scientist. She received a BSc in
Engineering Science and a PhD in Materials Science from Warwick University,
UK. After stints as a visiting scholar at MIT and as researcher in Tsukuba, Japan
and London, she set up her current studio in London in 2001. Since 2003 she
has been selling through galleries across the UK and internationally, and her
tableware is stocked by Liberty and David Mellor. She is a frequent contributor
to Ceramic Review and is the author of two previous books, Colourin Glazes
(Bloomsbury, 2011) and Contemporary Tableware (Bloomsbury, 2013).
AVN
Ph The American Book Center: sake stands
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10% discount for students Bloomsbury
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